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Chinese Chemical Letters 2024年第7期35卷 428-432页

作者： Yiyue Ding Qiuxiang zhang Lei zhang Qilu Yao gang Feng zhang-Hui Lu Key Laboratory of Energy Catalysis and Conversion of Nanchang College of Chemistry and Chemical EngineeringJiangxi Normal UniversityNanchang 330022China School of Chemistry and Chemical Engineering Nanchang UniversityNanchang 330031China

Formic acid(FA),which is obtainable through CO_(2)hydrogenation with green hydrogen or biomass conversion,has been used as a prospective liquid organic hydrogen carrier(LOHC)because of the abundant advantages of renewability,wide availability,stability,and high volumetric capacity(53 g H_(2)/L).The development of highly efficient catalytic systems to achieve enhanced catalytic activity is attractive but still ***,ultrafine and highly dispersed PdAu nanoclusters(NCs)anchored on amino-modified reduced graphene oxide(ArGO)were successfully synthesized via a facile impregnation-reduction method and applied as a catalyst toward formic acid dehydrogenation(FAD).Benefiting from the promoting effect of amino groups,the strain and ligand effect in the alloy,and the Mott–Schottky effect between PdAu NCs and ArGO,the resultant PdAu/ArGO affords an ultrahigh activity under visible light irradiation with an exceptional turnover frequency value of 10,699.5 h^(-1)at 298 K without any additives,more than 2.6times improvement than that under dark,which is the highest among all reported catalysts under the same *** study provides a green and convenient strategy for developing more efficient and sustainable FAD catalysts and promotes the effective utilization of FA as a prospective renewable LOHC.

关键词： Visible-light-enhanced Hydrogen production Formic acid Pd-Au Heterogeneous catalyst

Small molecule deoxynyboquinone triggers alkylation and ubiquitination of Keap1 at Cys489 on Kelch domain for Nrf2 activation and inflammatory therapy

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Journal of Pharmaceutical Analysis 2024年第3期14卷 401-415页

作者： Ke-gang Linghu Tian zhang Guang-Tao zhang Peng Lv wen-Jun zhang Guan-Ding Zhao Shi-Hang Xiong Qiu-Shuo Ma Ming-Ming Zhao Meiwan Chen Yuan-Jia Hu Chang-Sheng zhang Hua Yu State Key Laboratory of Quality Research in Chinese Medicine Institute of Chinese Medical SciencesUniversity of MacaoMacao SARChina Macao Centre for Research and Development in Chinese Medicine Institute of Chinese Medical SciencesUniversity of MacaoMacao SARChina Key Laboratory of Tropical Marine Bio-resources and Ecology Guangdong Key Laboratory of Marine Materia MedicaRNAM Center for Marine MicrobiologySouth China Sea Institute of OceanologyChinese Academy of SciencesGuangzhou510301China State Key Laboratory of Functions and Applications of Medicinal Plants&School of Pharmaceutical Sciences Guizhou Medical UniversityGuiyang550025China

Activation of nuclear factor erythroid 2-related factor 2(Nrf2)by Kelch-like ECH-associated protein 1(Keap1)alkylation plays a central role in anti-inflammatory ***,activators of Nrf2 through alkylation of Keap1-Kelch domain have not been ***(DNQ)is a natural small molecule discovered from marine *** current study was designed to investigate the anti-inflammatory effects and molecular mechanisms of DNQ via alkylation of *** exhibited significant anti-inflammatory properties both in vitro and in *** pharmacophore responsible for the anti-inflammatory properties of DNQ was determined to be theα,β-unsaturated amides moieties by a chemical reaction between DNQ and *** exerted anti-inflammatory effects through activation of Nrf2/ARE ***1 was demonstrated to be the direct target of DNQ and bound with DNQ through conjugate addition reaction involving *** specific alkylation site of DNQ on Keap1 for Nrf2 activation was elucidated with a synthesized probe in conjunction with liquid chromatography-tandem mass *** triggered the ubiquitination and subsequent degradation of Keap1 by alkylation of the cysteine residue 489(Cys489)on Keap1-Kelch domain,ultimately enabling the activation of *** findings revealed that DNQ exhibited potent anti-inflammatory capacity throughα,β-unsaturated amides moieties active group which specifically activated Nrf2 signal pathway via alkylation/ubiquitination of Keap1-Kelch domain,suggesting the potential values of targeting Cys489 on Keap1-Kelch domain by DNQ-like small molecules in inflammatory therapies.

关键词： Deoxynyboquinone Anti-inflammation Target Keap1/Nrf2 Alkylation Ubiquitination

Degradable magnesium alloy suture promotes fibrocartilaginous interface regeneration in a rat rotator cuff transosseous repair model

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Journal of Magnesium and Alloys 2024年第1期12卷 384-393页

作者： Baoxiang zhang wen zhang Fei zhang Chao Ning Mingyang An Ke Yang Lili Tan Qiang zhang Department of Sports Medicine Chinese PLA General HospitalBeijing 100853China Shi-changxu Innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of Materials Science and Engineering University of Science and Technology of ChinaShenyang 110016China Medical School of PLA Beijing 100853China Institute of Orthopedics Chinese PLA General HospitalBeijing Key Lab of Regenerative Medicine in OrthopedicsKey Lab of Musculoskeletal Trauma&War Injuries of Chinese PLABeijing 100853China

Despite transosseous rotator cuff tear repair using sutures is widely accepted for tendon-bone fixation,the fibrocartilaginous enthesis regeneration is still hardly achieved with the traditional *** the present work,degradable magnesium(Mg)alloy wire was applied to suture supraspinatus tendon in a rat acute rotator cuff tear model with Vicryl Plus 4±0 absorbable suture as *** shoulder joint humerus-supraspinatus tendon complex specimens were retrieved at 4,8,and 12 weeks after *** Mg alloy suture groups showed better biomechanical properties in terms of ultimate load to *** observation showed that hyperplastic response of the scar tissue at the tendon-bone interface is progressively alleviated over time in the both Mg alloy suture and Vicryl suture *** the histological analysis,for Mg alloy suture groups,chondrocytes appear to proliferate at 4 weeks postoperatively,and the tendon-bone interface showed an orderly structural transition zone at 8 weeks *** collagenous fiber tended to be aligned and the tendon-bone interlocking structures apparently formed,where transitional structure from unmineralized fibrocartilage to mineralized fibrocartilage was closer to the native fibrocartilaginous *** vivo degradation of the magnesium alloy wire was completed within 12 *** results indicated that Mg alloy wire was promising as degradable suture with the potential to promotes fibrocartilaginous interface regeneration in rotator cuff repair.

关键词： Rotator cuff repair Mg alloy wire Tendon-bone healing Fibrocartilaginous interface

分布式全相参雷达相干参数估计及相参性能分析

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通信学报 2015年第3期36卷 232-240页

作者：宋靖张剑云张文刚电子工程学院

针对一般结构的分布式全相参雷达,首先推导了包括时延差及"和相位差"的相干参数估计的克拉美—罗界(CRB)闭式解;然后考虑时延和相位补偿误差同时存在时,分析了全相参模式下的输出信噪比增益(oSNRg),基于相干参数估计的CRB,给出了oSNRg... 详细信息

针对一般结构的分布式全相参雷达,首先推导了包括时延差及"和相位差"的相干参数估计的克拉美—罗界(CRB)闭式解;然后考虑时延和相位补偿误差同时存在时,分析了全相参模式下的输出信噪比增益(oSNRg),基于相干参数估计的CRB,给出了oSNRg的上界的数值解。结论表明,"和相位差"的CRB与信号载频及有效带宽均无关;oSNRg随着发射天线数的增加而提高;而增加接收天线数,能否提高oSNRg取决于输入信噪比大小,较大时则oSNRg随之提高,较小时反而随之下降。最后仿真实验验证了研究结论的正确性。

关键词：全相参克拉美-罗界参数估计费歇尔信息矩阵

Energy-based Directional Pilot Protection for Distribution Networks with IBDGs Considering Unmeasured Load Switching

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CSEE Journal of Power and Energy Systems 2024年第1期10卷 139-150页

作者： Chenghan Zhou Guibin Zou Shuo zhang Xuhui wen Key Laboratory of Power System Intelligent Dispatch and Control of Ministry of Education Shandong UniversityJinan 250061China

Inverter-based distributed generations(IBDGs)are the main approach to utilizing clean energy in distribution networks(DNs).Compared with synchronous source,fault response of IBDG is very *** a result,in DNs with high penetration of IBDGs,legacy protection schemes will no longer be *** this paper,an energy-based directional pilot protection scheme suitabie for DNs with IBDGs is *** scheme considers the large range of phase angle caused by IBDG integration and uses improved energy polarity criterion to determine fault *** addition,magnitude of energy is used to distinguish between faults and load switching to overcome maloperation of directional pilot protection caused by internal unmeasured load *** proposed scheme first uses local measured information to determine fault direction sign and then exchanges the direction sign with the remote *** scheme does not require high-bandwidth communication and strict data synchronization,so it can be implemented at a low ***,simulation studies verify effectiveness of the proposed scheme.

关键词： Distribution network energy polarity inverterbased distributed generation pilot protection unmeasured load

Regulating the intrinsic electronic structure of carbon nanofibers with high-spin state Ni for sodium storage with high-power density

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Journal of Materials Science & Technology 2024年第4期171卷 16-23页

作者： Zhijia zhang gang Xie Yuefang Chen Yanhao Wei Mengmeng zhang Shulei Chou Yunxiao Wang Yifang zhang Yong Jiang School of Materials Science and Engineering Institute of Quantum Materials and DevicesState Key Laboratory of Separation Membrane and Membrane ProcessesTiangong UniversityTianjin 300387China Institute for Carbon Neutralization College of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325035China Institute for Superconducting and Electronic Materials University of WollongongWollongongNSW 2522Australia

Carbon nanofibers(CNFs)with high specific surface area show great potential for sodium storage as a hard carbon ***,CNFs anchored with Ni nanoparticles(CNFs/Ni)were prepared through chemical vapor deposition and impregnation reduction methods,in situ growing on the three-dimensional porous copper current collector(3DP-Cu).The coupling effect of high-spin state Ni nanopar-ticles leads to the increase of defect density and the expansion of lattice spacing of ***,the 3DP-Cu ensures a high loading capacity of CNFs and short ion/electron transport *** an integral binder-free anode,the 3DP-Cu/CNFs/Ni exhibits excellent electrochemical performance,which demon-strates a high specific capacity with 298.5 mAh g^(-1)at 1000 mA g^(-1)after 1500 cycles,and a high power density with 200 mAh g^(-1)over 1000 cycles at 5000 mA g^(-1).Density functional theory calculation re-sults show that the high-spin state Ni regulates the electronic structure of CNFs,which significantly reduces the adsorption energy for Na^(+)(-2.7 Ev)and thus enables high-rate *** regulation of the electronic structure of carbon materials by high-spin state metal provides a new strategy for developing high-power carbonaceous anode materials for sodium-ion batteries.

关键词： Carbon nanofibers Ni nanoparticles High-spin state Sodium-ion batteries Anode materials Density functional theory calculation

Effects of surface morphology on tribological properties of Arapaima gigas scales

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Friction 2024年第7期12卷 1469-1482页

作者： Shuaijun zhang Pengpeng BAI Xiangli wen Chengwei wen Hui CAO Wanyou YANG Yu TIAN State Key Laboratory of Tribology in Advanced Equipment Department of Mechanical EngineeringTsinghua UniversityBeijing 100084China Key Laboratory of Bionic Engineering(Ministry of Education China)Jilin UniversityChangchun 130022China

The remarkable mechanical adaptability of arapaima(Arapaima gigas)scales has made them an important subject of ***,no research has been conducted into their tribological properties,which are crucial for the protectability and flexibility of *** this study,by combining morphological characterizations,friction experiments,and theoretical analyses,the relationship between the surface morphology and tribological properties of arapaima scales is *** results indicate that arapaima scales exhibit varying surface morphologies in different *** specifically,the exposed regions of scales feature grooves and a circulus,whereas the covered regions exhibit *** specific surface morphology of arapaima scales produces varying tribological properties across different regions and sliding *** unique tribological properties of arapaima scales influence the forces received from predator attacks and neighboring scales,directly influencing the arapaima’s protective *** study provides new insights into the mechanisms of natural flexible dermal armors,and it has potential applications in personal protective systems.

关键词： arapaima scales surface morphology tribological properties protectability

Rapid report of source parameters of 2023 M6.2 Jishishan,Gansu earthquake sequence

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Earth and Planetary Physics 2024年第2期8卷 436-443页

作者： ZhiGao Yang Jie Liu YingYing zhang wen Yang XueMei zhang China Earthquake Networks Center Beijing 100045China

The M6.2 earthquake in Jishishan,Gansu Province,on December 18,2023,caused extraordinary earthquake *** was located in the northern part of the north−south seismic zone,which is a key area for earthquake monitoring in *** newly built dense strong motion stations in this area provide unprecedented conditions for high-precision earthquake relocation,especially the earthquake focal *** paper uses the newly built strong motion and traditional broadband seismic networks to relocate the source locations of the M3.0 and above aftershocks and to invert their focal *** horizontal error of earthquake location is estimated to be 0.5−1 km,and the vertical error is 1−2 *** focal depth range of aftershocks is 9.6−14.6 km,distributed in a 12-km-long strip with SSE *** in the south are more concentrated horizontally and vertically,while aftershocks in the north are more *** focal mechanisms of the main shock and aftershocks are relatively consistent,and the P-axis orientation is consistent with the regional strain *** is a seismic blank area of M3.0 and above,about 3−5 km between the main shock and *** is suggested that the energy released by the main shock rupture is concentrated in this *** on the earthquake location and focal mechanism of the main shock,it is inferred that the Northern Lajishan fault zone is the seismogenic structure of the main shock,and the main shock did not occur on the main fault,but on a secondary *** initial rupture depth and centroid depth of the main shock were 12.8 and 14.0 km,*** source rupture depth may not be the main reason for the severe earthquake disaster.

关键词： Jishishan earthquake earthquake relocation focal mechanism strong motion data

Designing ultrastrong and thermally stable FeCrAl alloys with the fine-grained structure

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Journal of Materials Science & Technology 2024年第4期171卷 198-208页

作者： Shuaiyang Liu Jinyu zhang Hui Wang gang Liu Xiangdong Ding Jun Sun State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi’an 710049China Science and Technology on Reactor Fuel and Materials Laboratory Nuclear Power Institute of ChinaChengdu 610041China

Designing microstructurally stable FeCrAl alloys with excellent strength-ductility synergy is highly desir-able for their engineering ***,due to the preference nucleation of precipitates at grain boundaries(GBs),the improved precipitation strengthening of these alloys is usually accompanied by in-tergranular ***,we propose a novel thermomechanical processing route coupled with the Si alloying strategy via precipitation of coherent deformable Laves precipitates inside equiaxed fine-grains to achieve FeCrAl alloys with ultrahigh yield strength over∼992 MPa,excellent uniform elongation of∼7.6%at room temperature,and superior thermal stability at temperature∼1200℃.The Si alloying not only decreases the stacking fault energy of Laves precipitates favorable for their stacking-fault-mediated deformation but also hinders grain coarsening at 1200℃due to the Si-enrichment favorable for GB pin-ning *** results prove the possibility of achieving the collaborative enhancement of mutually exclusive properties in alloys,such as strength-ductility-thermal stability via nanoprecipitation engineer-ing,and offer a promising route to prepare dispersion-strengthened materials.

关键词： FeCrAl alloys Si alloying Mechanical properties Thermal stability Laves phase

Assessment of the Influence of Tunnel Settlement on Operational Performance of Subway Vehicles

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Structural Durability & Health Monitoring 2024年第1期18卷 55-71页

作者： gang Niu Guangwei zhang Zhaoyang Jin Wei zhang Xiang Liu China Communications Construction Rail Transit Subsidiary Beijing100000China China Communications Construction Strait Construction Investment Development Co. Ltd.Fuzhou350000China School of Civil Engineering Fujian University of TechnologyFuzhou350118China

In the realm of subway shield tunnel operations,the impact of tunnel settlement on the operational performance of subway vehicles is a crucial *** study introduces an advanced analytical model to investigate rail geometric deformations caused by settlement within a vehicle-track-tunnel coupled *** model integrates the geometric deformations of the track,attributed to settlement,as track irregularities.A novel“cyclic model”algorithm was employed to enhance computational efficiency without compromising on precision,a claim that was rigorously *** model’s capability extends to analyzing the time-history responses of vehicles traversing settlement-affected *** research primarily focuses on how settlement wavelength,amplitude,and vehicle speed influence operational *** findings indicate that an increase in settlement wavelength can improve vehicle performance,whereas a rise in amplitude can degrade *** study also establishes settlement thresholds,based on vehicle operation comfort and *** insights are pivotal for maintaining and enhancing the safety and efficiency of subway systems,providing a valuable framework for urban infrastructure management and long-term maintenance strategies in metropolitan transit systems.

关键词： Settlement running performance subway tunnel dynamic analysis track irregularity threshold