检索结果-南通市图书馆

3d过渡金属单原子掺杂石墨烯缺陷电催化还原CO_(2)的第一性原理研究

在线全文

学校读者我要写书评

暂无评论

无机材料学报 2024年第7期39卷 845-852,I0012-I0014页

作者：靳宇翔宋二红朱永福吉林大学材料科学与工程学院长春130025 中国科学院上海硅酸盐研究所上海200050

将CO_(2)高效转化为有价值的化学品(如CO和HCOOH等)是缓解环境问题、实现碳中和的重要措施。然而CO_(2)还原反应(CO_(2)RR)有着产物多样和路径复杂的特点,再加上目前难以确定影响CO_(2)RR活性的真正因素,使得设计对特定产物有高选择性... 详细信息

将CO_(2)高效转化为有价值的化学品(如CO和HCOOH等)是缓解环境问题、实现碳中和的重要措施。然而CO_(2)还原反应(CO_(2)RR)有着产物多样和路径复杂的特点,再加上目前难以确定影响CO_(2)RR活性的真正因素,使得设计对特定产物有高选择性和高活性的催化剂十分具有挑战性。本研究从第一性原理出发,系统研究了3d过渡金属单原子掺杂石墨烯单个空位(TM@CSV)和双空位(TM@CDV)电催化还原CO_(2)的潜力,具体涵盖基底的稳定性、中间产物热力学吸附以及与之竞争的析氢反应(HER)。通过对Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu和Zn掺杂石墨烯缺陷后形成的20种催化剂进行筛选,发现Sc原子掺杂石墨烯单个空位的Sc@CSV和Sc、Ti原子掺杂石墨烯双空位的Sc@CDV和Ti@CDV同时具备吸附CO_(2)分子和抑制HER的能力。其中Sc@CDV对HCOOH表现出最佳的活性和选择性,速率决定步骤的吉布斯自由能差仅为0.96 eV。最后,通过电子结构分析进一步揭示了Sc@CDV优于其他催化剂的原因是Sc@CDV调整了费米能级附近的活性电子态,从而实现对CO_(2)的高效还原。

关键词：第一性原理单原子催化剂 CO_(2)还原反应 HCOOH 碳中和

Old Pinus massoniana forests benefit more from recent rapid warming in humid subtropical areas of central-southern China

在线全文

学校读者我要写书评

暂无评论

Journal of Forestry Research 2024年第5期35卷 155-170页

作者： Wenxin Li Liangjun zhu Lianhua zhu Mengdan Jing Censhi Qian Yu zhu Paolo Cherubini College of Life Science and Technology Central South University of Forestry and TechnologyChangsha 410004People’s Republic of China Swiss Federal Institute for Forest Snow and Landscape Research WSL8903 BirmensdorfSwitzerland Department of Forest and Conservation Sciences Faculty of ForestryUniversity of British Columbia2004-2424 Main MallVancouverBC V6T 1Z4Canada

Trees progress through various growth stages,each marked by specific responses and adaptation strate-gies to environmental *** the importance of age-related growth responses on overall forest health and management policies,limited knowledge exists regarding age-related effects on dendroclimatic relationships in key subtropical tree *** this study,we employed a den-drochronological method to examine the impact of rapid warming on growth dynamics and climatic sensitivity of young(40–60 years)and old(100–180 years)Pinus mas-soniana forests across six sites in central-southern *** normalized log basal area increment of trees in both age groups increased significantly following rapid warming in *** in young forests further showed a distinct growth decline during a prolonged severe drought(2004–2013),whereas those in old forests maintained growth *** growth was more strongly influenced by temperature than by moisture,particularly in old *** tem-peratures strongly and positively impacted the growth of old trees but had a weaker effect on young *** forests had a significantly lower resistance to extreme drought but faster recovery compared to young ***“divergence problem”was more pronounced in younger forests due to their heightened sensitivity to warming-induced drought and heat *** ongoing warming,young forests also may initially experience a growth decline due to their heightened sensitivity to winter *** findings underscore the importance of considering age-dependent changes in forest/tree growth response to warming in subtropical forest man-agement,particularly in the context of achieving“Carbon Peak&Carbon Neutrality”goals in China.

关键词： Tree rings Pinus massoniana Age effects Drought resilience Subtropical forests Rapid warming

Synergistic catalysis of the N-hydroxyphthalimide on flower-like bimetallic metal-organic frameworks for boosting oxidative desulfurization

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Petroleum Science 2024年第1期21卷 674-682页

作者： Jing He Kun zhu Wei Jiang Dong-Ao zhu Lin-Hua zhu Hai-Yan Huang Wen-Shuai zhu Hua-Ming Li Institute for Energy Research Jiangsu UniversityZhenjiang212013JiangsuChina College of Chemistry and Chemical Engineering Hainan Normal UniversityKey Laboratory of Water Pollution Treatment and Resource Reuse of Hainan ProvinceHaikou571158HainanChina

Synergic catalytic effect between active sites and supports greatly determines the catalytic activity for the aerobic oxidative desulfurization of fuel *** this work,Ni-doped Co-based bimetallic metal-organic framework(CoNi-MOF)is fabricated to disperse N-hydroxyphthalimide(NHPI),in which the whole catalyst provides plentiful synergic catalytic effect to improve the performance of oxidative desulfurization(ODS).As a bimetallic MOF,the second metal Ni doping results in the flower-like morphology and the modification of electronic properties,which ensure the exposure of NHPI and strengthen the synergistic effect of the overall *** with the monometallic Co-MOF and naked NHPI,the NHPI@CoNi-MOF triggers the efficient activation of molecular oxygen and improves the ODS performance without an *** sulfur removal of dibenzothiophene-based model oil reaches 96.4%over the NHPI@CoNi-MOF catalyst in 8 h of ***,the catalytic product of this aerobic ODS reaction is sulfone,which is adsorbed on the catalyst surface due to the difference in *** work provides new insight and strategy for the design of a strong synergic catalytic effect between NHPI and bimetallic supports toward high-activity aerobic ODS materials.

关键词： Metal-organic frameworks Doped Bimetallic N-hydroxyphthalimide Aerobic processes Oxidative desulfurization

A review of recent advances in the effects of surface and interface properties on marine propellers

在线全文

学校读者我要写书评

暂无评论

Friction 2024年第2期12卷 185-214页

作者： Manfu zhu Liran MA State Key Laboratory of Tribology in Advanced Equipment Tsinghua UniversityBeijing 100084China

Marine propellers are important propulsion devices for both surface ships and underwater *** severe environmental problems have required further performance enhancement for ***,traditional methods to improve propeller performances through geometrical and structural optimizations have been extensively investigated,while the underlying mechanisms of the effects of surface and interface properties on marine propellers are still far from being fully *** paper presented a comprehensive review of recent advances in the effects of surface and interface properties,such as surface roughness and surface wettability,on marine propellers with an emphasis on the significant improvements in both hydrodynamic and cavitation performances,hoping to arouse more in-depth investigations in the field of surface/interface science and technologies on marine propellers,and also promote the state-of-the-art technologies,such as superlubricity technology,into practical applications.

关键词： marine propellers hydrodynamics cavitation surface roughness surface wettability

Paving the way toward soil safety and health:current status,challenges,and potential solutions

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Frontiers of Environmental Science & Engineering 2024年第6期18卷 63-73页

作者： Chiheng Chu Lizhong zhu College of Environmental and Resource Sciences Zhejiang UniversityHangzhou 310058China

Soil is a non-renewable resource,providing a majority of the world’s food and fiber while serving as a vital carbon ***,the health of soil faces global threats from human activities,particularly widespread contamination by industrial *** physical,chemical,and biological remediation approaches encounter challenges in preserving soil structure and function throughout the remediation process,as well as addressing the complexities of soil contamination on a regional *** solutions encompass monitoring and simulating soil processes,with a focus on utilizing big data to bridge micro-scale and macro-scale ***,reducing pollutant emissions to soil is paramount due to the significant challenges associated with removing contaminants once they have entered the soil,coupled with the high economic costs of ***,it is imperative to implement advanced remediation technologies,such as monitored natural attenuation,and embrace holistic soil management approaches that involve regulatory frameworks,soil health indicators,and soil safety monitoring *** the enduring health and resilience of soils necessitates a blend of interdisciplinary research,technological innovation,and collaborative initiatives.

关键词： Soil safety and health Source emission reduction Process monitoring and simulation Green remediation technology Soil health management

Engineering applications and technical challenges of active array microsystems

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Frontiers of Information Technology & Electronic Engineering 2024年第3期25卷 342-368页

作者： Jiaguo LU Haoran zhu East China Research Institute of Electronic Engineering Hefei 230039China School of Electronic and Information Engineering Anhui UniversityHefei 230601China

In the post-Moore era,the development of active phased array antennas will inevitably trend towards active array *** this paper,the characteristics and composition of the active array antenna are briefly *** to the high efficiency,low profile,and light weight of the active array microsystems,the application prospects and advantages in the engineering of multi-functional airborne radar,spaceborne radar,and communication systems are ***,according to the characteristics of the post-Moore era of integrated circuits,scientific and technological problems in the active array microsystems are presented,including multi-scale,multi-signal,and multi-physics field *** challenges are also discussed,such as new architectures and algorithms,miniaturization of passive components,novel materials and processes,ultra-wideband technology,and new interdisciplinary technological *** paper is expected to inspire in-depth research on active array microsystems.

关键词： Microelectronics Heterogeneous integration Packaging materials Antenna array microsystems Multi-functional radar Communication

Leaching kinetics of fluorine during the aluminum removal from spent Li-ion battery cathode materials

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2024年第4期138卷 312-325页

作者： Shengjie Li Jianxin zhu Research Center for Eco-Environmental Sciences Chinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China

The high content of aluminum(Al)impurity in the recycled cathode powder seriously affects the extraction efficiency of Nickel,Cobalt,Manganese,and Lithium resources and the actual commercial value of recycled materials,so Al removal is crucially important to conform to the industrial standard of spent Li-ion battery cathode *** this work,we systematically investigated the leaching process and optimum conditions associated with Al removal from the cathode powder materials collected in a wet cathode-powder peeling and recycling production line of spent Li-ion batteries(LIBs).Moreover,we specifically studied the leaching of fluorine(F)synergistically happened along with the removal process of Al,which was not concerned about in other studies,but one of the key factors affecting pollution prevention in the recovery *** mechanism of the whole process including the leaching of Al and F from the cathode powder was indicated by using NMR,FTIR,and XPS,and a defluoridation process was preliminarily investigated in this *** leaching kinetics of Al could be successfully described by the shrinking core model,controlled by the diffusion process and the activation energy was 11.14 kJ/***,the leaching of F was attributed to the dissolution of LiPF6and decomposition of PVDF,and the kinetics associated was described by Avrami *** interaction of Al and F is advantageous to realize the defluoridation to some *** is expected that our investigation will provide theoretical support for the large-scale recycling of spent LIBs.

关键词： Al removal F leaching Cathode powder Heating alkali leaching Leaching kinetics

Efficient Removal of Phosphate from Aqueous Solutions Using Corundum-hollow-spheres Supported Caclined Hydrotalcite Porous Thin Films

在线全文

学校读者我要写书评

暂无评论

Journal of Wuhan University of Technology(Materials Science) 2024年第1期39卷 44-49页

作者：刘云才 zhu Chen School of Architecture and Materials Engineering Hubei Second Normal UniversityWuhan 430205China

Phosphate was removed from aqueous environment by corundum-hollow-spheres supported caclined hydrotalcite (cHT) thin films. Mg-Al-CO3 hydrotalcite (HT) thin films were deposited on corundumhollow-sphere substrates by hydrothermal homogeneous precipitation at 120℃for 30-240 min and cHT thin films were obtained by annealing of the HT thin films at 500℃for 180 min. Their crystal phase, morphology and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM).The results show that homogeneous, well-crystallized and hierarchical flower-like thin films were deposited firmly on the surface of the corundum. The mechanism of nucleation and growth of the HT thin films was fitted well with the anion coordination polyhedron growth unit model. To determine the absorption of phosphate by this adsorbent, different bed depth (10-30 cm) and flow rate (1.0-3.0 m L/min) were examined by column experiments. The highest removal efficiency of phosphate amounted to 98.5%under optimum condition (pH=7.2). The adsorption capacity increased as the bed depth increased and decreased as the flow rate increased.

关键词： adsorption phosphate hydrotalcite corundum-hollow-sphere hydrothermal homogeneous precipitation thermal anneal

A proof system of the CaIT calculus

在线全文

学校读者我要写书评

暂无评论

Frontiers of Computer Science 2024年第2期18卷 123-137页

作者： Ningning CHEN Huibiao zhu Shanghai Key Laboratory of Trustworthy Computing East China Normal UniversityShanghai 200062China

The Internet of Things(IoT)can realize the interconnection of people,machines,and things anytime,*** of the existing research mainly focuses on the practical applications of IoT,and there is a lack of research on modeling and reasoning about IoT systems from the perspective of formal ***,the Calculus of the Internet of Things(CaIT)has been proposed to specify and analyze IoT systems before the actual implementation,which can effectively improve development efficiency,and enhance system quality and *** verify the correctness of IoT systems described by CaIT,this paper presents a proof system for CaIT,in which specifications and verifications are based on the extended Hoare Logic with ***,we explore the cooperation between isolated proofs to validate the postconditions of the communication actions occurring in these proofs,with a particular focus on broadcast *** also demonstrate the soundness of our proof system.A simple“smart home”is given to illustrate the availability of our proof system.

关键词： Internet of Things(loT) Calculus of the Internet of Things(CalT) extended hoare logic cooperation smart home