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Thermal decomposition mechanism and kinetics of bastnaesite in suspension roasting process:A comparative study in N_(2) and air atmospheres

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Journal of Rare Earths 2024年第9期42卷 1809-1816,I0006页

作者： Wenbo Li Jijia chen Shaokai cheng Junyan Sun Xiaolong Zhang School of Resources and Civil Engineering Northeastern UniversityShenyang110819China National-Local Joint Engineering Research Center of High-Efficient Exploitation Technology for Refractory Iron Ore Resources Shenyang110819China

To investigate the thermal decomposition behavior and reaction kinetics of bastnaesite in suspension roasting,the gas and solid products of bastnaesite roasted in N2 and air atmospheres were examined using a gas analyzer,X-ray diffraction(XRD),scanning electron microscopy(SEM),and energy dispersive spectrometry(EDS).Subsequently,the kinetic parameters of bastnaesite in the suspension roasting process were derived and calculated using the isothermal *** results show that the decomposition product of bastnaesite in N_(2) is ***,once the roasting temperature exceeds 600℃,CO is generated in addition to CO_(2),and all the XRD diffraction peaks of CeOF are shifted to the right,indicating that CO_(2) can oxidize CeOF and lead to the transformation of Ce(Ⅲ) into Ce(Ⅳ).When roasted in air,the decomposition product CeOF can be completely converted to CeF3 and Ce_(7)O_(12) as it easily ***,the reaction rate of bastnaesite in air is higher than that of N_(2),and the starting reaction temperature is lower than that of N_(2).A large number of irregular cracks and holes appear on the surface of solid-phase products following suspension roasting,which are due to the thermal decomposition of bastnaesite that produces CO_(2) as well as the reconstruction of the lattice of the solid-phase *** reaction kinetic model of bastnaesite roasted in N_(2)(temperature range 600-750℃) and air(temperatu re range 500-575℃) confo rms to the A_(3/2) model with the mechanism function G(α)=-ln(1-α)^(2/3),and the reaction activation energy is 59.78 kj/mol and lnA is 1.65 s^(-1) in N_(2) *** air,the reaction activation energy is 100.30 kj/mol and lnA is 9.63 s^(-1).

关键词： Rare earths Bastnaesite Suspension roasting Thermal decomposition mechanism Reaction kinetics

Improving anammox activity and reactor start-up speed by using CO_(2)/NaHCO_(3) buffer

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Journal of Environmental Sciences 2024年第5期139卷 60-71页

作者： Shaoan cheng Huahua Li Xinyuan He Hua chen Longxin Li State Key Laboratory of Clean Energy Utilization College of Energy EngineeringZhejiang UniversityHangzhou 310027China

Anammox bacteria grow slowly and can be affected by large pH *** suitable buffers could make the start-up of anammox reactors easy and *** this study,the effects of three kinds of buffers on the nitrogen removal and growth characteristics of anammox sludge were *** with CO_(2)/NaHCO_(3)buffer solution(CCBS)performed the best in nitrogen removal,while 4-(2-hydroxyerhyl)piperazine-1-ethanesulfonic acid(HEPES)and phosphate buffer solution(PBS)inhibited the anammox *** with 50 mmol/L CCBS could start up in 20 days,showing the specific anammox activity and anammox activity of 1.01±0.10 gN/(gVSS·day)and 0.83±0.06 kgN/(m^(3)·day),*** Kuenenia was the dominant anammox bacteria,with a relative abundance of 71.8%.Notably,anammox reactors could also start quickly by using 50 mmol/L CCBS under nonstrict anaerobic *** findings are meaningful for the quick start-up of engineered anammox reactors and prompt enrichment of anammox bacteria.

关键词： Anammox bacteria Buffer solution CO_(2)/NaHCO_(3) Physiological characteristics Microbial community shift

Electrothermal Model Based Remaining Charging Time Prediction of Lithium-Ion Batteries against Wide Temperature Range

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Chinese Journal of Mechanical Engineering 2024年第2期37卷 330-339页

作者： Rui Xiong Zian Zhao cheng chen Xinggang Li Weixiang Shen School of Mechanical Engineering Beijing Institute of TechnologyBeijing 100081China School of Science Computing and Engineering TechnologiesSwinburne University of TechnologyHawthornVIC 3122Australia

Battery remaining charging time(RCT)prediction can facilitate charging management and alleviate mileage anxiety for electric vehicles(EVs).Also,it is of great significance to improve EV users’***,the RCT for a lithiumion battery pack in EVs changes with temperature and other battery *** study proposes an electrothermal model-based method to accurately predict battery ***,a characteristic battery cell is adopted to represent the battery pack,thus an equivalent circuit model(ECM)of the characteristic battery cell is established to describe the electrical behaviors of a battery ***,an equivalent thermal model(ETM)of the battery pack is developed by considering the influence of ambient temperature,thermal management,and battery connectors in the battery pack to calculate the temperature which is then fed back to the ECM to realize electrothermal ***,the RCT prediction method is proposed based on the electrothermal model and validated in the wide temperature range from-20℃to 45℃.The experimental results show that the prediction error of the RCT in the whole temperature range is less than 1.5%.

关键词： Electric vehicles Lithium-ion batteries Remaining charging time Electrothermal model

Parameter selection for the hydroconversion of waste polyethylene plastic under mild conditions: A comprehensive evaluation

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Science China(Technological Sciences) 2024年第8期67卷 2413-2426页

作者： cheng LeiLei chen RuiZhe ZHU WeiQiang TIAN ShaoNan GU Jing YUAN HaoRan chen Yong Guangzhou Institute of Energy Conversion Chinese Academy of SciencesGuangzhou 510640China School of Energy Science and Engineering University of Science and Technology of ChinaHefei 230026China Institute of Process Engineering Chinese Academy of SciencesBeijing 100190China

The hydrogenolysis/hydrocracking of waste polyethylene(PE) has recently been intensively studied, with the general pursuit of low-temperature reaction conditions, increased oil-phase yield, and narrower carbon chain distribution. Before this, we utilized a ball-milled ZSM-22 catalyst loaded with Ru nanoparticles(NPs), which exhibited excellent hydroconversion performance. It deconstructed PE into >80 wt.% oil products under low temperatures and short reaction times. Herein, we investigated the influence of varying temperature/pressure parameters on the degree of specific hydrocracking/internal hydrogenolysis/terminal hydrogenolysis reactions. From the comprehensive energy efficiency perspective, including stirring, reaction, and product separation, as well as taking into account the degree of product isomerization and catalyst lifespan, we analyzed the optimization of parameters. This research abandons the notion that lower temperatures are better and proposes a more comprehensive evaluation framework for low-consumption hydroconversion of PE to produce high-value products.

关键词： plastic upcycling polyethylene hydrocracking hydrogenolysis comprehensive energy efficiency

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A vector sum analysis method for stability evolution of expansive soil slope considering shear zone damage softening

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第9期16卷 3746-3759页

作者： Junbiao Yan Lingwei Kong cheng chen Mingwei Guo State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan430071China University of Chinese Academy of Sciences Beijing100049China

Slope stability analysis is a classical mechanical problem in geotechnical engineering and engineering *** is of great significance to study the stability evolution of expansive soil slopes for engineering construction in expansive soil *** of the existing studies evaluate the slope stability by analyzing the limit equilibrium state of the slope,and the analysis method for the stability evolution considering the damage softening of the shear zone is *** this study,the large deformation shear mechanical behavior of expansive soil was investigated by ring shear *** damage softening characteristic of expansive soil in the shear zone was analyzed,and a shear damage model reflecting the damage softening behavior of expansive soil was derived based on the damage ***,by skillfully combining the vector sum method and the shear damage model,an analysis method for the stability evolution of the expansive soil slope considering the shear zone damage softening was *** results show that the shear zone subjected to large displacement shear deformation exhibits an obvious damage softening *** damage variable equation based on the logistic function can be well used to describe the shear damage characteristics of expansive soil,and the proposed shear damage model is in good agreement with the ring shear test *** vector sum method considering the damage softening behavior of the shear zone can be well applied to analyze the stability evolution characteristics of the expansive soil *** stability factor of the expansive soil slope decreases with the increase of shear displacement,showing an obvious progressive failure behavior.

关键词： Expansive soil slope Stability analysis Ring shear test Vector sum method Damage model Strain softening

HEN:a novel hybrid explainable neural network based framework for robust network intrusion detection

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Science China(Information Sciences) 2024年第7期67卷 72-90页

作者： Wei WEI Sijin chen Cen chen Heshi WANG Jing LIU Zhongyao cheng Xiaofeng ZOU School of Computer Science and Engineering Xi'an University of TechnologyShaanxi Key Laboratory for Network Computing and Security Technology School of Computer Science and Technology Wuhan University of Science and Technology School of Future Technology South China University of Technology Shenzhen Research Institute of Hunan University School of Computer Science Hunan University of Technology and Business Institute for Infocomm Research (I2R) Agency for Science Technology and Reseach (A*STAR)

With the rapid development of network technology and the automation process for 5G, cyberattacks have become increasingly complex and threatening. In response to these threats, researchers have developed various network intrusion detection systems(NIDS) to monitor network traffic. However, the incessant emergence of new attack techniques and the lack of system interpretability pose challenges to improving the detection performance of NIDS. To address these issues, this paper proposes a hybrid explainable neural network-based framework that improves both the interpretability of our model and the performance in detecting new attacks through the innovative application of the explainable artificial intelligence(XAI)method. We effectively introduce the Shapley additive explanations(SHAP) method to explain a light gradient boosting machine(Light GBM) model. Additionally, we propose an autoencoder long-term short-term memory(AE-LSTM) network to reconstruct SHAP values previously generated. Furthermore, we define a threshold based on reconstruction errors observed during the training phase. Any network flow that surpasses the specified threshold is classified as an attack flow. This approach enhances the framework's ability to accurately identify attacks. We achieve an accuracy of 92.65%, a recall of 95.26%, a precision of 92.57%,and an F1-score of 93.90% on the dataset NSL-KDD. Experimental results demonstrate that our approach generates detection performance on par with state-of-the-art methods.

关键词： explainable artificial intelligence light gradient boosting machine machine learning network intrusion detection Shapley additive explanation hybrid explainable neural network (HEN)

An Interactive Collaborative Creation System for Shadow Puppets Based on Smooth Generative Adversarial Networks

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Computers, Materials & Continua 2024年第6期79卷 4107-4126页

作者： cheng Yang Miaojia Lou Xiaoyu chen Zixuan Ren Department of Industrial Design Hangzhou City UniversityHangzhou310000China College of Computer Science and Technology Zhejiang UniversityHangzhou310000China

Chinese shadow puppetry has been recognized as a world intangible cultural ***,it faces substantial challenges in its preservation and advancement due to the intricate and labor-intensive nature of crafting shadow *** ensure the inheritance and development of this cultural heritage,it is imperative to enable traditional art to flourish in the digital *** paper presents an Interactive Collaborative Creation System for shadow puppets,designed to facilitate the creation of high-quality shadow puppet images with greater *** system comprises four key functions:Image contour extraction,intelligent reference recommendation,generation network,and color adjustment,all aimed at assisting users in various aspects of the creative process,including drawing,inspiration,and content ***,we propose an enhanced algorithm called Smooth Generative Adversarial Networks(SmoothGAN),which exhibits more stable gradient training and a greater capacity for generating high-resolution shadow puppet ***,we have built a new dataset comprising high-quality shadow puppet images to train the shadow puppet generation *** qualitative and quantitative experimental results demonstrate that SmoothGAN significantly improves the quality of image generation,while our system efficiently assists users in creating high-quality shadow puppet images,with a SUS scale score of *** study provides a valuable theoretical and practical reference for the digital creation of shadow puppet art.

关键词： Shadow puppets deep learning image generation co-create

Exploration of instantaneous frequency for local control assessment in real-time hybrid simulation

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Earthquake Engineering and Engineering Vibration 2024年第4期23卷 995-1008页

作者： Xu Weijie Peng Changle Guo Tong chen cheng Key Laboratory of Concrete and Prestressed Concrete Structures of the Ministry of Education Southeast UniversityNanjing 211189China School of Engineering San Francisco State UniversitySan Francisco 94132-1722USA

Local control parameters such as instantaneous delay and instantaneous amplitude play an essential role in evaluating the performance and maintaining the stability of real-time hybrid simulation(RTHS).However,existing methods have limitations in obtaining this local assessment in either the time domain or frequency *** this study,the instantaneous frequency is introduced to determine local control parameters for actuator tracking assessment in a real-time hybrid *** properties,including amplitude,delay,frequency and phase,are then calculated based on analytic signals translated from actuator tracking signals through the Hilbert *** issues are discussed and solutions are proposed for calculation of local control *** simulations are first conducted for sinusoidal and chirp signals with time varying amplitude error and delay to demonstrate the potential of the proposed *** tests also are conducted for a predefined random signal as well as the RTHS of a single degree of freedom structure with a self-centering viscous damper to experimentally verify the effectiveness of the proposed use of the instantaneous *** from the ensuing analysis clearly demonstrate that the instantaneous frequency provides great potential for local control assessment,and the proposed method enables local tracking parameters with good accuracy.

关键词： real-time hybrid simulation tracking assessment instantaneous frequency Hilbert transform

Top Five Stories of the Cellular Landscape and Therapies of Atherosclerosis:Current Knowledge and Future Perspectives

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Current Medical Science 2024年第1期44卷 1-27页

作者： Qi PAN cheng chen Yue-jin YANG State Key Laboratory of Cardiovascular Disease Department of CardiologyFuwai HospitalNational Center for Cardiovascular DiseasesChinese Academy of Medical Science and Peking Union Medical CollegeBeijing 100037China

Atherosclerosis(AS)is characterized by impairment and apoptosis of endothelial cells,continuous systemic and focal inflammation and dysfunction of vascular smooth muscle cells,which is documented as the traditional cellular ***,the mechanisms appear much more complicated than we thought since a bulk of studies on efferocytosis,transdifferentiation and novel cell death forms such as ferroptosis,pyroptosis,and extracellular trap were *** of novel pathological cellular landscapes provides a large number of therapeutic *** the other side,the unsatisfactory therapeutic effects of current treatment with lipid-lowering drugs as the cornerstone also restricts the efforts to reduce global AS *** cell-or nanoparticle-based strategies spurred a lot of attention due to the attractive therapeutic effects and minimized adverse *** the complexity of pathological changes of AS,attempts to develop an almighty medicine based on single mechanisms could be theoretically *** this review,the top stories in the cellular landscapes during the initiation and progression of AS and the therapies were summarized in an integrated perspective to facilitate efforts to develop a multi-targets strategy and fill the gap between mechanism research and clinical *** future challenges and improvements were also discussed.

关键词： atherosclerosis transdifferentiation extracellular traps efferocytosis stem cell nanoparticles