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Geology and Geochemistry of K-feldspar Veins in Lamprophyre at the Zhenyuan Gold Deposit,Yunnan,Southwest China:Implications for Gold Mineralization

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Acta Geologica Sinica(English Edition) 2024年第1期98卷 104-116页

作者： ZHANG Huichao CHAI Peng ZHANG Hongrui Zhou Limin hou zengqian Key Laboratory of Submarine Geosciences Second Institute of OceanographyMinistry of Natural ResourcesHangzhou 310012China Institute of Geology Chinese Academy of Geological SciencesBeijing 100037China Key Laboratory of Marine Hazards Forecasting Ministry of Natural ResourcesHohai UniversityNanjing 210024China National Research Center for Geoanalysis Beijing 100037China

Lamprophyres typically appear in hydrothermal gold *** relationship between lamprophyres and gold deposits is investigated *** researchers suggest that the emplacement of lamprophyres triggers gold mineralization,whereas others hypothesize that the formation of lamprophyres increases the fertility of mantle sources and ore-forming fluids.K-feldspar veins,with ages between those of lamprophyres and gold deposits,appear in lamprophyres in ***,K-feldspar veins are ideal for investigating the relationship between lamprophyres and gold *** in K-feldspar veins has lower Mg#,Ni,and Cr contents and higher TiO2,Li,Ba,Sr,Sc,Zr,Nb,and Cs contents than phlogopite in *** in-situ Sr isotopic values of apatites(0.7063–0.7066)in K-feldspar veins are within the range for apatites(0.7064–0.7078)from *** large-ion lithophile element concentrations and low Nb and Ta concentrations in phlogopite from lamprophyres,in addition to high(87Sr/86Sr)i values of apatite(0.7064–0.7078),indicate that the magma parental to these phlogopite and apatite crystals is derived from an enriched *** veins are genetically correlated with lamprophyres,whereas sulfide mineral assemblage and trace element compositions of pyrite in K-feldspar veins suggest that K-feldspar veins in lamprophyres are not directly related to gold mineralization of the Zhenyuan deposit.

关键词： lamprophyre K-feldspar vein apatite Sr isotope gold Zhenyuan deposit Yunnan

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碳酸岩研究进展

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岩石学报 2024年第3期40卷 1003-1022页

作者：尹淑苹谢玉玲侯增谦曲云伟北京科技大学土木与资源工程学院北京100083 中国地质科学院地质研究所北京100037

碳酸岩(carbonatite)一词自首次被提出至今已有一百多年的历史,它是一种神秘而颇具争议的岩石类型。碳酸岩富含碳酸盐矿物,通常与基性、超基性或碱性硅酸盐岩伴生形成碳酸岩-硅酸盐岩杂岩体,具有独特的化学成分和矿物学特征并具有承载... 详细信息

碳酸岩(carbonatite)一词自首次被提出至今已有一百多年的历史,它是一种神秘而颇具争议的岩石类型。碳酸岩富含碳酸盐矿物,通常与基性、超基性或碱性硅酸盐岩伴生形成碳酸岩-硅酸盐岩杂岩体,具有独特的化学成分和矿物学特征并具有承载重要经济矿床的能力。在过去的几十年里,碳酸岩的研究在岩石成因及岩浆起源、地球化学与地质年代学、高温高压实验、与碳酸岩相关的经济矿产、碳酸岩型稀土矿床中稀土元素的富集分异及成矿机理等领域取得了巨大进步。本文从碳酸岩的定义与分类、成岩背景与时空分布、岩石学特征及矿物组成、岩浆起源及演化过程以及与碳酸岩相关的矿产资源等方面对碳酸岩的研究进展进行了综述与评论,提出从成因角度探索碳酸岩分类方案的必要性,总结和梳理了我国目前发现的碳酸岩的产地和分布特征,并认为碳酸岩岩浆与硅酸盐岩浆演化具有差异性,应重视对碳酸岩岩浆演化过程中熔体-流体过渡阶段的研究。最后从文献计量学角度利用大数据和可视化手段对来自Scopus数据库的近十年以“carbonatite”为检索词的近千篇文献进行了可视化分析,总结归纳了碳酸岩现阶段的研究热点,并对未来碳酸岩的研究趋势进行了展望。

关键词：碳酸岩定义与分类时空分布岩石矿物学特征岩浆经济矿产

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埃达克岩与热液成矿过程中钾镁同位素分馏及其指示意义:以驱龙斑岩铜矿床为例

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地学前缘 2024年第3期31卷 150-169页

作者：字艳梅田世洪陈欣阳侯增谦杨志明龚迎莉唐清雨东华理工大学核资源与环境国家重点实验室江西南昌330013 东华理工大学地球科学学院江西南昌330013 自然资源部深地科学与探测技术实验室北京100094 华盛顿大学地球与空间科学系美国西雅图华盛顿98195 成都理工大学沉积与生物地球化学国际研究中心四川成都610059 中国地质科学院地质研究所北京100037 清华大学能源与动力工程系北京100084

为研究后碰撞埃达克质岩岩浆分异和热液过程中的钾镁同位素分馏行为及其对斑岩铜矿床岩石成因的指示意义,本文对藏南驱龙斑岩铜矿床的一套埃达克质岩石开展了钾镁同位素分析。该套岩石包括闪长质包体、花岗闪长岩和花岗斑岩,后者是超大... 详细信息

为研究后碰撞埃达克质岩岩浆分异和热液过程中的钾镁同位素分馏行为及其对斑岩铜矿床岩石成因的指示意义,本文对藏南驱龙斑岩铜矿床的一套埃达克质岩石开展了钾镁同位素分析。该套岩石包括闪长质包体、花岗闪长岩和花岗斑岩,后者是超大型斑岩铜矿床的成矿母岩。已有研究结果证实,这3套岩石很可能是由同一来源的不同程度的部分熔融和分离结晶作用形成的。研究结果表明,闪长质包体、花岗闪长岩和花岗斑岩的δ^(41)K组成分别为-0.38‰~-0.22‰、-0.43‰~-0.34‰和-0.59‰~-0.36‰。尽管3类岩石各自变化范围较小,但整体上δ^(41)K与K 2O和SiO_(2)含量呈现明显负相关趋势,表明全岩钾元素迁移和钾同位素发生了解耦,钾同位素产生了分馏。在闪长质包体花岗闪长岩演化期间,δ^(41)K与Sc和Y含量呈明显正相关关系,这指示了在该演化期间可能主要是角闪石分离结晶导致了钾同位素分馏。相比之下,花岗斑岩中具有明显的钾同位素组成变化,在花岗斑岩演化期间,δ^(41)K与Eu/Eu*和Sr含量呈正相关关系,表明在岩石演化晚期钾同位素的分馏可能主要跟斜长石分离结晶有关。然而,通过瑞利分馏模拟表明仅矿物分离结晶难以实现如此大的钾同位素分馏,花岗斑岩中的钾同位素分馏是岩浆热液共同作用的结果。值得注意的是,闪长质包体具有比地幔更重的钾同位素组成,导致这种现象的原因可能是复杂多样的:一方面,下地壳可能具有比地幔更重的钾同位素组成,岩浆混合机制下导致源区具有重钾同位素组成;另一方面,驱龙斑岩铜矿床的岩浆源区受到俯冲板片来源的富重钾流体/熔体所交代,导致其源区的钾同位素组成偏重。相比之下,这3类岩石的镁同位素组成比较类似(闪长质包体:-0.36‰~-0.19‰;花岗闪长岩:-0.28‰~-0.13‰;花岗斑岩:-0.44‰~-0.13‰),并且落在了地幔和下地壳范围内。这3类岩石的δ^(26)Mg跟MgO和SiO_(2)含量之间不存在相关性,表明埃达克质岩浆分异过程中(角闪石和黑云母)也不产生镁同位素分馏,与前人对花岗岩中镁同位素分馏行为的结论相一致。作为典型的热液型矿床,藏南驱龙斑岩铜矿床和江西德兴斑岩铜矿床在热液蚀变过程中均产生了钾镁同位素分馏。德兴斑岩铜矿床大部分蚀变岩的钾镁同位素值都高于新鲜岩浆岩,具有显著的钾镁同位素组成变化;相比之下,驱龙斑岩铜矿床埃达克质岩岩石的钾镁同位素组成大部分位于岩浆岩基线值范围内,受热液蚀变作用影响不显著。此外,驱龙斑岩铜矿床花岗斑岩中铜大量富集,岩浆热液流体出溶是导致铜大量富集的主要原因,可能至少有两种不同性质(温度、盐度)的热液流体导致花岗斑岩中钾镁同位素组成局部波动变化,这些流体不仅改变了花岗岩斑岩的钾镁同位素组成,并且从高度演化的岩浆中提取金属元素,最终导致铜成矿。

关键词：驱龙斑岩铜矿床埃达克质岩石钾镁同位素同位素分馏岩浆热液流体出溶

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The Centennial Message:Retrospect and Outlook

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Acta Geologica Sinica(English Edition) 2022年第1期96卷 I0001-I0006页

作者： hou zengqian 不详

The year 2022 marks the 100;anniversary for the founding of the Geological Society of China(GSC),one of the oldest scientific societies in *** GSC was established to address a pressing need for like-minded people to e... 详细信息

关键词： Outlook Message knowledge

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Geochronology and Geochemistry of the Granite Xenolith within the Lamprophyre at the Zhenyuan Gold Deposit(Yunnan Province, SW China)

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Acta Geologica Sinica(English Edition) 2022年第2期96卷 477-489页

作者： ZHANG Huichao ZHANG Hongrui hou zengqian CHAI Peng Zhou Kai Institute of Marine Geology College of OceanographyHohai UniversityNanjing 210098China Institute of Geology Chinese Academy of Geological SciencesBeijing 100037China No.208 Team of Geological Survey China National Nuclear CorporationBaotouInner Mongolia 014000China

The xenoliths in host rocks of hydrothermal gold deposits can generally provide much geochemical information of the deep rocks, which may have an implication for the sources of ore-forming materials. Geochronology and geochemical characteristics are reported for a granite xenolith, which is enclosed by the lamprophyre in the Zhenyuan gold deposit(Yunnan Province, SW China). This granite xenolith mainly consists of K-feldspar, quartz, and plagioclase with trace amounts of magnetite, titanite, apatite, zircon, and sulfides. Zircons from the granite xenolith yield a weighted average U-Pb age of 281.1 ± 1.3 Ma(MSWD = 2.1), which could represent the crystallization age of this granite xenolith. The Ti-in-zircon geothermometer and the Mn concentration in apatite calculate that this granite xenolith formed at 685 ± 43℃ with the logf_(O2) values ranging from NNO + 3.7 to NNO + 6.4. The zircons in the granite xenolith have a restricted range of positive ε_(Hf)(t) values ranging from +9.4 to +10.8, and the corresponding Hf TDM2 model ages range from 588 to 678 Ma. The zircon U-Pb age and the Hf isotopic compositions indicate this granite xenolith within the lamprophyre is mainly derived from partial melting of juvenile crustal rocks before the completed closure of the Ailaoshan Ocean. The pyrites in the granite xenolith have higher Bi concentrations, and lower As, Sb, and Tl concentrations than the gold-bearing pyrites of the ores in the Zhenyuan gold deposit. The low Au concentrations of the pyrites together with the ore-forming age of the Zhenyuan gold deposit(Oligocene) indicate the granite xenolith may have limited contribution to the gold mineralization of the Zhenyuan gold deposit.

关键词： granite xenolith lamprophyre pyrite trace element concentrations Zhenyuan gold deposit

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Palynological constraints on the age of the Mississippi Valley-type Changdong Pb-Zn deposit,Sanjiang belt,West China

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Science China Earth Sciences 2022年第1期65卷 167-181页

作者： Yingchao LIU Yucai SONG zengqian hou Dangpeng XI Suping LI Longlong YUE Wang MA Bolang TANG Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resources Institute of GeologyChinese Academy of Geological SciencesBeijing 100037China School of Earth Science and Resources China University of Geosciences(Beijing)Beijing 100083China Jiangsu Nanjing Institute of Geo-Engineering Investigation Nanjing 210041China

Mississippi Valley-type(MVT)Pb-Zn deposits serve as the world’s major supply of Pb-Zn ***,the age constraint of MVT Pb-Zn deposits has long been a big challenge,due to the lack of minerals that are unequivocally related to ore deposition and that can be used for radioisotopic *** we show sporopollens can provide useful chronological information on the Changdong MVT Pb-Zn deposit in the Simao basin,Sanjiang belt,West *** Pb-Zn ores in the Changdong deposit are hosted by internal sediments in paleo-karst caves of meteoric *** and galena occur as replacements of carbonate minerals and void infillings in the internal *** relations suggest that the Pb-Zn mineralization occurred after the deposition of the internal sediments.A palynological assemblage mainly composed of angiosperm pollen dominated by Castanea,Quercus,and Carya and fern spores dominated by Polypodiaceae,Pteris,and Athyriaceae was *** pollen and spores place the ore-hosting internal sediments and the Changdong paleo-karst at early to middle ***,the Changdong Pb-Zn deposit must have formed after the early Oligocene(~34 Ma).These age constraints,together with the geological characteristics,indicate that the Changdong Pb-Zn deposit is a paleo-karst-controlled MVT deposit related to fold-thrust systems in the Sanjiang *** Changdong deposit is similar to other MVT Pb-Zn deposits in the northern part of the Sanjiang belt,making it possible to extend this Pb-Zn belt 500 km further to the *** presented here highlights the potential of sporopollens in dating the age of MVT deposits related to paleo-karst formation in young orogenic belts.

关键词： Mississippi Valley-type(MVT)Pb-Zn deposits Age constraint Palynomorphs Internal sediments Paleo-karst Changdong deposit Sanjiang fold-thrust belt

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Metallogenesis within continental collision zones: Comparisons of modern collisional orogens

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Science China Earth Sciences 2018年第12期61卷 1737-1760页

作者： Hongrui ZHANG zengqian hou Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resources Institute of Geology Chinese Academy of Geological Sciences

Modern collisional orogens represent the natural laboratory for the study of metallogeny in continental collision zones. The Pyrenees, Alps, Zagros and Himalaya are all associated with Neo-Tethyan subduction and represent the youngest collisional orogens on Earth. Here, we compare these four orogens in terms of their composition, architecture, tectonic evolution,and metallogenic systems. The four orogens can be divided into simple and composite types. Simple orogens are represented by the Pyrenees and the Alps, and are characterized by narrow linear shapes in plain view and symmetric structures in cross-section,are free of arc magmatism, and are associated with the Mississippi Valley Valley-type Pb-Zn and orogenic gold deposits. The mineral deposits that form in these simple collisional orogens are generally related to processes that occur in the middle and upper crust. In contrast, composite orogens, as exemplified by the Zagros-Iranian and Himalayan-Tibetan Plateaus, are associated with broad orogenic plateaus in plain view and asymmetrical structures in cross-section, record extensive arc magmatism in continental margins, and are associated with a variety of deposit types including carbonatite-related rare earth element(REE),porphyry Cu-Mo, orogenic Au, Mississippi Valley type Pb-Zn, and detachment-fault-related polymetallic deposits. Although the subduction of Neo-Tethys oceanic crust occurred before the creation of simple collisional orogens in the Pyrenees and the Alps,these areas do not show the record of continental arc magmatism. In contrast, the composite collisional orogens are associated with the development of huge continental margin arcs prior to continental subduction, and the subduction was followed by reactivation of the subduction-modified arc lithospheric material, generating the ore-forming systems in these regions.

关键词： Pyrenees Alps Zagros Himalaya Collisional orogeny Accretionary orogeny Collisional metallogenesis

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Hydrous Juvenile Lower Crust at the Western Yangtze Craton Margin as the Main Source of the Beiya Porphyry-skarn Au Deposit

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Acta Geologica Sinica(English Edition) 2022年第3期96卷 972-992页

作者： WANG Zixuan ZHENG Yuanchuan XU Bo hou zengqian ZHANG Aiping SHEN Yang MA Rui WU Changda XU Peiyan State Key Laboratory of Geological Processes and Mineral Resources and School of Earth Sciences and Resources China University of GeosciencesBeijing 100083China School of Gemmology China University of GeosciencesBeijing 100083China Institute of Geology Chinese Academy of Geological SciencesBeijing 100037China College of Resource Environment and Earth Sciences Yunnan UniversityKunming 650091China

The Beiya porphyry-skarn Au deposit is one of the largest gold deposits in China,temporally and spatially associated with Eocene intrusions in a post-collisional setting in western Yunnan,*** this study,we report new whole-rock geochemistry,Sr-Nd isotope,zircon U-Pb geochronology and in situ zircon Hf-O isotopes of quartz-monzonite and biotite-monzonite porphyries from the Beiya *** porphyry-skarn mineralization at the Beiya deposit is mainly associated with the quartz monzonite porphyry(35.8±0.6 Ma),while the biotite-monzonite porphyry(34.3±0.5 Ma)represents a post-mineralization intrusion crosscutting the main orebodies and the quartz-monzonite *** intrusions have high-K and adakitic composition and are characterized by high Sr/Y ratios,high SiO_(2)and Al_(2)O_(3)concentrations(SiO_(2)=69.80-73.86 wt%;Al_(2)O_(3)=14.11-15.19 wt%),and low MgO,Cr,and Ni concentrations(MgO=0.2-1.0 wt%;Cr=1.76-11.13 ppm;Ni=2.52-11.72 ppm).Their Sr-Nd isotope compositions(^(87)Sr/^(86)Sr=0.7066-0.7077;εNd(t)=−5.3 to−1.5)are consistent with the lower crustal-derived amphibolite xenoliths(^(87)Sr/^(86)Sr=0.7060-0.7100;εNd(t)=−10.0 to 0.0),indicating that they might be derived from a thickened juvenile lower crust beneath the Yangtze *** biotite-monzonite porphyry has lower zirconδ^(18)O values of+5.3‰to+6.8‰and higherεHf(t)values of−2.3 to+5.5 than those of the quartz-monzonite porphyry withδ^(18)O values of+7.1‰to+8.2‰andεHf(t)values of−3.8 to+1.5,implying that they were derived from different parts of the lower *** Ba/La and Pb/Ce ratios suggest that the quartz-monzonite porphyry is derived from a volatiles-rich *** higher La/Yb,Sm/Yb and Dy/Yb ratios of the biotite-monzonite porphyry indicate residual garnet in the source,indicating a deeper source than that of the quartz-monzonite *** hydrous components should be represented by the amphibole-rich lithologies,which has relatively shallower depth than that of the garnet-bea

关键词： Beiya Au deposit magma fertility adakitic intrusion juvenile lower crust western Yangtze Craton

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中亚成矿域西部早二叠世金、镍重大成矿事件

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矿床地质 2024年第4期43卷 749-784页

作者：薛春纪赵晓波赵云赵伟策莫宣学肖文交马华东朱炳玉 Nikolay Pak Bakhtiar Nurtaev 邓军侯增谦地质过程与矿产资源国家重点实验室中国地质大学地球科学与资源学院北京100083 新疆维吾尔自治区人民政府国家305项目办公室新疆乌鲁木齐830063 北京市矿产地质研究院有限责任公司北京100012 中国科学院新疆生态与地理研究所新疆矿产资源研究中心新疆乌鲁木齐830011 吉尔吉斯斯坦国家科学院地质研究所比什凯克720481 乌兹别克斯坦国立地质大学地质与地球物理研究所塔什干100041 中国地质科学院地质研究所自然资源部深地动力学重点实验室北京100037

晚古生代是地球历史上一个重要时期,蕴含着潘吉亚超大陆、规模最大冰期、最严重的生物大灭绝以及巨量矿产资源形成的关键信息。地处欧亚大陆腹地的中亚成矿域是全球最大的显生宙大陆增生区,以晚古生代大规模成矿为显著特色,尤其早二叠世... 详细信息

晚古生代是地球历史上一个重要时期,蕴含着潘吉亚超大陆、规模最大冰期、最严重的生物大灭绝以及巨量矿产资源形成的关键信息。地处欧亚大陆腹地的中亚成矿域是全球最大的显生宙大陆增生区,以晚古生代大规模成矿为显著特色,尤其早二叠世(270~290 Ma)在中亚成矿域西部天山及邻区巨量金、镍爆发性集中成矿作用,造就出世界第二大金成矿省,形成了超过10000 t金,造就出具有世界特色的造山带岩浆型镍矿集区,形成了包括8个大型-超大型矿床在内的东天山、额尔齐斯、北山3个重要镍矿床集中区,镍资源达250万t,是一次全球罕见的金-镍时间耦合重大成矿事件。文章基于最新研究成果,系统论述了中亚成矿域西部早二叠世金、镍大规模成矿的时空分布和基本地质特征,探讨了该重大成矿事件的区域动力学背景和可能成矿机制。研究认为,早二叠世金矿床产于天山古缝合带附近的脆/韧性构造变形带,构成独具特色的大陆变形带金成矿系统,已有成矿理论难以涵盖,含碳碎屑岩系、地块抬升导致的大规模区域变质作用、多来源的流体作用、多期构造活化富集、多种因素耦合叠加等,可能是大规模金成矿的关键条件;早二叠世镍矿床沿天山、北山、阿尔泰地区深大断裂附近的镁铁-超镁铁质岩体线性展布,是全球造山带镍成矿作用最强烈、发现矿床数量最多的地区,俯冲熔/流体的交代岩石圈地幔/软流圈发生高程度部分熔融、区域超壳深断裂为玄武质岩浆提供快速运移的通道、壳源物质加入触发硫化物熔离、硫化物与多幕脉动侵位的岩浆反应是造山带岩浆型镍大规模成矿的关键。整体上,中亚成矿域西部早二叠世金、镍重大成矿事件表现为“时间耦合、西金东镍”的时空格局,但大规模成矿的全球和区域动力学背景、金与镍富集机制及成矿响应机理还是未解之谜。

关键词：早二叠世大陆变形带金成矿系统造山带岩浆型镍成矿系统重大成矿事件中亚成矿域西部

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Geological and Fluid Inclusion Constraints on Gold Deposition Processes of the Dayingezhuang Gold Deposit, Jiaodong Peninsula, China

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Acta Geologica Sinica(English Edition) 2019年第4期93卷 955-971页

作者： CHAI Peng ZHANG Zhiyu hou zengqian Institute of Geology Chinese Academy of Geological ScienceBeijing 100037China

The Dayingezhuang gold deposit,hosted mainly by Late Jurassic granitoids on Jiaodong Peninsula in eastern China,contains an estimated 170 t of gold and is one of the largest deposits within the Zhaoping fracture *** orebodies consist of auriferous altered pyrite–sericite–quartz granites that show Jiaojia-type(i.e.,disseminated and veinlet)*** and alteration are structurally controlled by the NE-to NNE-striking Linglong detachment *** mineralization can be divided into four stages:(K-feldspar)–pyrite–sericite–quartz,quartz–gold–pyrite,quartz–gold–polymetallic sulfide,and quartz–carbonate,with the majority of the gold being produced in the second and third *** on a combination of petrography,microthermometry,and laser Raman spectroscopy,three types of fluid inclusion were identified in the vein minerals:NaCl–H2 O(A-type),CO2–H2 O–NaCl(AC-type),and pure CO2(PC-type).Quartz crystals in veinlets that formed during the first stage contain mainly AC-type fluid inclusions,with rare PC-type *** fluid inclusions homogenize at temperatures of 251°C–403°C and have low salinities of 2.2–9.4 wt%NaCl *** crystals that formed in the second and third stages contain all three types of fluid inclusions,with total homogenization temperatures of 216°C–339°C and salinities of 1.8–13.8 wt%NaCl equivalent for the second stage and homogenization temperatures of 195°C–321°C and salinities of 1.4–13.3 wt%NaCl equivalent for the third *** contrast,quartz crystals that formed in the fourth stage contains mainly A-type fluid inclusions,with minor occurrences of AC-type inclusions;these inclusions have homogenization temperatures of 106°C–287°C and salinities of 0.5–7.7 wt%NaCl *** in the ore-forming fluids may have changed from Au(HS)0 as the dominant species under acidic conditions and at relatively high temperatures and f O2 in the early stages,to Au(HS)2–under neutral-pH conditions at lower temperatures

关键词： fluid inclusion gold deposition Dayingezhuang gold deposit Jiaodong Peninsula

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