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Nano Research 2024年第5期17卷 3724-3732页

作者： Bowen Wang Nan zhang Ping Xiao Jian zhang Sónia A.c.carabineiro Junjiang Zhu Hubei Key Laboratory of Biomass Fibers and Eco-dyeing&Finishing College of Chemistry and Chemical EngineeringWuhan Textile UniversityWuhan 430200China college of chemistry and Materials Engineering Wenzhou UniversityWenzhou 325035China LAQV-REQUiMTE Department of ChemistryNOVA School of Science and TechnologyUniversidade NOVA de LisboaLargo da Torre2829-516 CaparicaPortugal

catalytic transfer hydrogenation(cTH)is a green and efficient pathway for selec.ive hydrogenation of unsaturated aldehydes and ***,managing the abilities of solid catalysts to adsorb substrates and to convert them into desired products is a challenging ***,we report the synthesis of carbon coated LaFe_(0.92)Pd_(0.08)O_(3) composites(LFPO-8@c)for cTH of benzaldehyde(BzH)into benzyl alcohol(BzOH),using isopropanol(iPA)as hydrogen *** coating with carbon improves the ability to adsorb/transfer reactants from solution to ac.ive sites,and the doping of Pd2+at Fe3+site strengthens the ability of LaFeO_(3) to convert BzH into BzOH.A balanced point between them(i.e.,abilities to adsorb BzH and to convert BzH into BzOH)is obtained at LFPO-8@c,which exhibits a BzOH formation rate of 3.88 mmol·gcat^(-1)·h^(-1) at 180℃ for 3 h,which is 1.50 and 2.72 times faster than those of LFPO-8 and LaFeO_(3)@c.A reac.ion mechanism is proposed,in which the acidic sites(e.g.,Fe^(4+),oxygen vacancy)are used for the ac.ivation of c=O bond of BzH and O-H bond of iPA,and the basic sites(e.g.,lattice oxygen)for the ac.ivation ofα-H(O-H)bond of iPA.

关键词： LaFe_(0.92)Pd_(0.08)O_(3) porous carbon catalytic transfer hydrogenation isopropanol reac.ion mechanism

A core-satellite self-assembled SERS aptasensor containing a“biological-silent region”Raman tag for the accurate and ultrasensitive detec.ion of histamine

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Food Science and Human Wellness 2024年第2期13卷 1029-1039页

作者： chen chen Yingfang zhang Ximo Wang Xuguang Qiao Geoffrey i.N.Waterhouse Zhixiang Xu Key Laboratory of Food Processing Technology and Quality control in Shandong Province College of Food Science and EngineeringShandong Agricultural UniversityTai’an 271018China School of chemical Sciences The University of AucklandAuckland 1142New Zealand

Herein,a novel interference-free surface-enhanced Raman spectroscopy(SERS)strategy based on magnetic nanoparticles(MNPs)and aptamer-driven assemblies was proposed for the ultrasensitive detec.ion of histamine.A core-satellite SERS aptasensor was constructed by combining aptamer-decorated Fe_(3)O_(4)@Au MNPs(as the recognize probe for histamine)and complementary DNA-modified silver nanoparticles carrying 4-mercaptobenzonitrile(4-MBN)(Ag@4-MBN@Ag-c-DNA)as the SERS signal probe for the indirect detec.ion of *** an applied magnetic field in the absence of histamine,the assembly gave an intense Raman signal at“Raman biological-silent”region due to *** the presence of histamine,the Ag@4-MBN@Ag-c-DNA SERS-tag was released from the Fe_(3)O_(4)@Au MNPs,thus decreasing the SERS *** optimal conditions,an ultra-low limit of detec.ion of 0.65×10^(-3)ng/mL and a linear range 10^(-2)-10^5 ng/mL on the SERS aptasensor were *** histamine content in four food samples were analyzed using the SERS aptasensor,with the results consistent with those determined by high performance liquid *** present work highlights the merits of indirect strategies for the ultrasensitive and highly selec.ive SERS detec.ion of small biological molecules in complex matrices.

关键词： Surface-enhanced Raman spectroscopy Raman biological-silent region Aptamer Histamine detec.ion Universal SERS-tag

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An improved pulse coupled neural networks model for semantic.ioT

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Digital communications and Networks 2024年第3期10卷 557-567页

作者： Rong Ma Zhen zhang Yide Ma Xiping Hu Edith c.H.Ngai Victor c.M.Leung School of information Science and Engineering Lanzhou UniversityLanzhou 730000China School of Medical Technology Beijing Institute of TechnologyBeijing100081China Department of Electrical and Electronic Engineer The University of Hong KongHong Kong 999077China college of computer Science and Software Engineering Shenzhen UniversityShenzhen 518060China Department of Electrical and computer Engineering the University of British ColumbiaVancouverBC V6T 1Z4Canada

in recent years,the internet of Things(ioT)has gradually developed applications such as collec.ing sensory data and building intelligent services,which has led to an explosion in mobile data ***,with the rapid development of artificial intelligence,semantic communication has attracted great attention as a new communication ***,for ioT devices,however,processing image information efficiently in real time is an essential task for the rapid transmission of semantic *** the increase of model parameters in deep learning methods,the model inference time in sensor devices continues to *** contrast,the Pulse coupled Neural Network(PcNN)has fewer parameters,making it more suitable for processing real-time scene tasks such as image segmentation,which lays the foundation for real-time,effec.ive,and accurate image ***,the parameters of PcNN are determined by trial and error,which limits its *** overcome this limitation,an improved Pulse coupled Neural Networks(iPcNN)model is proposed in this *** iPcNN constructs the connec.ion between the static properties of the input image and the dynamic properties of the neurons,and all its parameters are set adaptively,which avoids the inconvenience of manual setting in traditional methods and improves the adaptability of parameters to different types of *** segmentation results demonstrate the validity and efficiency of the proposed self-adaptive parameter setting method of iPcNN on the gray images and natural images from the Matlab and Berkeley Segmentation *** iPcNN method ac.ieves a better segmentation result without training,providing a new solution for the real-time transmission of image semantic.information.

关键词： internet of things(ioT) Semantic.information Real-time application improved pulse coupled neural network image segmentation

The preface: interplay of topological and magnetic orders in the Mn-Bi-Te family

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National Science Review 2024年第2期11卷 6-7页

作者： Fu-chun zhang Hai-Zhou Lu X.c.Xie Kavli institute for Theoretical Sciences University of Chinese Academy of Sciences Department of Physics Southern University of Science and Technology (SUSTech) international center for Quantum Materials School of Physics Peking University

The discovery and synthesis of MnBi2Te4in 2013 initially garnered little attention [1]. Yet, the revelation of its topological properties in 2019 [2–6] sparked a surge of research into the MnBiTe family. These extensive studies are primarily driven by two objec.ives:the realization of a high-temperature quantum anomalous Hall effect （QAHE） and the exploration of exotic phases born from the interplay of topological and magnetic orders,

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N-doped graphene quantum dot-decorated N-TiO2/P-doped porous hollow g-c_(3)N_(4) nanotube composite photocatalysts for antibiotic photodegradation and H2 produc.ion

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international Journal of Minerals,Metallurgy and Materials 2024年第1期31卷 165-178页

作者： Jingshu Yuan Yao zhang Xiaoyan zhang Junjie zhang Shen’gen zhang institute for Advanced Materials and Technology University of Science and Technology BeijingBeijing 100083China Xi’an Fanyi University Xi’an 710105China Shunde Graduate School of University of Science and Technology Beijing Foshan 528399China State Key Laboratory of Lunar and Planetary Sciences Macao University of Science and TechnologyMacao SAR 820000China

Exclusive responsiveness to ultraviolet light (~3.2 eV) and high photogenerated charge recombination rate are the two primary drawbacks of pure TiO_(2). We combined N-doped graphene quantum dots (N-GQDs), morphology regulation, and heterojunc.ion construc.ion strategies to synthesize N-GQD/N-doped TiO_(2)/P-doped porous hollow g-c_(3)N_(4) nanotube (PcN) composite photocatalysts (denoted as G-TPcN). The optimal sample (G-TPcN doped with 0.1wt% N-GQD, denoted as 0.1% G-TPcN) exhibits significantly enhanced photoabsorption, which is attributed to the change in bandgap caused by elemental doping (P and N), the improved light-harvesting resulting from the tube structure, and the upconversion effect of N-GQDs. in addition, the internal charge separation and transfer capability of0.1% G-TPcN are dramatically boosted, and its carrier concentration is 3.7, 2.3, and 1.9 times that of N-TiO_(2), PcN, and N-TiO_(2)/PcN(TPcN-1), respec.ively. This phenomenon is attributed to the formation of Z-scheme heterojunc.ion between N-TiO_(2) and PcNs, the excellent electron conduc.ion ability of N-GQDs, and the short transfer distance caused by the porous nanotube structure. compared with those of N-TiO_(2), PcNs, and TPcN-1, the H2 produc.ion ac.ivity of 0.1%G-TPcN under visible light is enhanced by 12.4, 2.3, and 1.4times, respec.ively, and its ciprofloxacin (ciP) degradation rate is increased by 7.9, 5.7, and 2.9 times, respec.ively. The optimized performance benefits from excellent photoresponsiveness and improved carrier separation and migration efficiencies. Finally, the photocatalytic mechanism of 0.1% G-TPcN and five possible degradation pathways of ciP are proposed. This study clarifies the mechanism of multiple modification strategies to synergistically improve the photocatalytic performance of 0.1% G-TPcN and provides a potential strategy for rationally designing novel photocatalysts for environmental remediation and solar energy conversion.

关键词： N-doped TiO_(2) N-doped graphene quantum dots P-doped g-c_(3)N_(4) porous hollow nanotube heterojunc.ion photocatalysis

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Finite barrier bound state

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Light(Science & Applications) 2024年第4期13卷 664-671页

作者： Tao Liu Kai Bai Yicheng zhang Duanduan Wan Yun Lai c.T.chan Meng Xiao Key Laboratory of Artificial Micro-and Nano-structures of Ministry of Education and School of Physics and Technology Wuhan University430072 WuhanChina. National Laboratory of Solid State Microstructures School of Physicsand Collaborative Innovation Center of Advanced MicrostructuresNanjing University210093 NanjingChina. Department of Physics The Hong Kong University of Science and TechnologyClear Water BayKowloon999077Hong KongChina. Wuhan institute of Quantum Technology 430206 WuhanChina

A boundary mode localized on one side of a finite-size lattice can tunnel to the opposite side which results in unwanted *** wisdom tells that the tunneling probability decays exponentially with the size of the system which thus requires many lattice sites before eventually becoming negligibly *** we show that the tunneling probability for some boundary modes can apparently vanish at specific ***,similar to bound states in the continuum,a boundary mode can be completely trapped within very few lattice sites where the bulk bandgap is not even *** intriguingly,the number of trapped states equals the number of lattice sites along the normal direc.ion of the *** provide two configurations and validate the existence of this peculiar finite barrier-bound state experimentally in a dielectric photonic crystal at microwave *** work offers extreme flexibility in tuning the coupling between localized states and channels as well as a new mechanism that facilitates unprecedented manipulation of light.

关键词： boundary state eventually

Postbiotics from Saccharomyces cerevisiae fermentation stabilize microbiota in rumen liquid digesta during grain-based subacute ruminal acidosis(SARA) in lactating dairy cows

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Journal of Animal Science and Biotechnology 2024年第5期15卷 2059-2080页

作者： Junfei Guo Zhengxiao zhang Le Luo Guan ilkyu Yoon Jan c.Plaizier Ehsan Khafipour Department of Animal Science University of ManitobaWinnipegMB R3T 2N2Canada Present Address:college of Food and Biological Engineering Jimei UniversityXiamenFujian 361021China Department of Agriculture Food and Nutrition DepartmentUniversity of AlbertaEdmontonAB T6G 2R3Canada Faculty of Land and Food Systems University of British ColumbiaVancouverBC V6T 1Z4Canada Diamond V Cedar RapidsIA 52404United States Present Address:cargill Animal Nutrition 15407 McGinty Road WestWayzataMN 55391USA

Background Subacute ruminal acidosis(SARA)is a common metabolic disorder of high yielding dairy cows,and it is associated with dysbiosis of the rumen and gut microbiome and host *** study evaluated the impact of two postbiotics from Saccharomyces cerevisiae fermentation products(ScFP)on rumen liquid associated microbiota of lactating dairy cows subjected to repeated grain-based SARA challenges.A total of 32 rumen cannulated cows were randomly assigned to 4 treatments from 4 weeks before until 12 weeks after *** groups included a control diet or diets supplemented with postbiotics(ScFPa,14 g/d Original XPc;ScFPb-1X,19 g/d Nutri Tek;ScFPb-2X,38 g/d Nutri Tek,Diamond V,cedar Rapids,iA,USA).Grain-based SARA challenges were conducted during week 5(SARA1)and week 8(SARA2)after parturition by replacing 20%DM of the base total mixed ration(TMR)with pellets containing 50%ground barley and 50%ground *** DNA from rumen liquid samples was subjected to V3–V416S r RNA gene amplicon *** of rumen microbiota were compared among treatments and SARA *** Both SARA challenges reduced the diversity and richness of rumen liquid microbiota,altered the overall composition(β-diversity),and its predicted func.ionality including carbohydrates and amino acids metabolic *** SARA challenges also reduced the number of significant associations among different taxa,number of hub taxa and their composition in the microbial co-occurrence *** with ScFP postbiotics,in particular ScFPb-2X,enhanced the robustness of the rumen *** ScFP supplemented cows had less fluctuation in relative abundances of community members when exposed to SARA *** ScFP supplementation promoted the populations of lactate utilizing and fibrolytic bacteria,including members of Ruminococcaceae and Lachnospiraceae,and also increased the numbers of hub taxa during non-SARA and SARA *** with S

关键词： Postbiotics Rumen microbiota Saccharomyces cerevisiae fermentation products SARA

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Proximal Femur Bionic Nail (PFBN): A Panacea for Unstable intertrochanteric Femur Fracture

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Engineering 2024年第6期37卷 152-158页

作者： Kaixuan zhang Wei chen Yingze zhang School of Medicine Nankai UniversityTianjin 300071China Department of Orthopedic Surgery of Hebei Province The Third Hospital of Hebei Medical UniversityShijiazhuang 050051China Key Laboratory of Biomechanics of Hebei Province Orthopaedic Research Institute of Hebei ProvinceShijiazhuang 050051China National Health commission(NHc)Key Laboratory of intelligent Orthopeadic Equipment The Third Hospital of Hebei Medical UniversityShijiazhuang 050051China c.inese Academy of Engineering Beijing 100088China

With the aging population,intertrochanteric femur fracture in the elderly has become one of the most serious public health issues and a hot topic of research in trauma *** to the limitations of internal fixation techniques and the insufficient mechanical design of nails,the occurrence of complications delays patient recovery after surgical *** of a proximal femur bionic nail(PFBN)based on zhang’s N triangle theory provides triangular supporting fixation,which dramatically decreases the occurrence of complications and has been widely used for c.inical treatment of unstable intertrochanteric femur fracture *** this work,we developed an equivalent biomechanical model to analyze improvement in bone remodeling of unstable intertrochanteric femur fracture through PFBN *** results show that compared with proximal femoral nail antirotation(PFNA)and interTan,PFBN can dramatically decrease the maximum strain in the proximal *** on Frost’s mechanostat theory,the local mechanical environment in the proximal femur can be regulated into the medium overload region by using a PFBN,which may render the proximal femur in a state of physiological overload,favoring post-operative recovery of intertrochanteric femur fracture in the *** work shows that PFBN may constitute a panacea for unstable intertrochanteric femur fracture and provides insights into improving methods of internal fixation.

关键词： intertrochanteric femur fracture internal fixation Proximal femur bionic nail(PFBN) Biomechanics Bone remodeling

Summarizing the evidence for robotic-assisted bladder neck reconstruc.ion: Systematic review of patency and incontinence outcomes

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Asian Journal of Urology 2024年第3期11卷 341-347页

作者： Tenny R.zhang Ashley Alford Lee c.Zhao Department of Urology NewYork-Presbyterian Hospital/Weill Cornell MedicineNew YorkNYUSA Department of Urology NYU Langone Medical CenterNew YorkNYUSA

Objec.ive:Bladder neck contracture and vesicourethral anastomotic stenosis are difficult to manage endoscopically,and open repair is associated with high rates of *** recent years,there have been increasing reports of robotic-assisted bladder neck reconstruc.ion in the ***,existing studies are small,heterogeneous case *** objec.ive of this study was to perform a systematic review of robotic-assisted bladder neck reconstruc.ion to better evaluate patency and incontinence ***:We performed a systematic review of PubMed from first available date to May 2023 for all studies evaluating robotic-assisted reconstruc.ive surgery of the bladder neck in adult *** in non-English,author replies,editorials,pediatric-based studies,and reviews were *** of interest were patency and incontinence rates,which were pooled when ***:After identifying 158 articles on initial search,we included only ten studies that fit all aforementioned c.iteria for robotic-assisted bladder neck *** were case series published from March 2018 to March 2022 ranging from six to 32 men,with the median follow-up of 5e23 months.A total of 119 patients were included in our analysis.A variety of etiologies and surgical techniques were *** rates ranged from 50%to 100%,and pooled patency was 80%(95/119).De novo incontinence rates ranged from 0%to 33%,and pooled incontinence was 17%(8/47).Our findings were limited by small sample sizes,relatively short follow-ups,and heterogeneity between studies.

关键词： Bladder neck continence incontinence Patency Posterior urethra Reconstruc.ive surgery Robotic surgery Stenosis Stricture Surgical outcome

Unveiling the protec.ive role of biofilm formation on the photoaging of microplastics

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Science c.ina Technological Sciences 2024年第10期67卷 3067-3078页

作者： zhang HaiYu LiU Peng zhang JiaYu DAi JiaMin zhang XinRui zhang ZiXuan JiA HanZhong Key Laboratory of Plant Nutrition and the Agri-environment in Northwest c.ina Ministry of AgricultureCollege of Natural Resources and EnvironmentNorthwest A&F University Key Laboratory of Organic compound Pollution control Engineering School of Environmental and Chemical EngineeringShanghai University

in natural water, microplastics（MPs） inevitably undergo microbial colonization to form biofilm, while the effect of biofilm formation on the photoaging of MPs remains unknown. This study systematically investigated the photoaging behavior of disposable box-derived polypropylene（PPMPs） and polystyrene（PSMPs） mediated by formed biofilm in water. After incubating in Weihe water samples for 105 d, the biofilm was validated to form in PPMPs and PSMPs, with higher formation in PSMPs. in particular, biofilm formation inhibited the photoaging of PPMPs and PSMPs, with an 11.1% and 50.6% decrease in photooxidation compared to their virgin counterparts after 20 d of ultraviolet（UV） irradiation. Moreover, the photoaging route of MPs such as the reac.ion priority of func.ional groups（e.g., c–H, c=O, and benzene ring） was altered, indicating the important role of biofilm formation in the photoaging process of MPs. The protec.ive effect of the biofilm was mainly caused by the role of optical light filters that absorbed UV energy by sac.ificing themselves. Also, as the main attacker on MPs, the produc.ion of reac.ive oxygen species（ROS, mainly1O2and ·OH） was inhibited by biofilm, which was mainly responsible for the decreased photoaging of MPs. This study revealed the important role of biofilm in the photoaging process of MPs and suggested a higher resistance of（micro）plastics in natural water than that in the laboratory using pure MPs, which contributed to a deeper understanding of the environmental fate and pollution of MPs.

关键词： microplastics biofilm photoaging physical shielding reac.ive oxygen species