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Permian carbonates of Baoshan block, Western Yunnan and their paleoclimatic implications

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Science china earth Sciences 2004年第5期47卷 385-392页

作者： YAN Jiaxin1, LIANG Dingyi1 & WU Ming2.1. faculty of {2. Sciences, china {4. of Geosciences, wuhan 430074, china 2. College of Chemistry and Life Sciences, South-Central {4. for Nationalities, wuhan 430074, china china Univ Geosci Fac Earth Sci Wuhan 430074 Peoples R China S Cent Univ National Coll Chem & Life Sci Wuhan 430074 Peoples R China

Recently, much attention has been paid to the climatic significance of carbonates originating in shallow water. Permian carbonates of shallow shelf origin are present in the upper part of the Dingjiazhai Formation, the upper part of the Yongde Formation, and the Shazipo Formation on the Baoshan block of Western Yunnan. Their skeleton and non-skeleton grain as-sociations have been investigated in this study. The carbonates of the Dingjiazhai Formation indicate a Bryonoderm (bryozoans-echinoderm) association without non-skeleton grains. The carbonates of Yongde and Shazipo formations show Chloroforam (green algae-foraminifers) association with peloids. Oolites develop in the Shazipo Formation. Based on the comparisons of grain association with coeval carbonates formed in different paleolatitudes (i.e. various paleo-climatic zones), the carbonates of the Dingjiazhai Formation were thought to have been accu-mulated in shelf environments of warm-temperate zone, and those of the Yongde and Shazipo formations in shelf environments of warm-water.

关键词： Early Permian, carbonate, paleoclimate, Western Yunnan.

Experimental study of ore gabbro liquid immiscibility

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Science china earth Sciences 2005年第4期48卷 496-505页

作者： SANG Zunan1,2. XIA Bin1, ZHOU Yongsheng3 & JIN Zhenmin4.1. Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 51064.,{4. 2. wuhan university, wuhan 4.0072.{4. 3. Institute of Geology,{4. Seismological Bureau, Beijing 10002.,{4. 4. {14. of earth Sciences,{4. university of Geosciences, wuhan 430074,{4. 1. Guangzhou Institute of Geochemistry Chinese Academy of Sciences 510640 Guangzhou China 2. wuhan university 430072 Wuhan China 3. Institute of Geology China Seismological Bureau 100029 Beijing China 4. faculty of earth Sciences China University of Geosciences 430074 Wuhan China

In this paper, the authors present the results of a preliminary experimental study on partial melting of fine-grained gabbro, Panzhihua, Sichuan Province,{2.. Experiments were conducted under (confining) pressure ranging from 4.0 to 500 MPa and temperature of 900— 12.0℃. The results show that the initial melt is distributed along grain boundaries and triple junctions. Liquid immiscibility phenomena are noted in the melt with two compositional different melt phases, i.e. matrix and sphere phases. The matrix phase is relatively rich in Si, Al and K, and is depleted in Mg, Fe, Ca, Na and Ti, whereas the sphere phase shows opposite trends. The calculation of the melt free energy indicates that the liquid immiscibility is governed by the rule of thermodynamics, as the liquid immiscibility would result in the decrease in free energy of the melt system. The field relationships suggest that the liquid immiscibility may have played an important role in the generation of ore magma of Panzhihua V-Ti magnetite ore deposit. This study thus provides experimental constraints on the mechanism of the formation of V-Ti magnetite deposite.

关键词： partial melting, experimental study, gabbro, liquid immiscibility, ore formation mechanism.

Exsolution of ilmenite and Cr-Ti magnetite from olivine of garnet-wehrlite

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Science china earth Sciences 2005年第9期48卷 1368-1376页

作者： LIU Xiangwen1,2. JIN Zhenmin1,3, QU Jing2.& WANG Lu2.1. State Key Laboratory of Geological Processes and Mineral Resources,{2. university of Geosciences, wuhan 430074,{2. 2. Graduate School of{2. university of Geosciences, wuhan 430074,{2. 3. faculty of {14. Sciences,{2. university of Geosciences, wuhan 430074,{2. 1. State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences 430074 Wuhan China 2. Graduate School of china university of Geosciences 430074 Wuhan China 3. faculty of earth Sciences China University of Geosciences 430074 Wuhan China

Exsolution of rod-like ilmenite (Ilm) and Cr-Ti magnetite (Mt) have been found in olivine of garnet-wehrlite from the core of Chinese Continental Sciences Drilling (CCSD). Their composition, morphology, crystal structure and their topotaxies with host olivine have been studied in detail by the transmission electron microscopy (TEM) and electron probe microanaly- sis (EPMA) technique. It shows that rod-like Ilm exsolution reported in this paper has similar characteristic with that of Alpe Arami olivine, while Cr-Ti magnetite exsolution mentioned in this paper has large discrepancy with chromite exsolution in Alpe Arami olivine. These observations suggest that both of the exsolutions found in this paper should be solid solution phases in β-olivine at their first period, then experiencing decomposition of solid solution and therefore forming Ilm and Cr-Ti magnetite exsolution with the pressure decreasing. So, this garnet-wehrlite perhaps had been ever located in mantle transition zone with a minimum depth of 300 km.

关键词： garnet-wehrlite, ilmenite, magnetite, exsolution, CCSD.

Experimental remolding on the caprock's 3D strain field of the Indosinian-Yanshanian epoch in Tongling deposit concentrating area

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Science china earth Sciences 2005年第7期48卷 863-874页

作者： DENG Jun1,HUANG Dinghua2.WANG Qingfei1,WAN Li1,SUN Zhongshi3,yang Liqiang1 & GAO Bangfei1 1. State Key Laboratory of Geological Processes and Mineral Resources,china {2. of Geosciences,Beijing 100083,china 2. faculty of earth Sciences,china {2. of Geosciences,wuhan 430074,china 3. Department of earth Sciences,Jilin {2.,Changchun 130061,china State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China faculty of earth Sciences China University of Geosciences Wuhan 430074 China Department of earth Sciences Jilin University Changchun 130061 China

Based on field observations and rheology analysis, we perform one analogue experiment and remold the 3D structural frame of Tongling deposit concentrating area firstly. Then we disassemble and dialyze the 3D structures of the model using the methods of "slicing" and "stripping". A series of sliced planes vertical to the fold hinges show similar landscapes of that in the drill hole profiles. Meanwhile, layer stripping analysis indicates that the deformation features of each layer in the model are qualitatively analogical to those obtained from field observations. Through contrasting the 3D structure between the experimental model and the field phenomena, we verify the following 3D deformation features of the caprock in this area: (1) the Tongling area mainly consists of three series of NE S-typed fold groups; (2. in the uniform stress field, the incoherent folds universally develop in different positions, along different axes as well as in different strata; (3) the faults propagate upward which are mostly inter-bedded detachment faults, while the fold amplitudes decrease while going deeper; and (4. the folds and cleavages are highly developed in the Silurian System indicating that the deformation effect of the Indosin-ian-Yanshanian structural layer terminates at this layer, which suggests that the Silurian System is the crucial layer for the inversion between brittle and plastic deformation domains and the underlying strata are subject to the control of another deformation system with distinct properties.

关键词： Tongling deposit concentrating area Indosinian-Yanshanian epoch 3D structural frame of the caprock analogue experiment slicing and stripping analysis structural model.

Distributions of fatty acids in a stalagmite related to paleoclimate change at Qingjiang in Hubei,southern china

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Science china earth Sciences 2005年第9期48卷 1463-1469页

作者： XIE Shucheng1,HUANG Junhua1,WANG Hongmei2.YI Yi1,HU Chaoyong1, CAI Yanjun3 & CheNG Hai4.1. {2. of {4. Science,china university of Geosciences,wuhan 430074,china 2. School of Environmental Studies,china university of Geosciences,wuhan 430074,china 3. SKLLQG,Institute of {4. Environment,Chinese Academy of Sciences,Xi’an 710075,china 4. Department of Geology and Geophysics,university of Minnesota,MN554.5,USA 1. faculty of earth Science China University of Geosciences 430074 Wuhan China 2. School of Environmental Studies China University of Geosciences 430074 Wuhan China 3. SKLLQG Institute of Earth Environment Chinese Academy of Sciences 710075 Xi’an China 4. Department of Geology and Geophysics University of Minnesota 55455 MN USA

Fatty acids extracted from a subtropical stalagmite at Qingjiang in Southern china’s Hubei Province were analysed using gas chromatography-mass spectrometry. These n-alkanoic acids range from C14.to C2. in carbon number, maximizing at C16, with a second dominance at C2.. In contrast to the stalagmite analysed, the overlying soils are characterized by the dominance of heavy-molecular-weight homologues (>C2.). The n-fatty acids in the stalagmite were proposed to be contributed by both the soil ecosystems and the microbes harboring in the percolating water and the cave. The ratios of unsaturated to saturated n-fatty acids (C16:1i/C16:0, C18:1/C18:0) appear to show trends comparable with the oxygen isotope records of the stalagmite carbonate, with enhanced values associated with the cold episode such as heinrich event 1. This paleoclimate-dependent record of the n-fatty acids might reflect microbial changes in physiology and activity in response to the temperature. This record shows somewhat difference from the previous paleoclimate signal extracted from n-alkanols and n-alkan-2.ones of the same stalagmite. The acid record fails to document the well-known Younger Dryas event which was effectively shown by the latter two biomarkers derived from soil ecosystems. This discrepancy might result from the changing biogeochemical impact on different lipid fractions as well as the varied organism populations in different ecosystems.

关键词： biomarker, ecosystem, microbe, speleothem, paleoclimate, Quaternary.

Anatexis in Himalayan crust:Evidence from geochemical and chronological investigations of Higher Himalayan Crystallines

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Science china earth Sciences 2005年第9期48卷 1347-1356页

作者： yang Xiaosong1, JIN Zhenmin2.& MA Jin1 1. State Key Laboratory of {2.quake Dynamics, Institute of Geology,{4. {2.quake Administration, Beijing 10002.,{4. 2. faculty of {2. Sciences,{4. university of Geosciences, wuhan 430074,{4. 1. State Key Laboratory of earthquake Dynamics Institute of Geology China Earthquake Administration 100029 Beijing China 2. faculty of earth Sciences China University of Geosciences 430074 Wuhan China

Migmatization in Higher Himalayan Crystallines (HHC) results from anatexis. The widely distributed migmatites in HHC are an important clue to investigate the relationship be- tween anatexis and the origins of Higher Himalayan leucogranites (HHL), and to understand the effect of anatexis on crustal evolution during the post-collision period. We studied in detail the chemical features of three basic constituent parts of the migmatites, i.e. leucosome, mesosome and melanosome, and determined the K-Ar ages of leucosomes. Our studies indicate that type-I leucosome is the product of crystallization of melt generated by partial melting of mesosome at source region, but type-II leucosome and HHL probably underwent crystallization differentiation of plagioclase during melt aggregation and migration. The age of 2..67 Ma of Type-I leucosome, which is a little older than the beginning of MCT movement, indicates that anatexis may have played an important role in the formation of MCT. That the ages of type-II leucosome (ranging from 14.82.to 18.37 Ma) are consistent with that of HHL provides new chronological evidence for the relationship between migmatization and HHL. We obtained a very young age of 6.2. Ma of Type-II leucosome that provides new time constraint on magma activity in the central segment of Higher Himalayas.

关键词： Higher Himalayan Crystallines, migmatite, anatexis, leucosome, K-Ar age.

Sedimentary geochemistry of the Cambrian-Ordovician cherts: Implication on archipelagic ocean of North Qilian orogenic belt

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Science china earth Sciences 2007年第11期50卷 1628-1644页

作者： DU YuanSheng1,2. ZHU Jie1, GU SongZhu1, 2. XU YaJun1 & yang JiangHai1 1 {2. of earth Sciences, china university of Geosciences, wuhan 430074, china 2.Key Laboratory of Biogeology and Environment Geology of Education Ministry, wuhan 430074, china 1. faculty of earth Sciences China University of Geosciences Wuhan 430074 China 2. Key Laboratory of Biogeology and Environment Geology of Education Ministry Wuhan 430074 China

The Caledonian North Qilian orogenic belt lies between the North{2. plate and the Qaidam mi-croplates, and resulted from the collision among the Qaidam microplate, mid-Qilian block and the North{2. plate. The orogen initiated from the rifting of the Late Proterozoic Rodinia, and then it experi-enced stages of Cambrian rift basin and Ordovician archipelagic oceanic basin, and foreland basin during Silurian to Early-Middle Devonian. The average ratios of Al/(Al+Fe+Mn), Al/(Al+Fe), δ Ce, Lan/Ybn and Lan/Cen from cherts of Cambrian heicigou Formation are 0.797, 0.62., 1.114. 0.994.and 1.034.re-spectively. In the NAS standardized REE distribution pattern, the cherts from Xiangqianshan is slightly HREE enriched, and the cherts from Ganluci and Shiqingdong are plane. All of these features indicated that Cambrian cherts of the heicigou Formation originated from a continental margin rift background. On the contrary, the average ratios of Al/(Al+Fe+Mn), Al/(Al+Fe), δ Ce, Lan/Ybn, Lan/Cen of the Ordovician chert from Dakecha, Cuijiadun, Shihuigou, Laohushan, heicigou, Maomaoshan, Bianmagou, Da-chadaban, Baiquanmen, Jiugequan and Angzanggou, are respectively 0.72. 0.58, 0.99, 1.09 and 0.96 respectively. Their NAS standardized REE distribution patterns of most Ordovician cherts are plane mode or slightly HREE enriched. The REE distribution pattern of few samples of cherts are slightly LREE enriched. Characteristics of sedimentary geochemistry and tectonic evolution demonstrated that the Cambrian-Ordovician cherts, associated with rift, oceanic, island arc and back-arc volcanic rocks, was not formed in a typical abyssal oceanic basin or mid-oceanic ridge. On the contrary, they formed in a deepwater basin of continental margin or a archipelagic ocean tectonic setting. Several Early Paleo-zoic ophiolite belts in North Qilian and adjacent periphery Qaidam microplate imply that an archipelagic ocean during Ordovician existed in the east of Pro-Tethys.

关键词： North Qilian orogenic belt,Cambrian-Ordovician,cherts sedimentary geochemistry,archipelagic ocean

New stylophorans(Echinodermata) from the Upper Cambrian of Guangxi,South china

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Science china earth Sciences 2008年第2期51卷 181-186页

作者： HAN NaiRen1 & CheN GuiYing1,2.1 Department of Resources and Environmental Engineering, Guilin {2. of Technology, Gulin 54.004. china 2.faculty of earth Sciences, china {2. of Geoscience, wuhan 430074, china Department of Resources and Environmental Engineering Guilin University of Technology Gulin 541004 China faculty of earth Sciences China University of Geoscience Wuhan 430074 China

This paper describes for the first time the cornute stylophorans (Echinodermata) in{2.. The new material came from the Guole Formation of the Furongian (Late Cambrian) in the Guole area of Jingxi, Guangxi Province, South{2.. These new cornute specimens are preserved in situ and found along with well-preserved trilobites and brachiopods. One new species, Phyllocystis jingxiensis sp. nov., is proposed to accommodate these unusual materials. The new species is defined by the small, heart-shaped theca with the frame composed of ten narrow, smooth and thick marginal plates, three adoral plates and distinctive zygal and aulacophore. Both supracentrals and infracentrals are polygonal-outlined. The marginal plate M1' on the inferior face extends posteriorly to form zygal that possesses a broadened proximal end and the proximal portion joining with the conjunction between M4.and M5 on the inferior face. Aulacophore comprises ten segments at its proximal part and is conical at the middle part (named stylocone). Its distal portion is rather long and bears conspicuous ambulacrum grooves. Tectals are horizontally arranged on superior face and obliquely arranged on inferior face. Both cothurnopore and anal pyramid are vaguely seen on the right anterior corner and the extremity of theca's superior face.

关键词： Phyllocystis Stylophora Echinodermata Cambrian Guangxi South china

Analytical method of Cr stable isotope and its application to water pollution survey

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Chinese Science Bulletin 2010年第7期55卷 664-669页

High Cr(VI) concentration is a potential serious risk to environment and ecologic ***,it is essential to effectively monitor Cr contamination in water systems and scientifically evaluate its evolution trend.A new method of in-situ tracer technique by Cr isotopic analysis for quantitatively estimating Cr-contamination and its regional evolution in natural waters as well as a case application are reported in this *** on documented literatures,an experimental procedure for chemical separation and purification of Cr in water samples and its analytical method for Cr isotopic measurement by thermal ionization mass spectrometry(TIMS) are *** samples collected around a chemical factory in Hubei Province were analyzed by this *** samples showδ53Cr values ranging from-1.7‰to 7.3‰and an elevating trend with an increasing in distance from the sampling site to pollution source.A functional correlation following Rayleigh fractionation law was established between sample'sδ53Cr value and its extent of Cr *** study suggests that Cr isotopic analysis is an effective method to reveal the spatial distribution and its evolution trend of Cr contamination in the regional water *** is thus helpful to assessing the self-purifying ability of local water system according to Cr isotopic fractionation.

关键词：铬(VI) 水污染调查稳定同位素应用同位素分析供水系统演变趋势示踪技术