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Chemical Research in Chinese Universities 2006年第6期22卷 765-767页

作者： XU Liang-zhong ZHOU Kai HU zhi-qiang BI wen-zhao College of Chemistry and Molecular Engineering Qingdao University of Science and Technology Qingdao 266042 P. R. China

The two title compounds, 2-oxo-2-p-tolyl-1-（ 1,2,4-triazol-1-yl） ethyl phenylcarbamodithioate （ compound 3a ） and 2-oxo-2-p-biphenyl-1-（1,2,4-triazol-1-yl） ethyl phenylcarbamodithioate （ compound 3b）, were synthesized and identified by IR, EA and ^1H NMR spectra. The crystal structure of compound 3b was determined by X-ray diffraction analysis. The compound crystallized in a monoclinic system of space group P21/c with Mr =398.47（C23H18N4OS） , a=0.8769（2） nm, b=1. 1924（2） nm, c=2.0440（6） nm, β=109.66（3）°, V=2.0126（8） nm^3, Z=4, Dc= 1. 315 g/cm^3, F（000） =832,μ =0. 183 mm^-1, final R1 =0. 0819. The biological test result shows that the two title compounds exhibit certain fungicidal activities.

关键词： 1,2,4-Triazole Crystal structure Biological activity

The Multi-parameter Test of Gravitational Wave Dispersion with Principal Component Analysis

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Research in Astronomy and Astrophysics 2024年第5期24卷 140-150页

作者： zhi-Chu Ma Rui Niu wen zhao CAS Key Laboratory for Research in Galaxies and Cosmology Department of AstronomyUniversity of Science and Technology of ChinaHefei 230026China School of Astronomy and Space Sciences University of Science and Technology of ChinaHefei 230026China

In this work, we consider a conventional test of gravitational wave(GW) propagation which is based on the phenomenological parameterized dispersion relation to describe potential departures from General Relativity(GR)along the propagation of GWs. But different from tests conventionally performed previously, we vary multiple deformation coefficients simultaneously and employ the principal component analysis(PCA) method to remedy the strong degeneracy among deformation coefficients and obtain informative posteriors. The dominant PCA components can be better measured and constrained, and thus are expected to be more sensitive to potential departures from the waveform model. Using this method we analyze ten selected events and get the result that the combined posteriors of the dominant PCA parameters are consistent with GR within 99.7% credible intervals. The standard deviation of the first dominant PCA parameter is three times smaller than that of the original dispersion parameter of the leading order. However, the multi-parameter test with PCA is more sensitive to not only potential deviations from GR but also systematic errors of waveform models. The difference in results obtained by using different waveform templates hints that the demands of waveform accuracy are higher to perform the multiparameter test with PCA. Whereas, it cannot be strictly proven that the deviation is indeed and only induced by systematic errors. It requires more thorough research in the future to exclude other possible reasons in parameter estimation and data processing.

关键词： gravitational waves-gravitation-black hole physics

Contribution of moderate overall coal-bearing basin uplift to tight sand gas accumulation:case study of the Xujiahe Formation in the Sichuan Basin and the Upper Paleozoic in the Ordos Basin,China

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Petroleum Science 2015年第2期12卷 218-231页

作者： Cong-Sheng Bian wen-zhi zhao Hong-Jun Wang zhi-Yong Chen Ze-Cheng Wang Guang-Di Liu Chang-Yi zhao Yun-Peng Wang zhao-Hui Xu Yong-Xin Li Lin Jiang Research Institute of Petroleum Exploration & Development CNPC College of Geosciences China University of Petroleum Guangzhou Institute of Geochemistry Chinese Academy of Sciences

Tight sand gas is an important unconventional gas resource occurring widely in different petroleum basins. In coal-bearing formations of the Upper Triassic in the Sichuan Basin and the Carboniferous and Permian in the Ordos Basin, coal measure strata and tight sandstone constitute widely distributed source-reservoir assemblages and form the basic conditions for the formation of large tight sand gas fields. Similar to most tight gas basins in North America, the Sichuan, and Ordos Basins, all experienced overall moderate uplift and denudation in Meso- Cenozoic after earlier deep burial. Coal seam adsorption principles and actual coal sample simulation experiment results show that in the course of strata uplift, pressure drops and desorption occurs in coal measure strata, resulting in the discharge of substantial free gas. This ac- counts for 28 %-42 % of total gas expulsion from source rocks. At the same time, the free gases formerly stored in the pores of coal measure source rocks were also dis- charged at a large scale due to volumetric expansion re- sulting from strata uplift and pressure drop. Based on experimental data, the gas totally discharged in the uplift period of Upper Paleozoic in the Ordos Basin, and Upper Triassic Xujiahe Formation in the Sichuan Basin is calcu- lated as （3-6） × 10^5 m^3/km^2. Geological evidence for gasaccumulation in the uplift period is found in the gas reservoir analysis of the above two basins. Firstly, natural gas discharged in the uplift period has a lighter carbon isotope ratio and lower maturity than that formed in the burial period, belonging to that generated at the early stage of source rock maturity, and is absorbed and stored in coal measure strata. Secondly, physical simulation experiment results at high-temperature and high-salinity inclusions, and almost actual geologic conditions confirm that sub- stantial gas charging and accumulation occurred in the uplift period of the coal measure strata of the two basins. Diffusiv

关键词： Sichuan Basin Ordos Basin Tight sand gasStratigraphic uplift Coalaccumulation mechanismmeasure Hydrocarbon Diffusion

Design study of charge-stripping scheme of heavy ion beams for HIAF-BRing

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Nuclear Science and Techniques 2024年第5期35卷 30-41页

作者： Jun-Jie Zhang zhi-You Xu Jin-Quan Zhang wen-wen Ge Liang-Ting Sun Huan-Yu zhao Institute of Modern Physics Chinese Academy of SciencesLanzhou 730000China School of Nuclear Science and Technology University of Chinese Academy of SciencesBeijing 100049China

Charge strippers play an essential role in heavy-ion accelerators by stripping the projectile ions to higher charge states to enhance the acceleration efficiency downstream of the *** the high-energy mode of the booster ring(BRing)of the high-intensity heavy-ion accelerator facility,the pre-accelerated ions from the iLinac will be stripped by a carbon foil to higher charge states and then injected into the *** key parameters of the stripper and stripped ions were calculated,and the influence of stripping on the beam quality was *** get high stripping efficiencies,the foil thicknesses and resultant charge state distributions for the typical ions were determined by the code *** equilibrium thickness was obtained for the U beam,while the stripper thicknesses for the Xe and Kr beams were determined based on a compromise between the stripped charge states and the stripping *** energy loss,energy straggling,and emittance growth due to stripping have a non-negligible impact on the transport of the stripped beams and the injection of the ***,these parameters were simulated by *** addition,the foil’s temperature evolution,which greatly affects the foil lifetime,was simulated by *** maximum temperature of the foil bombarded by the U and Xe beams with the nominal parameters will exceed the safe value in terms of the impact of evaporation on the foil’s *** the foil temperature constraint,the highest tolerable beam intensity and the injected ion number into the ring were derived for different beam *** results of this paper will present important reference data for the optimization design and commissioning of the beamline and injection to the BRing for the stripped ions.

关键词： High-intensity heavy-ion accelerator facility Charge stripper Energy spread Thermal analysis Emittance growth Injection turns

P-symmetric Subharmonic Solutions for Nonlinear Hamiltonian Systems

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Acta Mathematica Sinica,English Series 2024年第6期40卷 1388-1408页

作者： Duan zhi ZHANG zhi Hao zhao School of Mathematical Sciences Nankai UniversityTianjin 300071P.R.China

In this paper,we prove that for each positive k≡1 mod m there exists a P-symmetric kmτ-periodic solution xk for asymptotically linear mτ-periodic Hamiltonian systems,which are nonautonomous and endowed with a *** the P-symmetric Hamiltonian function is semi-positive,one can prove,under a new iteration inequality of the Maslov-type P-index,that xk_(1) and xk_(2) are geometrically distinct for k_(1)/k_(2)≥(2n+1)m+1;and xk_(1),xk_(2) are geometrically distinct for k_(1)/k_(2)≥m+1 provided xk_(1) is non-degenerate.

关键词： P-symmetric subharmonic Hamiltonian systems Maslov-type index theory iteration inequality asymptotically linear

Cluster planting impact on cotton growth, yield and biomass accumulation in an arid region oasis

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Research in Cold and Arid Regions 2018年第3期10卷 271-278页

作者： Ting Ting Xie Pei Xi Su wen zhi zhao Li Shan Shan College of Forestry Gansu Agricultural University Linze Inland River Basin Research Station/Key Laboratory of Ecohydrology of Inland River Basin Northwest Institute of Eco-Environment and Resources Chinese Academy of Sciences Linze Inland River Basin Research Station/Key Laboratory of Land Surface Process and Climate Change in Cold and Arid Regions Northwest Institute of Eco-Environment and Resources Chinese Academy of Sciences

The cluster planting pattern （3 plants per hole） for cotton （Gossypium hirsutum L.） may increase economic yield over those of the traditional planting pattern （1 plant per hole） in arid regions of China. This increase in yield depends on either increased biomass production or greater partitioning to fruit. This study was conducted to determine whether differences in biomass accumulation or partitioning to reproductive growth contributed to higher yield in the cluster planting pattern compared with the traditional one. Growth parameters, biomass accumulation, crop growth rate and partitioning between cluster planting pattern and traditional planting pattern was compared in northwest of China. The biomass production and partitioning in cluster planting plot was higher than in traditional planting one. Biomass accumulation was faster early in the clustered treatment, and it was also higher at harvest time. Total dry matter production per unit area was significantly higher than in the traditional planting. On a per plant basis, dry matter accumulation was faster and total biomass production was significantly higher in the cluster planting pattern. Numbers of sympodia and boll sizes were also larger, indicating that facilitation among plants was promoting crop yield. The increase in yield in the cluster planting treatment occurred through increased partitioning of dry matter to fruits than in the traditional planting pattern, resulting in more bolls and increased lint yield in arid regions.

关键词： cluster planting growth parameter biomass crop growth rate distribution ratio

Oscillation properties of eigenfunctions for Sturm-Liouville problems with interface conditions via Prufer transformation

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Applied Mathematics(A Journal of Chinese Universities) 2024年第2期39卷 191-200页

作者： LI zhi-yu LI Kun CAI Jin-ming QIN Jian-fang ZHENG zhao-wen School of Mathematical Sciences Qufu Normal UniversityQufu 273165China College of Mathematics and Systems Science Guangdong Polytechnic Normal UniversityGuangzhou 510665China

A class of Sturm-Liouville problems with discontinuity is studied in this *** oscillation properties of eigenfunctions for Sturm-Liouville problems with interface conditions are *** main method used in this paper is based on Prufer transformation,which is different from the classical ***,we give two examples to verify our main results.

关键词： Sturm-Liouville problem interface condition oscillatory solution

Reducing Operation Emissions and Improving Work Efficiency Using a Pure Electric Wheel Drive Tractor

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Engineering 2024年第6期37卷 230-245页

作者： Chang-Kai wen wen Ren Qing-Zhen Zhu Chun-Jiang zhao Zhen-Hao Luo Sheng-Li Zhang Bin Xie zhi-Jun Meng Research Center of Intelligent Equipment Beijing Academy of Agriculture and Forestry SciencesBeijing 100097China State Key Laboratory of Intelligent Agricultural Power Equipment Beijing 100097China BYD Company Limited Shenzhen 518118China College of Agricultural Engineering Jiangsu UniversityZhenjiang 212013China College of Engineering China Agricultural UniversityBeijing 100083China

In response to the problems of excessive greenhouse-gas and particulate emissions and the low traction efficiency of conventional diesel tractors in the field,a purely electric wheel-side drive tractor was studied,including an electric motor drive system,a battery ballast system,and an electro–hydraulic suspension *** paper develops a dynamics model of an electric tractor-ploughing unit under complex soil conditions,leading to the proposal of an active control method for drive wheel torque and a joint control method for the traction force of the suspension system and the front-and rear-axle loads of a ***,the tractor is prototyped and assembled,and ploughing tests are carried *** ploughing results show that the active torque-distribution control method proposed in this study reduces the tractor slip by 14.83%and increases the traction efficiency by 10.28%compared with the average torquedistribution *** with the conventional traction control mode,the joint control method for traction and ballast proposed in this paper results in a 3.7%increase in traction efficiency,a 15.05%decrease in slip,and a 4.9%reduction in total drive motor energy *** study will help to improve the operation quality and traction efficiency of electric tractors in complex soil conditions.

关键词： Electric tractor Ploughing unit Torque distribution Active ballast Traction performance

Radical Mechanism of IrⅢ/NiⅡ Metallaphotoredox-Catalyzed C(sp^(3))-H Functionalization Triggered by Proton-Coupled Electron Transfer:Theoretical Insight

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CCS Chemistry 2022年第4期4卷 1429-1440页

作者： Yu-Jiao Dong Bo Zhu Yun Geng zhi-wen zhao Zhong-Min Su Wei Guan Institute of Functional Material Chemistry Faculty of ChemistryNortheast Normal UniversityChangchun 130024 College of Chemistry Jilin UniversityChangchun 130012

Photoredox catalysis can be induced to activate organic substrates or to modulate the oxidation state of transition-metal catalysts via unique singleelectron transfer processes,so as to achieve challenging C(sp^(3))-H functionalization under mild ***,the specific reaction mechanism and relevant electron transfer process still need to be ***,a highly regioselective Ir^(Ⅲ)/Ni^(Ⅱ)-metallaphotoredox-catalyzed hydroalkylation of asymmetrical internal alkyne with an etherα-hetero C(sp^(3))-H bond has been investigated by density functional theory(DFT)calculations.A novel radical mechanism was predicted to merge oxidative quenching(Ir^(Ⅲ)-*Ir^(Ⅲ)-Ir^(Ⅳ)-Ir^(Ⅲ))and nickel catalytic cycles(NiⅡ-NiⅢ-NiI-NiⅢ-NiⅡ)for this C(sp^(3))-H functionalization to construct C(sp^(3))-C(sp^(2))*** consists of seven major steps:the single-electron transfer involved in the photoredox cycle for generating active Ni(Ⅰ)-chloride complexes,proton-coupled electron transfer process to provide α-carbon-centered tetrahydrofuran(THF)radicals,radical capture by Ni(Ⅱ),reductive elimination to obtain 2-chlorotetrahydrofuran,alkyne oxidative hydrometallation,innersphere electron transfer,and σ-bond metathesis to yield the desired alkyne hydroalkylation ***,both the thermodynamic performance for redox potentials and the kinetic exploration for energy barriers and electron-transfer rates have also been evaluated for the corresponding electron transfer *** addition,the steric effects play a major role in determining the regioselectivity of alkyne oxidative hydrometallation.

关键词： C(sp^(3))-H functionalization photoredox catalysis iridium nickel density functional calculations

Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries:A DFT study

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Chinese Chemical Letters 2024年第6期35卷 180-184页

作者： Xin-Tong zhao Jin-zhi Guo wen-Liang Li Jing-Ping Zhang Xing-Long Wu MOE Key Laboratory for UV Light-Emitting Materials and Technology Northeast Normal UniversityChangchun 130024China Faculty of Chemistry Northeast Normal UniversityChangchun 130024China Key Laboratory of Organo-Pharmaceutical Chemistry of Jiangxi Province Gannan Normal UniversityGanzhou 341000China

Nowadays,lithium-ion batteries(LIBs)play a crucial role in modern society in the aspect of portable electronic devices and large-scale smart ***,the current performance of lithium-ion batteries has been unable to meet the growing expectations of society and scientific ***,we have synthetically investigated availability of 2D Ni-TABQ monolayer as anode based on DFT for LIBs *** findings have demonstrated that 2D Ni-TABQ monolayer is a semiconductor with a small band gap of 0.2 eV,which suggest that the electronic property of 2D Ni-TABQ monolayer would take place an evident shift from semiconductor property to metallic property after Li ***,we checked the stability of 2D Ni-TABQ monolayer and investigated the viability of exfoliation from bulk multilayer Ni-TABQ to form 2D Ni-TABQ monolayer in the light of exfoliation energy and binding *** continuously studied electrochemical properties of 2D Ni-TABQ monolayer with respect of theoretical specific capacity,Li-ion diffusion barriers and open-circuit *** the charging process,2D Ni-TABQ monolayer can achieve a high specific capacity of 722 m Ah/g with an open-circuit voltage range from 1.12 V to 0.22 *** aforementioned results make the 2D Ni-TABQ monolayer a promising anode for LIBs.

关键词： The first principles Density functional theory Lithium-ion battery Anode material Two-dimensional material