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Geochemical characteristics and diagenetic systems of dolomite reservoirs of the Changxing Formation in the eastern Sichuan Basin, China

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Petroleum Science 2012年第2期9卷 141-153页

作者： Zhang Bing zheng rongcai Wang Xuben zheng Chao Wen Huaguo Luo Yuan Chi Yuelong State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Engineering Chengdu University of TechnologySichuan 610059China Chongqing Gas Mine PetroChina Southwest Oil and Gasfield CompanyChongqing 401120China Sichuan Science and Technology Worker University Sichuan 610059China

In order to discuss the relationship between dolomite reservoirs and diagenetic systems of the Changxing Formation, we studied carbon, oxygen and strontium stable isotopes, iron, manganese and strontium trace elements and the Mg/Ca （mol%） ratio, dolomite order degree, and determined that burial dolomitization is the key to controlling the distribution of high quality dolomite reservoir in the Changxing Formation in the eastern Sichuan Basin. The dolomite of the Changxing Formation is divided into four diagenetic systems：（1） penecontemporaneous stage syngenetic brine diagenetic system, （2） early diagenetic stage strata seal brine diagenetic system, （3） middle-late diagenetic stage mixed hot brine diagenetic system and （4） tectonic uplift stage mixed hydrothermal fluid diagenetic system. New understanding of the controlling factors and distribution of dolomite reservoir development is discussed. Reef shoal facies belts controlled regional reservoir distribution and the scale of development. Burial dolomitization of a strata seal brine diagenetic system is the foundation of reservoir development, mainly developing pore reservoir. Burial dolomitization of mixed hot brine diagenetic system expanded the reservoir distribution and improved the reservoir quality, mainly developing pore-vug reservoir. Fracturing and dissolution of a mixed hydrothermal fluid diagenetic system is the key to improving the reservoir quality, mainly developing pore-vug-crack complex reservoirs.

关键词： Eastern Sichuan Basin Changxing Formation dolomite reservoir diagenesis geochemical characteristics diagenetic system

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Deep-water Depositional Features of Miocene Zhujiang Formation in Baiyun Sag,Pearl River Mouth Basin

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Acta Geologica Sinica(English Edition) 2013年第1期87卷 197-210页

作者： LI Yun zheng rongcai YANG Baoquan ZHU Guojin GAO Boyu HU Xiaoqing State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Chengdu University of Technology China National Offshore Oil Corporation Research Center

Eleven lithofacies and five lithofacies associations were indentified in the Miocene Zhujiang Formation on the basis of detailed core analysis. It could he determined that three depositional types developed, namely submarine fan, basin and deep-water traction current. Six microfacies were further recognized within the fan, including main channels in the inner fan, distributary channels in the middle fan, inter-channels, levees and the outer fan. The lower Zhujiang Formation, mainly sandstone associations, was inner fan and inner-middle fan deposits of the basin fan and the slope fan. The middle part, mainly mudstone associations, was outer fan deposits. With the transgression, the submarine fan was finally replaced by the basinal pelagic deposits which were dominated by mudstone associations, siltstone associations, and deep-water limestone associations. During the weak gravity flow activity, the lower channels, the middle-upper outer fans and basin deposits were strongly modified by the deep-water traction current. The identification of the deep-water traction deposition in Miocene Zhujiang Formation would be of great importance. It could be inferred that the deep- water traction current had been existing after the shelf-break formation since the Late Oligocene （23.8 Ma） in the Baiyun sag, influencing and controlling the sediment composition, the distribution, and depositional processes. It would provide great enlightenment to the paleo-oceanic current circulation in the northern South China Sea.

关键词： northern South China Sea Pearl River Mouth Basin Baiyun Sag Zhujiang Formation,submarine fan

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Primary dolostone related to the Cretaceous lacustrine hydrothermal sedimentation in Qingxi sag, Jiuquan Basin on the northern Tibetan Plateau

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Science China Earth Sciences 2013年第4期56卷 2080-2093页

作者： WEN HuaGuo zheng rongcai QING HaiRuo FAN MingTao LI YanAn GONG BoShi State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Chengdu University of Technology Institute of Sedimentary Geology Chengdu University of Technology Department of Geology University of Regina Yumen Oilfield Company of PetroChina

Based on comprehensive studies in petrography,petrofabric analysis and geochemistry,this paper describes a unique and rare laminated micritic ferruginous primary dolostone crystallized and precipitated from the alkaline hot brine under the conditions of the Mesozoic faulted lake basin.The main rock-forming mineral of this dolostone is ferruginous dolomite with a micritic structure.This dolomite mostly exhibits laminae of 0.1–1 mm thick and is often discovered with other minerals,such as albite,analcite,barite and dickite,which have at least two types of interbedded laminae.Petrogeochemistry reveals that this dolostone contains a large number of typomorphic elements of hydrothermal sedimentation,including Sb,Ba,Sr,Mn,and V.In addition,the LREE is in relatively high concentrations and possesses the typical REE distribution pattern with negative Eu anomaly.Oxygen isotope values(δ18OPDB)range from 5.89‰to 14.15‰with an average of 9.69‰.The ratio of87Sr/86Sr is between0.711648 and 0.719546,with an average of 0.714718.These data indicate that the depositional environment is a stable,blocked,anoxic low-lying hot brine pool in the bottom of deep lake controlled by basement faults.The hydrothermal fluid is the alkaline hot brine formed by the combination of the infiltration lake water and mantle-derived magmatic water,consisting of many ions,including Ca2+,Mg2+and Fe2+.Under the driving flow power of magmatic heat,gravity and compaction,the hydrothermal fluid overcame the overburden pressure and hydrostatic pressure of the lake water body,and boiled to explosion,and then the explosion shattered the original laminated micritic ferruginous primary dolostone near the vent and then formed a new type of dolostone called shattered"hydroexplosion breccias".In the low-lying,unperturbed hot brine pool,far from the vent,the laminated micritic ferruginous primary dolostone was quickly crystallized and chemicals precipitated from the hydrotherm.This study of special rocks contributes to research into the causes of the formation of la

关键词：湖相白云岩湖相碳酸盐岩藏北高原热水沉积酒泉盆地白垩系岩石地球化学下垂

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Geochemical characteristics and diagenetic fluids of dolomite reservoirs in the Huanglong Formation, Eastern Sichuan Basin, China

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Petroleum Science 2014年第1期11卷 52-66页

作者： Wen Huaguo Wen Longbin Chen Haoru zheng rongcai Dang Lurui Li Yanan State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Chengdu University of Technology Institute of Sedimentary Geology Chengdu University of Technology Chongqing Gas District of Southwest Oil and Gas Company of CNPC

Based on a comprehensive study of texture,diagenetic behavior and evolution of dolomite in the Huanglong Formation,trace （e.g.,Fe,Mn and Sr） and rare earth element （REE） geochemistry,andisotopic characteristics （e.g.,C,O and Sr）,four types of diagenetic fluids are identified in the Huanglong Formation dolomite reservoirs of the Eastern Sichuan Basin,China：1）：marine-derived pore waters in the marine diagenetic environment,2） sabkha compaction brine conserved in the early shallowburied diagenetic environment,3） strongly-oxidizing low-temperature meteoric water in the seepagesubsurface flow diagenetic environment,and 4） strongly reducing deeply seated mixed hot brine in the middle and deep burial diagenetic environment.The fluids developed hereditarily from one environment to another,which resulted in its respective characteristics.Fluid characteristics play an important role in the development of dolomite reservoirs：1） dolomitization by marine-derived pore water in the quasisyngenetic stage did not form an effective reservoir; 2） early diagenetic burial dolomitization by the sabkha compaction brine formed the basis for reservoir development; 3） meteoric water karstification in the paleo-epidiagenetic stage expanded both the distribution and the size of the reservoirs,and improved the reservoir quality; 4） deep-burial dissolution and tectonic fracturing in the reburial diagenetic stage further improved reservoir porosity and permeability.

关键词： Dolomite reservoir geochemistry diagenetic fluids Huanglong Formation Carboniferous Sichuan Basin

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The Origin of Paleokarst in the Huanglong Formation of the Eastern Sichuan Basin:Evidence from δ^(13)C, δ^(18)O and ^(87)Sr/^(86)Sr

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Acta Geologica Sinica(English Edition) 2014年第6期88卷 1852-1862页

作者： CHEN Haoru zheng rongcai WEN Huaguo LI Shilin LI Shuang ZHOU Gang WEN Longbin State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Chengdu University of Technology Chongqing Gas District of Southwest Oil and Gas Company of CNPC Petroleum Exploration and Development Research Institute PetroC hina Southwest Oil and Gasfield Company

Karst rocks from the Huanglong Formation exposed at the margin of the Eastern Sichuan Basin can be divided into four types：slightly corroded, moderately corroded porous, intensely corroded brecciated and intensely corroded and replaced secondary calcic karstic rocks. The carbon, oxygen and strontium isotope compositions of the various karst rocks are analyzed systematically and compared to rocks without karst corrosion. The results indicate that（1） the Huanglong Formation in the eastern Sichuan Basin was a restricted bay supplied and controlled by freshwater in which mudmicrite and mud-dolomicrite exhibit low δ13C and δ18O values and high 87Sr/86 Sr ratios;（2） all types of karstic rocks in the paleokarst reservoirs of the Huanglong Formation in the research area are affected by atmospheric freshwater with the δ13C and δ18O values and 87Sr/86 Sr ratios in the original formation approaching those of atmospheric freshwater, which reflects ancient hydrological conditions, fluid properties, isotopic source and the fractionation effect;（3） the intensely corroded and replaced secondary limestone is affected by a variety of diagenetic fluids, often reflected by δ13C and δ18O values, while the 87Sr/86 Sr ratios exhibit the strong degree of the corrosion;（4） after comparing the 87Sr/86 Sr ratios of each type of karst rock, the diagenetic fluids are determined to be mainly atmospheric freshwater, and depending on the strength of corrosion, and the low 87Sr/86 Sr ratio fluids in the layer will participate in the karst process. The carbon, oxygen, and strontium isotopes of different karstic reservoirs can provide meaningful geochemical information for forecasting and evaluating the development and distribution rules of the Huanglong Formation at the margin of the eastern Sichuan Basin in time and space.

关键词： paleokarst reservoirs,carbon and oxygen isotope,strontium isotope,geochemistry,Huanglong Formation,eastern Sichuan area

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Occurrence of Laminated Dolomitic Exhalative Rocks in Continental Rift Basins of Northwest China

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Acta Geologica Sinica(English Edition) 2017年第5期91卷 1934-1935页

作者： WEN Huaguo LUO Lianchao zheng rongcai Hairuo QING XU Wenli State Key Laboratory of oil and Gas Reservoir Geology and Exploitation Chengdu University of Technology Chengdu 610059 Sichuan China Institute of Sedimentary Geology Chengdu University of Technology Chengdu 610059 Sichuan China Department of Geology University of Regina Regina SK S4SOA2 Canada

Objective Researchers have recently discovered that sublacustrine sedimentary exhalative mechanism associated with volcanism,is the principle way to form lacustrine exhalative rocks.These rocks differentiate themselve... 详细信息

关键词： Occurrence of Laminated Dolomitic Exhalative Rocks in Continental Rift Basins of Northwest China REE

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基于熵权法-TOPSIS-灰色关联法的储层综合评价:以莺歌海盆地黄流组为例

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成都理工大学学报（自然科学版） 2024年第1期51卷 91-101页

作者：梁玉凯宋荣彩郑华安张超梁元陈海雯郑峰中海石油(中国)有限公司海南分公司海口570312 成都理工大学能源学院成都610059 油气藏地质及开发工程国家重点实验室(成都理工大学) 成都610059 成都理工大学数学地质四川省重点实验室成都610059

莺歌海盆地上中新统黄流组是高温高压系统,地层地温梯度超过4℃/100 m、压力系数大于1.6。地热资源潜力丰富,但地热资源评价的相关工作还未开展。通过9口钻井、测井录井、生产资料以及最新7口井地层测温数据和岩石热物性参数测试,在储... 详细信息

莺歌海盆地上中新统黄流组是高温高压系统,地层地温梯度超过4℃/100 m、压力系数大于1.6。地热资源潜力丰富,但地热资源评价的相关工作还未开展。通过9口钻井、测井录井、生产资料以及最新7口井地层测温数据和岩石热物性参数测试,在储层储集性能基础上,结合热物性参数,开展储层综合评价工作。以黄流组为例,在储层六参数关系评价基础上,优选孔隙度(Ф)、渗透率(K)、泥质含量(Vsh)、地层系数(DФ)、地层温度(T)、生热率(A)、热导率(J)7个热储评价指标,采用熵权-TOPSIS-灰色关联方法,对该类型热储进行综合评价。研究认为:7个评价指标中,孔隙度、渗透率、地层系数的权重占比较大,分别为21.31%,21.07%和20.42%,是主要影响因素。考虑评价参数的正负理想解的欧氏距离和各指标与正负理想解的灰色关联度,开展不同决策偏好情况下的相对贴近度角度来定量评价,结果显示,储层H1-2、H1-1、H2-2相对贴近度较高,分别为0.624,0.606,0.529,储层性质较好,可作为莺歌海盆地黄流组热储层的重点研究对象。

关键词：莺歌海盆地黄流组热储熵权—TOPSIS—灰色关联方法热储评价

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Geochemical characteristics of Callovian-Oxfordian carbonates in Samandepe gas field,Amu Darya Basin,Turkmenistan

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Petroleum Science 2011年第4期8卷 371-381页

作者： zheng rongcai Li Yun Wu Lei Wu Xianzhong Li Fengjie Niu Gang State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Chengdu University of Technology Chengdu 610059 China CNPC Amu Darya Turkmenistan

The Callovian-Oxfordian carbonate reservoirs are the most important hydrocarbon reservoir in the Samandepe gas field,Amu Darya basin,Turkmenistan.Based on the analysis of Fe,Mn and Sr trace elements,and carbon,oxygen and strontium isotopes,the genesis and evolutionary characteristics of the carbonate reservoirs were studied,and the conclusions were follows：1） Sustained transgressive-regressive cycles played an important role during Callovian-Oxfordian.The reservoir of reef-bank facies was well developed in the period of transgression,while the regional dense cap rocks developed in the period of regression;2） The 87 Sr/86 Sr ratio measured from rudist shells yields an age of 157.2 Ma according to the global strontium isotope curve;3） As diagenetic intensity increased,δ 13 C changed little,and δ 18 O showed strong negative deviation but was still limited to the range of Late Jurassic seawater.High Fe and Sr contents,and low Mn content,and the evolutionary trend of δ 13 C and δ 18 O all indicate that diagenesis occurred in a relatively confined environment,where the fluids were relatively reducing and contained hot brine.The stage of diagenesis reached is mesodiagenesis,which is very favorable for preservation of primary pores in carbonates;4） Strong dissolution of reef limestones,burial dolomitization and hydrothermal calcite precipitation were all the results of the interaction between the 87 Sr-rich diagenetic fluid and rocks;5） The analysis results of isotopes,fluid inclusions and vitrinite reflectance show that the diagenetic fluid was compaction-released water that originated from the deep,coal-bearing clastic strata.

关键词： Trace element (Fe, Sr, Mn) carbon oxyge n strontium stable isotopes diagenetic fluid Callovian-Oxfordian Samandepe gas field Turkmenistan

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红河断裂对莺歌海盆地地热系统的控制作用

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成都理工大学学报（自然科学版） 2024年第3期51卷 428-438页

作者：杨培张佳豪宋荣彩董贵宇陈海雯郑峰成都理工大学管理科学学院成都610059 成都理工大学地球与行星科学学院成都610059 油气藏地质及开发工程全国重点实验室(成都理工大学) 成都610059 中国电力工程顾问集团东北电力设计院有限公司长春130021

基于莺歌海盆地地热背景,从地热系统的水源、流体通道、热储和盖层4个方面系统地去评价红河断裂对其的控热作用。研究结果表明,通过水样、气样分析,断裂构造在地热水循环中起到重要的控制作用;红河断裂的差异变形显著影响裂隙型热液热... 详细信息

基于莺歌海盆地地热背景,从地热系统的水源、流体通道、热储和盖层4个方面系统地去评价红河断裂对其的控热作用。研究结果表明,通过水样、气样分析,断裂构造在地热水循环中起到重要的控制作用;红河断裂的差异变形显著影响裂隙型热液热储的平面分布范围和纵向发育深度的异质性;莺歌海盆地地热系统是以地幔热物质作为主要热源,红河断裂带和盆地内中央凹陷底辟带为主要通道,裂隙型热液热储和上部大面积水道、海底扇、三角洲等储集体为主要热储,莺歌海组巨厚泥岩为主要盖层。

关键词：莺歌海盆地红河断裂底辟带控热作用地热系统

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β-NaYF_(4):Yb^(3+),Tm^(3+)/g-C_(3)N_(4)复合水凝胶材料的制备及其应用

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化工进展 2022年第6期41卷 3146-3154页

作者：陈彰旭陈冰冰王荣财叶晨光郑炳云莆田学院环境与生物工程学院福建莆田351100 福建省新型污染物生态毒理效应与控制重点实验室福建莆田351100 福建省高校生态环境及其信息图谱重点实验室福建莆田351100

为了有效解决日益严重的水污染问题,本文研究了β-NaYF_(4):Yb^(3+),Tm^(3+)/g-C_(3)N_(4)复合材料的制备及其在可见光下催化降解亚甲基蓝模拟废水的最佳工艺条件。首先,利用溶剂热法合成了β-NaYF_(4):Yb^(3+),Tm^(3+),再将煅烧法制备... 详细信息

为了有效解决日益严重的水污染问题,本文研究了β-NaYF_(4):Yb^(3+),Tm^(3+)/g-C_(3)N_(4)复合材料的制备及其在可见光下催化降解亚甲基蓝模拟废水的最佳工艺条件。首先,利用溶剂热法合成了β-NaYF_(4):Yb^(3+),Tm^(3+),再将煅烧法制备的g-C_(3)N_(4)加入聚丙烯酸/聚乙烯醇水溶液,后滴入饱和硼酸溶液获得β-NaYF_(4):Yb^(3+),Tm^(3+)/g-C_(3)N_(4)/聚丙烯酸/聚乙烯醇复合水凝胶。利用X射线衍射仪、场发射扫描电子显微镜、紫外-可见分光光度计、热重分析仪、全自动比表面积微孔孔隙分析仪等进行表征;利用正交试验L_(16)(4^(5))考察复合材料的投加量、复合材料的比例、温度、亚甲基蓝溶液的pH、光照时间等因素,探索降解亚甲基蓝的最佳工艺条件。正交试验结果表明:光照时间为20.0h、pH为7.00、复合材料的投加量0.25g、温度20.0℃、复合材料活性组分β-NaYF_(4):Yb^(3+),Tm^(3+)与g-C_(3)N_(4)的比例为1∶4,此时对30.0mg/L亚甲基蓝降解率达到94.84%,循环降解亚甲基蓝模拟废水4次后的降解率仍高达为86.22%。

关键词： β-NaYF_(4):Yb^(3+) Tm^(3+)氮化碳水凝胶亚甲基蓝复合材料催化降解再生

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