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Halysis Høeg,1932—An ancestral tabulate coral from the Ordos Basin,North China

Journal of Palaeogeography 2020年第4期9卷 480-494页

作者： Li-Jing zheng Hong-Xia Jiang Ya-Sheng Wu Hong-Ping Bao Yue-Yang Zhang Jun-Feng Ren zheng-liang huang Key Laboratory of Cenozoic Geology and Environment Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China Innovation Academy for Earth Science Chinese Academy of SciencesBeijing 100029China China United Coalbed Methane Corporation LTDBeijing 100011China Institute of Paleontology Hebei Geo UniversityShijiazhuang 050031Hebei ProvinceChina University of Chinese Academy of Sciences Beijing 100049China Research Institute of Petroleum Exploration and Development Changqing OilfieldXi'an 710021Shaanxi ProvinceChina

The problematic calcareous microfossil Halysis is abundant in the Middle Ordovician Darriwilian Stage of the western edge of the Ordos Basin,North *** rich and well-preserved specimens of Halysis in this area facilitate detailed studies for its skeletal construction and tube *** differs from calcified cyanobacteria and calcareous red and green algae in morphology,skeletal construction and microstructure,as well as reproduction *** typically consists of multiple juxtaposed parallel tubes arranged in sheets(‘multiple-tube'type)or is just composed of one tube(‘single-tube'type).In‘multiple-tube'Halysis,tube fission by bifurcation results from the insertion of a microcrystalline wall at the center of a mother *** study demonstrates for the first time that the tube walls of Halysis have a laminofibrous(fibronormal)microstructure,composed of fibrous calcite perpendicular to wall surface,and recognizes the‘single-tube'type Halysis composed of one tube;in addition,for the first time,this study finds out that‘multiple-tube'Halysis develops buddings from the conjunction of two tubes and‘single-tube'Halysis shows wide-angle Y-shaped *** on these findings,this study further compares Halysis with tabulate *** appears stratigraphically earlier than Catenipora and Aulopora,and has a smaller tube size.‘Multiple-tube'Halysis resembles Catenipora and‘single-tube'Halysis resembles Aulopora in skeletal construction and microstructure,and in their tube walls of laminofibrous microstructure composed of fibrous calcite perpendicular to the tube wall *** and Halysis are both characterized by the absence of septal *** similarities suggest that Halysis may be the ancestor of Catenipora-like and Aulopora-like tabulate corals.

关键词： Halysis Morphology Taxonomic affinity Middle Ordovician Tabulate coral Wuhai Inner Mongolia

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Preparation of Aryloxy-aluminoxanes and Their Use as Activators in the Bis(imino)pyridyl Iron-catalyzed Oligomerization of Ethylene

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Chinese Journal of Polymer Science 2018年第11期36卷 1207-1207,1208-1216页

作者： Wei Zhang Bin-Bo Jiang Jian Ye Zu-Wei Liao zheng-liang huang Jing-Dai Wang Yong-Rong Yang Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology State Key Laboratory of Chemical Engineering College of Chemical and Biological Engineering Zhejiang University

In this study, a series of aryloxy-aluminoxanes originated directly from the hydrolysis of reaction products of A1Me3 and phenols were synthesized, which could serve as effective polymer-retarding activators for the iron-catalyzed ethylene oligomerization. The molar ratios of [PhOH]/[AlMe3] and [H2O]/[Al] during the preparation were explored and their impacts on the oligomerization activity and product distribution were discussed. To obtain the effective activators with good polymer-retarding effect and relatively high activity, the optimized conditions were proposed to be [PhOH]/[AlMe3] = 0.5 and [H2O]/[Al] = 0.7. Various aluminoxanes with different [-OH] sources confirmed the importance of using phenols in preparing the effective polymer-retarding activators. By utilizing these aryloxy-aluminoxanes, the mass fraction of polymers in the total products could be reduced to lower than 1.0 wt%, which is much lower than that of the MAO-activated systems （〉 30 wt%）. This is a potential benefit for the industrial application of the iron-catalyzed oligomerization process.

关键词： Ethylene oligomerization Bis(imino)pyridyl iron catalysts Aryloxy-aluminoxanes Phenols Trimethylaluminum hydrolysis

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The role of axon guidance molecules in the pathogenesis of epilepsy

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Neural Regeneration Research 2025年第5期20卷 1244-1257页

作者： zheng Liu Chunhua Pan Hao huang Department of Neurology Affiliated Hospital of Zunyi Medical UniversityZunyiGuizhou ProvinceChina

Current treatments for epilepsy can only manage the symptoms of the condition but cannot alter the initial onset or halt the progression of the disease. Consequently, it is crucial to identify drugs that can target novel cellular and molecular mechanisms and mechanisms of action. Increasing evidence suggests that axon guidance molecules play a role in the structural and functional modifications of neural networks and that the dysregulation of these molecules is associated with epilepsy susceptibility. In this review, we discuss the essential role of axon guidance molecules in neuronal activity in patients with epilepsy as well as the impact of these molecules on synaptic plasticity and brain tissue remodeling. Furthermore, we examine the relationship between axon guidance molecules and neuroinflammation, as well as the structural changes in specific brain regions that contribute to the development of epilepsy. Ample evidence indicates that axon guidance molecules, including semaphorins and ephrins, play a fundamental role in guiding axon growth and the establishment of synaptic connections. Deviations in their expression or function can disrupt neuronal connections, ultimately leading to epileptic seizures. The remodeling of neural networks is a significant characteristic of epilepsy, with axon guidance molecules playing a role in the dynamic reorganization of neural circuits. This, in turn, affects synapse formation and elimination. Dysregulation of these molecules can upset the delicate balance between excitation and inhibition within a neural network, thereby increasing the risk of overexcitation and the development of epilepsy. Inflammatory signals can regulate the expression and function of axon guidance molecules, thus influencing axonal growth, axon orientation, and synaptic plasticity. The dysregulation of neuroinflammation can intensify neuronal dysfunction and contribute to the occurrence of epilepsy. This review delves into the mechanisms associated with

关键词： axon guidance drug-resistant epilepsy epilepsy nerve regeneration nervous system diseases neural pathways neuroinflammatory diseases neuronal plasticity neurons synaptic remodeling

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Hole-growth phenomenon during pyrolysis of a cation-exchange resin particle

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2022年第12期23卷 974-987页

作者： zheng-liang huang Yun-bo YU Qi SONG Yao YANG Jing-yuan SUN Jing-dai WANG Yong-rong YANG Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology College of Chemical and Biological EngineeringZhejiangUniversityHangzhou 310027China State Key Laboratory of Chemical Engineering College of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310027China

A novel central hole-expansion phenomenon is identified, in which the cation-exchange resin is pyrolyzed in a mixed atmosphere of nitrogen and oxygen at 400–500 ℃. In this reaction, the reaction path is predictable and always starts from the center of the resin particle to form a central hole, then continues and expands around the hole, finally forming a uniformly distributed hole group;the particle surface remains intact. Analysis shows that this formation mode is due to the different reaction paths of sulfonic groups between the surface and interior of the particle, caused by the temperature difference. On the surface, transformation reactions happen at high temperatures(410–500 ℃) to form stable organic sulfur structures, while decomposition occurs inside the particle at a relatively low temperature(<410 ℃) and promotes complete pyrolysis of the copolymer matrix to form holes.

关键词： Non-catalytic gas-solid reaction Cation-exchange resin Pyrolysis Central-hole expansion Temperature difference Transformation

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Modification of acidity in HZSM-5 zeolite for methane-methanol co-reaction

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2021年第2期22卷 106-115页

作者： Bing-jie ZHOU Zhi-xiang XI Yue YU Bin-bo JIANG Jing-dai WANG Zu-wei LIAO zheng-liang huang Yong-rong YANG Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology Department of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310027China State Key Laboratory of Chemical Engineering Zhejiang UniversityHangzhou 310027China

A co-reaction of methane with methanol over zeolite catalysts has emerged as a new approach to the long-standing challenge of methane ***,the effect of catalyst acid properties on the co-reaction has been rarely *** this study,a series of HZSM-5 zeolites with comparable diffusion abilities and various acidities were synthesized directly through steaming with 100%water vapor at 693 *** co-reaction of methane and methanol was subsequently ***?nsted acidity at 0.262 mmol/g was detected to reach the maximum methane conversion of 5.42%at 673 K,which was also the odd point in the relationship between acid concentration and C4 hydrogen transfer ***,the influence of methanol feed was investigated over parent and steamed ZSM-5 catalyst,with results showing that excessive acid sites or methanol molecules reduce methane *** is proposed that acid sites adsorbed with methanol molecules construct the methane activation ***,a proper design of zeolite acidity should be achieved to obtain higher methane conversion in the co-reaction process.

关键词： Methane conversion Methanol Co-reaction Acidity HZSM-5

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模拟研究气液两相在带缩径管的90°弯管内的流动(英文)

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2017年第3期18卷 212-224页

作者： Dong-fang HU zheng-liang huang Jing-yuan SUN Jing-dai WANG Zu-wei LIAO Bin-bo JIANG Jian YANG Yong-rong YANG State Key Laboratory of Chemical Engineering College of Chemical and Biochemical Engineering Zhejiang University Hangzhou 310027 China Shanghai Key Laboratory of Catalysis Technology for Polyolefins Shanghai 200062 China

目的:90°弯管广泛应用于工业中的流体输送,但是流体在经过弯头时会由于离心力的作用而导致弯头下游管道内出现流体分布不均的现象,从而影响后续的生产过程。本文将实验和计算流体力学(CFD)模拟的方法结合研究缩径管对经过弯头后的流体... 详细信息

目的:90°弯管广泛应用于工业中的流体输送,但是流体在经过弯头时会由于离心力的作用而导致弯头下游管道内出现流体分布不均的现象,从而影响后续的生产过程。本文将实验和计算流体力学(CFD)模拟的方法结合研究缩径管对经过弯头后的流体整流作用并分析原因,以期为缩径管在工业中的应用提供一定的参考。创新点:1.提出在弯头后的管路中增加缩径管来调整流体的方法;2.在冷模实验数据验证模拟结果的正确性的基础上,根据CFD模拟得到的管道内的压力、流体速度、相分布及湍动能分布详细分析了缩径管能起整流作用的原因。方法:1.通过冷模实验所得的压力数据与模拟值进行对比,证明模拟所采用模型的正确性;2.通过对不同流体入口条件模拟结果的比较,找到缩径管的作用规律;3.通过CFD模拟得到管道内的压力、流体速度、相分布及湍动能,分析缩径管的整流原理。结论:1.模拟所采用的模型可较好地反映管道内的流体流动情况;2.缩径管能起到很好的整流效果;3.缩径管可使流体加速,促进流体的快速混合,因此能够使不稳定的流体快速达到稳定状态。

关键词： 90°弯管缩径管 CFD 均匀分布流体力学

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从噪声到信息:基于声发射监控的聚烯烃流化床反应器新技术（英文）

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2017年第4期18卷 245-255页

作者： Hao-tong WANG zheng-liang huang Zu-wei LIAO Bin-bo JIANG Jing-dai WANG Yong-rong YANG Guo-dong HAN Bao-zhu YANG State Key Laboratory of Chemical Engineering & Department of Chemical and Biological Engineering Zhejiang University Tianjin Petrochemical Engineering Co.Ltd SINOPEC Shandong Qilu Petrochemical Engineering Co.Ltd SINOPEC

目的:在全球所有的合成树脂中,聚烯烃的产能位居榜首,在国民经济建设和社会发展中发挥着重要作用。但流化床聚合反应器内的高静电会引起颗粒团聚,一旦传热受阻,颗粒极易熔融结块,甚至导致装置爆聚停车。本研究旨在针对流化床聚合反应过... 详细信息

目的:在全球所有的合成树脂中,聚烯烃的产能位居榜首,在国民经济建设和社会发展中发挥着重要作用。但流化床聚合反应器内的高静电会引起颗粒团聚,一旦传热受阻,颗粒极易熔融结块,甚至导致装置爆聚停车。本研究旨在针对流化床聚合反应过程具有强放热、高静电、变粒径的特点,提出基于声发射技术的多种检测手段和信息提取方法。创新点:针对聚合过程的爆聚结块问题,本研究主要解决了以下难题:(1)流化床内颗粒和结块的原位表征技术缺失,难以检测;(2)颗粒熔融结块过程的在线干预机制不清楚,难以调控;(3)流动传热过程强耦合,反应器放大规律不明,导致反应器难放大等问题。方法:创立声发射信号的多尺度解析方法,通过小波分解和重标极差分析法分类重构将声发射信号分解为微尺度、介尺度和宏尺度信号;提出基于声发射检测的反应器操作优化技术,并通过建模确立流化床聚合反应器的时空产率数学模型。成果:新技术成功应用于"十一五"国家重点建设项目——天津百万吨乙烯工程相配套的年产30万吨气相法聚乙烯流化床反应器的设计建设。并且,新技术已成功应用于14套大型聚烯烃装置的设计或改造,所涉及的聚乙烯产能达263万吨。作者所在团队也因该技术发明获得了2016年度国家技术发明奖二等奖。

关键词：流化床声发射聚团介尺度放大

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Cholesterol metabolism: physiological versus pathological aspects in intracerebral hemorrhage

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Neural Regeneration Research 2025年第4期20卷 1015-1030页

作者： Ruoyu huang Qiuyu Pang Lexin zheng Jiaxi Lin Hanxi Li Lingbo Wan Tao Wang Department of Forensic Science School of Basic Medicine and Biological SciencesSuzhou Medicine College of Soochow UniversitySuzhouJiangsu ProvinceChina

Cholesterol is an important component of plasma membranes and participates in many basic life functions,such as the maintenance of cell membrane stability,the synthesis of steroid hormones,and *** plays a key role in the establishment and maintenance of the central nervous *** brain contains 20%of the whole body’s cholesterol,80%of which is located within myelin.A huge number of processes(e.g.,the sterol regulatory element-binding protein pathway and liver X receptor pathway)participate in the regulation of cholesterol metabolism in the brain via mechanisms that include cholesterol biosynthesis,intracellular transport,and *** brain injuries or diseases involving crosstalk among the processes above can affect normal cholesterol metabolism to induce detrimental ***,we hypothesized that cholesterol-related molecules and pathways can serve as therapeutic targets for central nervous system *** hemorrhage is the most severe hemorrhagic stroke subtype,with high mortality and *** cholesterol levels are associated with the risk of intracerebral ***,secondary pathological changes after intracerebral hemorrhage are associated with cholesterol metabolism dysregulation,such as neuroinflammation,demyelination,and multiple types of programmed cell *** cholesterol accumulation in the brain has been found after intracerebral *** this paper,we review normal cholesterol metabolism in the central nervous system,the mechanisms known to participate in the disturbance of cholesterol metabolism after intracerebral hemorrhage,and the links between cholesterol metabolism and cell *** also review several possible and constructive therapeutic targets identified based on cholesterol metabolism to provide cholesterol-based perspectives and a reference for those interested in the treatment of intracerebral hemorrhage.

关键词： cell death cholesterol metabolism intracerebral hemorrhage myelination therapeutic target

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Hypoxia-preconditioned bone marrow-derived mesenchymal stem cells protect neurons from cardiac arrest-induced pyroptosis

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Neural Regeneration Research 2025年第4期20卷 1103-1123页

作者： Xiahong Tang Nan zheng Qingming Lin Yan You zheng Gong Yangping Zhuang Jiali Wu Yu Wang Hanlin huang Jun Ke Feng Chen Shengli Clinical Medical College of Fujian Medical University Fujian Medical UniversityFuzhouFujian ProvinceChina Department of Emergency Fujian Provincial HospitalFuzhouFujian ProvinceChina Fujian Provincial Key Laboratory of Emergency Medicine FuzhouFujian ProvinceChina The Second Department of Intensive Care Unit Fujian Provincial Hospital South BranchFuzhouFujian ProvinceChina

Cardiac arrest can lead to severe neurological impairment as a result of inflammation,mitochondrial dysfunction,and post-cardiopulmonary resuscitation neurological *** preconditioning has been shown to improve migration and survival of bone marrow–derived mesenchymal stem cells and reduce pyroptosis after cardiac arrest,but the specific mechanisms by which hypoxia-preconditioned bone marrow–derived mesenchymal stem cells protect against brain injury after cardiac arrest are *** this end,we established an in vitro co-culture model of bone marrow–derived mesenchymal stem cells and oxygen–glucose deprived primary neurons and found that hypoxic preconditioning enhanced the protective effect of bone marrow stromal stem cells against neuronal pyroptosis,possibly through inhibition of the MAPK and nuclear factor κB ***,we transplanted hypoxia-preconditioned bone marrow–derived mesenchymal stem cells into the lateral ventricle after the return of spontaneous circulation in an 8-minute cardiac arrest rat model induced by *** results showed that hypoxia-preconditioned bone marrow–derived mesenchymal stem cells significantly reduced cardiac arrest–induced neuronal pyroptosis,oxidative stress,and mitochondrial damage,whereas knockdown of the liver isoform of phosphofructokinase in bone marrow–derived mesenchymal stem cells inhibited these *** conclude,hypoxia-preconditioned bone marrow–derived mesenchymal stem cells offer a promising therapeutic approach for neuronal injury following cardiac arrest,and their beneficial effects are potentially associated with increased expression of the liver isoform of phosphofructokinase following hypoxic preconditioning.

关键词： bone marrow–derived mesenchymal stem cells cardiac arrest cardiac resuscitation hypoxic preconditioning liver isoform of phosphofructokinase mitochondria neuroinflammation oxidative stress pyroptosis reactive oxygen species

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Synergistic promotion strategy of “dual-site” and “dual-path” to enhance the C–C coupling between CO2 and HCHO driven by photoelectrocatalysis

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Journal of Energy Chemistry 2025年第1期100卷 39-49页

作者： Hongqiang Yang Jianfeng zheng Guoyu Wang Yifei Gao Yatao Yang Jia Li Xiaojin Han Yan Cui Zhanggen huang National Key Laboratory of High Efficiency and Low Carbon Utilization of Coal Institute of Coal Chemistry Chinese Academy of Science University of Chinese Academy of Science Shenyang University of Chemical Technology

Photoelectrocatalytic coupling CO2and volatile organic compounds （VOCs） is a promising green strategy for the synergistic conversion of the two carbon-containing resources to *** catalytic efficiency is always at the mercy of chemical inertness of CO2and the competitive hydrogen evolution of ***,a modified g-C3N4/ZnAl-LDH Z-scheme heterojunction catalyst with dual reaction site was rationally designed and precisely *** Faraday efficiency of ethanol reached 68.67%with a corresponding formation rate of 227.3μmol *** revealed by in-situ characterizations and density functional theory calculations,CO2and HCHO were absorbed at Zn site and N site,***,*CO generated from CO2and HCHO was converted to*CH3O and*CHO on the dual-active-site *** detailed reaction mechanism experiments indicated that C–C coupling only occurred between*CO and*CH3O in electrocatalysis *** from the“*CO+*CH3O”path,another“*CO+*CHO”coupling path was also detected in photoelectrocatalytic *** selectivity of ethanol was significantly enhanced due to the synthesis of dual-site catalyst and the dual-path coupling path between CO2and HCHO simultaneously driven by light and electricity.

关键词： Ethanol

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