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Metal-organic nanosheet assembly ions sieving membrane for precise lithium ion and anion/solvent separation toward robust lithium metal battery

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Science China Chemistry 2024年第10期67卷 3320-3327页

作者： Jian-Qiang Shen tian-tian zhao Ying-Li Song Lingjuan Zhang Ya-Nan Gao Xiao-Nan Cui Peng zhao Xian-Ming Zhang Key Laboratory of Magnetic Molecules & Magnetic Information Materials Ministry of EducationSchool of Chemistry & Material ScienceShanxi Normal University College of Chemistry and Chemical Engineering Taiyuan University of Technology

Metal-organic nanosheets（MONs） as a novel material with tunable pore structures and low mass transfer resistance,have emerged as molecular sieves for the separation of gases and *** theory,they can also serve as ion sieves for lithium metal batteries（LMBs）,realizing the high-energy and dendritic free ***,there are rarely relevant reports,because it is difficult to simultaneously balance efficient ion sieving ability,high ion passing rate and high electrochemical ***,we synthesized a stable ultrathin MON[Zn2（Bim）4]([Zn2（Bim）4]Nanosheet,HBim=benzimidazolate),which can achieve both efficient lithium ion sieving ability,high lithium ion passing rate and high electrochemical stability at the same *** separator assembled by this MON exhibits high Li+transfer number of 0.81 due to the accurate lithium ion and anion/solvent *** battery containing such separator shows high lithium ionic conductivity of 0.74 m S cm-1and low activation energy of 0.099 eV,which can be attributed to the nanometer level thickness and the ion sieving *** is more,we realized the application of MONs-based ion sieves in LMBs with intercalation cathodes for the first *** the LiFePO4|Li battery with as-assembled separator demonstrates improved Coulombic efficiency（>99%） and significantly extended cycling life（>1600 cycles） with 80% capacity retention.

关键词： lithium sieving membrane metal-organic nanosheets lithium metal battery lithium ion and anion separation lithium ion and solvent separation

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A Comprehensive Study of a Low-Grade Heat-Driven Cooling and Power System Based on Heat Current Method

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Journal of Thermal Science 2024年第4期33卷 1523-1541页

作者： zhao tian XU Ronghong XIN Yonglin HE Kelun MA Huan YUAN Mengdi CHEN Qun School of Energy Storage Science and Engineering North China University of TechnologyBeijing100144China Key Laboratory for Thermal Science and Power Engineering of Ministry of Education Department of Engineering MechanicsTsinghua UniversityBeijing100084China

Combined cooling and power(CCP)system driven by low-grade heat is promising for improving energy *** work proposes a CCP system that integrates a regenerative organic Rankine cycle(RORC)and an absorption chiller on both driving and cooling fluid *** system is modeled by using the heat current method to fully consider nonlinear heat transfer and heat-work conversion constraints and resolve its behavior *** off-design system simulation is performed next,showing that the fluid inlet temperatures and flow rates of cooling water as well as RORC working fluid strongly affect system *** off-design operation even becomes infeasible when parameters deviate from nominal values largely due to limited heat transfer capability of components,highlighting the importance of considering heat transfer constraints via heat current *** optimization aiming to minimize the total thermal conductance is also *** efficiency increases by 7.9%and decreases by 12.4%after optimization,with the hot fluid inlet temperature increase from 373.15 to 403.15 K and mass flow rate ranges from 10 to 30 kg/s,emphasizing the necessity of balancing system cost and performance.

关键词： combined cooling and power system organic Rankine cycle absorption chiller cascade heat utilization heat current method off-design analysis

Clinical evolution of antisynthetase syndrome-associated interstitial lung disease after COVID-19 in a man with Klinefelter syndrome:A case report

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World Journal of Clinical Cases 2024年第6期12卷 1144-1149页

作者： Xiang-Xiang Wu Jian Cui Shi-Yao Wang tian-tian zhao Ya-Fei Yuan Long Yang Wei Zuo Wen-Jian Liao Department of Respiratory and Critical Care The First Affiliated HospitalJiangxi Medical CollegeNanchang UniversityNanchang 330006Jiangxi ProvinceChina China-Japan Friendship Jiangxi Hospital Nanchang 330006Jiangxi ProvinceChina Department of Pulmonary and Critical Care Medicine Center of Respiratory MedicineChina-Japan Friendship HospitalBeijing 100029China

BACKGROUND This study presents a case of rapidly developing respiratory failure due to antisynthetase syndrome(AS)following coronavirus disease 2019(COVID-19)in a 33-year-old man diagnosed with Klinefelter syndrome(KS).CASE SUMMARY A 33-year-old man with a diagnosis of KS was admitted to the Department of Pulmonary and Critical Care Medicine of a tertiary hospital in China for fever and shortness of breath 2 wk after the onset of *** tomography of both lungs revealed diffuse multiple patchy heightened shadows in both lungs,accompanied by signs of partial bronchial *** next-generation sequencing of the bronchoalveolar lavage fluid suggested absence of pathogen.A biopsy specimen revealed organizing pneumonia with alveolar septal ***,extensive auto-antibody tests showed strong positivity for anti-SSA,anti-SSB,anti-Jo-1,and *** multidisciplinary discussions,the patient received a final diagnosis of AS,leading to rapidly progressing respiratory *** This study underscores the clinical progression of AS-associated interstitial lung disease subsequent to viral infections such as COVID-19 in patients diagnosed with KS.

关键词： Antisynthetase syndrome COVID-19 Klinefelter syndrome Interstitial lung disease Anti-Jo-1 Case report

A Win-Win Undergraduate Graduation Design Model for Students, Teachers, and Training Platforms

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Journal of Contemporary Educational Research 2024年第8期8卷 142-146页

作者： Xiaoqing Zhang Lili Wang tian zhao Hebei Science and Technology Normal University Qinhuangdao 066000Hebei ProvinceChina

Undergraduate graduation design is an important link in the process of undergraduate training,and university platforms have invested a lot of manpower and material resources for this ***,while carrying out student training,it has gradually become the consensus of most university platforms to achieve a win-win situation for teachers and training platforms in order to achieve optimization of resource allocation and motivation of student *** discussion and practice,this paper proposes a set of undergraduate graduation design training concepts and training modes with a win-win situation for students,teachers,and training platforms.

关键词： Graduation design Thesis Undergraduate teaching Research project Platform construction

Coercivity mechanism of La-Nd-Fe-B films with Y spacer layer

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Chinese Physics B 2024年第3期33卷 138-143页

作者：马俊赵晓天刘伟李阳刘龙赵新国张志东 Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of Materials Science and Engineering University of Science and Technology of ChinaShenyang 110016China

The effect of the Y spacer layer on the phase composition,coercivity,and magnetization reversal processes of La-Nd-Fe-B films has been *** addition of a 10 nm Y spacer layer increases the coercivity of the film to 1.36 T at 300 K and remains 0.938 T at 380 *** the thickness of the Y spacer layer increases,Y participates in the formation of the main phase in the film,and further regulates the formation of La-B *** results of the first-order reversal curve(FORC)and micromagnetic fitting show that the coercivity of all the films is dominated by nucleation *** c-axis preferred orientation,good magnetic microstructure parameters and the largest dipole interaction enhance the ***,the introduction of the Y spacer layer can be an effective way to improve the coercivity of La-Nd-Fe-B film over a wide temperature range of 150 K-380 K.

关键词： La-Nd-(Y)-Fe-B films magnetization reversal mechanisms coercivity multilayers

数智赋能专精特新企业国际化经营:进程、机制与对策

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当代经济管理 2024年第9期46卷 29-37页

作者：赵甜山东科技大学工商管理系山东济南250031

专精特新企业专注于特定领域的深度开发和创新,为全球市场提供了独特的价值,深入了解这些企业在全球市场中的运营策略,有助于提高其国际化管理能力,增强全球竞争力。文章将专精特新企业国际化经营的进程划分为初始阶段、市场拓展阶段和... 详细信息

专精特新企业专注于特定领域的深度开发和创新,为全球市场提供了独特的价值,深入了解这些企业在全球市场中的运营策略,有助于提高其国际化管理能力,增强全球竞争力。文章将专精特新企业国际化经营的进程划分为初始阶段、市场拓展阶段和国际化阶段,分别描述了各个阶段企业国际化经营的特点和数智赋能在其中发挥的作用。然后,从概率、速度和节奏三个维度归纳了数智赋能对专精特新企业国际化经营的影响机制,并分别从内部和外部两个角度总结了不同维度下的影响因素。最后,文章建议通过加强数智基础设施建设、增强数智化应用和创新能力、利用国际化平台与合作伙伴网络、建立健全风险管理机制从而完善数智赋能专精特新企业国际化经营的进程。

关键词：专精特新国际化经营数智赋能

Relationship between the change of ATP level controlled by ectonucleotidases and endometriosisassociated infertility and pain

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Gynecology and Obstetrics Clinical Medicine 2024年第2期4卷 115-121页

作者： Yiling Wang Qingjie Zhai zhao tian Xiaohong Chang Honglan Zhu Department of Obstetrics and Gynecology Peking University People's HospitalBeijingChina

Background Thedysfunction ofthe immune system is one of the pathogeneses of *** cells can not onlyaffect the microenvironmentof the endometrium by secreting cytokines and defensins but also promote angiogenesis,growth and invasion of endometrial stromal *** ATP is a key mediator in the immune mechanism of endometriosis and plays a crucial role in *** ATP acts as a purinergic signaling molecule,it has a close relationship with the pain of endometriosis via activating ATP receptors,including P2X3,P2X4,P2X7 and P2Y receptors,after being activated by the immune ***,ATP levels reflect the impairment of mitochondrial function in granulosa cells,which could lead to *** modulation of ATP expression levels is controlled by *** content of ectonucleotidases is altered in endometriosis which may be emerging non-invasive *** In the present review,we briefly introduce the relationship between the change of ATP level controlled by ectonucleotidases and endometriosis-associated infertility and pain,and illustrate our prospects for future research.

关键词： endometriosis pain infertility

黄土微观结构优先连通模型及其对优先渗流的意义

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岩土力学 2024年第6期45卷 1709-1719页

作者：潘网生赵恬茵李鑫黔南民族师范学院旅游与资源环境学院贵州都匀558000 石家庄铁道大学土木工程学院河北石家庄050043

开展黄土微观结构研究有助于揭示宏细观黄土体渗流、黄土滑坡滑动面形成机制和过程。构建了含裂隙和不含裂隙两类黄土微观结构连通模型,探讨了孔隙连通率p、孔隙变异系数λ、裂隙最大跨度ω及裂隙网络贯通率q等参数之间的关系,并通过黄... 详细信息

开展黄土微观结构研究有助于揭示宏细观黄土体渗流、黄土滑坡滑动面形成机制和过程。构建了含裂隙和不含裂隙两类黄土微观结构连通模型,探讨了孔隙连通率p、孔隙变异系数λ、裂隙最大跨度ω及裂隙网络贯通率q等参数之间的关系,并通过黄土微观结构扫描式电子显微镜试验和野外渗流试验对两类模型的连通阈值进行了验证。结果表明:裂隙的存在,特别是其跨度大小,对黄土孔隙形态大小及其分布特征具有重要影响;裂隙是优先流的重要通道,是较低孔隙率条件下发生黄土优先流的重要原因;黄土微观结构优先连通模型研究结论与黄土渗流试验结论基本吻合,揭示了泾阳南塬“漫灌式”灌溉行为对含裂缝的高陡边坡稳定性的不利影响以及东风村、蒋刘村等大型滑坡发生的根本原因。

关键词：黄土优先流连通性微观结构地理信息系统

Assessing recent recurrence after hepatectomy for hepatitis Brelated hepatocellular carcinoma by a predictive model based on sarcopenia

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World Journal of Gastroenterology 2024年第12期30卷 1727-1738页

作者： Hong Peng Si-Yi Lei Wei Fan Yu Dai Yi Zhang Gen Chen Ting-Ting Xiong tian-zhao Liu Yue Huang Xiao-Feng Wang Jin-Hui Xu Xin-Hua Luo Department of Infectious Diseases Guizhou Provincial People’s HospitalGuiyang 550002Guizhou ProvinceChina Department of Hepatobiliary Surgery Guizhou Provincial People’s HospitalGuiyang 550002Guizhou ProvinceChina

BACKGROUND Sarcopenia may be associated with hepatocellular carcinoma(HCC)following *** traditional single clinical variables are still insufficient to predict *** still lack effective prediction models for recent recurrence(time to recurrence5 cm(HR=2.222,95%CI:1.285-3.842,P<0.05),and hepatitis B virus DNA level≥2000 IU/mL(HR=2.1,95%CI:1.407-3.135,P<0.05)were independent risk factors associated with postoperative recurrence of *** on the sarcopenia to assess the RFS model of hepatectomy with hepatitis B-related liver cancer disease(SAMD)was established combined with other the above risk *** area under the curve of the SAMD model was 0.782(95%CI:0.705-0.858)in the training cohort(sensitivity 81%,specificity 63%)and 0.773(95%CI:0.707-0.838)in the validation ***,a SAMD score≥110 was better to distinguish the high-risk group of postoperative recurrence of *** Sarcopenia is associated with recent recurrence after hepatectomy for hepatitis B-rel

关键词： Alpha-fetoprotein Hepatitis B virus Hepatectomy Hepatocellular carcinoma Nomogram Predictive models Recurrence Recurrence-free survival Risk factors Sarcopenia