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Modeling of LF refining process:a review

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Journal of Iron and Steel Research International 2024年第2期31卷 289-317页

作者： zi-cheng xin Jiang-shan zhang Kai-xiang Peng Jun-guo zhang Chun-hui zhang Qing Liu State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing100083China School of Automation and Electrical Engineering University of Science and Technology BeijingBeijing100083China Tangshan Branch Hebei Iron and Steel Co.Ltd.Tangshan063000HebeiChina xinjiang Bayi Iron and Steel Co. Ltd.Baosteel GroupWulumuqi830022XinjiangChina

With the increasing demand for energy conservation and emission reduction,more attentions have been paid to the intelligentization,greenization and low carbonization during the transformation and upgrading of steelmaking *** furnace(LF)refining is one of the key procedures in steelmaking process and has been widely used in steelmaking plants for its high equipment matching degree,low equipment investment and outstanding refining *** to the main tasks of LF refining process,the modeling methods of temperature prediction model,slag-making model,alloying model,argon blowing model and model of inclusions behavior were systematically reviewed,and the advantages and disadvantages of each modeling method were *** addition,the technical framework for the future has also been proposed based on existing works,including classification of raw materials,graphic representation of knowledge,introduction,upgradation and management of device/equipment,customization of steelmaking,modeling of refining process,synergy of models,intelligentization of decision-making,automation of control,and digitization of processes and operations,aiming to provide a reference for the modeling and intelligent development of LF refining process.

关键词： LF refining Temperature prediction Slag-making Alloying Argon blowing Inclusion behavior Modeling method

Spherical Polyelectrolyte Brush Nanoreactor:Preparation of Hollow TiO_(2) Nanospheres and Characterization by Small Angle X-Ray Scattering

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Chinese Journal of Polymer Science 2024年第9期42卷 1393-1400,I0009页

作者： Yu-Hua zhang zi-Yu zhang xin Liu En-Guang Ma Jiang-Tao Guo Li Li Xu-Hong Guo State Key Laboratory of Chemical Engineering East China University of Science and TechnologyShanghai200237China Shandong Provincial Key Laboratory of Monocrystalline Silicon Semiconductor Materials and Technology College of Chemistry and Chemical EngineeringDezhou UniversityDezhou253023China Institute of Bast Fiber Crops&Center of Southern Economic Crops Chinese Academy of Agricultural SciencesChangsha410205China

Titanium dioxide(TiO_(2))hollow nanoparticles present significant potential for photocatalytic applications while their straightforward preparation with precise structure control is still *** work reports the approach to preparing tunable hollow TiO_(2) nanospheres by utilization of spherical polyelectrolyte brushes(SPB)as nanoreactors and *** the preparation,the evolution of the structure was characterized by small angle X-ray scattering(SAXS),and in combination with dynamic light scattering and transmission electron *** formation of TiO_(2) shell within the brush(SPB@TiO_(2))is confirmed by the significant increase of the electron density,and its internal structure has been analyzed by fitting SAXS data,which can be influenced by Titanium precursors and ammonia *** calcining SPB@TiO_(2) in a muffle furnace,hollow TiO_(2) nanospheres are produced,and their transition to the anatase crystal form is triggered,as confirmed by X-ray diffraction *** the advantages of their hollow structure,these TiO_(2) nanospheres exhibit exceptional catalytic degradation efficiency of methylene blue(MB),tetracycline(TC),and 2,4-dichlorophenoxyacetic acid(2,4-D),and also demonstrate excellent recyclability.

关键词： Spherical polyelectrolyte brush Nanoreactor Hollow titanium dioxide X-ray scattering

Construction of an ultra-deep diaphragm wall:a case study

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Journal of Chongqing University 2018年第1期17卷 1-16页

作者： SUN Jie zhang zi-xin HUANG xin JU xin Department of Geotechnical Engineering Tongji Univers#y Shanghai 200092 P. R. China Key Laboratory of Geotechnical and Underground Engineering of the Ministry of Education Tongji University Shanghai 200092 P. R. China

This paper presents a case study on an ultra-deep diaphragm wall with a depth of 110 m constructed in Ningbo City. The in-situ application shows that using Bauer BC40 cutter machine in conjunction with cutter wheels specified for different strata would be qualified for constructing the 110 m diaphragm wall with high efficiency and precision given that the quality of slurry and poured concrete can be guaranteed. The ground settlement can be effectively controlled by using the overlapping construction method. Sliding failure as a whole characterized by pronounced lateral deformation is likely to occur in the upper muddy clay layer due to its high compressibility and sensitivity. In contrast, local collapse of trench walls tends to happen in the sandy silt strata. Furthermore, careful attention should be paid to sandy silt during the entire construction period as the vertical displacement of the sandy silt continues to develop even atter concrete pouring.

关键词： diaphragm wall soft soil quality control settlement overlapping method trench cutter BC40

软土地层TBM开挖面支护压力计算模型及可视化

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岩土力学 2015年第11期36卷 3193-3200页

作者：张子新张帆同济大学地下建筑与工程系上海200092 中国矿业大学深部岩土力学与地下工程国家重点实验室江苏徐州221116

隧道掘进机(TBM)近年来在世界范围内得到了广泛应用,通常通过完全充满压力仓的泥土或泥浆来支护开挖面。但在较差的地层和水力条件下,开挖面失稳时有发生。事实上,TBM开挖面的支护压力的大小直接决定了施工安全及地表变形。基于所建立... 详细信息

隧道掘进机(TBM)近年来在世界范围内得到了广泛应用,通常通过完全充满压力仓的泥土或泥浆来支护开挖面。但在较差的地层和水力条件下,开挖面失稳时有发生。事实上,TBM开挖面的支护压力的大小直接决定了施工安全及地表变形。基于所建立的开挖面支护压力计算模型,并考虑复合地层下土体分层带来的影响,通过计算机编程方法,建立了界面友好、使用便捷的开挖面支护压力可视化计算平台(TBM Studio);并结合阿拉斯加隧道、钱江隧道工程实例进行了不同模型结果的验证分析,给出了各模型计算结果的差异性;讨论了软土复合地层条件下,土体自稳性对开挖面稳定的影响,认为软土地层中定量确定有效支护压力和水头高度至关重要,研究为正确评价TBM开挖面稳定性提供了相应的计算模型。

关键词： TBM 开挖面支护压力可视化复合地层

Oxidation Performance of Fe-Al/WC Composite Coatings Produced by High Velocity Arc Sprayed at 650 ℃

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材料热处理学报 2004年第5B期25卷 930-933页

作者： MENGFan-Jun XUBin-Shi ZHUSheng MAShi-Ning zhangWeiZHUzi-xin NationalKeyLaboratoryforRemanufacturing Beijng100072China

The Fe-Al/WC intermetallic composite coatings have been prepared by high velocity arc spraying(HVAS) technology on 20G steel and the oxidation performance of Fe-Al/WC composite coatings has been studied by means of thermogrativmetic analyzer. The results demonstrate that the kinetics curve of oxidation approximately follows the logarithmic law. The composition of the oxidized coating surface mainly is composed of A12O3, Fe2O3, Fe3O4 and FeO which distribute unevenly. The protective A12O3 film firstly forms and preserves the coatings from further oxidation.

关键词： WC HVAS Al2O3 Fe3O4 Fe2O3

Advances in immunotherapy for hepatitis B virus associated hepatocellular carcinoma patients

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World Journal of Hepatology 2024年第10期16卷 1158-1168页

作者： Wei-Hua Cao Ya-Qin zhang xin-xin Li zi-Yu zhang Ming-Hui Li Department of Hepatology Division 2 Beijing Ditan HospitalCapital Medical UniversityBeijing 100015China Department of Hepatology Division 2 Beijing Ditan HospitalCapital Medical UniversityPeking University Ditan Teaching HospitalBeijing 100015China

Hepatitis B virus(HBV)infection plays an important role in the occurrence and development of hepatocellular carcinoma(HCC),and the rate of HBV infection in liver cancer patients in China is as high as 92.05%.Due to long-term exposure to chronic antigens from the gut,the liver needs to maintain a certain level of immune tolerance,both to avoid severe inflammation caused by non-pathogenic antigens and to maintain the possibility of rapid and violent responses to infection and ***,HBV infection interacts with the tumor microenvironment(TME)through a highly complex and intertwined signaling pathway,which results in a special TME in *** to changes in the TME,tumor cells can evade immune surveillance by inhibiting tumor-specific T cell function through cytotoxic T-lymphocy-associated protein-4(CTLA-4)and programmed cell death 1(PD-1)/programmed cell death ligand 1(PD-L1).Interferons,as a class of immune factors with strong biological activity,can improve the TME of HBV-HCC through various *** recent years,the systematic treatment of HCC has gradually come out of the *** addition to the continuous emergence of new multi-target anti-vascular tyrosine kinase inhibitor drugs,immune checkpoint inhibitors have opened up a new avenue for the systematic treatment of *** present,immunotherapy based on PD-1/L1 inhibitors has gradually become a new direction of systematic treatment for HCC,and the disease charac-teristics of patients included in global clinical studies are different from those of Chinese ***,whether a group of HCC patients with HBV background and poor prognosis in China can also benefit from immunotherapy is an issue of wide *** review aims to elucidate the advances of immuno-therapy for HBV related HCC patients with regard to:(1)Immunotherapy based on interferons;(2)Immunotherapy based on PD-1/L1 inhibitors;(3)Immunotherapy based on CTLA4 inhibitors;(4)Adoptive cell transfer;(5)Combination immunotherapy str

关键词： Hepatitis B virus Hepatocellular carcinoma Immune checkpoint inhibitors Peginterferon alpha Systematic treatment

Flotation separation of feldspar from quartz using sodium fluosilicate as a selective depressant

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Rare Metals 2024年第3期43卷 1288-1300页

作者： xin Hu Xian-Ping Luo zi-Shuai Liu Yong-Bing zhang He-Peng Zhou Zhi-Zhao Yang Xue-Kun Tang Faculty of Resource and Environmental Engineering Jiangxi University of Science and TechnologyGanzhou341000China Yichun Lithium New Energy Industry Research Institute Jiangxi University of Science and TechnologyYichun336000China

The physical and chemical properties of feldspar and quartz are highly similar,thus they cannot be easily separated *** this work,the flotation separation of feldspar from quartz using sodium fluosilicate(Na_(2)SiF_(6);SF)as a selective depressant was ***,the influence mechanism of SF on the selective flotation separation of feldspar and quartz was investigated via flotation tests,chemical analysis of flotation solution,Fourier transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS)and contact angle *** results of the flotation tests show that feld spar and quartz without SF treatment have good *** SF treatment,feldspar still has good floatability,whereas quartz has significantly reduced *** solution chemical analysis shows that the functional group plays an important role in depressing the quartz is[SiF_(6)]^(2-).FTIR,XPS and contact angle analysis results show that[SiF_(6)]^(2-)is adsorbed only on the surface of ***,a thin hydrophilic SiOF layer is generated on the surface,which interferes with the adsorption of the collector on the surface of the *** phenomenon leads to a significant reduction in quartz's ***,SF has a good ability to separate feldspar from quartz by flotation.

关键词： Flotation separation Depressants Sodium fluorosilicate Quartz Feldspar

Three-dimensional elasto-plastic finite element analysis of a soil-pilebridge interaction

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Journal of Chongqing University 2017年第1期16卷 25-37页

作者：朱叶艇 zhang zi-xin YUAN Deng-ping HUANG xin Department of Geotechnical Engineering Tongji University Shanghai 200092 P. R. China Shanghai Geotechnical Engineering Detecting Center Shanghai 200436 P. R. China

The soil-pile-bridge interaction of super-large pile groups is a very complex issue for the design of deep pile group foundations. In this paper, the load distribution on the pile top of a super large bridge foundation and its influential factors are analyzed comprehensively using a three-dimensional elasto-plastic finite element method. The adopted model and its input parameters are firstly verified by comparing the numerical results with the measured data of static loading tests of a single pile. Numerical analysis is then performed to investigate the load distribution and the load-settlement characteristics of super-large pile groups, and the models are verified using centrifuge laboratory model testing data. The mechanism of the interaction between pile groups and soil under different conditions is explored.

关键词： finite element interaction friction pile bridge foundation pile groups

Modulation of d-orbital to realize enriched electronic cobalt sites in cobalt sulfide for enhanced hydrogen evolution in electrocatalytic water/seawater splitting

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Rare Metals 2024年第2期43卷 511-521页

作者： Jian-Peng Sun Yu Zheng zi-Sheng zhang Xiang-Chao Meng zi-Zhen Li Key Laboratory of Marine Chemistry Theory and Technology(Ministry of Education) College of Chemistry and Chemical EngineeringOcean University of ChinaQingdao266100China Shanxi Institute of Energy Taiyuan030600China Department of Chemical and Biological Engineering Faculty of EngineeringUniversity of OttawaOttawaONK1N6 N5Canada

Herein,a novel single-atomic Pt doping and interface-rich CoS/Co(OH)_(2)(Pt-CoS/Co(OH)_(2)/C)electrocatalyst has been successfully *** from precise regulation of d-orbital electronic structure modulation on Co site,Pt-CoS/Co(OH)_(2)/C exhibited remarkable HER activity and high stability for hydrogen evolution in splitting both water(73 mV@10 mA·cm^(−2)) and seawater(87 mV@10 mA·cm^(−2)).Notably,atomic Pt doping was introduced into CoS/Co(OH)_(2),which could produce local unbalanced Coulombic force and significantly increased the number of S vacancies,and then expose abundant Co ***,Co(OH)_(2) in Pt-CoS/Co(OH)_(2)/C could act as the adsorption sites for H_(2)O in hydrogen evolution reaction *** functional theory results also proved that atomic Pt doping,S vacancies and Co(OH)_(2) coupling could result in the formation of enriched electronic Co sites and optimize d_(z2) orbital electronic structure,and then realize the depth upward shift of d-band center and enhance the adsorption of H*on Co sites.

关键词： Electrocatalysts Hydrogen evolution reaction Pt-CoS/Co(OH)_(2) d-band center Electronic structure Water/seawater electrolysis