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Reversed charge transfer induced by nickel in Fe-ni/Mo_(2)C@nitrogen-doped carbon nanobox for promoted reversible oxygen electrocatalysis

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Journal of Energy Chemistry 2024年第1期88卷 202-212,I0005页

作者： Zhicheng nie Lei zhang Qiliang Zhu Zhifan Ke Yingtang Zhou Thomas wågberg Guangzhi Hu School of Materials Science and Engineering Anhui University of Science and TechnologyHuainan 232001AnhuiChina institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental ScienceYunnan UniversityKunming 650504YunnanChina national Engineering Research Center for Marine Aquaculture Marine Science and Technology CollegeZhejiang Ocean UniversityZhoushan 316004ZhejiangChina Department of Physics UmeåUniversityUmeåS-90187Sweden

The interaction between metal and support is critical in oxygen catalysis as it governs the charge transfer between these two entities,influences the electronic structures of the supported metal,affects the adsorption energies of reaction intermediates,and ultimately impacts the catalytic *** this study,we discovered a unique charge transfer reversal phenomenon in a metal/carbon nanohybrid ***,electrons were transferred from the metal-based species to n-doped carbon,w.ile the carbon support reciprocally donated electrons to the metal domain upon the introduction of *** led to the exceptional electrocatalytic performances of the resulting ni-Fe/Mo_(2)C@nitrogen-doped carbon catalyst,with a half-wave potential of 0.91 V towards oxygen reduction reaction(ORR)and a low overpotential of 290 m V at 10 mA cm^(-2)towards oxygen evolution reaction(OER)under alkaline ***,the Fe-ni/Mo_(2)C@carbon heterojunction catalyst demonstrated high specific capacity(794 mA h g_(Zn)~(-1))and excellent cycling stability(200 h)in a Zn-air *** calculations revealed that Mo_(2)C effectively inhibited charge transfer from Fe to the support,w.ile secondary doping of ni induced a charge transfer reversal,resulting in electron accumulation in the Fe-ni alloy *** local electronic structure modulation significantly reduced energy barriers in the oxygen catalysis process,enhancing the catalytic efficiency of both ORR and ***,our findings underscore the potential of manipulating charge transfer reversal between the metal and support as a promising strategy for developing highly-active and durable bi-functional oxygen electrodes.

关键词： Metal-support interaction Charge transfer reversal Oxygen reduction reaction Oxygen evolution reaction Zinc-air battery

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A core-satellite self-assembled SERS aptasensor containing a“biological-silent region”Raman tag for the accurate and ultrasensitive detection of histamine

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Food Science and Human wellness 2024年第2期13卷 1029-1039页

作者： Chen Chen Yingfang zhang Ximo w.ng Xuguang Qiao Geoffrey i.n.waterhouse Zhixiang Xu Key Laboratory of Food Processing Technology and Quality Control in Shandong Province College of Food Science and EngineeringShandong Agricultural UniversityTai’an 271018China School of Chemical Sciences The University of AucklandAuckland 1142New Zealand

Herein,a novel interference-free surface-enhanced Raman spectroscopy(SERS)strategy based on magnetic nanoparticles(MnPs)and aptamer-driven assemblies was proposed for the ultrasensitive detection of histamine.A core-satellite SERS aptasensor was constructed by combining aptamer-decorated Fe_(3)O_(4)@Au MnPs(as the recognize probe for histamine)and complementary DnA-modified silver nanoparticles carrying 4-mercaptobenzonitrile(4-MBn)(Ag@4-MBn@Ag-c-DnA)as the SERS signal probe for the indirect detection of *** an applied magnetic field in the absence of histamine,the assembly gave an intense Raman signal at“Raman biological-silent”region due to *** the presence of histamine,the Ag@4-MBn@Ag-c-DnA SERS-tag was released from the Fe_(3)O_(4)@Au MnPs,thus decreasing the SERS *** optimal conditions,an ultra-low limit of detection of 0.65×10^(-3)ng/mL and a linear range 10^(-2)-10^5 ng/mL on the SERS aptasensor were *** histamine content in four food samples were analyzed using the SERS aptasensor,with the results consistent with those determined by high performance liquid *** present work highlights the merits of indirect strategies for the ultrasensitive and highly selective SERS detection of small biological molecules in complex matrices.

关键词： Surface-enhanced Raman spectroscopy Raman biological-silent region Aptamer Histamine detection Universal SERS-tag

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Detecting fake reviewers in heterogeneous networks of buyers and sellers:a collaborative training-based spammer group algorithm

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Cybersecurity 2024年第2期7卷 44-67页

作者： Qi zhang Zhixiang Liang Shujuan Ji Benyong Xing Dickson K.w.Chiu Shandong Provincial Key Laboratory of wisdom Mine information Technology Shandong University of Science and TechnologyQingdao 266590ShandongChina Zhejang University-University of linois at Urbana-Champaign institute Haining 314499ZhejiangChina School of Civil Engineering Beijing Jiaotong UniversityBeijing 100044China Faculty of Education The University of Hong KongPok Fu LamHong KongChina

it is not uncommon for malicious sellers to collude with fake reviewers(also called spammers)to w.ite fake reviews for multiple products to either demote competitors or promote their products'reputations,forming a gray industry *** detect spammer groups in a heterogeneous network with rich semantic information from both buyers and sellers,researchers have conducted extensive research using Frequent item Mining-based and graph-based ***,these methods cannot detect spammer groups with cross-product attacks and do not jointly consider structural and attribute features,and structure-attribute correlation,resulting in poorer detection ***-fore,we propose a collaborative training-based spammer group detection algorithm by constructing a heterogene-ous induced sub-network based on the target product set to detect cross-product attack spammer *** jointly consider all available features,we use the collaborative training method to learn the feature representations of *** addition,we use the DBSCAn clustering method to generate candidate groups,exclude innocent ones,and rank them to obtain spammer *** experimental results on real-world datasets indicate that the overall detection performance of the proposed method is better than that of the baseline methods.

关键词： Spammer group Heterogeneous network Collaborative training DBSCAn

Developing a two-decadal time-record of rice field maps using Landsat-derived multi-index image collections with a random forest classifier:A Google Earth Engine based approach

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information Processing in Agriculture 2024年第2期11卷 260-275页

作者： w.Ashane M.Fernando i.P.Senanayake Department of nano Science Technology Wayamba University of Sri LankaKuliyapitiya 60200Sri Lanka Dchoolf Engineing CllegeoEngineeringSience and EnionmentThe UniversyewcastleCallaghanW2Austraia

Historic maps show.ng the temporal distribution of rice fields are important for precision agriculture,irrigation optimisation,forecasting crop yields,land use management and formulating ***,mapping rice felds using traditional ground surveys is impractical when high cost,time and labour requirements are considered,and the availability of such detailed records is *** satellite remote sensing appears to be a viable solution,conventional segmentation and classification methods with spectral bands are often unable to contrast the distinct characteristics between rice fields and other vegetation *** this end,we explored a novel,Google Earth Engine(GEE)based multiindex random forest(RF)classification approach to map rice fields over two *** images from 2000 to 2020 of two Sri Lankan rice cultivation districts were extracted from GEE and a multi-index RF classification algorithm was applied to distinguish the rice *** results showed above 80%accuracy for both training and validation,when compared against high spatial resolution Google Earth *** essence,multi-index sampling and RF together synergised the compelling classifcation accuracy by effectively capturing vegetation,water(ponding)and soil characteristics unique to the rice felds using a single-click *** maps developed in this study were further compared against the MODiS land cover type product(MCD12Q1)and the corresponding superior statistics on rice fields demonstrated the robustness of the proposed *** work seeking effective index combinations is recommended,and this approach can potentially be extended to other crop analyses elsewhere.

关键词： Google Earth Engine(GEE) image classification Random forest Mapping rice fields Time series analysis Vegetation index

Charge qubits based on ultra-thin topological insulator films

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Frontiers of physics 2024年第3期19卷 71-81页

作者： Kexin zhang Hugo V.Lepage Ying Dong Crispin H.w.Barnes Research Center for Quantum Sensing Intelligent Perception Research InstituteZhejiang LabHangzhou 311121China Cavendish Laboratory Department of PhysicsUniversity of CambridgeCambridge CB30HEUnited Kingdom

we study how to use the surface states in a Bi2Se3 topological insulator ultra-thin film that are affected by finite size effects for the purpose of quantum *** demonstrate that:(i)surface states under the finite size effect can effectively form a two-level system where their energy levels lie in between the bulk energy gap and a logic qubit can be constructed,(ii)the qubit can be initialized and manipulated using electric pulses of simple forms,(iii)two-qubit entanglement is achieved through a√SwAP operation when the two qubits are in a parallel setup,and(iv)alternatively,a Floquet state can be exploited to construct a qubit and two Floquet qubits can be entangled through a Controlled-nOT *** Floquet qubit offers robustness to background noise since there is always an oscillating electric field applied,and the single qubit operations are controlled by amplitude modulation of the oscillating field,w.ich is convenient experimentally.

关键词： topological insulator quantum computing nanodevices

Superplasticity of fine-grained Mg-10Li alloy prepared by severe plastic deformation and understanding its deformation mechanisms

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Journal of Magnesium and Alloys 2024年第1期12卷 316-331页

作者： H.T.Jeong S.w.Lee w.J.Kim Department of Materials Science and Engineering Hongik UniversityMapo-guSangsu-dong 72-1Seoul 121-791Republic of Korea

The superplastic behavior and associated deformation mechanisms of a fine-grained Mg-10.1 Li-0.8Al-0.6Zn alloy(LAZ1011)with a grain size of 3.2μm,primarily composed of the BCCβphase and a small amount of the HCPαphase,were examined in a temperature range of 473 K to 623 *** microstructural refinement of this alloy was achieved by employing high-ratio differential speed *** best superplasticity was achieved at 523 K and at strain rates of 10^(-4)-5×10^(-4)s^(-1),where tensile elongations of 550±600%were *** the heating and holding stage of the tensile samples prior to tensile loading,a significant increase in grain size was observed at temperatures above 573 ***,it was important to consider this effect when analyzing and understanding the superplastic deformation behavior and *** the investigated strain rate range,the superplastic flow at low strain rates was governed by lattice diffusion-controlled grain boundary sliding,w.ile at high strain rates,lattice diffusion-controlled dislocation climb creep was the rate-controlling deformation *** was concluded that solute drag creep is unlikely to *** the late stages of deformation at 523 K,it was observed that grain boundary sliding led to the agglomeration of theαphase,resulting in significant strain *** mechanism maps were constructed forβ-Mg-Li alloys in the form of 2D and 3D formats as a function of strain rate,stress,temperature,and grain size,using the constitutive equations for various deformation mechanisms derived based on the data of the current tests.

关键词： Magnesium-lithium alloy Superplasticity Severe plastic deformation Grain size Grain growth

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Microstructure evolution and shape memory behaviors of ni_(47)Ti_(44)nb_(9)alloy subjected to multistep thermomechanical loading with different prestrain levels

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Journal of Materials Science & Technology 2024年第4期171卷 80-93页

作者： Y.H.zhang H.Li Z.w.Yang X.Liu Q.F.Gu State Key Laboratory of Solidification Processing School of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072China Shaanxi Key Laboratory of High-Performance Precision Forming Technology and Equipment Northwestern Polytechnical UniversityXi’an 710072China

ni_(47)Ti_(44)nb_(9)shape memory alloy(SMA)is a promising material in the aerospace field due to its wide transformation *** application of shape memory effect depends on multistep thermomechan-ical loading,viz.,low-temperature deformation and subsequent heating to ***-temperature deformation prestrain plays a pivotal role in shape memory properties tailoring of SMA ***,microstructure evolution and deformation mechanisms of ni_(47)Ti_(44)nb_(9)SMA subjected to vari-ous prestrain levels are still *** this end,microstructure evolution and shape memory behaviors of ni_(47)Ti_(44)nb_(9)alloy subjected to multistep thermomechanical loading with prestrain levels of 8%-16%at-28℃(M_(s)+30℃)were *** results demonstrate that the stress-strain curve of the specimen exhibits four distinct stages at a maximal prestrain of 16%.whereas stageⅡand stageⅢend at prestrains of∼8%and∼12%,*** stageⅡ,the stress-induced martensitic transformation is accompanied by the dislocation slip of the niTi matrix andβ-nb *** stageⅢ,in addition to the higher density of dislocations and further growth of stress-induced martensite variants(SiMVs),(001)compound tw.ns are introduced as a result of the(001)deformation tw.nning in stress-induced ***{20-1}martensite tw.ns are gradually introduced in stageⅣ.Correspondingly,after subsequent unloading and heating,a higher density ofnaustenite tw.ns form in the specimen with a larger prestrain of 16%.with increasing prestrain from 8%to 16%,the recoverable strainε_(re)^(T)upon heating increases first and then ***ε_(re)^(T)obtains a maximum of 7.03%at 10%prestrain and de-creases to 6.17%at 16%*** increase ofε_(re)^(T)can be attributed to the formation of new SiMVs,the further growth of existing SiMVs,and the recoverable(001)compound *** the decrease ofε_(re)^(T)is mainly associated with the irrecoverable strain by{20−1}martensite *** effe

关键词： ni_(47)Ti_(44)nb_(9)shape memory alloy wide transformation hysteresis Thermomechanical loading Microstructure evolution Shape memory behaviors Stress-induced martensitic transformation Deformation tw.nning

Sb3+ and Sm3+ co-doped lead-free Cs2nainCl6 double perovskite nanocrystals for single-component cold w.ite emitter

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Journal of Rare Earths 2024年第9期42卷 1646-1651页

作者： Biao Zhou Xiangtong zhang Ranran Hu Ruixue Hou william w.Yu Key Laboratory for Special Functional Materials of Ministry of Education National & Local Joint Engineering Research Centre for High-Efficiency Display and Lighting Technology School of Materials and EngineeringCollaborative Innovation Centre of Nano Functional Materials and ApplicationsHenan University School of Chemistry and Chemical Engineering Shandong University

Metal halide perovskites exhibit promising prospect in light-emitting diodes,solar cells,photodetectors and ***,the workhorse of metal halide perovskites relies on toxicity lead element,w.ich severely damages human body and *** lead-free perovskites,Cs2nainCl6double perovskite is one of the most promising candidates because of its great stability and easy synthesis,but suffers inadequate optical ***,we doped Sb3+and Sm3+into Cs2nainCl6nanocrystals by a hot injection ***2nainCl6:Sb3+exhibits blue emission at 447 ***2nainCl6:Sm3+,Sb3+nanocrystals simultaneously generate the blue emission of Sb3+and the multiple emissions of Sm3+at 565,602,650 and 710 *** the increase of Sm3+feed ratio,the emission color of Cs2nainCl6:Sm3+,Sb3+gradually moves to cold w.ite region at（0.27,0.28） in CiE chromaticity diagram and correlated color temperature of 11840 *** work shows the potential application of Cs2nainCl6:Sm3+,Sb3+nanocrystals as a single-component cold w.ite emitter.

关键词： Lead-free Double perovskites Single component w.ite emitter Doping Rare earths

Pervasive Attentive neural network for intelligent image Classification Based on n-CDE’s

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Computers, Materials & Continua 2024年第4期79卷 1137-1156页

作者： Anas w.Abulfaraj Department of information Systems Faculty of Computing and Information TechnologyKing Abdulaziz UniversityRabigh21911Saudi Arabia

The utilization of visual attention enhances the performance of image classification *** attentionbased models have demonstrated notable performance,but many of these models exhibit reduced accuracy when confronted with inter-class and intra-class similarities and ***-Controlled Differential Equations(n-CDE’s)and neural Ordinary Differential Equations(nODE’s)are extensively utilized within this ***’s possesses the capacity to effectively illustrate both inter-class and intra-class similarities and differences with enhanced *** this end,an attentive neural network has been proposed to generate attention maps,w.ich uses two different types of n-CDE’s,one for adopting hidden layers and the other to generate attention *** distinct attention techniques are implemented including time-wise attention,also referred to as bottom n-CDE’s;and element-wise attention,called topn-CDE’***,a trainingmethodology is proposed to guarantee that the training problem is sufficiently *** classification tasks including fine-grained visual classification andmulti-label classification,are utilized to evaluate the *** proposedmethodology is employed on five publicly available datasets,including CUB-200-2011,imagenet-1K,PASCAL VOC 2007,PASCAL VOC 2012,and MS *** obtained visualizations have demonstrated that n-CDE’s are better appropriate for attention-based activities in comparison to conventional nODE’s.

关键词： Differential equations neural-controlled DE image classification attention maps n-CDE’s