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Thermo-kinetic characteristics on stabilizing hetero-phase interface of metal matrix composites by crystal plasticity finite element method

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Journal of Materials Science & Technology 2024年第2期169卷 53-67页

作者： Y.b.zhang S.J.Song F.Liu State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi’an 710072China Analytical&Testing Center Northwestern Polytechnical UniversityXi’an 710072China

Using dislocation-based constitutive modeling in three-dimension crystal plasticity finite element(3D CPFE)simulations,co-deformation and instability of hetero-phase interface in different material systems were herein studied for polycrystalline metal matrix composites(MMCs).Local stress and strain fields in two types of 3layer MMCs such as fcc/fcc Cu-Ag and fcc/bcc Cu-Nb have been predicted under simple compressive ***,more severe strain-induced interface instability can be observed in the fcc/bcc systems than in the fcc/fcc systems upon refining to metallic nanolayered composites(MNCs).by detailed analysis of stress and strain localization,it has been demonstrated that the interface instability is always accompanied by high-stress concentration,i.e.,thermodynamic characteristics,or high strain prevention i.e.,kinetic characteristics,at the hetero-phase *** then follows that the thermodynamic driving forceG and the kinetic energy barrier Q during dislocation and shear banding can be adopted to classify the deformation modes,following the so-called thermo-kinetic *** by inserting a high density of high-energy interfaces into the Cu-Nb composites,such thermo-kinetic integration at the hetero-phase interface allows a successful establishment of MMCs with the high△G-high Q deformation mode,which ensures high hardening and uniform strain distri-bution,thus efficiently suppressing the shear band,stabilizing the hetero-phase interface,and obtaining an exceptional combination in strength and *** hetero-phase interface chosen by a couple of thermodynamics and kinetics can be defined as breaking the thermo-kinetic correlation and has been proposed for artificially designing MNCs.

关键词： Thermodynamics and kinetics Physics-based constitutive modeling Hetero-phase interface Crystal plasticity finite element

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Enumerating Pattern-avoiding Fishburn Permutations Subject to Seven Statistics

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Journal of Mathematical Research with Applications 2024年第4期44卷 427-436页

作者： Yujie DU Philip b.zhang College of Mathematical Science Tianjin Normal University

Fishburn permutations are in bijection with several important combinatorial structures including interval orders. In this paper, we use the method of generating trees to enumerate two classes of pattern-avoiding Fishburn permutations subject to 7 classical statistics simultaneously. The classes of our interest are(321,312)-avoiding and(321,4123)-avoiding Fishburn permutations. The statistics of our interest are ascents, descents, inversions, right-to-left maxima, right-to-left minima, left-to-right maxima and left-to-right minima. Our results generalize a result by Egge.

关键词： Fishburn permutation Fishburn number pattern avoidance generating tree

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Creep-induced redistribution of alloying elements in CZ1 zirconium alloys

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Journal of Materials Science & Technology 2024年第6期173卷 31-44页

作者： W.T.Lin Q.Y.Lv D.Jiao L.b.zhang J.Tan G.Sha J.Hu China Nuclear Power Technology Research Institute Shenzhen 518026China School of Material Science and Engineering Nanjing University of Science and TechnologyNanjing 210094China

Introducing minor alloying elements is an effective strategy to improve the corrosion and mechanical properties of zirconium alloys for nuclear *** in-reactor service,external environment and stress can affect the distribution of alloying elements,substantially changing the degradation process of zirconium *** date,there is a lack of in-depth understanding of the interaction between creep and microchemistry ***,we conducted systematic transmission electron microscopy(TEM)and atom probe tomography(APT)investigations to address creep-induced redistribution of alloying elements in CZ1(Zr-Sn-Nb-Fe-Cr-Cu)zirconium alloy with different initial ***,Fe,Sn,and Cu are found to co-segregate at grain *** higher the intermediate annealing temperature,the larger the Gibbsian interfacial excesses of solute elements *** further demonstrate that creep can reduce the excess value of Fe at grain boundaries due to the coarsening of Zr-Fe-Cr second phase particles via grain boundary and dislocation pipe *** the same time,the excess value of Sn is increased by diffusing from the matrix to grain ***,Cu as a minor element in the concentration range of 0.05-0.3 wt.%is found to segregate at dislocations to form the Cottrell atmosphere and develop Cu-rich nanoclusters for suppressing dislocation *** new understanding of the segregation and clustering of minor alloying elements provides guidance for developing zirconium alloys with enhanced creep resistance.

关键词： Zirconium alloy Thermal creep Grain boundary segregation Dislocation segregation Cu-rich nanoclusters

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In situ TEM investigation of electron irradiation and aging-induced high-density nanoprecipitates in an Mg-10Gd-3Y-1Zn-0.5Zr alloy

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Journal of Magnesium and Alloys 2024年第5期12卷 1841-1853页

作者： M.Lv H.L.Ge Q.Q.Jin X.H.Shao Y.T.Zhou b.zhang X.L.Ma Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of Sciences72 Wenhua RoadShenyang 110016China School of Materials Science and Engineering University of Science and Technology of ChinaShenyang 110016China Materials Science and Engineering Research Center Guangxi University of Science and TechnologyLiuzhou 545006China

In-situ electron irradiation and aging are applied to introduce high-density precipitates in an Mg-10Gd-3Y-1Zn-0.5Zr(GWZ1031K,wt.%)alloy to improve the *** results show that the hardness of the Mg alloy after irradiation for 10 h and aging for 9 h at 250℃ is 1.64 GPa,which is approximately 64% higher than that of the samples before being *** is mainly attributed to γ'precipitates on the basal plane after irradiation and the high-density nanoscale β'precipitates on the prismatic plane after aging,which should be closely related to the irradiation-induced homogenous *** latter plays a key role in precipitation *** result paves a way to improve the mechanical properties of metallic materials by tailoring the precipitation through irradiation and aging.

关键词： Mg alloy Electron beam irradiation Hardening Precipitates In-situ TEM

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Unlocking the potential of silicon anodes in lithium-ion batteries:A claw-inspired binder with synergistic interface bonding

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eScience 2024年第3期4卷 127-133页

作者： Jun Shen Shilin zhang b Haoli Wang Renxin Wang Yingying Hu Yiyang Mao Ruilin Wang Huihui zhang Yumeng Du Yameng Fan Yingtang Zhou Zaiping Guo baofeng Wang Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power Shanghai University of Electric PowerShanghai200090China School of Chemical Engineering The University of AdelaideAdelaide 5000Australia Institute for Superconducting&Electronic Materials University of WollongongWollongong2500Australia Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control National Engineering Research Center for Marine AquacultureMarine Science and Technology CollegeZhejiang Ocean UniversityZhoushan 316004China

binders play a crucial role in enhancing the cycling stability of silicon anodes in next-generation Li-ion ***,traditional linear polymer binders have difficulty withstanding the volume expansion of silicon during ***,inspired by the fact that animals’claws can grasp objects firmly,a claw-like taurine-grafted-poly(acrylic acid)binder(Tau-g-PAA)is designed to improve the electrochemical performance of silicon *** synergistic effects of different polar groups(sulfo and carboxyl)in Tau-g-PAA facilitate the formation of multidimensional interactions with silicon nanoparticles and the diffusion of Li ions,thereby greatly improving the stability and rate performance of silicon anodes,which aligns with results from density functional theory(DFT)*** expected,a Tau-g-PAA/Si electrode exhibits excellent cycling performance with a high specific capacity of 1003mAhg−1at 1C(1C=4200mAhg−1)after 300 cycles,and a high rate *** design strategy of using polar small molecule-grafted polymers to create claw-like structures could inspire the development of better binders for silicon-based anodes.

关键词： Si electrode Taurine-g-poly(acrylic acid) Claw-inspired binder High ionic conductivity

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STCF conceptual design report (Volume 1): Physics & detector

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Frontiers of physics 2024年第1期19卷 1-154页

作者： M.Achasov X.C.Ai L.P.An R.Aliberti Q.An X.Z.bai Y.bai O.bakina A.barnyakov V.blinov V.bobrovnikov D.bodrov A.bogomyagkov A.bondar I.boyko Z.H.bu F.M.Cai H.Cai J.J.Cao Q.H.Cao X.Cao Z.Cao Q.Chang K.T.Chao D.Y.Chen H.Chen H.X.Chen J.F.Chen K.Chen L.L.Chen P.Chen S.L.Chen S.M.Chen S.Chen S.P.Chen W.Chen X.Chen X.F.Chen X.R.Chen Y.Chen Y.Q.Chen H.Y.Cheng J.Cheng S.Cheng T.G.Cheng J.P.Dai L.Y.Dai X.C.Dai D.Dedovich A.Denig I.Denisenko J.M.Dias D.Z.Ding L.Y.Dong W.H.Dong V.Druzhinin D.S.Du Y.J.Du Z.G.Du L.M.Duan D.Epifanov Y.L.Fan S.S.Fang Z.J.Fang G.Fedotovich C.Q.Feng X.Feng Y.T.Feng J.L.Fu J.Gao Y.N.Gao P.S.Ge C.Q.Geng L.S.Geng A.Gilman L.Gong T.Gong b.Gou W.Gradl J.L.Gu A.Guevara L.C.Gui A.Q.Guo F.K.Guo J.C.Guo J.Guo Y.P.Guo Z.H.Guo A.Guskov K.L.Han L.Han M.Han X.Q.Hao J.b.He S.Q.He X.G.He Y.L.He Z.b.He Z.X.Heng b.L.Hou T.J.Hou Y.R.Hou C.Y.Hu H.M.Hu K.Hu R.J.Hu W.H.Hu X.H.Hu Y.C.Hu J.Hua G.S.Huang J.S.Huang M.Huang Q.Y.Huang W.Q.Huang X.T.Huang X.J.Huang Y.b.Huang Y.S.Huang N.Hüsken V.Ivanov Q.P.Ji J.J.Jia S.Jia Z.K.Jia H.b.Jiang J.Jiang S.Z.Jiang J.b.Jiao Z.Jiao H.J.Jing X.L.Kang X.S.Kang b.C.Ke M.Kenzie A.Khoukaz I.Koop E.Kravchenko A.Kuzmin Y.Lei E.Levichev C.H.Li C.Li D.Y.Li F.Li G.Li G.Li H.b.Li H.Li H.N.Li H.J.Li H.L.Li J.M.Li J.Li L.Li L.Li L.Y.Li N.Li P.R.Li R.H.Li S.Li T.Li W.J.Li X.Li X.H.Li X.Q.Li X.H.Li Y.Li Y.Y.Li Z.J.Li H.Liang J.H.Liang Y.T.Liang G.R.Liao L.Z.Liao Y.Liao C.X.Lin D.X.Lin X.S.Lin b.J.Liu C.W.Liu D.Liu F.Liu G.M.Liu H.b.Liu J.Liu J.J.Liu J.b.Liu K.Liu K.Y.Liu K.Liu L.Liu Q.Liu S.b.Liu T.Liu X.Liu Y.W.Liu Y.Liu Y.L.Liu Z.Q.Liu Z.Y.Liu Z.W.Liu I.Logashenko Y.Long C.G.Lu J.X.Lu N.Lu Q.F.Lü Y.Lu Y.Lu Z.Lu P.Lukin F.J.Luo T.Luo X.F.Luo Y.H.Luo H.J.Lyu X.R.Lyu J.P.Ma P.Ma Y.Ma Y.M.Ma F.Maas S.Malde D.Matvienko Z.X.Meng R.Mitchell A.Nefediev Y.Nefedov S.L.Olsen Q.Ouyang P.Pakhlov G.Pakhlova X.Pan Y.Pan E.Passemar Y.P.Pei H.P.Peng L.Peng X.Y.Peng X.J.Peng K.Peters S.Pivovarov E.Pyata b.b.Qi Y.Q.Qi W.b.Qian Y.Qian C.F.Qiao J.J.Qin J.J.Qin L.Q.Qin X.S.Qin T.L.Qiu J.Rademacker C.F.Redmer H.Y.Sang Anhui University Hefei 230039China beihang University Beijing 100191China budker Institute of Nuclear Physics Novosibirsk 630090Russia CAS Key Laboratory of Theoretical Physics Institute of Theoretical PhysicsChinese Academy of SciencesBeijing 100190China Cavendish Laboratory University of CambridgeJJ Thomson AveCambridge CB30HEUnited Kingdom Central China Normal University Wuhan 430079China Central South University Changsha 410083China China University of Geosciences Wuhan 430074China China University of Mining and Technology Xuzhou 221116China École Polytechnique Fédérale de Lausanne(EPFL) LausanneSwitzerland Fudan University Shanghai 200433China Goethe University Frankfurt D-60325 Frankfurt am MainGermany Guangxi Normal University Guilin 541004China Guangxi Uninversity Nanning 530004China Hangzhou Institute for Advanced Study UCASHangzhou 310024China Hebei Normal University Shijiazhuang 050024China Hebei University Baoding 071002China Hefei University of Technology Hefei 230601China Helmholtz Institute Mainz Staudinger Weg 18D-55099 MainzGermany Henan Normal University Xinxiang 453007China Henan University Kaifeng 475004China High Energy Physics Center Chung-Ang UniversitySeoul 06974Korea Higher School of Economy 11 Pokrovsky bulvar Moscow 109028Russia Huangshan University Huangshan 245000China Hubei University of Automotive Technology Shiyan 442002China Hunan Normal University Changsha 410081China Hunan University of Science and Technology Xiangtan 411201China Hunan University Changsha 410082China Indiana University BloomingtonIndiana 47405USA Inner Mongolia University Hohhot 010021China Institute of Advanced Science Facilities Shenzhen 518107China Institute of High Energy Physics Chinese Academy of SciencesBeijing 100049China Institute of Modern Physics Chinese Academy of SciencesLanzhou 730000China Institute of Physics Academia SinicaTaipeiTaiwan 11529China Institute of Theoretical Physics Chinese Academy of SciencesBeijing 100190China Jilin University Changch

The superτ-charm facility(STCF)is an electron–positron collider proposed by the Chinese particle physics *** is designed to operate in a center-of-mass energy range from 2 to 7 GeV with a peak luminosity of 0.5×10^(35) cm^(–2)·s^(–1) or *** STCF will produce a data sample about a factor of 100 larger than that of the presentτ-charm factory—the bEPCII,providing a unique platform for exploring the asymmetry of matter-antimatter(charge-parity violation),in-depth studies of the internal structure of hadrons and the nature of non-perturbative strong interactions,as well as searching for exotic hadrons and physics beyond the Standard *** STCF project in China is under development with an extensive R&D *** document presents the physics opportunities at the STCF,describes conceptual designs of the STCF detector system,and discusses future plans for detector R&D and physics case studies.

关键词： electron–positron collider tau-charm region high luminosity STCF detector conceptual design

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三功能共晶溶剂添加剂用于高性能锂金属电池

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Science bulletin 2024年第11期69卷 1686-1696页

作者：方文强温祖鑫王锋霖陈龙张颖张宁刘小鹤陈根 School of Materials Science and Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan ProvinceCentral South UniversityChangsha 410083China Zhongyuan Critical Metals Laboratory School of Chemical EngineeringZhengzhou UniversityZhengzhou 450001China

Rational carbonate electrolyte chemistry is critical for the development of high-voltage lithium metal batteries(LMbs).However,the implementation of traditional carbonate electrolyte is greatly hindered by the generation of an unstable electrode interphase and corrosive by-product(HF).Herein,we propose a triple-function eutectic solvent additive of N-methylacetamide(NmAc)with LiNO_(3) to enhance the stability and compatibility of carbonate ***,the addition of NmAc significantly improves the solubility of LiNO_(3) in carbonate electrolyte by forming an eutectic pair,which regulates the Li~+solvation structure and leads to dense and homogenous Li ***,the hydrolysis of acidic PF_5 is effectively alleviated due to the strong complexation of NmAc with PF_5,thus reducing the generation of corrosive *** addition,the optimized cathode electrolyte interphase layer decreases the structural degradation and transition metal ***,Li||LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)(NCM622)cells with the designed electrolyte deliver superior long-term cycle reversibility and excellent rate *** study unveils the rationale for incorporating eutectic solvent additives within carbonate electrolytes,which significantly contribute to the advancement of their practical application for high-voltage LMbs.

关键词： Eutectic solvent additive Solvation structure Interfacial chemistry PF_5 capturer Lithium metal battery

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火星探测:黄钾铁矾原地K-Ar定年

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中国科学：地球科学 2024年第3期54卷 661-676页

作者：杨静郑德文武颖陈虹杨莉张斌中国地质科学院地质力学研究所自然资源部活动构造与地质安全重点实验室北京100081 中国地震局地质研究所地震动力学国家重点实验室北京100037 中国地质大学(北京)科学研究院北京100083 中国科学院地质与地球物理研究所中国科学院新生代地质与环境重点实验室北京100029

为了更好地确定火星不同地形所记录的气候变化的时间尺度,确定火星历史上重大事件的绝对年龄,并校准陨石坑率,需要从火星原地或从返回样品中获得精确的年龄数据.原地K-Ar定年是目前比样品返回更为实用的一种精确远程定年技术.黄钾铁矾(K... 详细信息

为了更好地确定火星不同地形所记录的气候变化的时间尺度,确定火星历史上重大事件的绝对年龄,并校准陨石坑率,需要从火星原地或从返回样品中获得精确的年龄数据.原地K-Ar定年是目前比样品返回更为实用的一种精确远程定年技术.黄钾铁矾(KFe_(3)(SO_(4))_(2)(OH)_(6)),是火星上广泛存在的唯一一种通过就位探测、轨道遥感探测、陨石研究三种手段都确定存在的含钾硫酸盐矿物,它已被用于K-Ar和^(40)Ar/^(39)Ar精确定年.火星上黄钾铁矾的保存提供了火星上含水过程的性质和持续时间的信息,不同年龄的黄钾铁矾能有效地解读火星历史上地表水流动时期及过渡到当前干旱气候之间的演变历史.本文总结了近年来火星上黄钾铁矾存在的区域、矿物学特征、在火星上的稳定性、原地K-Ar定年的研究现状、黄钾铁矾氩扩散动力学等,探讨了黄钾铁矾原地K-Ar定年的关键科学问题、火星采样返回需求、未来研究方向等.

关键词：火星黄钾铁矾原地K-Ar定年氩扩散稳定性

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THE HOT DEFORMATION bEHAVIOR AND DYNAMIC RECRYSTALLIZATION MODEL OF 35CrMo STEEL

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Acta Metallurgica Sinica(English Letters) 2003年第3期16卷 183-191页

作者： b.zhang H.b.zhang X.Y.Ruan Y.zhang Department of Plasticity Technology Shanghai Jiao Tong University Shanghai 200030 ChinaDepartment of Materials Science and Engineering Shanghai Institute of Technology Shanghai 200053ChinaDepartment of Plasticity Technology Shanghai Jiao Tong UniversityShanghai 200030ChinaState Key Laboratory for Advanced Metals & MaterialsUniversity of Science and Technology BeliingBeijing 100083 China

The isothermal single-stage compression of 35CrMo structural steel has been carried out by using Gleeble 1500 simulator at the temperature range of 950℃ to 1150℃ and strain rate range of 0.01s-1 to 10s-1. The effect of hot deformation parameters, such as strain rate, deformed temperature and initial grain size on the flow stress behavior was investigated. The activation energy of tested alloy was calculated, which is 378.16kJ/mol; The relationships between the peak stress (σp), the peak stain (εp), the critical strain (εc) and Z parameter were established. The micro structure evolution shows the pre-existing austenite grain boundaries constitute the principal nucleation sites for dynamic recrystallization (DRX), and the initial austenite grain size affects the grain size of DRX slightly. The kinetic mathematical model of DRX of 35CrMo is: XDRX=1-exp(-3.23-2.28) and Ddyn = 2.252× 10Z-0.22.

关键词： dynamic recrystallization deformation activation energy stress/strain curve grain size

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The Log-Concavity of Kazhdan-Lusztig Polynomials of Uniform Matroids

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Journal of Systems Science & Complexity 2023年第1期36卷 117-128页

作者： XIE Matthew H Y zhang Philip b College of Science Tianjin University of TechnologyTianjin 300384China College of Mathematical Science Tianjin Normal UniversityTianjin 300387China

Elias,et al.(2016)conjectured that the Kazhdan-Lusztig polynomial of any matroid is *** by a computer proof of Moll’s log-concavity conjecture given by Kauers and Paule,the authors use a computer algebra system to pr... 详细信息

关键词： HolonomicFunctions Kazhdan-Lusztig polynomial log-concavity uniform matroid

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