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2D–3D dual carbon layer confined ultrasmall VN nanoparticles for improving lithium-ion storage in hybrid capacitors

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Rare Metals 2024年第1期43卷 65-75页

作者： zhao-Wei hu hui-Fang Li Peng Wang Wan-Li Wang Lei Yang Xiao-Jun Wang Zhi-Ming Liu College of Electromechanical Engineering Shandong Engineering Laboratory for Preparation and Application of High-Performance Carbon-MaterialsQingdao University of Science&TechnologyQingdao 266061China Research Center for Intelligent and Wearable Technology College of Textiles and ClothingQingdao UniversityQingdao 266071China

Lithium-ion capacitors(LICs) of achieving high power and energy density have garnered significant attention. However, the kinetics unbalance between anode and cathode can impede the application of LICs. Vanadium nitride(VN) with a high theoretical specific capacity(~ 1200 m Ah·g^(-1)) is a better pseudocapacitive anode to match the response of cathode in LICs. However, the insertion/extraction of Li-ions in VN's operation results in significant volume expansion. Herein, the VN/N-r GO-5composite that three-dimentional(3D) dicyandiamidederived-carbon(DDC) tightly wrapped VN quantum dots(VN QDTs) on two-dimentional(2D) reduced graphene oxid(r GO) was prepared by a facile strategy. The VN QDTs can reduce ion diffusion length and improve charge transfer kinetics. The 2D r GO as a template provides support for nanoparticle dispersion and improves electrical conductivity. The 3D DDC tightly encapsulated with VN QDTs mitigates agglomeration of VN particles as well as volume expansion. Correspondingly, the LICs with VN/Nr GO-5 composite as anode and activated carbon(AC) as cathode were fabricated, which exhibits a high energy density and power density. Such strategy provides a perspective for improving the electrochemical properties of LIC anode materials by suppressing volume expansion and enhancing conductivity.

关键词： Vanadium nitride(VN)quantum dots Reduced graphene oxide(rGO)nanosheets Dicyandiamide-derived-carbon 2D–3D dual carbon layer Lithium-ion capacitors

Optimizing FeCoNiCrTi high-entropy alloy with hydrogen pumping effect to boost de/hydrogenation performance of magnesium hydride

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Rare Metals 2024年第7期43卷 3273-3285页

作者： Meng-Chen Song Fu-Ying Wu Yi-Qun Jiang Xiu-Zhen Wang hu zhao Li-Xin Chen Liu-Ting Zhang School of Energy and Power Instrumental Analysis CenterJiangsu University of Science and TechnologyZhenjiang 212003China Max Planck Institute for Iron Research 40237DuisseldorfGermany School of Mechanical and Aerospace Engineering Nanyang Technological UniversitySingapore 639798Singapore State Key Laboratory of Silicon Materials Department of Materials Science and EngineeringZhejiang UniversityHangzhou 310027China

The exploration of efficient,long-lived and cost-effective transition metal catalysts is highly desirable for the practical hydrogen storage of magnesium hydride(MgH_(2)) in sustainable energy ***,FeCoNiCrTi high-entropy alloy(HEA) nanosheets were prepared via a facile wet chemical ball milling strategy and they were introduced into MgH_(2) to boost the hydrogen storage *** refined HEA exhibited superior catalytic activity on MgH_(2).In contrast to additive-free MgH_(2),the initial desorption temperature of the constructed MgH_(2)-HEA composite was reduced from 330.0 to 198.5℃ and a remarkable 51% reduction in the dehydrogenation activation energy was ***,the MgH_(2)-HEA composite only required one-twentieth time of that consumed by pure MgH_(2) to absorb 5.0 wt% of H_(2) at 225℃.The synergy between the "hydrogen pumping" effect of Mg_2Ni/Mg_2NiH_4 and Mg_2Co/Mg_2CoH_5 couples,as well as the good dispersion of Fe,Cr and Ti on the surface of MgH_(2) contributed to the enhanced de/hydrogenation performance of the MgH_(2)-HEA *** study furnishes important steering for the design and fabrication of multiple transition metal catalysts and may push the commercial application of magnesium-based hydrides one step forward.

关键词： Hydrogen storage Magnesium hydride High-entropy alloys Catalysis

YOLO-RLC: An Advanced Target-Detection Algorithm for Surface Defects of Printed Circuit Boards Based on YOLOv5

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Computers, Materials and Continua 2024年第3期80卷 4973-4995页

作者： Wang, Yuanyuan huang, Jialong Dipu, Md Sharid Kayes zhao, hu Gao, Shangbing Zhang, Haiyan Lv, Pinrong School of Computer and Software Engineering Huaiyin Institute of Technology Huai’an 223003 China huaiyin Institute of Technology Laboratory for Internet of Things and Mobile Internet Technology of Jiangsu Province Huai’an 223001 China Jiangsu Kesheng Xuanyi Technology Co. Ltd. Huai’an 223300 China

Printed circuit boards (PCBs) provide stable connections between electronic components. However, defective printed circuit boards may cause the entire equipment system to malfunction, resulting in incalculable losses. Therefore, it is crucial to detect defective printed circuit boards during the generation process. Traditional detection methods have low accuracy in detecting subtle defects in complex background environments. In order to improve the detection accuracy of surface defects on industrial printed circuit boards, this paper proposes a residual large kernel network based on YOLOv5 (You Only Look Once version 5) for PCBs surface defect detection, called YOLO-RLC (You Only Look Once-Residual Large Kernel). Build a deep large kernel backbone to expand the effective field of view, capture global information more efficiently, and use 1 × 1 convolutions to balance the depth of the model, improving feature extraction efficiency through reparameterization methods. The neck network introduces a bidirectional weighted feature fusion network, combined with a brand-new noise filter and feature enhancement extractor, to eliminate noise information generated by information fusion and recalibrate information from different channels to improve the quality of deep features. Simplify the aspect ratio of the bounding box to alleviate the issue of specificity values. After training and testing on the PCB defect dataset, our method achieved an average accuracy of 97.3% (mAP50) after multiple experiments, which is 4.1% higher than YOLOv5-S, with an average accuracy of 97.6% and an Frames Per Second of 76.7. The comparative analysis also proves the superior performance and feasibility of YOLO-RLC in PCB defect detection. Copyright © 2024 The Authors. Published by Tech Science Press.

关键词： Image coding

Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et_(3)NCH_(2)Cl]_(2)[MnBr_(4)]

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Chinese Chemical Letters 2024年第4期35卷 502-505页

作者： Yan Cheng hua-Peng Ruan Yan Peng Longhe Li Zhenqiang Xie Lang Liu Shiyong Zhang Hengyun Ye zhao-Bo hu Chaotic Matter Science Research Center Faculty of Materials Metallurgy and ChemistryJiangxi University of Science and TechnologyGanzhou 341000China College of Materials and Chemical Engineering Pingxiang UniversityPingxiang 337055China Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry Jiangxi University of Science and TechnologyGanzhou 341000China Key Laboratory of Jiangxi University for Functional Materials Chemistry School of Chemistry and Chemical EngineeringGannan Normal UniversityGanzhou 341000China

The application of multifunctional materials in various fields such as electronics and signal processors has attracted massive attention. Herein, a new organic-inorganic hybrid material [Et_(3)NCH_(2)Cl]_(2)[MnBr_(4)](1) is reported, which contains two organic amines cations and one [MnBr_(4)] tetrahedral ion. Compound 1 has a dielectric anomaly signal at 338 K, which proves its thermodynamic phase transition. The single crystal measurements at 200 K and 380 K show that the phase transition of compound 1 is caused by the thermal vibration of organic amine cations in the lattice. Moreover, compound 1 shows yellow-green luminescence under UV light irradiation. The magnetism measurements indicate that compound 1 shows switchable magnetic properties. This organic–inorganic material is a multifunctional material with dielectric, optical, and magnetic synergetic switchable effects, which expands a new direction for designing multifunctional materials.

关键词： Synergetic switchable effects Molecular materials Magnetism Dielectric Luminescence

WiFi Indoor Positioning and Tracking Algorithm Based on Compressive Sensing and Sage-husa Adaptive Kalman Filter

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Open Journal of Applied Sciences 2024年第2期14卷 379-390页

作者： Yingjie Sun Yi Zhong Congwei hu Ao Xiong hu zhao College of Railway Transportation Hunan University of Technology Zhuzhou China Jiangsu Shengtong Electric New Energy Technology Co. Ltd. Changsha China huazi Technology Co. Ltd. Changsha China

Aiming at the problem that the positioning accuracy of WiFi indoor positioning technology based on location fingerprint has not reached the requirements of practical application, a WiFi indoor positioning and tracking algorithm combining adaptive affine propagation (AAPC), compressed sensing (CS) and Kalman filter is proposed. In the off-line phase, AAPC algorithm is used to generate clustering fingerprints with optimal clustering effect performance;In the online phase, CS and nearest neighbor algorithm are used for position estimation;Finally, the Kalman filter and physical constraints are combined to perform positioning and tracking. By collecting a large number of real experimental data, it is proved that the developed algorithm has higher positioning accuracy and more accurate trajectory tracking effect.

关键词： WiFi Indoor Positioning Cluster Signal Recovery Trajectory Tracking

Graphene-loaded nickel−vanadium bimetal oxides as hydrogen pumps to boost solid-state hydrogen storage kinetic performance of magnesium hydride

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Transactions of Nonferrous Metals Society of China 2024年第8期34卷 2645-2657页

作者： Dong-qiang GAO Fu-ying WU Zhi ZHANG Zi-chuan LU Ren ZHOU hu zhao Liu-ting ZHANG School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China Instrumental Analysis Center Jiangsu University of Science and TechnologyZhenjiang 212003China School of Mechanical and Aerospace Engineering Nanyang Technological UniversitySingapore 639798Singapore

To modify the thermodynamics and kinetic performance of magnesium hydride(MgH_(2))for solid-state hydrogen storage,Ni_(3)V_(2)O_(8)-rGO(rGO represents reduced graphene oxide)and Ni_(3)V_(2)O_(8)nanocomposites were prepared by hydrothermal and subsequent heat *** beginning hydrogen desorption temperature of 7 wt.%Ni_(3)V_(2)O_(8)-rGO modified MgH_(2)was reduced to 208°C,while the additive-free MgH_(2)and 7 wt.%Ni_(3)V_(2)O_(8)doped MgH_(2)appeared to discharge hydrogen at 340 and 226°C,respectively.A charging capacity of about 4.7 wt.%H_(2)for MgH_(2)+7 wt.%Ni_(3)V_(2)O_(8)-rGO was achieved at 125°C in 10 min,while the dehydrogenated MgH_(2)took 60 min to absorb only 4.6 wt.%H_(2)at 215°*** microstructure analysis confirmed that the in-situ generated Mg_(2)Ni/Mg_(2)NiH4 and metallic V contributed significantly to the enhanced performance of MgH_(2).In addition,the presence of rGO in the MgH_(2)+7 wt.%Ni_(3)V_(2)O_(8)-rGO composite reduced particle aggregation tendency of Mg/MgH_(2),leading to improving the cyclic stability of MgH_(2)during 20 cycles.

关键词： hydrogen storage properties MgH_(2) graphene-loaded Ni−V bimetal oxides catalytic mechanism

One-step controlled electrodeposition nickel sulfides heterointerfaces favoring the desorption of hydroxyl groups for efficient hydrogen generation

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Rare Metals 2024年第9期43卷 4377-4386页

作者： Ru-Chun Li Xin-Yue Zhang Ze-Yue Qu Feng-Yi Liu Quan-Qing Xu zhao-Xia hu Jing-Wei Li Mohamed-Nawfal Ghazzal Jin-Li Yu Faculty of Chemistry and Chemical Engineering Yunnan Normal University Foshan Gaoke Hechuang Technology Co. Ltd. School of Chemistry and Chemical Engineering Guangzhou University Universite′Paris-Saclay UMR 8000 CNRSInstitut de Chimie Physique Department of Chemistry City University of Hong Kong

The heterointerface engineering involving different components or phases represents a desirable strategy for enhancing the sluggish kinetics of hydrogen evolution reaction （HER）.However,constructing desired heterointerfaces and elucidating the reaction mechanisms on the interface remains a considerable *** this work,we propose a straightforward electrochemical synthesis strategy to prepare the nickel sulfide-based heterointerfaces for *** mechanism of electrochemical synthesis is revealed,wherein metal-thiourea species can be formed at the cathode potential and subsequently oxidized to nickel sulfides at the anode *** this mechanism,a range of nickel sulfides,including NiS,Ni3S2/NiS,Ni/Ni3S2and Ni3S2,have been successfully synthesized by tuning the potential range of cyclic *** these,the obtained Ni3S2/NiS@CC（CC:carbon cloth） exhibits the smallest overpotential of84 mV at 10 mA·cm-2and high *** calculations further reveal that the combination of NiS and Ni3S2induces electron redistribution at the interface,and thus the Volmer process is effectively promoted with faster water dissociation and OH desorption ***,the simplicity method coupled with a clear synthesis mechanism and outstanding HER performance highlights its promising potential for practical applications.

关键词： Electrochemical synthesis Heterointerfaces Hydrogen evolution reaction OH desorption kinetics

High critical current density in Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12) electrolyte via interfacial engineering with complex hydride

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Rare Metals 2024年第2期43卷 692-701页

作者： Ying-Tong Lv Teng-Fei Zhang zhao-Tong hu Guang-Lin Xia Ze-Ya huang Zhen-hua Liu Li-hua Que Cai-Ting Yuan Fang-Qin Guo Takayuki Ichikawa Xue-Bin Yu College of Materials Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing210016China Centre for Hydrogenergy College of Materials Science and TechnologyNanjing University of Aeronautics and AstronauticsNanjing210016China Department of Materials Science Fudan UniversityShanghai200433China Graduate School of Advanced Science and Engineering Hiroshima University1-4-1 KagamiyamaHigashi-Hiroshima739-8527Japan

Garnet-type solid-state batteries(SSBs)are considered to be one of the most promising candidates to realize next-generation lithium metal batteries with high energy density and ***,the dendrite-induced short-circuit and the poor interfacial contact impeded the practical ***,interface engineering to achieve low interfacial resistance without high temperature calcination was developed,which Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO)was simply coated with complex hydride(Li_(4)(BH_(4))_(3)I(3L1L))in various mass ratios n(Li_(4)(BH_(4))_(3)I)-(100−n)LLZTO(10≤n≤40).The interfacial conductivity increases by more than three orders of magnitude from 8.29×10^(−6)S·cm^(−1)to 1.10×10^(−2)S·cm^(−1).Symmetric Li cells exhibit a high critical current density(CCD)of 4.0 mA·cm^(−2) and an excellent cycling stability for 200 h at 4.0 mA·cm^(−2).SSBs with polymeric sulfur-polyacrylonitrile(SPAN)cathode achieve a high discharge capacity of 1149 mAh·g^(−1) with a capacity retention of 91%after 100 cycles(0.2 C).This attempt guides a simple yet efficient strategy for obtaining a stable Li/LLZTO interface,which would promote the development of solid-state batteries.

关键词： Hydrides Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO) Critical current density Solid-state electrolytes(SSEs) Lithium-sulfur batteries

A Wnt10a-Notch signaling axis controls Hertwig's epithelial root sheath cell behaviors during root furcation patterning

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International Journal of Oral Science 2024年第03期 425-435页

作者： Kai Sun Miao Yu Jiayu Wang hu zhao Haochen Liu Hailan Feng Yang Liu Dong Han Department of Prosthodontics Peking University School and Hospital of Stomatology & National Center for Stomatology & National Clinical Research Center for Oral Diseases & National Engineering Research Center of Oral Biomaterials and Digital Medical Devices Chinese Institute for Brain Research

human with bi-allelic WNT10A mutations and epithelial Wnt10a knockout mice present enlarged pulp chamber and apical displacement of the root furcation of multi-rooted teeth, known as taurodontism; thus, indicating the critical role of Wnt10a in tooth root morphogenesis. However, the endogenous mechanism by which epithelial Wnt10a regulates Hertwig's epithelial root sheath（HERS） cellular behaviors and contributes to root furcation patterning remains unclear. In this study, we found that HERS in the presumptive root furcating region failed to elongate at an appropriate horizontal level in K14-Cre;Wnt10afl/flmice from post-natal day 0.5（PN0.5） to PN4.5. EdU assays and immunofluorescent staining of cyclin D1 revealed significantly decreased proliferation activity of inner enamel epithelial（IEE） cells of HERS in K14-Cre;Wnt10afl/flmice at PN2.5 and PN3.5. Immunofluorescent staining of E-Cadherin and acetyl-α-Tubulin demonstrated that the IEE cells of HERS tended to divide perpendicularly to the horizontal plane,which impaired the horizontal extension of HERS in the presumptive root furcating region of K14-Cre;Wnt10afl/flmice. RNA-seq and immunofluorescence showed that the expressions of Jag1 and Notch2 were downregulated in IEE cells of HERS in K14-Cre;Wnt10afl/flmice. Furthermore, after activation of Notch signaling in K14-Cre;Wnt10afl/flmolars by Notch2 adenovirus and kidney capsule grafts,the root furcation defect was partially rescued. Taken together, our study demonstrates that an epithelial Wnt10a-Notch signaling axis is crucial for modulating HERS cell proper proliferation and horizontal-oriented division during tooth root furcation morphogenesis.

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