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Activity Enhancement of Vanadium Catalysts with Ultrasonic Preparation Process for the Oxidation of Sulfur Dioxide

Journal of Natural Gas chemistry 2003年第2期12卷 139-144页

作者： zhenxing chen, honggui li, lingsen wangstate key laboratory for powder metallurgy,{3., central south University, changsha 410083. china State key laboratory for powder {3. College of Chemistry and Chemical Engineering Central South University Changsha 410083 China

The effect of ultrasonic cavitations on the activity of vanadium catalysts atlow temperatures for the oxidation of sulfur dioxide, in which refined carbonized mother liquor hadbeen added, was investigated. Twenty minutes were needed to produce obvious cavitations when thecatalyst raw material was treated in the 50 W ultrasonic generator. However, only 10 minutes wouldbe needed in a 150 W ultrasonic generator. The higher the temperature of the wet material, the lesstime was needed to produce cavitations, and the optimal temperature was 60℃. The water content inthe wet material mainly affected the quantity of cavitations. Ls-8 catalyst was prepared usingultrasonic. Its activity for conversion of SO_2 reached to 52.5% at 410℃ and 4.2% at 3.0℃. Thedifferential thermal analyses indicate that both endothermic peaks and exothermic peaks noticeablyshifted forward compared with Ls catalyst prepared without ultrasonic, and SEM results show auniform pore size distribution for Ls-8 catalyst.

关键词： ultrasonic dispersion vanadium catalyst low temperature activity sulfurdioxide cavitation

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Enhancement in Activity of a Vanadium Catalyst for the Oxidation of Sulfur Dioxide by Radio Frequency Plasma During the Preparation Process

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Journal of Natural Gas chemistry 2003年第3期12卷 195-200页

Radio frequency plasma was used to prepare a vanadium catalyst. The resultsshowed that activating time of the catalyst could be shortened quickly and the catalytic activitywas improved to some extent with the use of plasma. Catalyst Ls-9 was prepared under an optimalcondition of 40 W discharge power, 10 min discharge time and 8 Pa gas pressure. The catalyticactivity was up to 54.7% at 410℃, which was 2.2% higher than that of the Ls-8 catalyst. Only 10 minwas needed to activate the catalyst with plasma, which was 1/9 of the traditional calcination *** Ls-9, both the endothermic as well as the exothermic peaks detected by differential thermalanalysis shifted to higher temperatures obviously, indicating that its crystal phase could melteasily. There existed an apparent endothermic peak at 283.. SEM photographs showed a uniform sizedistribution. It is inferred that the quadrivalent vanadium compound may exist mainly in the form ofVOSO_4.

关键词： plasma activation dispersion vanadium catalyst low-temperature activity

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