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Chemical Research in Chinese Universities 2002年第3期18卷 287-289页

作者： LUO Xu yang zhao jian zhang LIN Ying jie LIU Zai qun College of Chemistry Jilin UniversityChangchun 130023P.R.China

The hemolysis of human red blood cells was initiated by a water soluble free radical initiator, 2,2′ azobis (2 amidinopropane hydrochloride)(AAPH), at 37 ℃ in phosphate buffered saline(pH=7.4). The respective addition of 1 [ N (o hydroxybenzylidene)amino]tetradecane(TDCA), 1,2 di[ N (o hydroxybenzylidene)amino]cyclohexane(DACH), 4 [ N (o hydroxybenzylidene)amino]benzoic acid(PABA), 4 nitro[ N (o hydroxybenzylidene)]aniline(APNA) or N (o hydroxybenzylidene)aniline(APA) can all prolong the inhibition period of hemolysis, indicating that the above Schiff bases play an antioxidative role in free radical induced hemolysis. It can be concluded that Schiff base with an alkyl group or a conjugated system in the molecule protect red blood cells against free radical induced hemolysis efficiently. This information may be useful for antioxidant drug design.

关键词： Red blood cell Hemolysis Schiff base Free radical

Radiation effect of Apocynum fiber

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Nuclear Science and Techniques 2006年第1期17卷 38-42页

作者： ZOU Qin zhao Xin zhang jian-Bing TANG Jun FAN zhao-Tian SUN Wan-Fu The Center of Analysis and Measurement of Xinjiang University Urumqi 830046 China

Changes of surface shape, aggregate state, and microstructure of Apocynum fiber before and after irradia-tion were studied by XRD, IR, SEM, ESR, and solid state 13C CP/ MAS NMR. The results show that the surface shape and microstructure were not spoiled under 50 kGy gamma irradiation, while the crystallization of Apocynum fiber changed under 280 kGy . It also shows that different free radicals appear after irradiation and their concentration increases with the increase of irradiation dose.

关键词：辐射效应罗布麻纤维氢键结合表面形状微结构

Disease Risks of Childhood Obesity in China

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Biomedical and Environmental Sciences 2005年第6期18卷 401-410页

作者： YAN-PING LI XIAO-GUANG YANG FENG-YING ZHAI jian-HUA PIAO WEN-HUA zhao jian zhang GUAN-SHENG MA National Institute for Nutrition and Food Safety Chinese Center for Disease Control and Prevention 29 Nanwei Road Beijing 100050 China

Objective To estimate the relative risks of dyslipidemia, hypertension, diabetes mellitus, and metabolic syndromes among overweight and obese Chinese children compared with their normal weight counterparts. Methods Overweight and obesity were defined by age- and sex-specific BMI classification reference for Chinese children and adolescents. Pediatric metabolic syndrome （MetS） and each risk factor for MetS were defined using the criteria for US adolescents. Definition of hyper-TC, LDL, and dyslipidemia for adults was applied as well. General linear model factor analysis and chi-square test were used to compare the difference in metabolic indicators among normal weight, overweight, and obese groups. Multiple logistic regression analysis was performed to estimate the odds ratio of metabolic abnormalities between obesity, overweight, and normal weight children, after adjustment for living area, family economic level, age, sex, and daily exercise time and TV watching time, as well as different dietary indices in the model. Results Significant increases in blood lipids, glucose, and blood pressure were found among overweight and obese children as compared with their counterparts with normal weight. By applying WGOC-recommended BMI classification, the risks for hypertriglyceridemia, low HDL and dyslipidemia among overweight children were 1.9, 1.4, and 1.5 times, and was 3.3, 1.5, and 1.8 times among obese groups compared to their counterparts with normal weight after adjustment for age, sex, region, socioeconomic status, physical activity, and dietary intakes. The overweight and obese children （15-17.9 years） had a high-risk of developing hypertension, which was 2.3 and 2.9 times higher than their counterparts with normal weight. Above 90% obese adolescents had abdominal obesity, while less than 1% normal weight ones had abdominal obesity. No obese adolescents were free from any risk factors for MetS, while 36.9% of normal weight adolescents were from the risk factors. 83.

关键词： Chinese obese children Metabolic syndrome (MetS) Hypertension Lipids Relative risk

High Energy Proton-Proton Elastic Scattering in the Pomeron Exchange Model

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Communications in Theoretical Physics 2002年第7期38卷 65-67页

作者： HU zhao-Hui zhang jian ZHOU Li-Juan LIU Ji-Feng MA Wei-Xing Department of Information and Computing Science Guangxi University of Technology Liuzhou 545006 China Department of Physics Guangxi Normal University Guilin 541004 China Department of Information and Computing Science Guangxi University of Technology Liuzhou 545006 China Department of Physics Guangxi Normal University Guilin 541004 China Department of Information and Computing Science Guangxi University of Technology Liuzhou 545006 China Institute of High Energy Physics the Chinese Academy of Sciences Beijing 100039 China Institute of Theoretical Physics the Chinese Academy of Scie

We study high energy proton-proton elastic scattering in the framework of Pomeron exchange model. The cross section of the process are calculated without any free parameters. Our finding is that Pomeron exchange theory gives perfect fits to total cross section at the energy of√s higher than 10 GeV and to differential cross section at the momentum transfer [t] less than 1.5 GeV2. For total cross section at lower energy √s ＜ 10 GeV and differential cross section at larger momentum transfer region of |t| ＞ 1.5 GeV2, the Pomeron exchange theory needs to be improved.

关键词： proton-proton elastic scattering, Pomeron exchange, cross section

Grain Size and Photocatalytic Activity of Nanometer TiO_2 Thin Films Prepared by the Sol-gel Method

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Journal of Wuhan University of Technology(Materials Science) 2001年第2期16卷 1-5页

作者：余家国 SKLATMSP Wuhan University of Technololgy Wuhan 430070 China

Transparent anatase TiO2 nanometer thin films with photocatalytic activity were prepared via the sol-gel method on soda-lime glass. The thickness , crystalline phase, grain size, surface hydroxyl amount and so on were characterized by scanning electron microscopy (SEM) , X-ray diffraction (XRD), transmission electron microscopy ( TEM), X-ray photoelectron spectroscopy (XPS) and UV-visible spectrophotometer ( UV-VIS). The photocatalytic activity of TiO2 thin films was evaluated for the photocatalytic decolorization of aqueous methyl orange . The effects of film thickness on the crystalline phase, grain size, transmittance and photocatalytic activity of nanometer Ti02 thin films were discussed.

关键词： sol-gel method titania thin films grain size photocatalytic activity

Chemoselective Catalytic Hydrogenation of α,β-Unsaturated Ketones and α,β-Unsaturated Carboxylic Esters

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Chemical Research in Chinese Universities 1998年第2期14卷 17-22页

作者： zhang Jing-wen zhao jian-zhang zhang Xiao-long jianG Yu-lin MA Xiu-li SUN Yun-xiu jianG Wen-pu LI Yao-xian XU Zhi-luo Department of Chemistry Jilin UniversityChangchun130023

The effect of catalysts P-2 00-Ni(Nickel boride) and P-2 00-Ni-M(M: Co, Fe, Cu, Sn), prepared by adopting a modified recipe, on the chemoselective hydrogenation of carbon carbon double bonds in α,β- unsaturated ketones, and the activity of catalysts P-1.80-Ni, P-2 00-Ni or P-1.80(2 00) -Ni-M(M: Pd, Co, Cu) in the selective hydrogenation of carbon carbon double bonds in α,β-unsaturated carboxylic esters, were investigated systematically. According to the experimental results, the selectivities of these catalysts toward the hydrogenation of the carbon carbon double bonds of α,β-unsaturated keones or α,β-unsaturated carboxylic esters are 96%—100% or 100%, respectively.

关键词： α β-Unsaturated ketone Nickel boride α β-Unsaturated carboxylic ester

Deceptive jamming discrimination based on range-angle localization of a frequency diverse array

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Frontiers of Information Technology & Electronic Engineering 2017年第9期18卷 1437-1446页

作者： zhao-jian zhang Jun-wei XIE Chuan SHENG Zhun TANG Air and Missile Defense College Air Force Engineering University Xi 'an 710051 China

We propose a method to suppress deceptive jamming by frequency diverse array （FDA） in radar electronic coun- termeasure environments. FDA offers a new range-angle-dependent beam pattern through a small frequency increment across elements. Due to the coupling between the angle and range, a mismatch between the test angle and physical angle occurs when the slant range on which the beam focuses is not equal to the slant range of the real target. In addition, the range of the target can be extracted by sum-difference beam except for time-delay testing, because the beam provides a range resolution in the FDA that cannot be deceived by traditional deceptive jamming. A strategy of using FDA to transmit two pulses with zero and nonzero frequency increments, respectively, is proposed to ensure that the angle of a target can be obtained by FDA. Moreover, the lo- calization performance is examined by analyzing the Cramer-Rao lower bound and detection probability. Effectiveness of the proposed method is confirmed by simulation results.

关键词： Frequency diverse array (FDA) Deceptive jamming Range-angle coupling Sum-difference beam Double-pulse

Synthesis of Enantiom eric Planar Square Ni^(2+) -and Cu^(2+) -Schiff Base Com plexes

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Chemical Research in Chinese Universities 1999年第3期15卷 248-252页

作者： zhao jian-zhang WANG Shu-gang WANG Xu LIU Ju-zheng QIAO Xiao-guang LI Yao-xian WANG Hua Department of Chemistry Jilin UniversityChangchun 130023P.R.China Third Clinical College&China Japan Union Hospital of Norman Bethune Unviersity of Me dical Sciences Changchun 130023P.R.China

Enantiomeric four chelated planar square schiff base Cu 2+ and Ni 2+ complexes were synthesized using ( 1R,trans ) and ( 1S,trans) N,N  bis(2 hydroxyphenyl methylene) 1,2 diaminocyclohexane. The chirality could not be shown by usual UV Vis spectra. The intrinsic chiral difference of the enantiomeric complexes can be displayed by circular dichroism(CD) spectra. The Cotton effect of every polarlight sensitive absorption of one enantiomer will be the opposite of that of the other enantiomer. It was found that no tetrahedron form exists for Ni 2+ complexes, which was determined with UV Vis spectra and Electron Paramagnetic Resonance(EPR) measures.

关键词： Chiral transition metal schiff base complex Circular dichroism(CD) Enantiomeric

Transforming waste particles into valuable adsorbents via amyloid-mediated molecular engineering

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Science China Chemistry 2025年第1期68卷 317-328页

作者： Qingmin Yang jian zhao Yujia zhang Xingyu Zhou Hao Ren Bowen Hu Zhongli Lei Lixin Chen Peng Yang School of Material and Chemical Engineering Bengbu University Anhui Provincial Engineering Laboratory of Silicon-Based Materials School of Chemistry and Chemical Engineering Northwestern Polytechnical University Key Laboratory of Applied Surface and Colloid Chemistry Ministry of Education School of Chemistry and Chemical EngineeringShaanxi Normal University Xi'an Key Laboratory of Polymeric Soft Matter School of Chemistry and Chemical Engineering Shaanxi Normal University International Joint Research Center on Functional Fiber and Soft Smart Textile School of Chemistry and Chemical EngineeringShaanxi Normal University

The high-value utilization of industrial solid waste using a facile and eco-friendly process is of great interest and significance in reducing environmental pollution and developing a green circular economy. Herein, we propose an amyloid-mediated molecular engineering strategy to transform particulate waste into valuable adsorbents for metal ions. Our method has the advantage of aqueous solution fabrication under mild conditions without the use of high-temperature hydrothermal methods and toxic chemical reagents. Amyloid-mediated molecular engineering manipulates the phase transition of bovine serum albumin(BSA)on particulate waste surfaces, resulting in a remarkable ～3.1 times improvement in the adsorption capacity of fly ash, a typical industrial solid waste for gold ions after modification with the phase-transitioned BSA(PTB). The resultant adsorption ability was 69–1,980 times higher than those of conventional and emerging adsorbent materials such as ion exchange resins, activated carbon(AC), covalent organic frameworks(COFs), and metal-organic frameworks(MOFs). We further demonstrated the application of our PTB-modified materials in the recovery of precious metals from low-grade gold ore and electronic waste leachates. Consequently, this strategy could increase the value of waste materials nearly 27 times. In addition, this method is generally extendable to other conventional industrial adsorbents such as resin, clay, and Al2O3, and enhances their adsorption capabilities at least twofold. Overall, this work provides a simple and green approach for improving the adsorption performance of solid particles, and is expected to develop into a universal strategy for transforming waste particles into high-value-added products.

关键词： amyloid-like protein aggregates surface engineering fly ash solid waste adsorption

Comparative proteomic analysis of plasma exosomes reveals the functional contribution of N-acetyl-alpha-glucosaminidase to Parkinson’s disease

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Neural Regeneration Research 2025年第10期20卷 2998-3012页

作者： Yuan zhao Yidan zhang Xin Liu jian zhang Ya Gao Shuyue Li Cui Chang Xiang Liu Guofeng Yang Department of Geriatrics Second Hospital of Hebei Medical UniversityShijiazhuangHebei ProvinceChina Department of Neurosurgery The Second Hospital of Hebei Medical UniversityShijiazhuangHebei ProvinceChina

Parkinson’s disease is the second most common progressive neurodegenerative disorder,and few reliable biomarkers are available to track disease *** proteins,DNA,mRNA,and lipids carried by exosomes reflect intracellular changes,and thus can serve as biomarkers for a variety of *** this study,we investigated alterations in the protein content of plasma exosomes derived from patients with Parkinson’s disease and the potential therapeutic roles of these proteins in Parkinson’s *** a tandem mass tag-based quantitative proteomics approach,we characterized the proteomes of plasma exosomes derived from individual patients,identified exosomal protein signatures specific to patients with Parkinson’s disease,and identified N-acetyl-alpha-glucosaminidase as a differentially expressed protein.N-acetyl-alpha-glucosaminidase expression levels in exosomes from the plasma of patients and healthy controls were validated by enzyme-linked immunosorbent assay and western *** results demonstrated that the exosomal N-acetyl-alpha-glucosaminidase concentration was not only lower in Parkinson’s disease,but also decreased with increasing Hoehn-Yahr stage,suggesting that N-acetyl-alpha-glucosaminidase could be used to rapidly evaluate Parkinson’s disease ***,western blot and immunohistochemistry analysis showed that N-acetyl-alpha-glucosaminidase levels were markedly reduced both in cells treated with 1-methyl-4-phenylpyridinium and cells overexpressingα-synuclein compared with control ***,N-acetyl-alpha-glucosaminidase overexpression significantly increased cell viability and inhibitedα-synuclein expression in 1-methyl-4-phenylpyridinium-treated *** together,our findings demonstrate for the first time that exosomal N-acetyl-alpha-glucosaminidase may serve as a biomarker for Parkinson’s disease diagnosis,and that N-acetyl-alpha-glucosaminidase may reduceα-synuclein expression and 1-methyl-4-phenylpyridinium-induced n

关键词： biomarker diagnosis exosomes N-acetyl-alpha-glucosaminidase Parkinson’s disease proteomic α-synuclein