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Study on Single-fiber Pull-out Method for Evaluating Interfacial Strength in CFRP

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high Tech.ology Letters 1995年第1期1卷 105-108页

作者： Yudong, h. zh.qian, zh. lixun, L. Qiwei, L. harbin Inst of Tech.ology Harbin China

Single-fiber pull-out testing (SFPoT) methods are frequently used to evaluate the interfacial adhesion between fiber and matrix in composite materials. To make such pull-out measurements, however, the length.of embedded fiber must be small enough so that the fiber does not break before it is pulled freely. This is difficult to achieve by conventional methods with fibers of small diameter, such as the carbon fibers. In this paper, a fiber pull-out experiment is described. Specialized apparatus in our laboratory, as well as this technique for sample preparation are discussed in detail. The interfacial shear strength.of carbon fiber/resin matrix composites is analyzed quantitatively by using the finite-element method. The SFPoT system has been proved to be an available means for the study of interfacial properties for carbon fiber/resin matrix composites.

关键词： Carbon fiber Composite materials Interfacial shear strength Single-fiber pull-out

Design of a cationic accelerator enabling ultrafast ion diffusion kinetics in aqueous zinc-ion batteries

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Journal of Energy Chemistry 2025年第1期100卷 377-384页

作者： Yawei Xiao Qianqian Gu h.oyu li Mengyao li Yude Wang National Center for International Research.on Photoelectric and Energy Materials School of Materials and Energy Yunnan University Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources School of Chemistry and Chemical Engineering Hainan University College of Chemical Engineering Fuzhou University Yunnan Key Laboratory of Carbon Neutrality and Green Low-carbon Tech.ologies Yunnan University

Aqueous zinc-ion batteries are highly favored for grid-level energy storage owing to their low cost and high safety,but their practical application is limited by slow ion *** address this,a strategy has been developed to create a cation-accelerating electric field on the surface of the cathode to achieve ultrafast Zn2+diffusion *** employing electrodeposition to coat MoS2on the surface of BaV6o16·3h.o nanowires,the directional built-in electric field generated at the heterointerface acts as a cation accelerator,continuously accelerating Zn2+diffusion into the active *** optimized Zn2+diffusion coefficient in CC@BaV-6o16·3h.o@MoS2(7.5×10～8cm2s-1) surpasses that of most reported V-based ***,MoS2serving as a cathodic armor extends the cycling life of the Zn-CC@BaV6o16·3h.o@MoS2full batteries to over 10000 *** work provides valuable insights into optimizing ion diffusion kinetics for high-performance energy storage devices.

关键词： Internal electric field Cationic accelerator Ion diffusion kinetics Cathode modification strategy Aqueous zinc ion battery

Selective De-o-acetylation in TCP-containing Carbohydrate Structures with Magnesium Methoxide

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Chinese Chemical Letters 2000年第11期11卷 941-944页

作者： Qin, zh.li, h Cai, MS li, ZJ Beijing Med Univ Sch Pharmaceut Sci Dept Bioorgan Chem Beijing 100083 Peoples R China

Magnesium methoxide can be used for TCP-containing substrates to remove acetyl group successfully while leaving the TCP-group virtually intact.

关键词： oCh TCP De

The W-11-4A Platform Comprehensive Strength Monitoring System

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China ocean Engineering 1998年第2期13卷 135-146页

作者： Shen, zh.li, h Xue, YI Chen, JC zh.o, Q Chinese Acad Sci Inst Mech Beijing 100080 Peoples R China Louisiana Tech Univ Appl & Computat Anal & Modeling Program Ruston LA 71272 USA Acad Sinica S China Sea Inst Oceanol Guangzhou 510301 Peoples R China

A comprehensive strength monitoring system used on a fixed jacket platform is presented in this paper. The long-term monitoring of W-11-4A platform achieved. Structural responses (strain and acceleration) at selected locations, as well as associated environmental parameters, have been obtained. The emphasis of the paper is placed on the system design, and the instrumentation and operation methodology employed in the monitoring of the structural responses. The performance of the system and the characteristic results obtained during its 13-month.operation are also summarized.

关键词： monitoring techniques comprehensive strength monitoring structural responses waterproof strain transducers underwater instrumentation techniques

Engineering atomic Rb-N configurations to tune radical pathways for highly selective photocatalytic h.o2 synthesis coupled with biomass valorization

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Journal of Energy Chemistry 2025年第1期100卷 215-225页

作者： Jiaye li Shuang Pan Yihuang Chen Qiong liu College of Chemistry and Materials Engineering Wenzhou University Guangdong Provincial Key Laboratory of Chemical Measurement and Emergency Test Tech.ology (China) Institute of Analysis Guangdong Academy of Sciences (China National Analytical CenterGuangzhou)

Photocatalytic oxygen reduction for hydrogen peroxide （h.o2） synthesis presents a green and costeffective production ***,achieving highly selective h.o2synthesis remains challenging,necessitating precise control over free radical reaction pathways and minimizing undesirable oxidative ***,we report for the visible light-driven simultaneous co-photocatalytic reduction of o2to h.o2and oxidation of biomass using the atomic rubidium-nitride modified carbon nitride（CNRb）.The optimized CNRb catalyst demonstrates a record photoreduction rate of 8.01 mM h-1for h.o2generation and photooxidation rate of 3.75 mM h-1for furfuryl alcohol to furoic acid,achieving a remarkable solar-to-chemical conversion （SCC） efficiency of up to 2.27%.Experimental characterizations and DFT calculation disclosed that the introducing atomic Rb–N configurations allows for the high-selective generation of superoxide radicals while suppressing hydroxyl free radical *** is because the Rb–N serves as the new alternative site to perceive a stronger connection position for o2adsorption and reinforce the capability to extract protons,thereby triggering a high selective redox product *** study holds great potential in precisely regulating reactive radical processes at the atomic level,thereby paving the way for efficient synthesis of h.o2coupled with biomass valorization.

关键词： Atomic economy Radical pathway regulation Rubidium atom coordination Biomass valorization

Correlation between the rock mass properties and maximum horizontal stress:A case study of overcoring stress measurements

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 39-48页

作者： Peng li Meifeng Cai Shengjun Miao Yuan li Yu Wang Key Laboratory of Ministry of Education for Efficient Mining and Safety of Metal Mines University of Science and Technology BeijingBeijing 100083China State Key Laboratory of Coal Resources and Safe Mining China University of Mining and TechnologyXuzhou 221116China

Understanding the mechanical properties of the lithologies is crucial to accurately determine the horizontal stress *** investigate the correlation between the rock mass properties and maximum horizontal stress,the three-dimensional(3D)stress tensors at 89 measuring points determined using an improved overcoring technique in nine mines in China were adopted,a newly defined characteristic parameter C_(ERP)was proposed as an indicator for evaluating the structural properties of rock masses,and a fuzzy relation matrix was established using the information distribution *** results indicate that both the vertical stress and horizontal stress exhibit a good linear growth relationship with *** is no remarkable correlation between the elastic modulus,Poisson's ratio and depth,and the distribution of data points is scattered and ***,there is no obvious relationship between the rock quality designation(RQD)and *** maximum horizontal stress σ_(h) is a function of rock properties,showing a certain linear relationship with the C_(ERP)at the same *** addition,the overall change trend of σ_(h) determined by the established fuzzy identification method is to increase with the increase of C_(ERP).The fuzzy identification method also demonstrates a relatively detailed local relationship betweenσ_h and C_(ERP),and the predicted curve rises in a fluctuating way,which is in accord well with the measured stress data.

关键词： overcoring stress measurements elastic modulus Poisson's ratio rock quality designation maximum horizontal stress fuzzy identification

Interfacial Zn2+-solvation regulator towards reversible and stable Zn anode

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Journal of Energy Chemistry 2025年第1期100卷 684-692页

作者： Miao zh.u Xiongbin Luo hang li Shan Guo zh.ang Tong Xiaotao zh.u Xu li zh.ohui hou Shuquan liang Guozh.o Fang College of Mechanical Engineering Key Laboratory of Hunan Province for Advanced Carbon-based Functional Materials Hunan Institute of Science and Technology Sch.ol of Materials Science and Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan Province Central South University College of Materials and Metallurgy Guizhou University National Energy Metal Resources and New Materials Key Laboratory Central South University

Aqueous zinc-ion batteries （AZIBs） are fundamentally challenged by the instability of the electrode/electrolyte interface,predominantly due to irreversible zinc （Zn） deposition and hydrogen ***,the intricate mechanisms behind the electrochemical discrepancies induced by interfacial Zn2+-solvation and deposition behavior demand comprehensive *** molecules endowed with special functional groups （such as hydroxyl,carboxyl,etc.） have the potential to significantly optimize the solvation structure of Zn2+and regulate the interfacial electric double layer （EDL）.By increasing nucleation overpotential and decreasing interfacial free energy,these functional groups facilitate a lower critical nucleation radius,thereby forming an asymptotic nucleation model to promote uniform Zn ***,this study presents a pioneering approach by introducing trace amounts of n-butanol as solvation regulators to engineer the homogenized Zn （h-Zn） anode with a uniform and dense *** interfacial reaction and structure evolution are explored by in/ex-situ experimental techniques,indicating that the h-Zn anode exhibits dendrite-free growth,no by-products,and weak hydrogen evolution,in sharp contrast to the bare ***,the h-Zn anode achieves a remarkable Zn utilization rate of approximately 20% and simultaneously sustains a prolonged cycle life exceeding 500 ***,the h-Zn//Nh4V4o10（NVo） full battery showcases exceptional cycle stability,retaining 95.04%capacity retention after 400 cycles at a large current density of 5 A *** study enlightens solvation-regulated additives to develop Zn anode with superior utilization efficiency and extended operational lifespan.

关键词： Aqueous zinc-ion batteries Interfacial reaction Asymptotic nucleation model Reversible and stable Zn anode

Constructive proof on the existence of periodic solution of Duffing equation

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Chinese Science Bulletin 1997年第22期42卷 1870-1874页

作者： li, WG Shen, zh Nanjing Univ Dept Math Nanjing 210093 Peoples R China

CoNSIDER the following boundary value problem of Duffing equation:{x(t)+Cx’(t)+g(t,x)=e(t), x(0)-x’(zπ)=x’(0)-x’(2π)=0,} (1)where g: R×R→R is continuous and continuously differentiable with respect to x, continu-ous and 2π-periodic with respect to t. C is a constant. e: R→R is continuous and 2π-period-ic. If there exist two almost everywhere continuous functions a(t), b(t)

关键词： Duffing equation periodic solution continuation.

SYNThESIS oF A 2-ARYLBENZoFURANoID DERIVATIVE

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Chinese Chemical Letters 1995年第4期6卷 289-292页

作者： Yan, zh.li, LN Beijing Union Med Coll Chinese Acad Med Sci Inst Mat Med Beijing 100050 Peoples R China

A derivative of 2-arylbenzofuranoid pattern fash.oned after the naturally occurring isolates from Salviamiltiorrhiza was synthesized by Perkin condensation and oxidative ring closure.

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