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Recent advances and perspectives of zinc metal-free anodes for zinc ion batteries

International Journal of Minerals,Metallurgy and Materials 2024年第1期31卷 33-47页

作者： Jiabing Miao Yingxiao Du Ruotong Li zekun zhang Ningning Zhao Lei Dai Ling Wang zhangxing He Science and Technology Innovation Center of Circular Economy Ha’erwusu Open-Pit Coal MineChina Shenhua Energy Co.Ltd.Ordos 010300China Research Center of Comprehensive Utilization of Coal Associated Resources National Energy GroupOrdos 010300China School of Chemical Engineering North China University of Science and TechnologyTangshan 063009China

Zinc-ion batteries(ZIBs) are recognized as potential energy storage devices due to their advantages of low cost, high energy density, and environmental friendliness. However, zinc anodes are subject to unavoidable zinc dendrites, passivation, corrosion, and hydrogen evolution reactions during the charging and discharging of batteries, becoming obstacles to the practical application of ZIBs. Appropriate zinc metal-free anodes provide a higher working potential than metallic zinc anodes, effectively solving the problems of zinc dendrites, hydrogen evolution, and side reactions during the operation of metallic zinc anodes. The improvement in the safety and cycle life of batteries creates conditions for further commercialization of ZIBs. Therefore, this work systematically introduces the research progress of zinc metal-free anodes in “rocking chair” ZIBs. Zinc metal-free anodes are mainly discussed in four categories: transition metal oxides,transition metal sulfides, MXene(two dimensional transition metal carbide) composites, and organic compounds, with discussions on their properties and zinc storage mechanisms. Finally, the outlook for the development of zinc metal-free anodes is proposed. This paper is expected to provide a reference for the further promotion of commercial rechargeable ZIBs.

关键词： zinc ion batteries anode zinc metal-free anode recent advances perspectives

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Regulating interfacial behavior of zinc metal anode via metal-organic framework functionalized separator

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Journal of Energy Chemistry 2024年第6期93卷 213-220,I0006页

作者： Ruotong Li Liang Pan Ziyu Peng Ningning Zhao zekun zhang Jing Zhu Lei Dai Ling Wang zhangxing He School of Chemical Engineering North China University of Science and TechnologyTangshan 063210HebeiChina

Aqueous zinc ion batteries(AZIBs)are one of the promising energy storage devices.However,uncontrolled dendrite and side reactions have seriously hindered its further application.In this study,the metal-organic framework(MOF)functionalized glass fiber separator(GF-PFC-31)was used to regulate interfacial behavior of zinc metal anode,enabling the development of high-performance AZIBs.In PFC-31,there areπ-πinteractions between two adjacent benzene rings with a spacing of 3.199 A.This spacing can block the passage of[Zn(H_(2)O)_6]^(2+)(8.6 A in diameter)through the GF-PFC-31 separator to a certain extent,which promotes the deposition process of Zn ions.In addition,the sulfonic acid group(-S03H)contained in GF-PFC-31 can form a hydrogen bonding network with H_(2)O,which can provide a desolvation effect and reduce the side reaction.Consequently,GF-PFC-31 separator achieves uniform deposition of Zn ions.The Zn‖GF-PFC-31‖Zn symmetric cell exhibits stable cycle life(3000 h at 1.2 mA cm^(-2),2000 h at 0.3 mA cm^(-2),and 2000 h at 5.0 mA cm^(-2)),and Zn‖GF-PFC-31‖MnO_(2) full cell with GF-PFC-31 separator can cycle for 1000 cycles at 1.2 A g^(-1)with capacity retention rate of 82.5%.This work provides a promising method to achieve high-performance AZIBs.

关键词： Aqueous zinc ion batteries Interfacial behavior Metal-organic framework Sulfonic acid group Separator

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Polymer engineering for electrodes of aqueous zinc ion batteries

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Journal of Energy Chemistry 2024年第4期91卷 345-369页

作者： Zhi Peng Zemin Feng Xuelian Zhou Siwen Li Xuejing Yin zekun zhang Ningning Zhao zhangxing He Lei Dai Ling Wang Chao Lu School of Chemical Engineering North China University of Science and TechnologyTangshan 063210HebeiChina State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China

With the increasing demand for scalable and cost-effective electrochemical energy storage,aqueous zinc ion batteries(AZIBs)have a broad application prospect as an inexpensive,efficient,and naturally secure energy storage device.However,the limitations suffered by AZIBs,including volume expansion and active materials dissolution of the cathode,electrochemical corrosion,irreversible side reactions,zinc dendrites of the anode,have seriously decelerated the civilianization process of AZIBs.Currently,polymers have tremendous superiority for application in AZIBs attributed to their exceptional chemical stability,tunable structure,high energy density and outstanding mechanical properties.Considering the expanding applications of AZIBs and the superiority of polymers,this comprehensive paper meticulously reviews the benefits of utilizing polymeric applied to cathodes and anodes,respectively.To begin with,with adjustable structure as an entry point,the correlation between polymer structure and the function of energy storage as well as optimization is deeply investigated in respect to the mechanism.Then,depending on the diversity of properties and structures,the development of polymers in AZIBs is summarized,including conductive polymers,redox polymers as well as carbon composite polymers for cathode and polyvinylidene fluoride-,carbonyl-,amino-,nitrile-based polymers for anode,and a comprehensive evaluation of the shortcomings of these strategies is provided.Finally,an outlook highlights some of the challenges posed by the application of polymers and offers insights into the potential future direction of polymers in AZIBs.It is designed to provide a thorough reference for researchers and developers working on polymer for AZIBs.

关键词： Aqueous zinc ion batteries Polymer Multi-function Anode protection Energy storage

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A sponge-based iron-tannic-acid hydrogel interface evaporator designed for clean water production

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Science China(Technological Sciences) 2024年第5期67卷 1579-1591页

作者： zhang zekun LI ChengLong TAO HuaYu GE Bo zhang YongLe ZHAO LiMin LIU JunChang REN GuiNa zhang ZhaoZhu School of Materials Science and Engineering Liaocheng UniversityLiaocheng252059China School of Environmental and Material Engineering Yantai UniversityYantai264405China State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou730000China

Due to the rapid advancement of technologies,there has been a significant increase in the discharge of industrial wastewater,and freshwater is becoming a scarce resource.Currently,research on solar evaporators is mainly focused on the efficient production of clean water,with less emphasis on the removal of residual pollutants remaining in the original solutions.Through this study,problems,including the difficult recovery of catalyst powder and the difficult removal of floating organic matter are solved by co-depositing low-surface-tension zirconia particles and bismuth tungstate onto the floating layer.Hydrogels and melamine sponges were combined to solve the problem that traditional hydrogels lack mechanical strength.An excellent water-repellent effect can be seen from the contact angle between the liquid globule and canvas/felt,which is greater than 155°.The steam generation rate of the assembled evaporation system is 1.78 kg m^(-2)h^(-1),and its purification efficiency for methyl orange and rhodamine B exceeds 99%.This study presents a novel strategy for treating wastewater contaminated with organic dyes,aiming to solve problems including environmental damage,water pollution,and water scarcity.

关键词： oil removal non-wetting interface

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Recent advances in cathodes for all-solid-state lithium-sulfur batteries

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Chinese Chemical Letters 2023年第7期34卷 58-69页

作者： Shengbo Yang Bo Wang Qiang Lv Nan zhang zekun zhang Yutong Jing Jinbo Li Rui Chen Bochen Wu Pengfei Xu Dianlong Wang MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage State Key Laboratory of Urban Water Resource and EnvironmentSchool of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001China

Lithium-sulfur(Li-S)batteries have been regarded as the candidate for the next-generation energy storage system due to the high theoretical specific capacity(1675 m Ah/g), energy density(2600 Wh/kg)and the abundance of elemental sulfur, but the application of Li-S batteries is impeded by a series of problems. Recently, all-solid-state Li-S batteries(ASSLSBs) have drawn great attention because many drawbacks such as safety issues caused by metallic lithium anodes and organic liquid electrolytes can be overcome through the use of solid-state electrolytes(SEs). However, not only the problems brought by sulfur cathodes still exist, but more trouble arouses from the interfaces between SEs and cathodes, hampering the practical application of ASSLSBs. Therefore, in order to deal with the problems, enormous endeavors have been done on ASSLSB cathodes during the past few decades, including engineering of cathode active materials, cathode host materials, cathode binder materials and cathode structures. In this review, the electrochemical mechanism and existing problems of ASSLSBs are briefly introduced. Subsequently, the strategies for developing cathode materials and designing cathode structures are presented. Then there follows a brief discussion of SE problems and expectations, and finally, the challenges and perspectives of ASSLSBs are summarized.

关键词： All-solid-state Li-S battery Cathode active material Cathode host material Cathode structure Solid-state electrolyte

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Quick fabrication of evenly porous PbO_(2) through potential linear increase electrodeposition

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Chinese Chemical Letters 2023年第7期34卷 240-243页

作者： Hua Guo Wenyu Hu zekun zhang Duowen Yang Siyuan Guo Xiaosheng Jing Hao Xu Wei Yan Department of Environmental Science and Engineering Xi'an Jiaotong UniversityXian 710049China Research Institute of Xi'an Jiaotong University Hangzhou 311200China

Anodic oxidation electrodeposition is the primary way to prepare lead dioxide anode. The regulation of the external circuit for the reaction is a unique advantage of electrocatalytic reaction, which can regulate crystallization and accelerate the reaction process. In this study, lead dioxide coatings with uniform pore size distribution were quickly prepared on three different substrates by potential linear increase electrodeposition(PLIED). Morphology and structure analysis shows that the prepared electrodes have uniform porous morphology, and Ti/SnO_(2)/PLIED has the smallest grain size. Three electrodes all display well degradation performance to azophloxine and diclofenac sodium. Ti/PLIED, and Ti/SnO_(2)/PLIED are appreciated for degrading organics with a simple structure in low concentrations. At the same time,Ti/SnO_(2)/PLIED is more suitable for complex organics in high concentrations. Electrochemical activity tests indicate the different mechanisms of the PLIED electrodes that build the other degradation performance.Three PLIED electrodes show excellent electrical and electrochemical stability during the cycle degradation process. The results provide a reference for the subsequent anodic oxidation electrodeposition research and the regulating effect of the external circuit on coating properties.

关键词： Lead dioxide Bubble template Porous electrode Adsorption electrochemical porosity

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计及拓扑相似性的含分散式风电配网双层优化重构方法

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电网技术 2024年第6期48卷 2436-2447,I0050页

作者：张泽坤杨洁刘念新能源电力系统国家重点实验室(华北电力大学) 北京市昌平区102206

高比例风电接入背景下,配网优化重构是缓解弃风、失负荷问题的一种有效手段。多对象优化重构作为非凸非线性优化问题,同时含大量离散变量求解难度较大,为此建立了基于拓扑相似性的含高比例分散式风电配网双层交互式优化重构模型。模型... 详细信息

高比例风电接入背景下,配网优化重构是缓解弃风、失负荷问题的一种有效手段。多对象优化重构作为非凸非线性优化问题,同时含大量离散变量求解难度较大,为此建立了基于拓扑相似性的含高比例分散式风电配网双层交互式优化重构模型。模型设计了支路复介数相似度评价指标,来衡量所有辐射状拓扑的相似度,再将相似网络进行聚类,形成了重构层的树状解空间。重构层以分段/联络开关状态为决策变量优化网络拓扑结构,并传输至调度层;调度层以分散式风电出力、储能运行状态、无功补偿装置功率及需求响应量为决策变量,进行配电网有功无功协同优化调度,以确定各对象最优运行状态并反馈到重构层,两层不断交互迭代得出最终策略。为适应该模型提出了一种剪枝和声搜索算法,其中和声库从树枝切换到枝内的过程,提高了重构层网络重构的求解效率。采用IEEE 33节点系统仿真测试,验证了所提方法在提升系统电压安全性、降低系统运行成本方面的优越性。

关键词：配电网分散式风电拓扑相似性双层优化重构二阶锥规划

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Seven new 3,4-dihydro-furanocoumarin derivatives from Angelica dahurica

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Chinese Herbal Medicines 2023年第3期15卷 457-462页

作者： Yang Wang Fanyu Shi Zihan Lu Mingliang zhang zekun zhang Fangfang Jia Beibei zhang Lishan Ouyang Zhixiang Zhu Shepo Shi Modern Research Center for Traditional Chinese Medicine Beijing University of Chinese MedicineBeijing 102401China Gaoping Chinese Medicine Hospital Gaoping 048400China

Objective:To study the chemical constituents of the roots of Angelica dahurica,a well-known Chinese herbal medicine named Baizhi in Chinese.Methods:Compounds were separated by various chromatographies,and the structures of new compounds were elucidated based on the analysis of their spectroscopic and spectrometric data(1D,2D NMR,HRESI MS,IR,and UV).The absolute configurations of new compounds were determined by the calculated electronic circular dichroism and chemical derivatization.The inhibitory activities of all isolates against nitric oxide(NO)production were evaluated using lipopolysaccharide-activated RAW 264.7macrophage cells.Results:Seven new 3,4-dihydro-furanocoumarin derivatives(1a/1b,2a/2b,3a/3b,4)together with a known furanocoumarin(5)were isolated from the roots of A.dahurica.The new compounds included three pairs of enantiomers,(4S,2’’R)-angelicadin A(1a)/(4R,2’’S)-angelicadin A(1b),(4S,2’’S)-angelicadin A(2a)/(4R,2’’R)-angelicadin A(2b),and(4S,2’’S)-secoangelicadin A(3a)/(4R,2’’R)-secoangelicadin A(3b),together with(4R,2’’R)-secoangelicadin A methyl ester(4).The known xanthotoxol(5)inhibited the NO production with the half-maximal inhibitory concentration(IC50)value of(32.8±0.8)μmol/L,but all the new compounds showed no inhibitory activities at the concentration of100μmol/L.Conclusion:This is the first report of the discovery of 3,4-dihydro-furanocoumarins from A.dahurica.The results are not only meaningful for the understanding of the chemical constituents of A.dahurica,but also enrich the reservoir of natural products.

关键词： Angelica dahurica(Fisch.ex Hoffm.)Benth.et Hook.f. anti-inflammation coumarin 3,4-dihydro-furanocoumarin enantiomers(4S,2R)-angelicadin A (4R,2S)-angelicadin A (4S,2S)-angelicadin A (4R,2R)-angelicadin A (4S,2S)-secoangelicadin A (4R,2R)-secoangelicadin A (4R,2R)-secoangelicadin A methyl ester

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Multi-omics of Circular RNAs and Their Responses to Hormones in Moso Bamboo(Phyllostachys edulis)

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Genomics, Proteomics & Bioinformatics 2023年第4期21卷 866-885页

作者： Yongsheng Wang Huihui Wang Huiyuan Wang Ruifan Zhou Ji Wu zekun zhang Yandong Jin Tao Li Markus V.Kohnen Xuqing Liu Wentao Wei Kai Chen Yubang Gao Jiazhi Ding Hangxiao zhang Bo Liu Chentao Lin Lianfeng Gu Basic Forestry and Proteomics Research Center College of ForestryFujian Provincial Key Laboratory of Haixia Applied Plant Systems BiologyFujian Agriculture and Forestry UniversityFuzhou 350002China College of Forestry Fujian Agriculture and Forestry UniversityFuzhou 350002China Department of Molecular Cell and Developmental BiologyUniversity of California at Los AngelesLos AngelesCA 90095USA

Circular RNAs(circRNAs)are endogenous non-coding RNAs with covalently closed structures,which have important functions in plants.However,their biogenesis,degradation,and function upon treatment with gibberellins(GAs)and auxins(1-naphthaleneacetic acid,NAA)remain unknown.Here,we systematically identified and characterized the expression patterns,evolutionary conservation,genomic features,and internal structures of circRNAs using RNase R-treated libraries from moso bamboo(Phyllostachys edulis)seedlings.Moreover,we investigated the biogenesis of circRNAs dependent on both cis-and trans-regulation.We explored the function of circRNAs,including their roles in regulating microRNA(miRNA)-related genes and modulating the alternative splicing of their linear counterparts.Importantly,we developed a customized degradome sequencing approach to detect miRNA-mediated cleavage of circRNAs.Finally,we presented a comprehensive view of the participation of circRNAs in the regulation of hormone metabolism upon treatment of bamboo seedlings with GA and NAA.Collectively,our study provides insights into the biogenesis,function,and miRNA-mediated degradation of circRNAs in moso bamboo.

关键词： Alternative splicing Circular RNA Degradome Phyllostachys edulis Phytohormone

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基于数字运算的疲劳驾驶预警系统设计

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电子技术（上海） 2024年第4期53卷 184-185页

作者：张泽坤山西应用科技学院山西030062

阐述基于计算机数字运算技术的驾驶疲劳预警系统设计,分析系统的工作原理、系统的硬件选取、神经网络方法、图像数据处理技术。系统主要是对人眼定位方法的采用,具备较强的实时性。

关键词：单片机预警系统疲劳驾驶

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