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Research 2024年第2期6卷 319-327页

作者： Lihong hong Haiyao Yang Liqiang liu Mingzhou Li Yuanyuan liu Baoqin Chen Huakang Yu Wenbo Ju zhi-Yuan Li School of Physics and Optoelectronics South China University of TechnologyGuangzhou 510641China State Key Laboratory of Luminescent Materials and Devices South China University of TechnologyGuangzhou 510640China

An optical spectrometer is a basic spectral instrument that probes microscopic physical and chemical properties of macroscopic objects but generally suffers from difficulty in broadband time-resolved *** this work,we report the creation of ultrabroadband white-light laser with a 3-dB bandwidth covering 385 to 1,080 nm,pulse energy of 1.07 mJ,and pulse duration of several hundred femtoseconds by passing 3-mJ pulse energy,50-fs pulse duration Ti:Sapphire pulse laser through a cascaded fused silica plate and chirped periodically poled lithium niobate *** utilize this unprecedented superflat,ultrabroadband,and intense femtosecond laser light source to build a single-shot(i.e.,single-pulse)subpicosecond pulse laser ultraviolet-visible-near-infrared spectrometer and successfully measure various atomic and molecular absorption *** single-shot ultrafast spectrometer may open up a frontier to monitor simultaneously the ultrafast dynamics of multiple physical and chemical processes in various microscopic systems.

关键词： Pulse utilize frontier

Prediction for permeability index of blast furnace based on VMD-PSO-BP model

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Journal of Iron and Steel Research(International) 2024年第3期31卷 573-583页

作者： Xiao-jie liu Yu-jie Zhang Xin Li zhi-feng Zhang hong-yang Li Ran liu Shu-jun Chen School of Metallurgy and Energy North China University of Science and TechnologyTangshan 063210HebeiChina Chengde Branch HBIS Group Co.Ltd.Chengde 067000HebeiChina

The permeability index is one of the important production indicators to monitor the operation of blast *** is crucial to grasp the trends of changes in the new permeability index in *** the complex vibration spectrum of the permeability index,a prediction model of the permeability index based on the VMD-PSO-BP(variational mode decomposition-particle swarm optimization-back propagation)method was ***,the key factors that affect the permeability index of blast furnace were studied from multiple ***,the permeability index was divided into multiple sub-modes based on the difference of frequency bands by the VMD algorithm,and a PSO-BP prediction model was established for each ***,the prediction results of each sub-mode were summed to obtain the final *** results show that the composite prediction accuracy by using the VMD algorithm is 3%higher than that of the traditional prediction method,which has better applicability.

关键词： Big data-Blast furnace Air permeability Variational mode decomposition Particle swarm optimization Back propagation Model prediction

Precise editing of methylated cytosine in Arabidopsis thaliana using a human APOBEC3Bctd-Cas9 fusion

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Science China(Life Sciences) 2022年第1期65卷 219-222页

作者： zhi-hong liu Shanjie Tang Wentao Hu Ruo Lv Hailiang Mei Rongxin Yang Xianwei Song Xiaofeng Cao Dong Wang Key Laboratory of Molecular Biology and Gene Engineering in Jiangxi Province College of Life ScienceNanchang UniversityNanchang 330031China State Key Laboratory of Plant Genomics and National Center for Plant Gene Research(Beijing) Institute of Genetics andDevelopmental BiologyChinese Academy of SciencesBeijing 100101China University of Chinese Academy of Sciences Beijing 100049China Center for Excellence in Molecular Plant Sciences Institute of Genetics and Developmental BiologyChinese Academy of SciencesBeijing 100101China National Engineering Laboratory for Crop Molecular Breeding Institute of Crop ScienceChinese Academy of Agricultural SciencesBeijing 100081China

Dear Editor,Precise editing of specific genomic sites holds great promise in basic research and modern crop breeding,and some cytosine base editors(CBEs)have been developed for this purpose(Komor et al.,2016;Zong et a... 详细信息

关键词： Cas9 breeding

Chemoselective and Living/Controlled Polymerization of Alkenyl Methacrylates by the Phosphonium Ylide/Organoaluminum Lewis Pairs

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Chinese Journal of Polymer Science 2024年第2期42卷 159-167,I0005页

作者： zhi-Kang Chen Wu-Chao Zhao Yi-Ling Zhao Cong-Lei liu liu-Yin Jiang Yue-Tao Zhang hong-Ping Zhu State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringXiamen UniversityXiamen361005China State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun130012China

Chemoselective,living/controlled polymerizations of allyl methacrylate(AMA) and vinyl methacrylate(VMA) with/without methyl methacrylate(MMA) by using the phosphonium ylide/organoaluminum based Lewis pairs(LPs) have been *** P-ylide-2/AIMe(BHT)_(2)(Pylide-2=Ph_(3)P=CHMe and BHT=2,6-iBu_(2)-4-MeC_(6)H_(2)O) was demonstrated to be superior by which homopolymers PAMAs(M_(n)=27.6-111.5kg/mol and ■=1.14-1.25) and PVMAs(M_(n)=28.4-78.4 kg/mol and ■=1.12-1.18) and block copolymers PMMA-b-PAMA,PAMA-b-PVMA,PAMA-bPMMA,PMMA-b-PAMA-b-PMMA,PAMA-b-PMMA-b-PAMA,and PAMA-b-PVMA-b-PAMA were *** the polymerizations,all of the monomers were reacted by the conjugated ester vinyl groups leaving intactly the nonconjugated acryloxy *** pendant acryloxy groups attached to the main chain enable further to post-functionalization by the AIBN-induced radical "thiol-ene" reaction using PhCH_(2)*** thiolether side group-containing polymers PAMA-SCH_(2)Ph and PAMA-SCH_(2)Ph-b-PMMA-b-PAMA-SCH_(2)Ph were thus prepared.

关键词： Phosphonium ylide Alkenyl methacrylate Chemoselectivity Living/controlled polymerization Post-functionalization

Synthesis, characterization, and property test of crystalline polyferric sulfate adsorbent used in treatment of contaminated water with a high As(Ⅲ) content

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International Journal of Minerals,Metallurgy and Materials 2018年第10期25卷 1217-1225页

作者： Ping-chao Ke zhi-hong liu Lin Li School of Metallurgy and Environment Central South UniversityChangsha 410083China The Robert M.Buchan Department of Mining Queen's UniversityKingstonON K7L 3N6Canada

A crystalline polyferric sulfate(PFS) adsorbent was synthesized by oxidizing and precipitating ferrous ions in air atmospheric conditions. The morphology, structure, specific surface area(SSA), and adsorptive efficacy of the adsorbent to As(Ⅲ) were characterized by scanning electron microscope(SEM) and transmission electron microscopy(TEM) images, X-ray diffraction(XRD) patterns, Fourier-transform infrared(FTIR) spectra, BET SSA analyses, and adsorption experiments. The adsorbent showed a near-spherical aggregate structure and had good crystallinity. A significant amount of α-goethite co-precipitated with PFS in the case of the initial ferrous concentration of 1 mol/L and increased SSA of the adsorbent. The stability region of ferric compounds in the process was drawn and applied to analyze the iron behavior during the synthesis. The adsorption of As(Ⅲ) in high As(Ⅲ)-containing solutions fitted the Langmuir isotherm model adequately. The absorbent with co-precipitation of α-goethite showed good adsorbability for As(Ⅲ) and good filtering performance in the high As(Ⅲ)-containing solution of 10–100 mg/L under acidic, neutral, and alkaline conditions(pH 2.09–9.01). After the adsorption process, the stability of the residues bearing As(Ⅲ) was evaluated by toxic characteristic leaching procedure(TCLP) tests. The results indicated that the residues were extremely stable, and the concentrations of arsenic in the leaching solutions were less than 0.01 mg/L.

关键词： polyferric sulfate crystal structure α-goethite high As(III)-containing contaminated water wide pH range As(III)adsorption

Reduced graphene oxide-supported CoP nanocrystals confined in porous nitrogen-doped carbon nanowire for highly enhanced lithium/sodium storage and hydrogen evolution reaction

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Nano Research 2019年第11期12卷 2872-2880页

作者： Xiaojun Zhao Dan Luo Yan Wang zhi-hong liu Key Laboratory for Macromolecular Science of Shaanxi Province School of Chemistry and Chemical EngineeringShaanxi Normal UniversityXi’an710062China

Rational synthesis of a hierarchical porous architecture with highly active and consecutive conductive network is very critical to achieve the high-performance of nanomaterials in electrochemical energy conversion and *** propose here a hierarchical micro-/nanostructured hybrids constructed by the dual carbon shell nanowire host containing CoP nanocrystals of several nanometers,which generates Co-based metal-organic framework on graphene oxide nanosheets in situ and followed a direct phosphorization(CoP@NC/rGO).The dual carbon shell,consisting of Co-based metal-organic framework derived porous doped carbon(NC)and reduced graphene oxide(rGO),can not only impedes CoP nanocrystals from coalescing,and renders highly exposed the electrochemically accessible active sites,but also provides the multidimensional pathways for rapid electron and ion *** importantly,the covered dual carbon shell on CoP nanocrystals plays a role as a protective layer to impede the nanocrystals’*** virtue of compositional and structural advantages,the micro-/nanostructured CoP@NC/rGO hybrids manifest outstanding energy storage properties when evaluated as anodes for lithium/sodium ion ***,it also reveals highly efficient electrocatalytic performance for hydrogen evolution reaction in acid media with low Tafel slope,overpotential and robust durability.

关键词： micro-/nanostructured metal-organic framework CoP@NC/rGO lithium/sodium ion batteries hydrogen evolution reaction

Diagnostic significance of serum levels of serum amyloid A,procalcitonin,and high-mobility group box 1 in identifying necrotising enterocolitis in newborns

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World Journal of Gastrointestinal Surgery 2024年第7期16卷 2003-2011页

作者： Li-Ming Guo zhi-Hui Jiang hong-Zhen liu Lei Zhang Department of General Surgery Qingdao Women and Children’s HospitalQingdao 266000Shandong ProvinceChina Department of Pediatric Surgery Children's Hospital Affiliated to Shandong UniversityJinan 250022Shandong ProvinceChina Department of Pediatric Surgery Jinan Children's HospitalJinan 250022Shandong ProvinceChina Department of Pediatric Surgery Qilu Hospital of Shandong University(Qingdao)Qingdao 260010Shandong ProvinceChina

BACKGROUND Necrotising enterocolitis(NEC)is a critical gastrointestinal emergency affecting premature and low-birth-weight *** amyloid A(SAA),procalcitonin(PCT),and high-mobility group box 1(HMGB1)have emerged as potential biomarkers for NEC due to their roles in inflammatory response,tissue damage,and immune *** To evaluate the diagnostic value of SAA,PCT,and HMGB1 in the context of NEC in *** The study retrospectively analysed the clinical data of 48 newborns diagnosed with NEC and 50 healthy newborns admitted to the ***,radiological,and laboratory findings,including serum SAA,PCT,and HMGB1 Levels,were collected,and specific detection methods were *** diagnostic value of the biomarkers was evaluated through statistical analysis,which was performed using chi-square test,t-test,correlation analysis,and receiver operating characteristic(ROC)*** The study demonstrated significantly elevated levels of serum SAA,PCT,and HMGB1 Levels in newborns diagnosed with NEC compared with healthy *** correlation analysis indicated strong positive correlations among serum SAA,PCT,and HMGB1 Levels and the presence of *** analysis revealed promising sensitivity and specificity for serum SAA,PCT,and HMGB1 Levels as potential diagnostic *** combined model of the three biomarkers demonstrating an extremely high area under the curve(0.908).CONCLUSION The diagnostic value of serum SAA,PCT,and HMGB1 Levels in NEC was *** biomarkers potentially improve the early detection,risk stratification,and clinical management of critical *** findings suggest that these biomarkers may aid in timely intervention and the enhancement of outcomes for neonates affected by NEC.

关键词： Serum amyloid A Procalcitonin High-mobility group box 1 Necrotising enterocolitis in newborns Serum biomarkers

Double-confined nanoheterostructure Sb/Sb_(2)S_(3)@Ti_(3)C_(2)T_(x)@C toward ultra-stable Li-/Na-ion batteries

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Rare Metals 2024年第5期43卷 2067-2079页

作者： Dan Wang Qun Ma Huan He zhi-Yuan Wang Run-Guo Zheng hong-Yu Sun Yan-Guo liu Chun-Li liu School of Materials Science and Engineering Northeastern UniversityShenyang110819China School of Resources and Materials Northeastern University at QinhuangdaoQinhuangdao 066004China Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province Qinhuangdao 066004China Department of Physics and Oxide Research Center Hankuk University of Foreign StudiesYongin 17035Korea

Antimony-based materials with high capacities and moderate potentials are promising anodes for lithium-/-sodium-ion ***,their tremendous volume expansion and inferior conductivity lead to poor structural stability and sluggish reaction ***,a doubleconfined nanoheterostructure Sb/Sb_(2)S_(3)@Ti_(3)C_(2)T_(x)@C has been fabricated through a solvothermal method followed by low-temperature heat *** dual protection of“MXene”and“carbon”can better accommodate the volume expansion of Sb/Sb_(2)S_(3).The strong covalent bond(Ti-S,Ti-O-Sb,C-O-Sb)can firmly integrate Sb-based material with Ti_(3)C_(2)T_(x)and carbon,which significantly improves the structure *** addition,the carbon layer can restrain the oxidation of MXenes,and the nano-Sb/Sb_(2)S_(3)can facilitate electron/ion transport and suppress the restacking of *** heterogeneous interface between Sb and Sb_(2)S_(3)can further promote interfacial charge *** MXene-Sb/Sb_(2)S_(3)@C-1 with the optimal Sb content shows high specific capacities,comparable rate properties and ultra-stable cycling performances(250 m Ah·g^(-1)after 2500 cycles at 1 A·g^(-1)for sodium-ion batteries).Ex situ X-ray diffractometer(XRD)test reveals the storage mechanism including the conversion and alloying process of MXene-Sb/Sb_(2)S_(3)@*** voltammetry(CV)test results demonstrate that the pseudocapacitance behavior is dominant in MXene-Sb/Sb_(2)S_(3)@C-1,especially at large *** design paves the way for exploring high-performance alloy-based/conversion-type anode for energy storage devices.

关键词： Sb/Sb_(2)S_(3) MXene Carbon Anode Lithium-ion batteries Sodium-ion batteries

Microdynamic mechanical properties and fracture evolution mechanism of monzogabbro with a true triaxial multilevel disturbance method

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International Journal of Mining Science and Technology 2024年第3期34卷 385-411页

作者： zhi Zheng Bin Deng hong liu Wei Wang Shuling Huang Shaojun Li State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Key Laboratory of Disaster Prevention and Structural Safety of Ministry of EducationCollege of Civil Engineering and ArchitectureGuangxi UniversityNanning 530004China State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan 430071China Key Laboratory of Ministry of Education for Geomechanics and Embankment Engineering Hohai UniversityNanjing 210098China Key Laboratory of Geotechnical Mechanics and Engineering of Ministry of Water Resources Changjiang River Scientific Research InstituteWuhan 430015China

The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to ***,the mechanical properties and damage/fracture evolution mechanisms of deep rock induced by microdynamic disturbance under three-dimensional stress states are ***,a true triaxial multilevel disturbance test method is proposed,which can completely simulate natural geostress,excavation stress redistribution(such as stress unloading,concentration and rotation),and subsequently the microdynamic disturbance triggering damaged rock *** on a dynamic true triaxial test platform,true triaxial microdynamic disturbance tests under different frequency and amplitudes were carried out on *** results show that increasing amplitude or decreasing frequency diminishes the failure strength of *** modulus gradually decreases during disturbance *** frequency and amplitude increase,the degradation rate of deformation modulus decreases slightly,disturbance dissipated energy increases significantly,and disturbance deformation anisotropy strengthens obviously.A damage model has been proposed to quantitatively characterize the disturbance-induced damage evolution at different frequency and amplitude under true triaxial *** disturbance failure,the micro-tensile crack mechanism is dominant,and the micro-shear crack mechanism increases significantly at *** the increase of amplitude and frequency,the micro-shear crack mechanism *** approaching disturbance failure,the acoustic emission fractal dimension changes from a stable value to local large oscillation,and finally increases sharply to a high value at ***,the disturbance-induced failure mechanism of surrounding rock in deep engineering is clearly elucidated.

关键词： True triaxial disturbance test Mechanical properties Fracture evolution mechanism Disturbance-induced damage evolution Failure mechanism and precursor

Green synthesis of luminescent La-MOF nanoparticle from waste poly(ethylene terephthalate) for high-performance in Fe(Ⅲ) detection

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Rare Metals 2024年第8期43卷 3833-3843页

作者： zhi Gong zhi-Kui Dai zhi-Yue Dong Qiu-Xuan liu Valentin A.Milichko Hua-Jian liu Jie liu Ran Niu Jiang Gong Key Laboratory of Material Chemistry for Energy Conversion and Storage Hubei Key Laboratory of Material Chemistry and Service FailureHubei Engineering Research Center for Biomaterials and Medical Protective MaterialsSemiconductor Chemistry CenterSchool of Chemistry and Chemical EngineeringMinistry of EducationHuazhong University of Science and Technology School of Chemical Engineering and Pharmacy Wuhan Institute of Technology Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical EngineeringHubei University School of Physics and Engineering ITMO University School of Materials Science and Engineering Hubei University Guangdong Provincial Key Laboratory of Technique and Equipment for Macromolecular Advanced Manufacturing School of Mechanical and Automotive EngineeringKey Laboratory of Polymer Processing EngineeringMinistry of EducationSouth China University of Technology

Developing luminescent metal-organic frameworks（MOFs） capable of high-efficiency Fe3+sensing has aroused great attraction in the fields of biology,chemistry,***,previous solvothermal methods are limited by organic solvent usage,time consuming,high pressure,and high-energy ***,we propose the waste-toMOF strategy towards the scale-up production of La-MOF nanoparticles through the ball milling of recycled poly（-ethylene terephthalate）(PET) bottles and La（NO3）3·*** goes on alkaline hydrolysis to form 1,4-benzenedicarboxylic acid sodium salt（Na2BDC） and ethylene glycol by ball ***,BDC reacts with La3+to form *** as-prepared La-MOF crystal nanoparticles possess a rod-like morphology with the size of few hundred ***,La-MOF nanoparticles display high selectivity and sensitivity for Fe3+*** quenching constant and limit of detection are 5.29×10～3(mol·L-1)-1and 0.147 μmol·L-1,respectively,thus surpassing many advanced Fe3+*** to the result of density functional theory,the high Fe3+detection performance of La-MOF is related to the complexing of Fe3+with La-MOF,which leads to the gradual dissociation of the coordination bond between terephthalic acid and La3+.It is anticipated that the mechanochemistry milling-based wasteto-MOF strategy provides a new platform for the massive production of functional MOFs in a green manner.

关键词： Metal–organic framework Waste polyester Mechanochemistry milling Fluorescence sensor