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W, Mo, Co Co-diffusion on Steel with Different Carbon Content

材料热处理学报 2004年第05B期25卷 688-691页

作者： zhangyan-mei lizhong-hou liuyan-ping xuzhong ResearchInstituteofSurfaceEngineering TaiyuanUniversityofTechnologyTaiyuanChina

Tungsten, molybdenum and cobalt were co-diffused into the surface of ingot, 20 steel, 45 steel and T8 steel by a double glow plasma surface alloying technique. Surface alloyed layers formed on ingot and 20 steel are composed of -Fe +(Fe,Co)7(W,Mo)6, which possess the same strong age-hardening ability as the metallurgical age-hardened high speed steel, the maximum hardness can reach 1100 HV0.o25 after ageing treatment. Surface alloyed layers formed on 45 steel and T8 steel are composed of M6C, hardness of which are over 1100-1400 HV0.o25- Alloyed layers formed on ingot and 20 steel possess good toughness. Alloyed layer of carbide type exhibits slightly brittleness.

关键词：碳含量表面铸合碳钢硬度脆性钼钴共扩散

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维普期刊数据库

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High Carbon Alloy Steels with Multiple Types of Ultra-fine Carbides and Their Characteristics

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材料热处理学报 2004年第5期25卷 117-121页

作者： MAYong-qing GAOHong-tao QIYu-hong ZHANGZhan-ping DAIYu-mei liuyan-xia DalianMaritimeUniversity DalianChina

Under normal forging and annealing conditions, there are different ultra fine carbides (M3C, M23C6, M7Cj, M6C and MC) in high carbon alloy steels when alloy composition design is carried out properly. On the basis of carbides transformation orderliness, the alloy composition design of the high carbon alloy steels is conducted by phase-equilibrium thermodynamic calculation for Fe-Cr-W-Mo-V-C system. The nucleation and growth of new carbides, dissolution of previous partial carbides in these steels during annealing process, all these lead to ultra-fine distribution of carbides. Due to different crystal structures of carbides and different thermodynamics as well dynamics parameters of the carbides dissolution and precipitation, the range of quenching temperature of these steels is widened, and the good temper-resistance is obtained. The characteristics of heat treatment process and microstructure variance, and the carbides transformation for different temperature are explained by the phase-equilibrium component satisfactorily. Their bend and yield strength, flexibility and toughness all are advanced markedly comparing with that of kindred steels. Results of the applications have proved that the microstructure of ultra-fine carbides in these steels played importance roles in the enhancement of edginess and fatigue crack resistance of the die and knives.

关键词：超细硬质合金高碳钢结构设计成分设计

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维普期刊数据库

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Microstructures and Hardness of 8CrWMoV Steel with Multiple Types of Ultra Fine Carbides

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材料热处理学报 2004年第5期25卷 279-283页

作者： DAIYu-mei ZHANGZhan-ping MAYong-qing QIYu-hong liuyan-xia YUTao Instituteofmaterialsandtechnology DalianMaritimeUniversityDalian116026

The structure and hardness of 8CrWMoV steel with multiple types of ultra fine carbides are studied after annealing, quenching and tempering in this paper. The results show that multiple types of carbides M3C, M7C3, M23C6, M6C and MC were observed in the annealed steel. Nucleation and coalescence of new carbides, partial dissolution of original carbides in γ phase region during annealing at 800～840℃, result in ultra-fine carbides. Average size of the carbides is0.33～0.34μm in the steel annealed at 800～840℃. Because M3C and M23C6 dissolve easily in austenite, the high hardness HRC63～65 can be obtained by quenching at 840～860℃. Un-dissolved carbides M6C and MC (VC) can effectively prevent the coarsening of austenitic grain, and conduce to obtain very fine martensite. The retained austenite can be easy to decompose during tempering at low and middle temperature due to the precipitation of multiple types of carbides and the good tempering-resistance of the steel is obtained. The microstructure and property of the steel after heat treatment can be accurately explained by calculating based on phase equilibrium *** Words: 8CrWMoV steel, ultra-fine carbide, heat treatment, microstructure,

关键词：显微结构 8CrWMoV钢超细硬质合金硬度热处理

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