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Determination of Latent Heats of Vaporization and Fusion

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Advances in Chemical Engineering and Science 2024年第3期14卷 113-124页

作者： Lahbib Abbas Lahcen Bih Khalid Yamni Abderrahim Elyahyaouy Abdelmalik El Attaoui zahra Ramzi Chemistry Department Faculty of Science and Technology Moulay Ismail University Meknes Er-Rachidia Morocco Engineering Sciences and Professions Laboratory National School of Arts and Crafts Moulay Ismail University Meknes Meknes Morocco Materials Membranes and Nanotechnology Chemistry Department Faculty of Sciences Moulay Ismail University Meknes Zitoune Mekns Morocco Physics Department Faculty of Sciences Ibn Tofail University Kenitra Morocco Laboratory of Molecular Chemistry Materials and Environment (LCM2E) Multidisciplinary Faculty of Nador Mohamed 1st University Oujda Nador Morocco Laboratory of SCiMATOP Chemistry Department Faculty of Sciences Semlalia Cadi Ayyad University Marrakech Morocco

Water is the most abundant liquid on the surface of the earth. It is a liquid whose properties are quite surprising, both as a pure liquid and as a solvent. Water is a very cohesive liquid: its melting and vaporization temperatures are very high for a liquid that is neither ionic nor metallic, and whose molar mass is low. Thus, water remains liquid at atmospheric pressure up to 100C while similar molecules such as H2S, H2Se, H2Te for example would give a vaporization temperature close to 80C. This cohesion is in fact ensured by hydrogen bonds between water molecules. This type of bonds between neighboring molecules, hydrogen bonds, is quite often found in chemistry [1] [2]. Any change in the state of aggregation of a substance occurs with the absorption or release of a certain amount of latent heat of transformation. Latent heat of fusion, vaporization or sublimation is the ratio of the energy supplied as heat to the mass of the substance that is melted, vaporized or sublimated. As a result of the reversibility of the processes, the fusion heat is equal to the heat released in the reverse process: crystallization and solidification heat. And likewise the heat of vaporization is equal to the heat of condensation. This equality of heat is often used to determine experimentally either of these quantities. There are two main measurement methods: 1) Direct measurement using the calorimeter, 2) Indirect measure based on the use of the VantHoff relationship. The objective of this work is to measure the latent heat of water vaporization and verify the compatibility of the experimental values with the values given by the tables using the indirect method.

关键词： Latent Heat of Vaporization Latent Heat of Fusion Calorimetry Relationship of Vant’Hoff

Systematic Method for Constructing Lewis Representations

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Open Journal of Inorganic Chemistry 2024年第1期14卷 1-18页

作者： Lahbib Abbas Lahcen Bih Khalid Yamni Abderrahim Elyahyaouy Abdelmalik El Attaoui zahra Ramzi Materials Membranes and Nanotechnology Faculty of Science and Technology Moulay Ismail University Meknes Er-Rachidia Morocco Engineering Sciences and Professions Laboratory National School of Arts and Crafts Moulay Ismail University Meknes Meknes Morocco Materials Membranes and Nanotechnology Chemistry Department Faculty of Sciences Moulay Ismail University Meknes Meknes Morocco Physics Department Faculty of Sciences Ibn Tofail University Kenitra Morocco Laboratory of Molecular Chemistry Materials and Environment (LCM2E) Multidisciplinary Faculty of Nador Mohamed 1st University Oujda Nador Morocco Laboratory of SCiMATOP Chemistry Department Faculty of Sciences Semlalia Cadi Ayyad University Marrakech Morocco

The systematic method for constructing Lewis representations is a method for representing chemical bonds between atoms in a molecule. It uses symbols to represent the valence electrons of the atoms involved in the bond. Using a number of rules in a defined order, it is often better suited to complicated cases than the Lewis representation of atoms. This method allows us to determine the formal charge and oxidation number of each atom in the edifice more efficiently than other methods.

关键词： Systematic Method Lewis Representation Chemical Bond Formal Charge Oxidation Number

Dissemination of carbapenem-non-susceptible Acinetobacter baumannii isolates collected from educational hospitals in Qazvin province of Iran

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Infectious Diseases Research 2024年第1期5卷 3-7页

作者： Shahin Bolori Somayeh Alijani zahra Hadi Saina Shegefti Amir Peymani Rasoul Samimi Student Research Committee Qazvin University of Medical SciencesQazvin ***Iran. Medical Microbiology Research Center Qazvin University of Medical SciencesQazvin ***Iran.

Background:Acinetobacter baumannii(***)is known as an opportunistic pathogen related to health-care-associated infection that has a high antibiotic resistance potential,notably against carbapenems that are widely used to combat *** *** study aimed to detect oxacillin-hydrolyzing(OXA)carbapenemases and metallo-β-lactamases(MBL)among carbapenem-resistant *** isolated strains and to determine their clonal relationship by repetitive extragenic palindromic PCR(rep-PCR).Methods:In the present study,a total of 211 non-repetitive isolates of *** were collected from Qazvin educational hospitals(2016–2017).The disk diffusion method was used to investigate the antibiotic susceptibility of studied strains,followed by the detection of MBL and OXA-type genes using polymerase chain reaction(PCR)and sequencing *** rep-PCR method assessed the clonal relationship of carbapenem-non-susceptible *** ***:The obtained results showed that 87.2%and 86.7%of isolates were non-susceptible to imipenem and *** blaOXA-24(93.5%)was the most frequent gene,followed by the blaOXA-23(4.34%),blaIMP-1(1.63%),and blaVIM-1(0.54%).Meanwhile,blaOXA-58 and blaOXA-143 genes were not found.81.5%and 66.1%of isolates contained ISAba1 upstream of the blaOXA-23 and blaOXA-58 genes,***-PCR results revealed the carbapenem non-susceptible isolates belonged to three distinct clones:A 171(81%),B 34(16.1%),and C 6(2.8%).Conclusions:The results indicated a high prevalence of carbapenem-non-susceptible ***,with the emergence of the blaOXA-24 gene as the most common gene and the notable prevalence of MBL *** results revealed the need for appropriate therapeutic and infection control strategies and monitoring susceptibility patterns for controlling *** infections.

关键词： Acinetobacter baumannii Carbapenemase Metallo-β-lactamases Repetitive extragenic palindromic(rep)-PCR

Kostmann’s Neutropenia: A Case Report

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Open Journal of Pediatrics 2024年第5期14卷 869-872页

作者： Khaoula Achir Ilham Tadmori Mounia Lakhdar Idrissi Fatima zahra Souilmi Mohamed Hbibi Moustapha Hida Pediatric Department of CHU Hassan II in Fez Fez Morocco

Kostmann syndrome, or severe congenital neutropenia, is a rare condition in children marked by a neutrophil count of less than 500/mm 3 . This congenital agranulocytosis, an autosomal recessive genetic disorder, is often first identified by a neonatal infectious syndrome. The deficiency in neutrophils increases susceptibility to bacterial and fungal infections. Prior to the availability of hematopoietic growth factors, the disease was associated with significant morbidity and early mortality. We present the case of a 17-month-old boy who was admitted to the pediatric emergency department at Hassan II University Hospital in Fes with skin abscesses.

关键词： Kostmann Syndrome Severe Congenital Neutropenia Skin Abscesses

Expression level of interferon-stimulated genes PKR,OAS1,MX1,and ISG15 in peripheral blood mononuclear cells of COVID-19 patients:A retrospective study

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Journal of Acute Disease 2024年第3期13卷 111-115页

作者： Elham Jafari Maskouni Samaneh Abbasi Elham Mousavi zahra Najafimemar Ali Mohammad Arabzadeh Mehrdad Farrokhnia Saeedeh Ebrahimi Department of Medical Microbiology(Bacteriology&Virology) Afzalipour Faculty of MedicineKerman University of Medical SciencesKermanIran Abadan University of Medical Sciences AbadanIran Infectious Diseases Research Center Golestan University of Medical SciencesGorganIran Department of Internal Medicine Afzalipour School of MedicineKerman University of Medical SciencesKermanIran

Objective:To explore expression level of interferon-stimulated genes PKR,OAS1,MX1,and ISG15 in peripheral blood mononuclear cells of COVID-19 ***:In this study,changes in the expression of four interferon-stimulated genes(ISGs),including PKR,OAS1,MX1,and ISG15,in peripheral blood mononuclear cells of 45 COVID-19 patients with different severities were evaluated by real-time PCR ***:OAS1,MX1,PKR,and ISG15 were differently expressed in COVID-19 patients with different *** results showed that the expression of OAS1,MX1,PKR,and ISG15 genes was significantly(P=0.001)lower in severe ***:Weak and defective IFN response and subsequent disruption of ISGs may be associated with COVID-19 severity.

关键词： COVID-19 SARS-CoV-2 Interferon ISGs Severe COVID-19 Risk factors Interferon signaling

3D Modeling and Determination of Factors Responsible for Zinc-Lead Mineralization in the Mehdiabad Deposit,Central Iran,based on Statistical Analysis of Geochemical Data

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Acta Geologica Sinica(English Edition) 2022年第6期96卷 2040-2055页

作者： zahra BONYADI Department of Geology Faculty of SciencesImam Khomeini International UniversityQazvinIran

Although the Mehdiabad zinc-lead deposit is one of the most well-known deposits in the central Iran structural zone,the genesis of the deposit remains *** host rock of the ore is a dolomitic limestone of the Lower Cretaceous Taft *** the two main orebodies of the deposit,which includes the Black Hill and East Ridge ore zones,the oxide and sulfide ores are observed at the surface and at depth,*** elements Zn,Fe,Mn and Mg are more abundant in the East Ridge ore zone(in both sulfide and oxide ores),with Ba,Pb,Ag and Cu being more abundant in the Black Hill oxide *** on the distribution of elements and their correlation with each other in these ore zones,the elements are divided into three general groups,that of terrigenous elements,chemically-deposited elements and oreforming(hydrothermally deposited)elements,a division that is supported by the results of factor *** spatial distribution of elements is jointly affected by contact with host rocks,the boundary of oxide-sulfide ores and fault *** main factors governing the distribution of elements are the mechanical transfer of detrital sediments,chemical sedimentation,transfer by hydrothermal fluids,oxidation and surface dissolution,all of which affected the spatial distribution of *** ore-forming elements are mostly affected by hydrothermal fluids and *** study not only provides additional information about the genesis of the Mehdiabad deposit,but also could assist in the exploitation of ore and further exploration *** results of this study can aid in the exploration and exploitation of the Mehdiabad deposit and similar deposits in the region.

关键词： hydrothermal fluids geochemistry elemental distribution factor analysis Mehdiabad deposit MVT deposit

Synthesis of biaryls using palladium nanoparticles immobilized on peptide nanofibers as catalyst and hydroxybenzotriazole as novel phenylating reagent

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Chinese Journal of Catalysis 2017年第3期38卷 469-474页

作者： Arash Ghorbani-Choghamarani zahra Taherinia 伊拉姆大学理学院化学系伊朗伊拉姆69315516

Peptide nanofibers decorated with palladium nanoparticles catalyzed direct coupling of aryl halides with hydroxybenzotriazole to afford the corresponding biaryls in good to excellent *** coupling reactions proceeded under simple,green,and mild *** peptide nanofibers were used as recyclable supports in the coupling *** approach is the first to use hydroxybenzotriazole as a phenylating agent.

关键词： Peptide nanofiber Hydroxybenzotriazole Biaryl PEG Palladium

Barrier-Certified Learning-Enabled Safe Control Design for Systems Operating in Uncertain Environments

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IEEE/CAA Journal of Automatica Sinica 2022年第3期9卷 437-449页

作者： zahra Marvi Bahare Kiumarsi IEEE Department of Electrical and Computer Engineering Michigan State UniversityMI 48824 USA

This paper presents learning-enabled barriercertified safe controllers for systems that operate in a shared environment for which multiple systems with uncertain dynamics and behaviors *** is,safety constraints are imposed by not only the ego system’s own physical limitations but also other systems operating *** the model of the external agent is required to impose control barrier functions(CBFs)as safety constraints,a safety-aware loss function is defined and minimized to learn the uncertain and unknown behavior of external *** specifically,the loss function is defined based on barrier function error,instead of the system model error,and is minimized for both current samples as well as past samples stored in the memory to assure a fast and generalizable learning algorithm for approximating the safe *** proposed model learning and CBF are then integrated together to form a learning-enabled zeroing CBF(L-ZCBF),which employs the approximated trajectory information of the external agents provided by the learned model but shrinks the safety boundary in case of an imminent safety violation using instantaneous sensory *** is shown that the proposed L-ZCBF assures the safety guarantees during learning and even in the face of inaccurate or simplified approximation of external agents,which is crucial in safety-critical applications in highly interactive *** efficacy of the proposed method is examined in a simulation of safe maneuver control of a vehicle in an urban area.

关键词： Control barrier functions(CBFs) experience replay learning safety-critical systems uncertainty

A comprehensive layered approach for implementing internet of things-enabled smart grid:A survey

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Digital Communications and Networks 2022年第3期8卷 388-410页

作者： zahra Alavikia Maryam Shabro Electric Power Utility(EPU)Digital Transformation Center Niroo Research Institute(NRI)TehranIran

The current power grid confronts severe challenges in satisfying customers'*** transition to the much more flexible power grid enriched with renewable energies,micro-grid,and distributed energy resources has been considered as a straightforward solution to the customers’high *** smart equipment and renewable energies,electric power generation and storage through the power grid domains will be facilitated,which enables bi-directional energy and information *** power grid with such enhanced features is called Smart Grid(SG).Controlling and managing the diverse sets of variables in the SG requires precise measuring,monitoring,communicating,and analytic systems which increase the complexity of the *** complexity is the main barrier to the realization of the SG up to *** emergence of the Internet of Things(IoT)simplifies monitoring,communications,and data processing among smart things to connect to anything in the *** motivates the SG stakeholders and researchers to proceed with the best way to exploit the IoT technologies in the *** this survey paper,we summarize various efforts in this regard to highlight the advantages of the IoT-enabled SG and its probable *** this end,a comprehensive layered approach has been proposed in this paper to classify various applications of the IoT technologies in the *** IoT opportunities in each architecture layer facilitates the role of each technology and its relationship with other ***,open issues and future measures for the realization of IoT-enabled SG have been discussed in the paper.

关键词： Smart grid(SG) Internet of things(IoT) Layered approach Open issues