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Bridging microstructure and crystallography with the crack propagation behavior in Ti-6Al-4V alloy fabricated via dual laser beam bilateral synchronous welding

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Journal of Materials Science & Technology 2024年第7期174卷 1-14页

作者： Tingyan Yan Yuan Liu Jianfeng Wang Yong zheng Xiaohong zhan College of Materials Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing 211106China

The microstructure evolution and crack propagation behavior were systematically and thoroughly inves-tigated inα/βTi-6Al-4V alloy obtained under the inhomogeneous heating effect of a coupled dual laser beam via a combination of postmortem electron backscattering diffraction analyses and numerical *** effect of microstructural attributes(grain size,grain boundary,dislocation)on the fracture property and crack propagation behavior was investigated based on thermodynamic and crystallographic analyses,as well as the examinations of dislocation density and the Burgers *** quantifying the degree of variant selection using the degree of variant selection(DVS)equation,it was found that the higher the energy input,the weaker the variant selection,as the secondaryαphase suppresses further dislocation-induced variant selection via autocatalytic nucleation and *** proportion of high an-gle grain boundaries(HAGBs)concentrated around 60°gradually increases with improving cooling rate,mainly due to the change in the tendency of martensite transformation to be *** grain refine-ment was the primary mechanism for the enhancement of Ti-6Al-4V alloy T-joints,while the suppression of crack propagation by HAGBs also played a crucial role in improving strength and *** crack propagation direction frequently changes when the order is approximately parallel to the short axis ofαmartensite grains,forming a zigzag propagation *** above findings should shed light on optimiz-ing dual laser beam bilateral synchronous welding(DLBSW)technology to tailor the microstructure and improve the mechanical properties of Ti-6Al-4V alloy T-joints.

关键词： Ti-6Al-4V alloy Microstructure Grain refinement Crack propagation Dual laser beam bilateral synchronous welding

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Use of a Multiplex RT-PCR Assay for Simultaneous Detection of the North American Genotype Porcine Reproductive and Respiratory Syndrome Virus,Swine Influenza Virus and Japanese Encephalitis Virus

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Agricultural Sciences in China 2010年第7期9卷 1050-1057页

作者： CHEN Hong-ying WEI zhan-yong zhanG Hong-ying LüXiao-li zheng Lan-lan CUI Bao-an LIU Jinpeng ZHU Qian-lei WANG Zi-xin College of Animal Husbandry and Veterinary Henan Agricultural UniversityZhengzhou 450002P.R.China

A multiplex reverse transcriptase-polymerase chain reaction(multiplex RT-PCR) assay was developed and subsequently evaluated for its efficacy in the detection of multiple viral infections simultaneously,in *** primers for each of the 3 RNA viruses,North American genotype porcine reproductive and respiratory syndrome virus,Japanese encephalitis virus,and swine influenza virus,were used in the testing *** assay was shown to be highly sensitive because it could detect as little as 10-5 ng of each of the respective amplicons in a single sample containing a composite of all 3 *** assay was also effective in detecting one or more of the same viruses in various combinations in specimens,including lymph nodes,lungs,spleens,and tonsils,collected from clinically ill pigs and in spleen specimens collected from aborted pig *** results from the multiplex RT-PCR were confirmed by virus *** relative efficiency(compared to the efficiency of separate assays for each virus) and apparent sensitivity of the multiplex RT-PCR method show that this method has potential for application in routine molecular diagnostic procedures.

关键词： Japanese encephalitis virus multiplex RT-PCR porcine reproductive and respiratory syndrome virus swine influenza virus

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Effect of hydration on the surface basicity and catalytic activity of Mg-rare earth mixed oxides for aldol condensation

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Journal of Rare Earths 2018年第4期36卷 359-366页

作者： zheng Wang Pascal Fongarland Guanzhong Lu Wangcheng zhan Nadine Essayem Key Laboratory for Advanced Materials and REsearch Institute of Industrial Catalysis School of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai 200237China Institut de REcherches sur la Catalyse et l'Environnement de Lyon(IRCELYON) CNRS-Universite Lyon 12 Avenue Albert Einstein69626 Villeurbanne CedexFrance

Magnesium and rare earth mixed oxides（Mg3 REOx（RE=La, Y. Ce）） were prepared and characterized by Xray diffraction（XRD）, N_2 adsorption-desorption, infrared spectra and microcalorimetry of CO_2. The results reveal that the Mg_3 CeO_x catalyst is present in the form of Mg-Ce-O solid solution,while the Mg3 LaOx and Mg_3 YO_x catalysts are probably rare earth oxides dispersed on MgO surface. As a result, among the calcined Mg_3 REO_x catalysts, the Mg_3 CeO_x catalyst presents the highest rate constant for acetone aldolization, which is well correlated to its more homogeneous distribution of basic sites. In contrary, the Mg_3 YO_x catalyst exhibit the lowest catalytic activity for acetone aldolization. Upon hydration pre-treatment, the basic properties on the surface of the Mg_3 REO_x catalysts were changed markedly. The Mg_3 YO_x catalyst after hydration treatment shows the highest amount of basic sites on catalyst surface, and then exhibits the highest activity among the hydrated Mg_3 REO_x catalysts. These results make it possible to fine-tune basic sites for acetone aldolization.

关键词： Mg-rare earth mixed oxide Hydration treatment Water tolerance Aldol condensation Solid base catalyst Rare earths

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Numerical Simulation of Fretting Fatigue Damage Evolution of Cable Wires Considering Corrosion and Wear Effects

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Computer Modeling in Engineering & Sciences 2023年第8期136卷 1339-1370页

作者： ying Wang zheng Yan Yangyang Wu Key Laboratory of Concrete and Prestressed Concrete Structures of Ministry of Education Southeast UniversityNanjing211189China

In this paper,a numerical model of fretting fatigue analysis of cablewire and the fretting fatigue damage constitutive model considering the multi-axis effect were established,and the user material subroutine UMAT was ***,the constitutive model of wear morphology evolution of cable wire and the constitutive model of pitting evolution considering the mechanical-electrochemical effect were established,*** corresponding subroutines UMESHMOTION_Wear and UMESHMOTION_Wear_Corrosion were written,and the fretting fatigue lifewas further *** results showthat the numerical simulation life obtained by the programin this paper has the same trend as the tested one;the error is only about 0.7%in the medium life area;When the normal contact force increases from 120 to 240 N,the fretting life of cable wire decreases by 25%;When the evolution of wear morphology and corrosion effect are considered simultaneously,the depth of the wear zone exceeds 0.08mm after 600,000 loads,which ismuch larger than 0.04 mmwhen only the evolution of wear morphology is *** the evolution of wear morphology and corrosion morphology is considered simultaneously,the damage covers the whole contact surface after 300,000 loads,and the penetrating damage zone forms after 450,000 loads,which is obviously faster than that when only the wearmorphology evolution is *** proposed in this paper can provide a feasible numerical simulation scheme for the visualization of the damage process and accurate life prediction of cable-supported bridges.

关键词： Fretting fatigue multiaxial fatigue electrochemical corrosion damage evolution life prediction

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喜马拉雅山区中国西藏与尼泊尔的地质灾害灾情差异研究

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灾害学 2025年第1期40卷 187-193页

作者：兰思辰邵丽竹肖怡晴郑相宜王瑛北京师范大学环境演变与自然灾害教育部重点实验室北京100875 北京师范大学地理科学学部北京100875 应急管理部-教育部减灾与应急管理研究院北京100875

喜马拉雅山区是全球地质灾害最为多发的地区之一。其北侧的中国西藏地区与南侧的尼泊尔在地质灾害的灾情及其成因上存在显著差异。该研究选取这两个地区作为案例,对比分析了2012—2021年间的地质灾害情况。尼泊尔记录了2256次地质灾害,... 详细信息

喜马拉雅山区是全球地质灾害最为多发的地区之一。其北侧的中国西藏地区与南侧的尼泊尔在地质灾害的灾情及其成因上存在显著差异。该研究选取这两个地区作为案例,对比分析了2012—2021年间的地质灾害情况。尼泊尔记录了2256次地质灾害,远高于我国西藏地区的799次;同时,尼泊尔的人员伤亡也更为严重,两地年均每百万人的伤亡率分别为8.1人和2人;尼泊尔的年均因灾经济损失远低于西藏,两地地质灾害损失占GDP比例分别为0.006%、0.07%。尼泊尔近年来地质灾害次数的增加与道路建设密切相关,年均道路里程增加1036km,且37%的伤亡案例发生在道路沿线。研究结果表明,尼泊尔和中国在地质灾害防治措施上均有所加强,并已取得显著的减灾效果。

关键词：地质灾害灾情差异喜马拉雅中国西藏尼泊尔

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Computational Modeling of Solvent Effects on Protein-Ligand Interactions Using Fully Polarizable Continuum Model and Rational Drug Design

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Communications in Computational Physics 2013年第1期13卷 31-60页

作者： Fang zheng Chang-Guo zhan Department of Pharmaceutical Sciences College of PharmacyUniversity of Kentucky789 South Limestone StreetLexingtonKentucky 40536USA

This is a brief review of the computational modeling of protein-ligand interactions using a recently developed fully polarizable continuum model(FPCM)and rational drug *** modeling has become a powerful tool in understanding detailed protein-ligand interactions at molecular level and in rational drug *** study the binding of a protein with multiple molecular species of a ligand,one must accurately determine both the relative free energies of all of the molecular species in solution and the corresponding microscopic binding free energies for all of the molecular species binding with the *** this paper,we aim to provide a brief overview of the recent development in computational modeling of the solvent effects on the detailed protein-ligand interactions involving multiple molecular species of a ligand related to rational drug *** particular,we first briefly discuss the main challenges in computational modeling of the detailed protein-ligand interactions involving the multiple molecular species and then focus on the FPCM model and its *** FPCM method allows accurate determination of the solvent effects in the first-principles quantum mechanism(QM)calculations on molecules in *** combined use of the FPCM-based QM calculations and other computational modeling and simulations enables us to accurately account for a protein binding with multiple molecular species of a ligand in *** on the computational modeling of the detailed protein-ligand interactions,possible new drugs may be designed rationally as either small-molecule ligands of the protein or engineered proteins that bind/metabolize the *** computational drug design has successfully led to discovery and development of promising drugs.

关键词： Protein-ligand interaction solvent effect rational drug design binding affinity

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Microstructural evolution and aging behavior of Mg-4.5Y-2.5Nd-1.0Gd-0.5Zr alloys with different Zn additions

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Rare Metals 2021年第8期40卷 2188-2196页

作者： zheng Tian Qiang Yang Kai Guan zhan-Yi Cao Jian Meng Key Laboratory of Automobile Materials of Ministry of Education Department of Materials Science and EngineeringJilin UniversityChangchun130025China State Key Laboratory of Rare Earth Resources Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun130022China

Microstructures and mechanical properties of Mg-4.5 Y-2.5 Nd-1.0 Gd-0.5 Zr-xZn(x=0,0.5,1.0,and 1.5;wt%)alloys under as-cast and peak-aged states were investigated in this *** results indicate that the intermetallic phase components are closely dependent on Zn *** as-cast state,the dominant eutectic phase is Mg5 RE in the alloys with 0 wt%and 0.5 wt%Zn additions while Mg5 RE,18 R-and 14 H-LPSO(long period stacking ordered)phases in the alloys with 1.0 wt%and1.5 wt%Zn *** solution and peak-aging,the highest strength and hardness were obtained on the alloy with 0.5 wt%Zn *** electron microscopy(TEM)characterizations revealed that there are denser and finer precipitates on basal(β’)and prismatic(γ’)planes,***,the excellent mechanical performance of the alloy with 0.5 wt%Zn addition is mainly due to precipitation strengthening and grain boundary strengthening.

关键词： Magnesium alloy Intermetallic phase Precipitates Mechanical property

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Multi-electron reaction and fast Al ion diffusion of δ-MnO_(2) cathode materials in rechargeable aluminum batteries via first-principle calculations

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Chinese Chemical Letters 2024年第4期35卷 248-254页

作者： Lumin zheng ying Bai Chuan Wu School of Materials Science&Engineering Beijing Institute of TechnologyBeijing 100081China Yangtze Delta Region Academy of Beijing Institute of Technology Jiaxing 314019China

Rechargeable aluminum batteries with multi-electron reaction have a high theoretical capacity for next generation of energy storage devices. However, the diffusion mechanism and intrinsic property of Al insertion into MnO_(2) are not clear. Hence, based on the first-principles calculations, key influencing factors of slow Al-ions diffusion are narrow pathways, unstable Al-O bonds and Mn^(3+) type polaron have been identified by investigating four types of δ-MnO_(2)(O3, O'3, P2 and T1). Although Al insert into δ-MnO_(2) leads to a decrease in the spacing of the Mn-Mn layer, P2 type MnO_(2) keeps the long(spacious pathways)and stable(2.007–2.030 A) Al-O bonds resulting in the lower energy barrier of Al diffusion of 0.56 e V. By eliminated the influence of Mn^(3+)(low concentration of Al insertion), the energy barrier of Al migration achieves 0.19 e V in P2 type, confirming the obviously effect of Mn^(3+) polaron. On the contrary, although the T1 type MnO_(2) has the sluggish of Al-ions diffusion, the larger interlayer spacing of Mn-Mn layer,causing by H_(2)O could assist Al-ions diffusion. Furthermore, it is worth to notice that the multilayer δ-MnO_(2) achieves multi-electron reaction of 3|e|. Considering the requirement of high energy density, the average voltage of P2(1.76 V) is not an obstacle for application as cathode in RABs. These discover suggest that layered MnO_(2) should keep more P2-type structure in the synthesis of materials and increase the interlayer spacing of Mn-Mn layer for providing technical support of RABs in large-scale energy storage.

关键词： Rechargeable aluminum batteries δ-MnO_(2) First-principles calculations Multi-electron reaction Diffusion mechanism

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[Y(IO3)3(H2O)2]n: a New Rare Earth Iodate Featuring the Circle-shaped I4O12 Polyiodate Anion and Three-order Nonlinear Optical Property

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Chinese Journal of Structural Chemistry 2020年第7期39卷 1307-1313页

作者： CHEN Jing-Jing zheng Yu-ying College of Material Science and Engineering Fuzhou UniversityFuzhou 350108China

A new layered yttrium iodate[Y(IO3)3(H2O)2]n(1)has been prepared from the hydrothermal reaction of Y(NO3)3?6H2O with I2O5 at 170℃,and its structure was determined by X-ray single-crystal diffraction *** belongs to the triclinic system,space group P1 with a=7.355(5),b=7.515(5),c=9.413(7)?,α=79.65(2)o,β=85.18(3)o,γ=71.870(19)o,Z=2,V=486.2(6)?3.1 was further characterized by FTIR,powder X-ray diffraction(PXRD)and UV-Vis *** 1,the Y centers in a monocapped trigonal prism environment are bound by IO-3 anion and unique circle-shaped I4O12 polyiodate anion to generate a wave-like 2-D *** adjacent layers are further linked with each other by hydrogen bonds to form a quasi-3-D supramolecular network.1 exhibits a reverse saturation absorption and a self-defocusing effect with the nonlinear absorption coefficientβbeing–0.66×10-5 mW-1,which stems mainly from the electron transition from O-2p to I-5p orbital within iodates upon theoretical calculation.

关键词： rare earth iodate hydrothermal synthesis three-order nonlinear optical theoretical calculation

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Quasi-3-D Gadolinium Iodate Constructed from Infinite Polyiodate: Structure, Green-emission and UV Light-driven Degradation on Organic Dye

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Chinese Journal of Structural Chemistry 2020年第7期39卷 1323-1330页

作者： CHEN Jing-Jing zheng Yu-ying College of Material Science and Engineering Fuzhou UniversityFuzhou 350108China

A new gadolinium iodate has been synthesized via hydrothermal method,and its structure was determined as[Gd(H2O)(IO3)2(IO3H2O)]n(1)by X-ray single-crystal *** 2-D layer is built from the linkage of Gd2O16I4 dimer viaμ2/μ3-bridged iodates,and the quasi-3-D network is generated via weak I···O bonds and hydrogen ***,powder X-ray diffraction(PXRD)and UV-Vis spectra were conducted to characterize the as-synthesized ***,1 exhibits green emission,which might be assigned to electronic transfer within iodate *** UV adsorption of 1 hints its UV light-driven photocatalytic property,and as expected,it exhibits photocatalytic activity for the degradation of rhodamine *** calculation was conducted to give structure/property correlation.

关键词： rare earth iodate hydrothermal synthesis luminescence DFT calculation

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