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Microscopic and spectroscopic analysis of atmospheric iron-containing single particles in Lhasa,Tibet

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Journal of Environmental Sciences 2024年第7期141卷 40-50页

作者： Junyu Chen Daobin zhang Yiran Fu Jinhu Wang Xiaomei Cui Ci-ren Qu-zong Qiangying zhang Chan Jin Bu Duo School of Ecology and Environment Tibet UniversityLhasa 850000China Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China Institute of Tibetan Plateau Research Chinese Academy of SciencesBeijing 100101China

The Tibetan Plateau,known as the“Third Pole”,is currently in a state of perturbation caused by intensified human *** this study,56 samples were obtained at the five sampling sites in typical area of Lhasa city and their physical and chemical properties were investigated by TEM/EDS,STXM,and NEXAFS *** careful examination of 3387single particles,the results showed that Fe should be one of the most frequent metal *** Fe-containing single particles in irregular shape and micrometer size was about7.8%and might be mainly from local ***,the Fe was located on the subsurface of single particles and might be existed in the form of iron ***,the core-shell structure of iron-containing particles were about 38.8%and might be present as single-,dual-or triple-core shell structure and multi-core shell structure with the Fe/Si ratios of 17.5,10.5,2.9 and 1.2,***,iron and manganese were found to coexist with identical distributions in the single particles,which might induce a synergistic effect between iron and manganese in catalytic ***,the solid spherical structure of Fe-containing particles without an external layer were about 53.4%.The elements of Fe and Mn were co-existed,and might be presented as iron oxide-manganese oxide-silica ***,the ferrous and ferric forms of iron might be *** information can be valuable in expanding our understanding of Fe-containing particles in the Tibetan Plateau atmosphere.

关键词： Fe-containing single particle Irregular shape Core-shell structure Solid spherical structure Transmission electron microscopy Synchrotron X-ray microscopy

Melatonin decreases GSDME mediated mesothelial cell pyroptosis and prevents peritoneal fibrosis and ultrafiltration failure

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Science China(Life Sciences) 2024年第2期67卷 360-378页

作者： hongxia Ruan Xuejuan Li Lina Zhou Zihan Zheng Rulin Hua Xu Wang Yuan Wang Yujie Fan Shuwen Guo Lihua Wang Shafiq ur Rahman Ziwei Wang Yuyuan wei Shuangyan Yu Rongzhi zhang Qian Cheng Jie Sheng Xue Li Xiaoyan Liu Ruqiang Yuan Xiaoyan zhang Lihong Chen Guowang Xu Youfei Guan Jing Nie hongqiang Qin Feng Zheng Advanced Institute for Medical Sciences Dalian Medical UniversityDalian 116044China Department of Nephrology Second HospitalDalian Medical UniversityDalian 116023China CAS Key Laboratory of Separation Science for Analytical Chemistry Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China Chongqing International Institute for Immunology Chongqing 401320China Department of Nephrology Shenzhen HospitalSouthern Medical UniversityShenzhen 518101China Wuhu Hospital and Health Science Center East China Normal UniversityShanghai 200241China Peking University First Hospital Peking UniversityBeijing 100034China

Peritoneal fibrosis together with increased capillaries is the primary cause of peritoneal dialysis *** cell loss is an initiating event for peritoneal *** find that the elevated glucose concentrations in peritoneal dialysate drive mesothelial cell pyroptosis in a manner dependent on caspase-3 and Gasdermin E,driving downstream inflammatory responses,including the activation of ***,pyroptosis is associated with elevated vascular endothelial growth factor A and C,two key factors in vascular angiogenesis and lymphatic vessel *** deficiency mice are protected from high glucose induced peritoneal fibrosis and ultrafiltration *** of melatonin abrogates mesothelial cell pyroptosis through a MT1R-mediated action,and successfully reduces peritoneal fibrosis and angiogenesis in an animal model while preserving dialysis ***,melatonin treatment maintains mitochondrial integrity in mesothelial cells,meanwhile activating m TOR signaling through an increase in the glycolysis product dihydroxyacetone *** effects together with quenching free radicals by melatonin help mesothelial cells maintain a relatively stable internal environment in the face of high-glucose ***,Melatonin treatment holds some promise in preserving mesothelium integrity and in decreasing angiogenesis to protect peritoneum function in patients undergoing peritoneal dialysis.

关键词： melatonin mitochondria pyroptosis GSDME peritoneal fibrosis mTOR

智能汽车SINS/GNSS动态组合导航观测模型系统误差自适应估计方法

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中国公路学报 2024年第7期37卷 280-290页

作者：魏文辉袁伟张逸凡长安大学汽车学院陕西西安710064

为了满足当前汽车智能化发展对导航定位精度的更高需求,解决车辆非线性动态组合导航定位过程中,因观测模型偏差导致的定位精度下降问题,结合自适应滤波原理,提出了一种新的非线性动态组合导航系统观测模型系统误差自适应估计方法,用于... 详细信息

为了满足当前汽车智能化发展对导航定位精度的更高需求,解决车辆非线性动态组合导航定位过程中,因观测模型偏差导致的定位精度下降问题,结合自适应滤波原理,提出了一种新的非线性动态组合导航系统观测模型系统误差自适应估计方法,用于抑制观测模型系统误差对滤波估计精度的影响,克服现有误差估计方法的缺陷和不足,提升车辆动态组合导航定位精度。首先,利用预测观测协方差矩阵和新息信息构造自适应因子,提出了一种自适应无迹卡尔曼滤波算法(AUKF),通过自适应调整状态预测和观测信息的权重抑制异常观测对动态导航系统的影响。随后,在考虑观测模型系统误差影响的情况下,对非线性导航系统模型进行改进,并在此基础上将提出的AUKF扩展用于估计和补偿观测模型系统误差,以提高系统状态估计精度。最后,将提出的自适应估计方法应用于搭载SINS/GPS非线性组合定位系统的车辆在环山路的跑车试验中,分别从考虑和不考虑观测模型系统误差影响2个方面对算法性能进行验证,并与其他滤波方法进行对比分析。试验结果表明:与现有方法相比,提出的方法不仅能够控制异常观测对非线性导航系统的影响,而且能够有效地估计和补偿观测模型系统误差,因此具有较好的滤波解算精度;定位精度小于0.46 m,即使在系统误差干扰情况下,定位精度仍然达到0.50 m,在抑制观测模型系统误差干扰方面显著优于其他滤波方法,且算法简单易行,在精度和实时性方面达到了更佳的平衡。

关键词：汽车工程高精度导航定位多源融合导航自适应估计观测模型系统误差智能汽车

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富春江水库浮游植物功能群变化的成因

环境科学 2024年第1期45卷 181-193页

作者：张萍王炜朱梦圆国超旋邹伟许海朱广伟中国科学院南京地理与湖泊研究所湖泊与环境国家重点实验室南京210008 杭州市生态环境局淳安分局杭州311700

为探究富春江水库浮游植物群落结构的演替特征、水华风险机制及关键影响因素,分别于2020年8月和11月与2021年1月和4月在富春江库区及上下游11个断面采样分析浮游植物、浮游动物群落结构及相关理化指标,对浮游植物进行功能群(FG)分类,并... 详细信息

为探究富春江水库浮游植物群落结构的演替特征、水华风险机制及关键影响因素,分别于2020年8月和11月与2021年1月和4月在富春江库区及上下游11个断面采样分析浮游植物、浮游动物群落结构及相关理化指标,对浮游植物进行功能群(FG)分类,并应用非度量多维尺度分析(NMDS)和冗余分析(RDA)等统计方法探讨功能群变化的影响因素.结果发现,富春江水库浮游植物可分为18个功能类群,其中10个为优势类群;功能群的组成存在显著时空差异:空间上,库区上游江段主要以小环藻(Cyclotella)为代表的C类群和以沟链藻(Aulacoseira)为代表的P类群占优,与该江段中富营养混合水体的环境特征相符;富春江库区仍以P类群为主,但沿程优势度逐渐减小;库区下游江段MP类群逐渐占优,且在钱塘江口占据绝对优势,反映了感潮河流扰动频繁、浊度较高的环境特征;季节上,夏季功能群类型最为丰富,为P+L0+J+M+S1+H1+MP型,除了全年都占优的沟链藻为代表的P类群,还包括多个以蓝藻和绿藻为代表的类群,反映出生境多变、生产力旺盛的水环境特征;秋季演替以长孢藻(Dolichospermum)为代表的H1类群占优,总体为P+H1,反映了水量减少、流态趋于静止的水环境特征;冬季小环藻的突增,C类群占据优势,总体为P+C,反映出换水减弱、富营养化加剧的环境条件变化;而春季类群又逐渐丰富,为C+D+P+MP,也反映出降雨增多、气温升高引起的河流生境多变的环境背景特征.根据C-R-S生长策略分析,R策略类群是富春江水库浮游植物的主导类群,与富春江流域各江段高干扰、低胁迫的总体生境特征吻合.RDA分析表明,水温、浮游动物生物量、高锰酸盐指数、流量、总氮和总磷与浮游植物功能群组成显著相关(P<0.05),温度和流态是影响富春江水库浮游植物功能群时空差异的主导因素,浮游动物是影响浮游植物功能群时空差异的关键因素.研究表明,水文气象过程对富春江流域浮游植物群落结构影响至关重要,夏季高温季节流态变化可能是诱发富春江库区蓝藻水华的关键因子;降低藻类水华的风险,应在河流氮磷负荷控制的基础上,充分考虑水利调度的协同控制.

关键词：浮游植物功能群流态气温河流型水库浮游动物

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Type one autoimmune pancreatitis based on clinical diagnosis: A case report

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World Journal of Clinical Cases 2024年第14期12卷 2438-2444页

作者： Bi-Yu zhang Mou-Wang Liang Shuang-Xi zhang Department of Gastroenterology Guangzhou University of Chinese Medicine Shunde HospitalFoshan 528300Guangdong ProvinceChina Department of Gastroenterology Guangzhou University of Chinese MedicineGuangzhou 510006Guangdong ProvinceChina

BACKGROUND Autoimmune pancreatitis(AIP)is a rare form of autoimmune-mediated pancrea-titis,which is easily misdiagnosed as pancreatic cancer and thus treated *** studied the diagnosis and treatment of a patient with type 1 AIP recent-ly admitted to our hospital,and reviewed the literature to provide a reference for clinical diagnosis of *** SUMMARY The chief complaint was yellowing of the body,eyes and urine for 21 *** pa-tient's clinical presentation was obstructive jaundice and imaging suggested pan-creatic *** was difficult to distinguish between inflammation and *** immunoglobulin G4(IgG4)was markedly ***4 is an important serological marker for type 1 *** patient was diagnosed with AIP,IgG4-related cholangitis,acute cholecystitis and hepatic *** applying hormonal therapy,the patient's symptoms improved *** the same time,imaging suggested that pancreatic swelling subsided,and liver function and other biochemical indicators *** treatment was *** In patients with pancreatic swelling,the possibility of AIP should be considered.

关键词： Autoimmune pancreatitis Characteristics Diagnosis Immunoglobulin G4 Case report

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基于多丸粒模型的喷丸表面强化过程数值模拟

塑性工程学报 2012年第6期19卷 118-125页

作者：张洪伟陈家庆张以都北京石油化工学院机械工程学院北京102617 北京航空航天大学机械工程及自动化学院北京100191

针对喷丸表面强化过程,利用有限元法,建立了均匀分布的多丸粒喷丸强化数值模型,研究了喷丸速度、连续冲击及二次冲击弹丸速度对于目标靶体内残余应力场的影响;利用多丸粒偏置建模法,建立不同覆盖率的多丸粒仿真模型,研究喷丸覆盖率、连... 详细信息

针对喷丸表面强化过程,利用有限元法,建立了均匀分布的多丸粒喷丸强化数值模型,研究了喷丸速度、连续冲击及二次冲击弹丸速度对于目标靶体内残余应力场的影响;利用多丸粒偏置建模法,建立不同覆盖率的多丸粒仿真模型,研究喷丸覆盖率、连续冲击对于残余应力场的影响,对比了两种多丸粒喷丸模型。结果表明,提高喷丸速度可增加残余压应力层深度,但对残余应力最大幅值没有显著影响;连续冲击引起残余应力的饱和,残余应力分布没有明显变化;后续冲击弹丸的速度对于残余应力场有明显的影响;偏置高覆盖率喷丸强化模型可获得较均匀分布的残余应力场,压应力最大幅值与喷丸覆盖率及作用区域有关。

关键词：喷丸有限元残余应力冲击覆盖率

Intelligent Predetermination of Generator Tripping Scheme: Knowledge Fusion-based Deep Reinforcement Learning Framework

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CSEE Journal of Power and Energy Systems 2024年第1期10卷 66-75页

作者： Lingkang Zeng wei Yao Ze Hu Hang Shuai Zhouping Li Jinyu Wen Shijie Cheng State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronics EngineeringHuazhong University of Science and TechnologyWuhan 430074China Dispatching and Control Center Central China Branch of State Grid Corporation of ChinaWuhan 430077China. Department of Electrical Engineering and Computer Science University of TennesseeKnoxvilleTN 37996USA

Generator tripping scheme(GTS)is the most commonly used scheme to prevent power systems from losing safety and ***,GTS is composed of offline predetermination and real-time scenario ***,it is extremely time-consuming and labor-intensive for manual predetermination for a large-scale modern power *** improve efficiency of predetermination,this paper proposes a framework of knowledge fusion-based deep reinforcement learning(KF-DRL)for intelligent predetermination of ***,the Markov Decision Process(MDP)for GTS problem is formulated based on transient instability ***,linear action space is developed to reduce dimensionality of action space for multiple controllable ***,KF-DRL leverages domain knowledge about GTS to mask invalid actions during the decision-making *** can enhance the efficiency and learning ***,the graph convolutional network(GCN)is introduced to the policy network for enhanced learning *** simulation results obtained on New England power system demonstrate superiority of the proposed KF-DRL framework for GTS over the purely data-driven DRL method.

关键词： Deep reinforcement learning generator tripping scheme graph convolutional network invalid action masking knowledgefusion

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混凝土抗压强度的可解释深度学习预测模型

东北大学学报（自然科学版） 2024年第5期45卷 738-744,752页

作者：章伟琪王辉明新疆大学建筑工程学院新疆乌鲁木齐830017

为快速、准确地预测混凝土抗压强度,采用深度学习技术建立预测模型,使用贝叶斯优化算法进行模型自动优化调节,并结合SHapley Additive exPlanations(SHAP)可解释性方法对预测结果进行分析,以克服预测模型的“黑盒子”问题.利用深度学习... 详细信息

为快速、准确地预测混凝土抗压强度,采用深度学习技术建立预测模型,使用贝叶斯优化算法进行模型自动优化调节,并结合SHapley Additive exPlanations(SHAP)可解释性方法对预测结果进行分析,以克服预测模型的“黑盒子”问题.利用深度学习模型挖掘各输入特征参数与抗压强度之间潜在的规律;通过可视化输入特征参数的SHAP值分析参数对抗压强度预测结果的重要性及影响规律.结果表明,所建深度学习模型相比其他传统模型具有更好的性能;SHAP分析结果与试验结果一致,该模型较好地反映了各特征参数之间复杂的非线性关系,可为混凝土材料的工程设计提供依据和参考.

关键词：混凝土抗压强度深度学习 SHAP方法可解释性

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Effects of conductive agent type on lithium extraction from salt lake brine with LiFePO_(4) electrodes

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International Journal of Minerals,Metallurgy and Materials 2024年第4期31卷 678-687页

作者： Zhen zhang Pan Luo Yan zhang Yuhan Wang Li Liao Bo Yu Mingshan Wang Junchen Chen Bingshu Guo Xing Li School of New Energy and Materials Southwest Petroleum UniversityChengdu 610500China Energy Storage Research Institute Southwest Petroleum UniversityChengdu 610500China

Electrochemical lithium extraction from salt lakes is an effective strategy for obtaining lithium at a low ***,the elevated Mg:Li ratio and the presence of numerous coexisting ions in salt lake brines give rise to challenges,such as prolonged lithium extraction periods,diminished lithium extraction efficiency,and considerable environmental *** this work,Li FePO4(LFP)served as the electrode material for electrochemical lithium *** conductive network in the LFP electrode was optimized by adjusting the type of conductive *** approach resulted in high lithium extraction efficiency and extended cycle *** the single conductive agent of acetylene black(AB)or multiwalled carbon nanotubes(MWCNTs)was replaced with the mixed conductive agent of AB/MWCNTs,the average diffusion coefficient of Li+in the electrode increased from 2.35×10^(-9)or 1.77×10^(-9)to 4.21×10^(-9)cm^(2)·s^(-1).At the current density of 20 mA·g^(-1),the average lithium extraction capacity per gram of LFP electrode increased from 30.36 mg with the single conductive agent(AB)to 35.62 mg with the mixed conductive agent(AB/MWCNTs).When the mixed conductive agent was used,the capacity retention of the electrode after 30 cycles reached 82.9%,which was considerably higher than the capacity retention of 65.8%obtained when the single AB was ***,the electrode with mixed conductive agent of AB/MWCNTs provided good cycling *** the conductive agent content decreased or the loading capacity increased,the electrode containing the mixed conductive agent continued to show excellent electrochemical ***,a self-designed,highly efficient,continuous lithium extraction device was *** electrode utilizing the AB/MWCNT mixed conductive agent maintained excellent adsorption capacity and cycling performance in this *** work provides a new perspective for the electrochemical extraction of lithium using LFP electrodes.

关键词： salt lake brine lithium extraction electrochemical lithium extraction conductive agent extraction efficiency adsorption capacity