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Solvation structure design for stabilizing MXene in transition metal ion solutions

SusMat 2024年第3期4卷 214-226页

作者： Jie Wang Guohao Li Guanshun xie Zhaohui Huang Peng zhang Benhua Xu Xiuqiang xie Nan zhang College of Materials Science and Engineering Hunan UniversityChangshaChina Qinghai Provincial Engineering Research Center of High-Performance Light Metal Alloys and Forming Qinghai Provincial Key Laboratory of New Light AlloysQinghai UniversityXiningChina Chemical Engineering College Qinghai UniversityXiningChina

Although MXene has attracted great interest in diverse fields,it is susceptible to oxidation in water(H_(2)O)with transition metal ions such as Co^(2+),Fe^(2+),and Cu^(2+),which is pronounced at high *** impedes the preparation of MXene-based composites and their functional ***,this study revealed that Co^(2+)increases the maximum and average atomic charge of H in H_(2)O to improve the reactivity of H_(2)O,which leads to the fact that Co^(2+)catalyzes the oxidation of Ti_(3)C_(2)T_(x)***,the addition of N,Ndimethyl formamide(DMF)reduces theH_(2)Oactivity and improves the oxidation stability of Ti_(3)C_(2)T_(x)in the presence of Co^(2+)via preferentially forming coordination bonds with Co^(2+).This strategy is also effective in enhancing the oxidation tolerance of Ti_(3)C_(2)T_(x)to Fe^(2+)in H_(2)***,it is feasible to enhance the oxidation stability of Ti2CTx MXene in H_(2)O with the existence of Co^(2+).By virtue of these,the CoO/Ti_(3)C_(2)T_(x)composite was successfully prepared without obvious Ti_(3)C_(2)T_(x)oxidation,which is desirable to harness the advantages of Ti_(3)C_(2)T_(x)as the complementary component for lithium-ion *** work provides a straightforward paradigm to enhance the oxidation resistance of MXene in H_(2)O in the presence of transition metal ions and at high temperatures,which opens a new vista to use MXene for target applications.

关键词： hydrogen bonds N N-dimethyl formamide solvation structure stability Ti_(3)C_(2)T_(x)MXene transition metal ions

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Regularly Tuning Quantum Interference in Single-Molecule Junctions through Systematic Substitution of Side Groups with Varied Electron Effects

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Chinese Journal of Chemistry 2024年第11期42卷 1217-1222页

作者： Xianjing xie Yirong zhang Junrui zhang Xingyuan Cui Wei Liu Xunshan Liu Key Laboratory of Surface&Interface Science of Polymer Materials of Zhejiang Province School of Chemistry and Chemical EngineeringZhejiang Sci-Tech University928 Second StreetHangzhouZhejiang310018 China State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchunJilin130022 China School of Materials Science and Engineering Nanjing University of Science and TechnologyNanjingJiangsu210094 China

Investigating the quantum interference effect in single molecules is essential to comprehensively understand the underlying mechanism of single-molecule charge *** this study,we employed the mother molecule m-OPE and introduced a series of side groups with various electronic effects at the 2-position of the central phenyl ring,creating four daughter m-OPE *** single molecular conductivities of these molecule wires were measured using the scanning tunneling microscope breaking junction *** findings demonstrate that the substitutions regularly modulate the destructive quantum interference occurring within the m-OPE *** combining optical and electrochemical investigations,along with density functional theory computations,we discover that the conductivity of the molecules corresponds to the electron-donating/withdrawing ability of the ***,by adjusting the electron structures of the molecular backbone,we can systematically tailor the destructive quantum interference in the m-OPE molecules.

关键词： Quantum interference Single-molecule junctions Electron effect substituents Charge transport Molecular devices

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Regulating the intrinsic electronic structure of carbon nanofibers with high-spin state Ni for sodium storage with high-power density

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Journal of Materials Science & Technology 2024年第4期171卷 16-23页

作者： Zhijia zhang Gang xie Yuefang Chen Yanhao Wei Mengmeng zhang Shulei Chou Yunxiao Wang Yifang zhang Yong Jiang School of Materials Science and Engineering Institute of Quantum Materials and DevicesState Key Laboratory of Separation Membrane and Membrane ProcessesTiangong UniversityTianjin 300387China Institute for Carbon Neutralization College of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325035China Institute for Superconducting and Electronic Materials University of WollongongWollongongNSW 2522Australia

Carbon nanofibers(CNFs)with high specific surface area show great potential for sodium storage as a hard carbon ***,CNFs anchored with Ni nanoparticles(CNFs/Ni)were prepared through chemical vapor deposition and impregnation reduction methods,in situ growing on the three-dimensional porous copper current collector(3DP-Cu).The coupling effect of high-spin state Ni nanopar-ticles leads to the increase of defect density and the expansion of lattice spacing of ***,the 3DP-Cu ensures a high loading capacity of CNFs and short ion/electron transport *** an integral binder-free anode,the 3DP-Cu/CNFs/Ni exhibits excellent electrochemical performance,which demon-strates a high specific capacity with 298.5 mAh g^(-1)at 1000 mA g^(-1)after 1500 cycles,and a high power density with 200 mAh g^(-1)over 1000 cycles at 5000 mA g^(-1).Density functional theory calculation re-sults show that the high-spin state Ni regulates the electronic structure of CNFs,which significantly reduces the adsorption energy for Na^(+)(-2.7 Ev)and thus enables high-rate *** regulation of the electronic structure of carbon materials by high-spin state metal provides a new strategy for developing high-power carbonaceous anode materials for sodium-ion batteries.

关键词： Carbon nanofibers Ni nanoparticles High-spin state Sodium-ion batteries Anode materials Density functional theory calculation

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Biomimetic porous silicon oxycarbide ceramics with improved specific strength and efficient thermal insulation

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Journal of Materials Science & Technology 2024年第1期168卷 185-193页

作者： Zhuoqing zhang Jinghan Li Lei Cao Yu Shi Huajie Yang Rui Yang Fan xie Xing zhang Shi-changxu Innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of Materials Science and Engineering University of Science and Technology of ChinaHefei 230026China School of Materials Science and Engineering Shenyang Ligong UniversityShenyang 110159China Shenyang Aircraft Design and Research Institute Shenyang 110035China

Considering the challenge of aerodynamic heating,the development of high-performance insulating ce-ramic materials with lightweight and low thermal conductivity is crucially important for aerospace vehi-cles to achieve flight at high speed for a long *** this work,macro-porous silicon oxycarbide(SiOC)ceramics with directional pores(DP-SiOC)(mean pore size of 88.1μm)were prepared using polysiloxane precursors via freeze casting and photocrosslinking,followed by *** DP-SiOC samples were lightweight(density∼0.135 g cm^(-3))with a porosity of 90.4%,which showed good shapability through the molding of polysiloxane *** DP-SiOC samples also exhibited an ultra-low thermal con-ductivity of 0.048 W(m K)^(-1)at room temperature,which can also withstand heat treatment at 1200°C for 1 *** addition,scaffolds with triply periodic minimal surfaces(TPMS)were fabricated using digital light processing(DLP)printing,which was further filled with polysiloxane precursors for increasing the strength of *** TPMS scaffolds filled with macro-porous SiOC ceramics(TPMS-DP-SiOC)showed good integration between TPMS and macro-pore structures,which had a porosity∼75%and high specific strength of 9.73×10^(3)N m kg^(-1).The thermal conductivity of TPMS-DP-SiOC samples was 0.255 W(m K)^(-1)at room *** biomimetic TPMS-DP-SiOC ceramics developed in this study are likely used for thermal protection systems.

关键词： Thermal insulation Light weight Macro-porous ceramics SiOC

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Mesenchymal stem cell-derived exosomes: Versatile nanomaterials for skin wound treatment

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Nano Research 2024年第4期17卷 2836-2856页

作者： Yuzhen Xiao Hexi Li Junhui zhang Songyun Yang Chunsen zhang Yizhou Huang Xin Tang Huiqi xie Department of Orthopedic Surgery and Orthopedic Research Institute Laboratory of Stem Cell and Tissue EngineeringState Key Laboratory of BiotherapyWest China HospitalSichuan UniversityChengdu 610041China West China School of Basic Medical Sciences and Forensic Medicine Sichuan UniversityChengdu 610041China West China School of Public Health and West China Fourth Hospital Sichuan UniversityChengdu 610041China Sports Medicine Center West China HospitalSichuan UniversityChengdu 610041China

Accumulating studies reveal that mesenchymal stem cells(MSCs)promote skin wound healing mainly through the paracrine ***,one of the crucial paracrine mediators in wound healing,are cell-derived nanosized membranous vesicles containing diverse bioactive *** the potent ability of modulating skin cell behaviors,MSC-derived exosomes(MSC-Exos)are regarded as a promising nanomaterial for regenerative wound *** hostile conditions,MSC-Exos are efficient in protecting skin cells from severe damage and restoring their *** to recent studies,MSC-Exos possess remarkable pro-healing effects in a variety of skin wounds,typically resulting in increased wound closure,inhibited scar tissue formation,and better restoration of skin *** further enhance the therapeutic potential of MSC-Exos,the development of applicable pretreatment strategies and the optimization of exosome delivery are under intensive ***,we summarize current research progress of MSC-Exos for skin wound treatment,with an emphasis on the biological effects of these nanovesicles,the repair mechanisms,and future challenges in clinical translation.

关键词： exosomes mesenchymal stem cells diabetic wounds burn wounds scar wound healing

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Investigating the effect of volatility on the hygroscopicities of acetate nanoparticle aerosols by surface plasmon resonance microscopy

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Journal of Environmental Sciences 2024年第4期138卷 167-178页

作者： Bo Yang Zhibo xie Jianguo Liu Huaqiao Gui Jiaoshi zhang Xiuli Wei Zetao Fan Douguo zhang Key Laboratory of Environmental Optics and Technology Anhui Institute of Optics and Fine MechanicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China University of Science and Technology of China Hefei 230026China CAS Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Advanced Laser Technology Laboratory of Anhui Province Department of Optics and Optical EngineeringUniversity of Science and Technology of ChinaHefei 230026China

Under high relative humidity(RH)conditions,the release of volatile components(such as acetate)has a significant impact on the aerosol *** this work,one surface plasmon resonance microscopy(SPRM)measurement system was introduced to determine the hygroscopic growth factors(GFs)of three acetate aerosols separately or mixed with glucose at different *** Ca(CH_(3)COO)_(2) or Mg(CH_(3)COO)_(2) aerosols,the hygroscopic growth trend of each time was lower than that of the previous time in three cyclic humidification from 70% RH to 90% RH,which may be due to the volatility of acetic acid leading to the formation of insoluble hydroxide(Ca(OH)_(2) or Mg(OH)_(2))under high RH *** the third calculated GF(using the Zdanovskii-Stokes-Robinson method)for Ca(CH_(3)COO)_(2) or Mg(CH_(3)COO)_(2) in bicomponent aerosols with 1:1 mass ratio were 3.20% or 5.33% lower than that of the first calculated GF at 90% *** calculated results also showed that the hygroscopicity change of bicomponent aerosol was negatively correlated with glucose content,especially when the mass ratio of Mg(CH_(3)COO)_(2) to glucose was 1:2,the GF at 90% RH only decreased by4.67% after three cyclic *** coupled plasma atomic emission spectrum(ICP-AES)based measurements also indicated that the changes of Mg^(2+)concentration in bicomponent was lower than that of the *** results of this study reveal thatduring the efflorescence transitions of atmospheric nanoparticles,the organic acids diffusion rate may be inhibited by the coating effect of neutral organic components,and the particles aging cycle will be prolonged.

关键词： Hygroscopic growth Volatility Acetate aerosols Nanoparticle aerosol Surface plasmon resonance

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Variations and future projections of glacial discharge of Urumqi River Headwaters,eastern Tien Shan(1980s-2017)

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Advances in Climate Change Research 2024年第3期15卷 537-546页

作者： Hui zhang Fei-Teng WANG Ping ZHOU Yi-Da xie State Key Laboratory of Cryospheric Science Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China Key Laboratory of Cryospheric Science and Frozen Soil Engineering Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China

To address data scarcity on long-term glacial discharge and inadequacies in simulating and predicting hydrological processes in the Tien Shan,this study analysed the observed discharge at multiple timescales over 1980se2017 and projected changes within a representative glacierized high-mountain region:eastern Tien Shan,Central *** processes were simulated to predict changes under four future scenarios(SSP1,SSP2,SSP3,and SSP5)using a classical hydrological model coupled with a glacier dynamics *** rates at annual,monthly(June,July,August)and daily timescales were obtained from two hydrological gauges:Urumqi Glacier No.1 hydrological station(UGH)and Zongkong station(ZK).Overall,annual and summer discharge increased significantly(p<0.05)at both stations over the study *** intra-annual variations mainly resulted from differences in their recharge *** simulations show that a tipping point in annual discharge at UGH may occur between 2018 and 2024 under the four SSPs *** discharge is predicted to cease earlier at ZK than at *** relates to glacier type and size,suggesting basins with heavily developed small glaciers will reach peak discharge sooner,resulting in an earlier freshwater supply *** findings serve as a reference for research into glacial runoff in Central Asia and provide a decision-making basis for planning local water-resource projects.

关键词： Observed glacial discharge Temporal variations Urumqi River Headwaters Eastern Tien Shan Simulation and projection

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Dynamic Coupling Analysis of Semisubmersible Platform Float-over Method for Docking Case

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Journal of Ocean University of China 2024年第2期23卷 345-357页

作者： DING Hongyan QIN Licheng zhang Puyang SONG Zhengrong xie Weiwei State Key Laboratory of Hydraulic Engineering Simulation and Safety Tianjin UniversityTianjin 300072China Offshore Oil Engineering Co. Ltd.Tianjin 300461China

In this paper,the multi-body coupled dynamic characteristics of a semisubmersible platform and an HYSY 229 barge were ***,coupled hydrodynamic analysis of the HYSY 229 barge and the semisubmersible platform was *** hydrodynamic parameters were obtained using the retardation function method of three-dimensional frequency-domain potential flow *** results of the hydrodynamic analysis were highly consistent with the test findings,verifying the accuracy of the multifloating hydrodynamic coupling analysis,and key hydrodynamic parameters were solved for different water depths and the coupling *** to the obtained results,the hydrodynamic influence was the largest in shallow waters when the coupling effect was ***,the coupled motion equation combined with viscous damping,fender system,and mooring system was established,and the hydrodynamics,floating body motion,and dynamic response of the fender system were *** analysis revealed good agreement among the surge,sway,and yaw motions of the two floating ***,when the wave period reached 10 s,the motion of the two floating bodies showed severe shock,and a relative motion was also ***,excessive constraints should be added between the two floating bodies during construction to ensure construction *** numerical analysis and model test results of the semisubmersible platform and HYSY 229 barge at a water depth of 42 m and sea conditions of 0°,45°,and 90° were in good agreement,and the error was less than 5%.The maximum movement of the HYSY 229 barge reached 2.61 m in the sway direction,whereas that of the semisubmersible platform was 2.11 *** construction,excessive constraints should be added between the two floating bodies to limit their relative movement and ensure construction safety.

关键词： float-over method semisubmersible platform coupling hydrodynamic fender system time-domain analysis

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A review of rock macro-indentation:Theories,experiments,simulations,and applications

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第6期16卷 2351-2374页

作者： Weiqiang xie Xiaoli Liu Xiaoping zhang Xinmei Yang Xiaoxiong Zhou State Key Laboratory of Hydroscience and Engineering Tsinghua UniversityBeijing100084China Yunlong Lake Laboratory of Deep Underground Science and Engineering Xuzhou221116China State Key Laboratory of Water Resources and Hydropower Engineering Science Wuhan UniversityWuhan430072China

Rock macro-indentation plays a fundamental role in mechanical rock breaking for various rock engineering application,such as drilling,tunneling,cutting,and *** the past decades,extensive research has been conducted to understand the indentation mechanisms and responses through various *** review aims to provide an overview of the current status and recent advancements in theories,experiments,numerical simulations,and applications of macro-indentation in rock *** starts with elaborating on the mechanisms of macro-indentation,followed by a discussion of the merits and limitations of commonly used *** factors and their effects on indentation test results are then *** numerical simulation methods for rock macro-indentation are highlighted,along with their advantages and ***,the applications of indentation tests and indentation indices in characterizing rock properties are *** reveals that compression-tension,compression-shear,and composite models are widely employed in rock *** the compression-tension model is straightforward to use,it may overlook the anisotropic properties of *** the other hand,the composite model provides a more comprehensive description of rock indentation but requires complex ***,factors,such as indentation rate,indenter geometry,rock type,specimen size,and confining pressure,can significantly influence the indentation *** methods for macro-indentation encompass continuous medium,discontinuous medium,and continuous-discontinuous medium methods,with selection based on their differences in ***,rock macro-indentation can be practically applied to mining engineering,tunneling engineering,and petroleum drilling *** indices serve as valuable tools for characterizing rock strength,brittleness,and *** review sheds light on the development of rock macro-inde

关键词： Rock macro-indentation Indentation test Indentation indices Mechanism Rock breaking

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Study on metal recovery process and kinetics of oxidative leaching from spent LiFePO_(4)Li-batteries

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Chinese Journal of Chemical Engineering 2024年第4期68卷 94-102页

作者： Xiaoming zhang Wen xie Xiaolei Zhou Wenjie zhang Jiawei Wen Xin Wang Guoyong Huang Shengming Xu College of New Energy and Materials China University of PetroleumBeijing 102249China State Key Laboratory of Heavy Oil Processing College of Chemical EngineeringChina University of PetroleumBeijing 102249China Beijing Spacecrafts Beijing 100094China Ganfeng Lithium Group Co. Ltd.Xinyu 338000China Institute of Nuclear and New Energy Technology Tsinghua UniversityBeijing 100084China Beijing Key Laboratory of Fine Ceramics Tsinghua UniversityBeijing 100084China

A green environmental protection and enhanced leaching process was proposed to recover all elements from spent lithium iron phosphate(LiFePO_(4)) lithium *** order to reduce the influence of Al impurity in the recovery process,NaOH was used to remove *** impurity removal,the spent LiFePO_(4) cathode material was used as raw material under the H_(2)SO_(4) system,and the pressure oxidation leaching process was adopted to achieve the preferential leaching of *** E-pH diagram of the Fe-P-Al-H_(2)O system can determine the stable region of each element in the recovery process of spent LiFePO_(4)*** the optimal conditions(500 r·min^(-1),15 h,363.15 K,0.4 MPa,the liquid-solid ratio was 4:1 ml·g^(-1)and the acid-material ratio was 0.29),the leaching rate of Li was 99.24%,Fe,Al,and Ti were 0.10%,2.07%,and 0.03%,*** Fe and P were precipitated and recovered as FePO_(4)·2H_(2)*** kinetic analysis shows that the process of high-pressure acid leaching of spent LiFePO_(4) materials depends on the surface chemical *** the life cycle assessment(LCA)of the spent LiFePO_(4) whole recovery process,eight midpoint impact categories were selected to assess the impact of recovery *** results can provide basic environmental information on production process for recycling industry.

关键词： Spent LiFePO_(4)Li-batteries Oxidative leaching Kinetic study Life cycle assessment

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