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Recent applications of macrocycles in supramolecular catalysis

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Chinese Chemical Letters 2024年第4期35卷 132-141页

作者： Conghui Wang Lei Xu zhenhua jia Teck-peng Loh College of Advanced Interdisciplinary Science and Technology Henan University of TechnologyZhengzhou 450001China Division of Chemistry and Biological Chemistry School of Chemistry Chemical Engineeringand BiotechnologyNanyang Technological UniversitySingapore 637371Singapore Institute of Advanced Synthesis School of Chemistry and Molecular Engineering Nanjing Tech UniversityNanjing 211816China

Numerous supramolecular macrocycles have been utilized for developing catalysts by exploiting their specific molecular recognition and ability to form inclusion complexes through noncovalent interactions. The cyclic structure and modified functional groups of these macrocycles can influence substrate and transition state stability, as well as reaction selectivity. The inner cavities of these macrocycles are particularly beneficial, as they enable substrates to adopt preorganized arrangements and serve as versatile platforms for highly efficient supramolecular catalytic systems. This minireview provides an overview of recent advancements in supramolecular catalysis using various macrocycles, such as crown ethers, cyclodextrins,calixarenes, pillararenes, cucurbiturils, and other novel macrocycles.

关键词： Supramolecular catalysis Macrocycle Host-guest interactions Confinement Selectivity

Mucosal immune responses to Ichthyophthirius multifiliis in the ocular mucosa of rainbow trout(Oncorhynchus mykiss,Walbaum),an ancient teleost fish

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Marine Life Science & Technology 2024年第2期6卷 266-279页

作者： Weiguang Kong guangyi Ding gaofeng Cheng peng Yang zhen Xu Key Laboratory of Breeding Biotechnology and Sustainable Aquaculture Institute of HydrobiologyChinese Academy of SciencesWuhan 430072China Department of Aquatic Animal Medicine College of FisheriesHuazhong Agricultural UniversityWuhan 430070China

The eye,as a specialized visual organ,is directly exposed to the external environment,and,therefore,it faces constant chal-lenges from external pathogenic organisms and *** the ocular mucosa(OM)of mammals,mucosal-associated lymphoid tissues(MALTs)constitute the primary line of ***,the immune defense role of the OM remains unknown in aquatic *** gain insights into the immune processes within the OM of teleost fish,we developed an infection model of rainbow trout(Oncorhynchus mykiss)OM using a parasite,Ichthyophthirius multifiliis(Ich).Immunofluorescence,qPCR,and H&E staining revealed that Ich successfully infiltrates the OM of rainbow trout,leading to pathological struc-tural changes,as evidenced by A&B ***,the qPCR results indicate an up-regulation of immune-related genes following Ich infection in the ***,transcriptome analyses were conducted to detect immune responses and impairments in eye function within the OM of rainbow trout with Ich *** results of the transcriptome analysis that Ich infection can cause an extensive immune response in the OM,ultimately affecting ocular *** the best of our knowledge,our findings represent for the first time that the teleost OM could act as an invasion site for parasites and trigger a strong mucosal immune response to parasitic infection.

关键词： Ocular mucosa Mucosal immunity Transcriptome analysis Oncorhynchus mykiss Ichthyophthirius multifiliis

genetic dissection and origin of pleiotropic loci underlying multilevel fiber quality traits in upland cotton(gossypium hirsutum L.)

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Journal of Integrative Agriculture 2024年第10期23卷 3250-3263页

作者： Hongge Li Shurong Tang zhen peng guoyong Fu Yinhua jia Shoujun Wei Baojun Chen Muhammad Shahid Iqbal Shoupu He Xiongming Du zhengzhou Research Base State Key Laboratory of Cotton Bio-breeding and Integrated Utilization/School of Agricultural SciencesZhengzhou UniversityZhengzhou 450001China State Key Laboratory of Cotton Bio-breeding and Integrated Utilization/Institute of Cotton Research Chinese Academy of Agricultural SciencesAnyang 455000China

Cotton fiber quality is a persistent concern that determines planting benefits and the quality of finished textile ***,the limitations of measurement instruments have hindered the accurate evaluation of some important fiber characteristics such as fiber maturity,fineness,and neps,which in turn has impeded the genetic improvement and industrial utilization of cotton ***,12 single fiber quality traits were measured using Advanced Fiber Information System(AFIS)equipment among 383 accessions of upland cotton(gossypium hirsutum L.).In addition,eight conventional fiber quality traits were assessed by the High Volume Instrument(HVI)***-wide association study(gWAS),linkage disequilibrium(LD)block genotyping and functional identification were conducted sequentially to uncover the associated elite loci and candidate genes of fiber quality *** a result,the previously reported pleiotropic locus FL_D11 regulating fiber length-related traits was identified in this *** importantly,three novel pleiotropic loci(FM_A03,FF_A05,and FN_A07)regulating fiber maturity,fineness and neps,respectively,were detected based on AFIS *** highly promising candidate genes were screened out by integrating RNA-seq and qRT-PCR analyses,including the reported ghKRP6 for fiber length,the newly identified ghMAP8 for maturity and ghDFR for *** origin and evolutionary analysis of pleiotropic loci indicated that the selection pressure on FL_D11,FM_A03 and FF_A05 increased as the breeding period approached the present and the origins of FM_A03 and FF_A05 were traced back to cotton *** findings reveal the genetic basis underlying fiber quality and provide insight into the genetic improvement and textile utilization of fiber in ***.

关键词： upland cotton single fiber quality pleiotropic loci candidate genes locus origin

Theoretical study of aromaticity reversal in dimethyldihydropyrene derivatives

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Chinese Journal of Structural Chemistry 2024年第5期43卷 8-10页

作者： Fangwen peng zhen Luo Yingjin Ma Haibo Ma School of Chemistry and Chemical Engineering Nanjing UniversityNanjing210023China Computer Network Information Center Chinese Academy of SciencesBeijing100190China Qingdao Institute for Theoretical and Computational Sciences School of Chemistry and Chemical EngineeringShandong UniversityQingdaoShandong266237China

Aromaticity has always been an intriguing chemistry topic,which is considered to have close relations with materials'stability and chemical reactivity due to special energy *** conjugated cycles,Hückel's rule,proposed in 1931,suggests that annulenes having[4n+2]and[4n]πelectrons present aromatic and antiaromatic characters with closed and open electronic configurations,respectively[1].

关键词： Hückel aromatic reactivity

Si/TiO2 carbon fiber core encapsulated in hierarchical multiple MXene@Co-MoS2 shells for constructing a free-standing anode of lithium storage

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Rare Metals 2024年第9期43卷 4222-4233页

作者： Xian-ping Du Ying Huang jia-ming Wang zhen-he Feng Xu Sun MOE Key Laboratory of Material Physics and Chemistry Under Extraordinary Conditions School of Chemistry and Chemical Engineering Northwestern Polytechnical University Shanghai Institute of Space Power-Sources Ningbo Institute of Northwestern Polytechnical University

Silicon-based（Si-based） materials offer more possibilities for generating new portable electronic devices due to their high specific capacities. However, their inferior electrical conductivity and volume expansion during cycling seriously limit their development. The optimum solution is to select specific materials to establish an exceptionally conductive and volume buffer structure,which can assist Si materials in developing their excellent lithium storage properties. In this study, Si particles were confined in TiO2carbon fibers（TiO2CFs） via electrospinning, after which they were encapsulated with MXene and Co-MoS2（CMS） nanosheets to fabricate hierarchical ST-2@MXene@CMS films. TiO2CF, MXene and CMS were employed to establish a coherent conductive network with one-, two-and three-dimensional electronic pathways to permit the unimpeded flow of electrons inside the electrode material. TiO2CF, MXene and CMS acted precisely as multilayered buffers to ameliorate the volume change of Si particles during cycling. In addition, the CMS nanosheets were involved in lithium storage, contributing to the final electrochemical performance. Ultimately, the ST-2@MXene@CMS films served as free-standing electrodes, avoiding the impact of inactive interfaces on the electrochemical performance and fulfilling the lightweight requirement for new energy storage devices.

关键词： Co-MoS2 nanosheets Hierarchical structure Lithium-ion batteries MXene Si particles

Al-containing ge-rich IWV:rapid synthesis via interzeolite transformation and application in Baeyer-Villiger oxidation

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Science China Chemistry 2024年第7期67卷 2282-2291页

作者： Meichen jiao Chunmin jia Hao Xu peng Wu Xian-Ming Zhang School of Chemistry&Material Science Shanxi Normal UniversityTaiyuan 030006China Shanghai Key Laboratory of green Chemistry and Chemical Processes School of Chemistry and Molecular EngineeringEast China Normal UniversityShanghai 200062China School of Chemistry Taiyuan University of TechnologyTaiyuan 030024China

ge-containing Lewis acidic zeolites are typically synthesized using a conventional hydrothermal strategy from amorphous silica sources,through a long time-and energy-consuming approach limiting their wide *** study reports a rapid synthesis strategy for a series of IWV aluminogermanosilicate zeolites(T-x-Al)with a wide range of Si/ge molar ratios(5–15)by interzeolite transformation of dealuminated FAU(DA-FAU).Notably,ge-rich IWV could be obtained with crystallization time as short as one day by the equimolecular Si/ge ratio *** effect of synthetic parameters was investigated and the obtained T-x-Al samples were characterized by XRD,SEM,EDS,ICP,^(29)Si and^(27)Al MAS NMR,FTIR,and N_(2)physisorption *** with a previously reported IWV germanosilicate(H-3),T-x-Al displayed a better catalytic activity in Baeyer-Villiger(BV)oxidation,attributed to the presence of the active framework ge sites with the assistance of the extraframework Al *** cyclic catalysis tests revealed that the presence of framework Al species contributed to the stability of the ***,T-x-Al,with 14-membered ring(MR)supercages,outperformed the typical 12-MR Sn-beta catalyst in the BV oxidation of large ketone-like 2-admantanone,indicating a promising potential application in the macromolecular catalytic process.

关键词： ge-rich IWV interzeolite transformation Al assistance Baeyer-Villiger oxidation

Mechanical properties and fracture surface roughness of thermally damaged granite under dynamic splitting

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Deep Underground Science and Engineering 2024年第1期3卷 103-116页

作者： Yijin Qian peng jia Songze Mao jialiang Lu School of Resources and Civil Engineering Northeastern UniversityShenyangChina

In order to understand the mechanical properties and the fracture surface roughness characteristics of thermally damaged granite under dynamic splitting,dynamic Brazilian splitting tests were conducted on granite samples after thermal treatment at 25,200,400,and 600℃.Results show that the dynamic peak splitting strength of thermally damaged granite samples increases with increasing strain rate,showing obvious strain‐rate *** increasing temperature,thermally induced cracks in granite transform from intergranular cracks to intragranular cracks,and to a transgranular crack *** induced damages reduce the dynamic peak splitting strength and the maximum absorbed energy while increasing the peak radial *** fracture mode of the thermally damaged granite under dynamic loads is mode Ⅱ splitting *** using the axial roughness index Z2 a,the distribution ranges of the wedge‐shaped failure zones and the tensile failure zones in the fracture surfaces under dynamic Brazilian splitting can be effectively *** radial roughness index Z_(2)^(r)is sensitive to the strain rate and *** shows a linear correlation with the peak splitting strength and the maximum absorbed energy and a linear negative correlation with the peak radial strain.Z_(2)^(r)can be used to quantitatively estimate the dynamic parameters based on the models proposed.

关键词： dynamic splitting fracture surface roughness granite strain rate thermal treatment

Unraveling the complex roles of macrophages in obese adipose tissue:an overview

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Frontiers of Medicine 2024年第2期18卷 205-236页

作者： Chang peng Jun Chen Rui Wu Haowen jia.g jia Li Hangzhou Institute for Advanced Study University of Chinese Academy of SciencesHangzhou310000China State Key Laboratory of Drug Research Shanghai Institute of Materia MedicaChinese Academy of SciencesShanghai201203China University of Chinese Academy of Sciences Beijing100049China Department of Prosthodontics Shanghai Engineering Research Center of Advanced Dental Technology and MaterialsShanghai Key Laboratory of Stomatology&Shanghai Research Institute of StomatologyNational Clinical Research Center for Oral DiseasesShanghai Ninth People’s HospitalCollege of StomatologyShanghai Jiao Tong University School of MedicineShanghai200011China

Macrophages,a heterogeneous population of innate immune cells,exhibit remarkable plasticity and play pivotal roles in coordinating immune responses and maintaining tissue homeostasis within the context of metabolic *** activation of inflammatory macrophages in obese adipose tissue leads to detrimental effects,inducing insulin resistance through increased inflammation,impaired thermogenesis,and adipose tissue ***,adipose tissue macrophages also play a beneficial role in maintaining adipose tissue homeostasis by regulating angiogenesis,facilitating the clearance of dead adipocytes,and promoting mitochondrial *** the heterogeneity of macrophages in obese adipose tissue is crucial for unraveling the pathogenesis of obesity and holds significant potential for targeted therapeutic ***,the dual effects and some potential regulatory mechanisms of macrophages in adipose tissue have been elucidated using single-cell *** this review,we present a comprehensive overview of the intricate activation mechanisms and diverse functions of macrophages in adipose tissue during obesity,as well as explore the potential of drug delivery systems targeting macrophages,aiming to enhance the understanding of current regulatory mechanisms that may be potentially targeted for treating obesity or metabolic diseases.

关键词： obesity inflammation adipose tissue macrophages adipose tissue homeostasis

Axial segregation characteristics and size-induced flow behavior of particles in a novel rotary drum with curved sidewalls

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Particuology 2024年第4期87卷 1-19页

作者： Qiuhua Miao Wenchang Zhu Yudong Cao peng Huang Chaobin Hu Minping jia School of Mechanical Engineering Southeast UniversityNanjing211189China jia.gsu Key Laboratory for Elevator Inteligent Safety Changshu215500China

Particle mixing and segregation are common phenomena in rotary drums,which are challenging to be controlled and driven artificially in powder *** this work,the discrete element method(DEM)was applied to construct the novel rotary drum composed of different shaped curved *** varying the operation parameters of particle and sidewall shapes as well as the length-to-diameter(L/D)ratio of drums,the axial mixing and segregation processes of binary size-induced particles were *** results show that the axial flow velocity of the particle mixtures is noticeably weakened once the particle angularity increases,making the non-spherical particles to mix better in rotary drums compared to the spherical ***,in the short drums with size-induced spherical particles,the axial segregation characteristics are significantly enhanced by the convex sidewalls while suppressed by the concave ***,for size-induced non-spherical particles,the axial segregation structure can be present in rotary drums with plane and concave sidewalls while not in drums with convex ***,the axial segregation band structure of spherical particles eventually increases proportionally with the increased drum L/D *** contrast,the non-spherical particles cannot form obvious multi-proportional segregation bands.

关键词： Axial flow behaviors Size-induced particles Curved sidewalls Non-spherical particles Rotary drum