检索结果-南通市图书馆

Revealing the role of electrode potential micro-environments in single Mn atoms for carbon dioxide and oxygen electrolysis

在线全文

学校读者我要写书评

暂无评论

Nano Research 2024年第9期17卷 7957-7966页

作者： Pengcheng liu anyi liu Kaili Wang Shuai Shi Mengmeng Jin Jingxiu liu Tao Qin Qian liu Xijun liu Jia He Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion School of Chemistry and Chemical EngineeringInstitute of New-Energy Materials and Low-Carbon TechnologiesSchool of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China School of Chemistry and Chemical Engineering and Environmental Engineering Weifang UniversityWeifang 261061China Department of Electrical Engineering and Automation Luoyang Institute of Science and TechnologyLuoyang 471023China Institute for Advanced Study Chengdu UniversityChengdu 610106China State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured MaterialsSchool of ResourcesEnvironment and MaterialsGuangxi UniversityNanning 530004China

Elucidation the relationship between electrode potentials and heterogeneous electrocatalytic reactions has attracted widespread *** we construct the well-defined Mn single-atom(MnSA)catalyst with four N-coordination through a simple thermal pyrolysis preparation method to investigate the electrode potential micro-environments effect on carbon dioxide reduction reactions(CO_(2)RR)and oxygen reduction reactions(ORR).MnSA catalysts generate higher CO production Faradaic efficiency of exceeding 90%at-0.9 V for CO_(2)RR and higher H_(2)O_(2)yield from 0.1 to 0.6 V with excellent ORR *** functional theory(DFT)calculations based on constant potential models were performed to study the mechanism of MnSA on CO_(2)*** thermodynamic energy barrier of CO_(2)RR is lowest at-0.9 V *** hydrogen electrode(RHE).Similar DFT calculations on the H_(2)O_(2)yield of ORR showed that the H_(2)O_(2)yield at 0.2 V was *** study provides a reasonable explanation for the role of electrode potential micro-environments.

关键词： electrode potential micro-environments Mn single-atom catalyst carbon dioxide reduction reaction oxygen reduction reaction constant potential models

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

集流管结构对旋喷泵外特性及尾流影响

哈尔滨工程大学学报 2021年第3期42卷 368-375页

作者：黄祺刘在伦李琪飞权辉曾继来兰州理工大学能源与动力工程学院甘肃兰州730050

针对集流管结构严重影响旋喷泵性能这一问题,本文以专用的旋喷泵开式试验台和5种安装不同结构集流管的模型泵为研究对象,分析了集流管结构对旋喷泵内、外特性影响。数值计算为避免各向同性涡粘假设,选择雷诺应力RSM linear pressure-str... 详细信息

针对集流管结构严重影响旋喷泵性能这一问题,本文以专用的旋喷泵开式试验台和5种安装不同结构集流管的模型泵为研究对象,分析了集流管结构对旋喷泵内、外特性影响。数值计算为避免各向同性涡粘假设,选择雷诺应力RSM linear pressure-strain模型,将数值计算结果与试验结果对比以验证其可信度。结果表明:试验泵集流管进口直径过小或者过大都会导致旋喷泵扬程与效率的下降。集流管外形对旋喷泵的扬程、效率影响明显,翼形集流管扬程、效率较高。旋喷泵尾流区相对半径r′1.0范围内受旋壳效应影响,高速层和低速层之间动量传递剧烈,不同结构集流管在同一位置坐标雷诺应力数值差异普遍在10-4量级。研究结果可为集流管结构设计及选型提供重要基础。

关键词：旋喷泵集流管测压管雷诺应力试验效率数值计算尾流

在线全文

学校读者我要写书评

暂无评论

离心泵平衡孔液体泄漏量试验与分析

农业工程学报 2017年第7期33卷 67-74页

作者：刘在伦陈小昌王东伟侯祎华兰州理工大学能源与动力工程学院兰州730050 兰州理工大学温州泵阀工程研究院温州325105

针对离心泵上叶轮平衡孔的实际液体泄漏量难以测量的问题,设计了通过调节平衡腔液体压力来测量平衡孔液体泄漏量的试验装置,在平衡孔直径4、6、8、11 mm条件下对泵性能、平衡孔液体泄漏量和平衡腔液体压力进行了测试及分析,获得了不同... 详细信息

针对离心泵上叶轮平衡孔的实际液体泄漏量难以测量的问题,设计了通过调节平衡腔液体压力来测量平衡孔液体泄漏量的试验装置,在平衡孔直径4、6、8、11 mm条件下对泵性能、平衡孔液体泄漏量和平衡腔液体压力进行了测试及分析,获得了不同直径平衡孔下泵的性能曲线、平衡孔泄漏量系数和轴向力系数与比面积的关系曲线。试验结果表明:加大叶轮平衡孔直径会使泵的扬程降低、输入功率增大和效率降低;平衡孔液体泄漏量系数与比面积关系曲线有明显的规律性,其随着比面积增大而减小,且扬程系数对其有较大的影响;轴向力系数曲线是非线性曲线,在比面积小于2.5时,轴向力系数随比面积增大而急剧减小;比面积大于等于2.5小于等于4.5时,轴向力系数曲线趋于平坦,其均值为0.112;比面积大于4.5时,轴向力系数曲线几乎与横坐标平行,其均值为0.067。该研究为较精确计算平衡孔液体泄漏量与平衡腔区域的轴向力提供了参考。

关键词：离心泵试验叶轮平衡孔泄漏量轴向力

Experimental and numerical study on ignition and combustion characteristics of boron-magnesium composite powders

在线全文

学校读者我要写书评

暂无评论

Particuology 2024年第1期84卷 12-29页

作者： Shuyuan liu Luyang Han Hongmei liu Yingkai Song Linlin liu Songqi Hu Science and Technology on Combustion Internal Flow and Thermo-Structure LaboratoryNorthwestern Polytechnical UniversityXi'an710072China School of Mechanical Engineering and Rail Transit Changzhou UniversityChangzhou213164China Shanghai Institute of Space Propulsion Shanghai201112China Shanghai Engineering Research Center of Space Engine Shanghai201112China

A high-pressure laser ignition and combustion system with adjustable oxidizer gas atmosphere is established to investigate the ignition and combustion characteristics of boron-magnesium(BM)com-posite *** ignition and combustion model of BM powders is established and validated in the present *** results show that increasing water content,O_(2) content and Mg content all result in shorter ignition delay time of BM powders,among which the effect of water content is the most ***,ignition delay time increases as pressure *** combustion time decreases with increasing Mg content and ambient pressure but increases with water *** the increase of O_(2) content,combustion time of BM powders first increases and then decreases,which means a critical O_(2) content exists above which combustion time *** results show that there exists a trade-off between ignition and combustion performance of BM composite powders.

关键词： Boron magnesium powder Laser ignition Ignition and combustion model Reaction mechanism Numerical model

CFD-DEM simulation of high density particles fluidization behaviors in 3D conical spouted beds

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Particuology 2024年第5期88卷 266-281页

作者： Lin Jiang Mofan Qiu Rongzheng liu Bing liu Youlin Shao Malin liu Institute of Nuclear and New Energy Technology Collaborative Innovation Center of Advanced Nuclear Energy TechnologyTsinghua UniversityBeijing 100084China

The spouted bed has been used in the coating process of high-density nuclear fuel *** particle fluidization behaviors in pseudo-2D and 3D spouted beds were simulated and *** effects of four independent variables(cone angle,particle density,inlet gas velocity,and particle loading)on particle fluidization behaviors in the 3D spouted bed were investigated *** cone angle effect on fluidization mechanism was studied quantitatively first time.A new fluidization quality index was proposed based on the particle entrainment principle,and an extreme value was obtained when the cone angle was 60°,considered to be the optimum value for the 3D conical spouted *** was indicated the gas–solid contact efficiency can be kept up if the gas velocity was proportional to ρ_(p)^(0.65) and N_(p)^(0.78) when the particle density or loading was *** results will be useful for geometry and operation parameters design of the 3D conical spouted bed and helpful for developing the fluidization mechanism of high-density particles.

关键词： Spouted bed High-density particle CFD-DEM Fluidization quality index Particle loading

Control Strategies for Digital Twin Systems

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

IEEE/CAA Journal of Automatica Sinica 2024年第1期11卷 170-180页

作者： Guo-Ping liu IEEE the Center for Control Science and Technology Southern University of Science and TechnologyShenzhen 518055China

With the continuous breakthrough in information technology and its integration into practical applications, industrial digital twins are expected to accelerate their development in the near future. This paper studies various control strategies for digital twin systems from the viewpoint of practical *** make full use of advantages of digital twins for control systems, an architecture of digital twin control systems, adaptive model tracking scheme, performance prediction scheme, performance retention scheme, and fault tolerant control scheme are proposed. Those schemes are detailed to deal with different issues on model tracking, performance prediction, performance retention, and fault tolerant control of digital twin systems. Also, the stability of digital twin control systems is analysed. The proposed schemes for digital twin control systems are illustrated by examples.

关键词： Digital twin control systems fault tolerant control model tracking performance prediction performance retention

Relation Between the Eventual Continuity and the E-property for Markov-Feller Semigroups

在线全文

学校读者我要写书评

暂无评论

Acta Mathematicae Applicatae Sinica 2024年第1期40卷 1-16页

作者： Yong liu Zi-yu liu LMAM School of Mathematical SciencePeking UniversityBeijing100871China

We investigate some relations between two kinds of semigroup regularities, namely the e-property and the eventual continuity, both of which contribute to the ergodicity for Markov processes on Polish *** precisely, we prove that for Markov-Feller semigroup in discrete time and stochastically continuous MarkovFeller semigroup in continuous time, if there exists an ergodic measure whose support has a nonempty interior,then the e-property is satisfied on the interior of the support. In particular, it implies that, restricted on the support of each ergodic measure, the e-property and the eventual continuity are equivalent for the discrete-time and the stochastically continuous continuous-time Markov-Feller semigroups.

关键词： Markov-Feller semigroup ergodicity e-property eventual continuity

Graph Signal Reconstruction from Low-Resolution Multi-Bit Observations

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Electronics 2024年第1期33卷 153-160页

作者： Zhaoting liu Chen YU Yafeng WANG Shuchen liu School of Communication Engineering Hangzhou Dianzi University

Low hardware cost and power consumption in information transmission, processing and storage is an urgent demand for many big data problems, in which the high-dimensional data often be modelled as graph *** paper considers the problem of recovering a smooth graph signal by using its low-resolution multi-bit quantized observations. The underlying problem is formulated as a regularized maximum-likelihood optimization and is solved via an expectation maximization scheme. With this scheme, the multi-bit graph signal recovery(MB-GSR) is efficiently implemented by using the quantized observations collected from random subsets of graph nodes. The simulation results show that increasing the sampling resolution to 2 or 3 bits per sample leads to a considerable performance improvement, while the energy consumption and implementation costs remain much lower compared to the implementation of high resolution sampling.

关键词： Quantization (signal) Costs Power demand Simulation Energy resolution Signal sampling Signal reconstruction

Optimized the vanadium electrolyte with sulfate-phosphoric mixed acids to enhance the stable operation at high-temperature

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Frontiers of Chemical Science and Engineering 2024年第2期18卷 13-26页

作者： Ling Ge Tao liu Yimin Zhang Hong liu School of Resource and Environmental Engineering Wuhan University of Science and TechnologyWuhan 430081China State Environmental Protection Key Laboratory of Mineral Metallurgical Resources Utilization and Pollution Control Wuhan University of Science and TechnologyWuhan 430081China Hubei Collaborative Innovation Center for High Efficient Utilization of Vanadium Resources Wuhan University of Science and TechnologyWuhan 430081China Hubei Provincial Engineering Technology Research Center of High Efficient Cleaning Utilization for Shale Vanadium Resource Wuhan University of Science and TechnologyWuhan 430081China School of Resource and Environmental Engineering Wuhan University of TechnologyWuhan 430070China

Herein, the influence of the concentration design and comprehensive performance of the sulfate-phosphoric mixed acid system electrolyte is investigated to realize an electrolyte that maintains high energy density and stable operation at high temperatures. Static stability tests have shown that VOPO4 precipitation occurs only with vanadium(V) electrolyte. The concentration of vanadium ion of 2.0–2.2 mol·L^(–1), phosphoric acid of 0.10–0.15 mol·L^(–1), and sulfuric acid of 2.5–3.0 mol·L^(–1) are suitable for a vanadium redox flow battery in the temperature range from –20 to 50 ℃. The equations for predicting the viscosity and conductivity of electrolytes are obtained by the response surface method. The optimized electrolyte overcomes precipitation generation. It has 2.8 times higher energy density than the non-phosphate electrolyte, and a coulomb efficiency of 94.0% at 50 ℃. The sulfate-phosphoric mixed acid system electrolyte promotes the electrode reaction process, increases the current density, and reduces the resistance. This work systematically optimizes the concentrations of composition of positive and negative vanadium electrolytes with mixed sulfate-phosphoric acid. It provides a basis for the different valence states and comprehensive properties of sulfate-phosphoric mixed acid system vanadium electrolytes under extreme environments, guiding engineering applications.

关键词： all vanadium redox flow battery mixed-acid vanadium electrolyte concentration optimization response surface methodology high-temperature stability