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3D-printed Mg-1Ca/polycaprolactone composite scaffolds with promoted bone regeneration

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Journal of Magnesium and Alloys 2024年第3期12卷 966-979页

作者： xiao zhao Siyi Wang Feilong Wang Yuan Zhu Ranli Gu Fan Yang Yongxiang Xu Dandan Xia Yunsong Liu Department of Prosthodontics Peking University School and Hospital of StomatologyBeijing 100081China National Center of Stomatology National Engineering Laboratory for Digital and Material Technology of StomatologyNational Clinical Research Center for Oral DiseasesBeijing Key Laboratory of Digital StomatologyResearch Center of Engineering and Technology for Computerized Dentistry Ministry of HealthNMPA Key Laboratory for Dental MaterialsBeijing 100081China Department of Dental Materials Peking University School and Hospital of StomatologyBeijing 100081China

In bone tissue engineering,polycaprolactone(PCL)is a promising material with good biocompatibility,but its poor degradation rate,mechanical strength,and osteogenic properties limit its *** this study,we developed an Mg-1Ca/polycaprolactone(Mg-1Ca/PCL)composite scaffolds to overcome these *** used a melt blending method to prepare Mg-1Ca/PCL composites with Mg-1Ca alloy powder mass ratios of 5,10,and 20 wt%.Porous scaffolds with controlled macro-and microstructure were printed using the fused deposition modeling *** explored the mechanical strength,biocompatibility,osteogenesis performance,and molecular mechanism of the Mg-1Ca/PCL *** 5 and 10 wt%Mg-1Ca/PCL composites were found to have good ***,they promoted the mechanical strength,proliferation,adhesion,and osteogenic differentiation of human bone marrow stem cells(hBMSCs)of pure *** vitro degradation experiments revealed that the composite material stably released Mg_(2)+ions for a long period;it formed an apatite layer on the surface of the scaffold that facilitated cell adhesion and *** tomography and histological analysis showed that both 5 and 10 wt%Mg-1Ca/PCL composite scaffolds promoted bone regeneration bone *** results indicated that the Wnt/β-catenin pathway was involved in the osteogenic ***,Mg-1Ca/PCL composite scaffolds are expected to be a promising bone regeneration material for clinical *** of significance:Bone tissue engineering scaffolds have promising applications in the regeneration of critical-sized bone ***,there remain many limitations in the materials and manufacturing methods used to fabricate *** study shows that the developed Ma-1Ca/PCL composites provides scaffolds with suitable degradation rates and enhanced boneformation ***,the fused deposition modeling method allows precise control of the macroscopic morphology and microsc

关键词： 3D printing Bone tissue engineering Magnesium Osteogenic Polycaprolactone Scaffold.

Experimental Research on Reverse Teaching in College Football Instruction

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Education and Teaching Research

Education and Teaching Research 2024年第1期 54-59页

作者： zhao xiao Hengshui University HengshuiChina

In higher education,football education faces challenges such as low student engagement and suboptimal teaching *** study explores the effectiveness of flipped classroom teaching in college-level football *** classroom teaching reverses traditional methods,emphasizing pre-class independent study and in-class *** experimental research,we assess its impact on student learning experiences and outcomes,aiming to enhance the quality of football education.

关键词： Flipped classroom College-level football education Innovative teaching methods Student engagement Educational outcomes

Molecular Mechanism of Polysaccharides Extracted from Chinese Medicine Targeting Gut Microbiota for Promoting Health

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Chinese Journal of Integrative Medicine 2024年第2期30卷 171-180页

作者： zhao Wen-xiao WANG Tong ZHANG Ya-nan CHEN Qian WANG Yuan XING Yan-qing ZHENG Jun DUAN Chen-chen CHEN Lijun zhao Hai-jun WANG Shijun School of Nursing Shandong University of Traditional Chinese MedicineShandong University of Traditional Chinese MedicineJi'nan(250355)China Shandong Co-innovation Center of Classic Traditional Chinese Medicine Formula Shandong University of Traditional Chinese MedicineJi'nan(250355)China College of Traditional Chinese Medicine Shandong University of Traditional Chinese MedicineJinan(250355)China

The accumulating evidence revealed that gut microbiota plays an important role in pathological process of disease including obesity,type 2 diabetes mellitus,heart failure,and non-alcoholic fatty liver *** extracted from Chinese medicine(CM)can not only alleviate pathological status but also promote health by anti-inflammatory,regulating immunity,lowering blood glucose and lipids,anti-cancer,and *** alterations of gut microbiota composition and metabolism pathways are the potential mechanisms of CM polysaccharides *** addition,they exert functions through gut-organ axis or play an indirect role by synergistic actions with other drugs or components mediated by gut *** review summarizes the molecular mechanisms of CM polysaccharides interacted with intestinal microbial inhabitants as potential prebiotics forpromoting health.

关键词： Chinese medicine polysaccharides gut microbiota short-chain fatty acids lipopolysaccharides gut-organaxis synergistic actions

Ethical Analysis of Ethical Issues and Countermeasures in Education in the Era of Artificial Intelligence

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Education and Teaching Research

Education and Teaching Research 2024年第3期 51-56页

作者： zhao xiao Chun Hengshui University HengshuiChina

The integration of artificial intelligence(AI)in education has revolutionized teaching and learning methodologies,offering personalized experiences and efficient resource ***,this technological advancement has also surfaced a plethora of ethical concerns that necessitate careful *** paper delves into the ethical issues arising from AI applications in education,such as data privacy,algorithmic bias,educational equity,and the evolving role of *** a comprehensive analysis,we identify the challenges and propose strategic countermeasures to mitigate these ethical *** studies from both domestic and international contexts are employed to illustrate real-world applications and the associated ethical decision-making *** paper concludes with a summary of findings,policy recommendations,and an outlook on future research directions,emphasizing the need for a balanced approach that respects both technological innovation and ethical standards in educational AI deployment.

关键词： Artificial Intelligence Educational Ethics Data Privacy Algorithmic Bias Educational Equity Teacher Role Evolution

Atomic Dispersed Hetero‑Pairs for Enhanced Electrocatalytic CO_(2)Reduction

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Nano-Micro Letters 2024年第1期16卷 55-67页

作者： zhaoyong Jin Meiqi Yang Yilong Dong Xingcheng Ma Ying Wang Jiandong Wu Jinchang Fan Dewen Wang Rongshen Xi xiao zhao Tianyi Xu Jingxiang zhao Lei Zhang David J.Singh Weitao Zheng xiaoqiang Cui State Key Laboratory of Automotive Simulation and Control School of Materials Science and EngineeringKey Laboratory of Automobile Materials of MOEElectron Microscopy CenterJilin UniversityChangchun 130012People’s Republic of China Key Laboratory of Photonic and Electronic Bandgap Materials Ministry of Educationand College of Chemistry and Chemical EngineeringHarbin Normal UniversityHarbin 150025People’s Republic of China College of Chemistry Jilin UniversityChangchun 130012People’s Republic of China Department of Physics and Astronomy and Department of Chemistry University of MissouriColumbiaMO 65211USA

Electrochemical carbon dioxide reduction reaction(CO_(2)RR)involves a variety of intermediates with highly correlated reaction and ad-desorption energies,hindering optimization of the catalytic *** example,increasing the binding of the*COOH to the active site will generally increase the*CO desorption *** this relationship may be expected to dramatically improve the intrinsic activity of CO_(2)RR,but remains an unsolved ***,we addressed this conundrum by constructing a unique atomic dispersed hetero-pair consisting of Mo-Fe di-atoms anchored on N-doped carbon *** system shows an unprecedented CO_(2)RR intrinsic activity with TOF of 3336 h−1,high selectivity toward CO production,Faradaic efficiency of 95.96%at−0.60 V and excellent *** calculations show that the Mo-Fe diatomic sites increased the*COOH intermediate adsorption energy by bridging adsorption of*COOH *** the same time,d-d orbital coupling in the Mo-Fe di-atom results in electron delocalization and facilitates desorption of*CO ***,the undesirable correlation between these steps is *** work provides a promising approach,specifically the use of di-atoms,for breaking unfavorable relationships based on understanding of the catalytic mechanisms at the atomic scale.

关键词： CO_(2)reduction reaction Atomic dispersed catalyst Hetero-diatomic pair Ad-desorption energy Linear scaling relation

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1952年中国农民代表赴苏参观团述评

中国农史 2024年第2期43卷 40-51,80页

作者：肖钊湘潭大学马克思主义学院湖南湘潭411105

1952年4月至8月,中国农民代表参观团对苏联进行了长达4个月的访问,其间参观了苏联各地的城市和农村,深入了解和学习了苏联农业技术和农业集体化经验,并体验了苏联农民的实际生活。回国后,他们大力推广苏联农业技术,广泛传播访苏经验和感... 详细信息

1952年4月至8月,中国农民代表参观团对苏联进行了长达4个月的访问,其间参观了苏联各地的城市和农村,深入了解和学习了苏联农业技术和农业集体化经验,并体验了苏联农民的实际生活。回国后,他们大力推广苏联农业技术,广泛传播访苏经验和感受,改变了中国农民对社会主义的认知,激发起大家学习苏联走社会主义道路的热情,有力地推动了农业集体化进程,同时也加深了两国人民的友谊。

关键词：中国农民参观团苏联农业集体化

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基于关键点运动轨迹建模的步态识别

东北大学学报（自然科学版） 2024年第1期45卷 33-39,48页

作者：徐久强赵肖肖钱龙飞东北大学计算机科学与工程学院辽宁沈阳110169

步态信息作为一个新兴的生物特征,在医疗、刑侦等方面具有广泛的应用前景.研究者已经提出了很多种步态识别方法,但普遍存在适应性不强、特征描述过于复杂或缺乏可解释性等问题.针对此问题,首先,通过改进三帧差分完成对视频图像中人体轮... 详细信息

步态信息作为一个新兴的生物特征,在医疗、刑侦等方面具有广泛的应用前景.研究者已经提出了很多种步态识别方法,但普遍存在适应性不强、特征描述过于复杂或缺乏可解释性等问题.针对此问题,首先,通过改进三帧差分完成对视频图像中人体轮廓的提取;然后,基于人体轮廓图获取人体骨架模型,通过骨架模型得到所需的人体关键点位置,并对视频图像中同一关键点的位置轨迹进行曲线建模;最后依据关键点轨迹曲线模型建立一种以模型参数作为步态特征向量的步态特征描述方法,并在此基础上选取合适的分类方法进行步态识别.实验结果表明,基于关键点运动轨迹模型的步态特征表达能够很好地描述步态信息,识别率也相对较高.

关键词：步态识别轮廓提取人体骨架提取关键点运动轨迹

纳米氧化锌对钙钛矿薄膜本征性能和光谱性能的影响研究

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光谱学与光谱分析 2024年第5期44卷 1482-1486页

作者：于嫚谢国鑫赵肖娟李兆西安航空学院材料工程学院陕西西安710077

有机-无机杂化钙钛矿太阳能电池因其优异的光电特性、低廉的制备成本、高效的转换效率等优越特性,成为光伏领域的研究热点。电子传输层作为钙钛矿电池的核心层,主要起到提取和传输光生载流子的作用,且能够作为空穴阻挡层,抑制钙钛矿活... 详细信息

有机-无机杂化钙钛矿太阳能电池因其优异的光电特性、低廉的制备成本、高效的转换效率等优越特性,成为光伏领域的研究热点。电子传输层作为钙钛矿电池的核心层,主要起到提取和传输光生载流子的作用,且能够作为空穴阻挡层,抑制钙钛矿活性层中电荷复合,所以优异性能的电子传输层对钙钛矿太阳能电池的发展至关重要。可目前钙钛矿光伏器件常用的刚性电子传输层(介孔层或致密层)均需要高温烧结,这限制了其在柔性钙钛矿器件方面的应用。因此,开发一种可应用于钙钛矿光伏领域的柔性电子传输层成为当前亟待解决的问题之一。纳米ZnO具有合适的能级和较高的电子迁移率,且可以通过低温制备,被广泛应用在光伏器件中作为电子传输层。因此,通过旋涂法和静电纺丝法分别制备了刚性纳米ZnO和柔性纳米ZnO电子传输层,确定了静电纺丝法制备柔性纳米ZnO的最佳制备工艺。利用扫描电子显微镜、X射线衍射仪、紫外可见分光光度计和稳态/瞬态荧光光谱系统研究了刚性和柔性纳米ZnO对钙钛矿薄膜形貌、结构和光谱性能的影响。结果表明,钙钛矿薄膜的形貌对基底纳米ZnO的形貌依赖性很强。而基于刚性和柔性纳米ZnO的钙钛矿薄膜几乎呈现相同的结构和光谱吸收范围,荧光发射峰均在770 nm附近,且柔性纳米ZnO的荧光猝灭效率为82%,几乎和刚性纳米ZnO的荧光猝灭效率(85%)相媲美。进一步,根据瞬态荧光动力学数据计算获得刚性和柔性纳米ZnO的界面电荷分离效率分别为61%和41%,这表明通过静电纺丝法制备的柔性纳米ZnO具备一定的界面电荷分离能力,有望成为新型的柔性电子传输层。这对柔性基底钙钛矿太阳能电池的设计具有重要参考价值,对促进钙钛矿光伏应用具有现实意义。

关键词：纳米氧化锌钙钛矿薄膜形貌结构光谱性能

三维整体式碳基光热转换材料在太阳能界面水蒸发中的应用研究进展

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新型炭材料（中英文） 2024年第2期39卷 240-253页

作者：韩悦张鹏赵晓明天津工业大学天津市先进纺织复合材料重点实验室天津市先进纤维与储能技术重点实验室纺织科学与工程学院天津300387 天津工业大学环境科学与工程学院天津300387

光热驱动的海水淡化技术被认为是最具潜力的解决全球淡水资源短缺难题的方法之一。其中,太阳能界面水蒸发(SVG)是海水淡化效率的核心过程,是保证光热海水淡化技术具有能量转换效率高、设备简单、成本效益高的关键。在所有高效SVG候选材... 详细信息

光热驱动的海水淡化技术被认为是最具潜力的解决全球淡水资源短缺难题的方法之一。其中,太阳能界面水蒸发(SVG)是海水淡化效率的核心过程,是保证光热海水淡化技术具有能量转换效率高、设备简单、成本效益高的关键。在所有高效SVG候选材料中,三维整体式碳基光热转换材料具有成本低、吸光效率高、结构可调性好、水蒸发速率高、无二次污染等优点。本综述首先简述了SVG的基本原理,以此为依据介绍了高效SVG材料的工作机制和设计原则,最后系统归纳和概述了4种不同类型的三维整体式碳基光热转换材料的研究进展。本综述为未来三维整体式碳基光热转换材料的构建及其在SVG领域的应用研究提供理论基础和研究指导。

关键词：光热转换三维整体材料碳质材料太阳能界面水蒸发海水淡化

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