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Atmospheric and Oceanic Science Letters 2013年第2期6卷 84-89页

作者： LIN Jin-Tai PAN Da zhang rui-xiong Department of Atmospheric and Oceanic Sciences & Laboratory for Climate and Ocean-Atmosphere Studies School of Physics Peking University

Abstract Chinese air pollution has increased in this century along with the rapid socioeconomic development and resulting anthropogenic emissions. While recent emission control measures have shown encouraging re sults and have reduced the levels of sulfur dioxide and primary aerosols, the concentrations of other air pollutants continue to grow, particularly secondary pollutants in cluding ozone and secondary aerosols. Meanwhile, a va riety of intentional and unintentional socioeconomic events have temporarily changed the pace, and even the signs, of growth of air pollution. These events include the short-term emission restrictions imposed during the Sino-African Summit, the Beijing Olympics and Para lympics, the Shanghai World Exposition （Shanghai Expo）, the Guangzhou Asian Olympics, and the Shenzhen Uni versiade, as well as the unintentional emission reductions associated with the recent economic recession and the annual Chinese New Year. This paper presents a brief overview of trends and temporary perturbations of Chi nese air pollution since 2000, summarizing studies on anthropogenic emission inventories, atmospheric meas urements, and inverse modeling. It concludes with rec ommendations for future research.

关键词： air pollution trend and variability socioeconomic development satellite measurements bottom-upemission inventories top-down constraints

Deep neural network-enabled battery open-circuit voltage estimation based on partial charging data

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Journal of Energy Chemistry 2024年第3期90卷 120-132,I0005页

作者： Ziyou Zhou Yonggang Liu Chengming zhang Weixiang Shen rui xiong State Key Laboratory of Mechanical Transmission for Advanced Equipment&College of Mechanical and Vehicle Engineering Chongqing UniversityChongqing 400000China Department of Vehicle Engineering School of Mechanical EngineeringBeijing Institute of TechnologyBeijing 100081China Department of Electrical Engineering Harbin Institute of TechnologyHarbin 150000HeilongjiangChina School of Science Computing and Engineering TechnologiesSwinburne University of TechnologyHawthornVictoria 3122Australia

Battery management systems(BMSs) play a vital role in ensuring efficient and reliable operations of lithium-ion *** main function of the BMSs is to estimate battery states and diagnose battery health using battery open-circuit voltage(OCV).However,acquiring the complete OCV data online can be a challenging endeavor due to the time-consuming measurement process or the need for specific operating conditions required by OCV estimation *** addressing these concerns,this study introduces a deep neural network-combined framework for accurate and robust OCV estimation,utilizing partial daily charging *** incorporate a generative deep learning model to extract aging-related features from data and generate high-fidelity OCV *** analysis is employed to identify the optimal partial charging data,optimizing the OCV estimation precision while preserving exceptional *** validation results,using data from nickel-cobalt-magnesium(NCM) batteries,illustrate the accurate estimation of the complete OCV-capacity curve,with an average root mean square errors(RMSE) of less than 3 *** this level of precision for OCV estimation requires only around 50 s collection of partial charging *** validations on diverse battery types operating under various conditions confirm the effectiveness of our proposed *** cases of precise health diagnosis based on OCV highlight the significance of conducting online OCV *** method provides a flexible approach to achieve complete OCV estimation and holds promise for generalization to other tasks in BMSs.

关键词： Lithium-ion battery Open-circuit voltage Health diagnosis Deep learning

Development review and the prospect of oil shale in-situ catalysis conversion technology

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Petroleum Science 2024年第2期21卷 1385-1395页

作者： Li Wang Chen-Hao Gao rui-Ying xiong Xiao-Jun zhang Ji-Xiang Guo The Unconventional Oil and Gas Institute China University of Petroleum-BeijingBeijing102200China

As an unconventional resource, oil shale possesses abundant reserves and significant potential for industrial applications. The rational and efficient development of oil shale resources holds immense importance in reducing national energy demand. In-situ catalytic technology, characterized by its high efficiency, low pollution, and minimal energy consumption, represents a key direction for future oil shale development. This paper provides a comprehensive review of research progress in in-situ oil shale mining technology, oil shale pyrolysis catalysts, the pyrolysis mechanism of kerogen, and the compatibility of different heating processes and catalysts. Furthermore, the paper proposes future research directions and prospects for oil shale in-situ catalytic technology, including reservoir modification, highefficiency catalyst synthesis, injection processes, and high-efficiency heating technology. These insights serve as valuable technical references for the advancement of oil shale in-situ catalytic technology.

关键词： Oil shale In-situ catalytic technology Pyrolysis catalyst Kerogen pyrolysis mechanism

In situ modification of heavy oil catalyzed by nanosized metal-organic framework at mild temperature and its mechanism

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Chinese Journal of Chemical Engineering 2024年第3期67卷 166-173页

作者： Li Wang Ji-Xiang Guo rui-Ying xiong Chen-Hao Gao Xiao-Jun zhang Dan Luo The Unconventional Oil and Gas Institute China University of Petroleum-BeijingBeijing 102200China Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of SciencesBeijing 101400China

Two catalysts, nano-sized cobalt-metal-organic framework(Co-MOF) and nickel(Ni)-MOF, were successfully prepared by the modification method. Tetralin(C10H12) was used as the hydrogen donor for the catalytic cracking and hydrogenation modification study of the dehydrated crude oil from the Shengli Oilfield. The optimal reaction conditions were determined through orthogonal experiments, and the components of the crude oil and modified oil samples were analyzed. The results revealed that the nanoMOF catalysts were successfully prepared and exhibited high catalytic activity. They could catalyze the cracking of large molecules in heavy oil at mild temperatures(<300°C), leading to the decomposition of the hydrogen donor. When the mass fraction of the catalyst was 0.2%, the mass fraction of the hydrogen donor was 1%, and the reaction temperature was 280°C, the Ni-MOF showed the best catalytic viscosity reduction effect. It could reduce the viscosity of heavy oil at 50°C from 15761.9 m Pa.s to 1266.2 m Pa.s,with a viscosity reduction rate of 91.97%. The modification effect of Co-MOF was the next best, which could reduce the viscosity of heavy oil to 2500.1 m Pa.s with a viscosity reduction rate of 84.14%. Molecular dynamics simulations revealed a strong interaction force between the MOF surface and asphaltene molecules. In the process of heavy-oil catalytic hydrogenation, the nano-MOF catalyst exhibited high catalytic activity. On the one hand, the empty d orbitals outside the metal atoms in the catalyst could polarize the carbon atoms in the organic matter, accelerating the breaking of long chains. On the other hand, the metal atoms in the catalyst could bond with the carbon σ bonds, breaking the carbon-carbon bonds. This disrupted the structure of the recombined components in the crude oil, irreversibly reducing the viscosity of the heavy oil and improving its fluidity.

关键词： Nano-sized MOF Petroleum Viscosity reduction Catalyst Nanomaterials

Preparation of crab-shell-based N,O co-doped graded porous carbon for supercapacitors using the confined nanospace deposition

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Waste Disposal and Sustainable Energy 2024年第2期6卷 173-183页

作者： Yiming Li Zhihao Yu Mengyan Guo Ming zhang Jian xiong Yina Qiao rui zhang Xuebin Lu School of Environmental Science and Engineering Tianjin UniversityTianjin 30000China School of Ecology and Environment Tibet UniversityLhasa 850000China School of Environment and Safety Engineering North University of ChinaTaiyuan 030051China School of Environmental and Municipal Engineering Tianjin Chengjian UniversityTianjin 300384China

Biomass-based carbon materials with hierarchical porous structures have attracted attention for their ability to provide more channels and shorten ion transport ***,we developed a simple method based on confined nanospace ***-ing high-temperature treatment,the mesoporous silica layer wrapped around the outside of the crab shells acted as a closed nanospace and effectively suppressed the severe deformation of the crab shell structure by shrinking *** prepared carbon material has a layered porous structure with abundant and stable N and O co-doping(N 7.32%,O 3.69%).The specific capacitance of the three-electrode system was 134.3 F/g at a current density of 0.5 A/g in a 6 mol/L KOH electrolyte,and the assembled aqueous symmetric supercapacitors exhibited an excellent cycling stability of 98.81%even after 5000 cycles.

关键词： Supercapacitor Confined nanospace deposition Biomass-based carbon materials Crab shell

Experimental and DFT Investigations of AlNbTiVZr High Entropy Alloys with Excellent Mechanical Properties

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Acta Metallurgica Sinica(English Letters) 2024年第9期37卷 1480-1490页

作者： Hongwei Yan Yong'an zhang Wei Xiao Boyu Xue rui Liu Xiwu Li Zhihui Li Baiqing xiong State Key Laboratory of Nonferrous Metals and Processes China GRINM Group Co.Ltd.Beijing100088China GRIMAT Engineering Institute Co. Ltd.Beijing101407China General Research Institute for Nonferrous Metals Beijing100088China

This study investigated the microstructure and mechanical properties of AlNbTiVZr series high-entropy alloys(HEAs)through both experimental studies and density functional theory *** improvements in the microstructures and mechanical properties were achieved for the AlNbTiVZr series HEAs by meticulously adjusting the alloy composition and employing homogenization heat ***,the specimen designated as Al_(0.5)NbTiVZr_(0.5) demonstrated excellent mechanical properties including a compressive yield strength of 1162 MPa and a compressive strength of 1783 *** homogenization heat treatment at 1000℃ for 24 h,the Al_(0.5)NbTiVZr_(0.5) alloy exhibits brittle-to-ductile *** atomic-scale theoretical simulations reveal that the decrease of Al content intrinsically enhances the ductility of the alloys,thereby indicating that the mechanical properties of the AlNbTiVZr series HEAs were significantly influenced by the chemical ***,specific atomic pair formations were observed to adversely affect the microstructure of the AlNbTiVZr series HEAs,particularly in terms of *** findings provide valuable insights for the design and optimization of light weight HEAs,emphasizing the synergistic adjustment of alloy composition and heat treatment processes to achieve a balance between the strength and ductility.

关键词： High-entropy alloy Microstructure Mechanical properties Density functional theory

Multi-scale structure engineering of covalent organic framework for electrochemical charge storage

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SusMat 2024年第1期4卷 4-33页

作者： Xiaofang zhang Fangling Li Shuangqiao Yang Baiqi Song Richu Luo rui xiong Weilin Xu State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhanChina State Key Laboratory of Polymer Materials Engineering Polymer Research Institute at Sichuan UniversityChengduChina

Covalent organic frameworks(COFs),which are constructed by linking organic building blocks via dynamic covalent bonds,are newly emerged and burgeoning crystalline porous copolymers with features including programmable topological architecture,pre-designable periodic skeleton,well-defined micro-/meso-pore,large specific surface area,and customizable electroactive *** benefits make COFs as promising candidates for advanced electrochemical energy ***,for now,structure engineering of COFs from multiscale aspects has been conducted to enable optimal overall electrochemical performance in terms of structure durability,electrical conductivity,redox activity,and charge *** this review,we give a fundamental and insightful study on the correlations between multi-scale structure engineering and eventual electrochemical properties of COFs,started with introducing their basic chemistries and charge storage *** careful discussion on the significant achievements in structure engineering of COFs from linkages,redox sites,polygon skeleton,crystal nanostructures,and composite microstructures,and further their effects on the electrochemical behavior of COFs are ***,the timely cutting-edge perspectives and in-depth insights into COFbased electrodematerials to rationally screen their electrochemical behaviors for addressing future challenges and implementing electrochemical energy storage applications are proposed.

关键词： covalent organic frameworks electrochemical energy storage multi-scale structure engineering structure-performance correlation

Large post-liquefaction deformation of sand:Mechanisms and modeling considering water absorption in shearing and seismic wave conditions

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Underground Space 2024年第5期18卷 3-64页

作者： Jian-Min zhang rui Wang Department of Hydraulic Engineering State Key Laboratory of Hydroscience and EngineeringTsinghua UniversityBeijing 100084China

Large deformation of sand due to soil liquefaction is a major cause for seismic *** this study,the mechanisms and modeling of large post-liquefaction deformation of sand considering the significant influence of water absorption in shearing and seismic wave *** of case histories from past earthquakes and review of existing studies highlight the importance of the two *** on the micro and macro scale mechanisms for post-liquefaction shear deformation,the mechanism for water absorption in shearing after initial liquefaction is *** is aided by novel designed constant water-absorption-rate shear *** absorption in shearing can be classified into three types,including partial water absorption,complete water absorption,and compulsory water *** the influence of water absorption in shearing,even a strongly dilative sand under naturally drained conditions could experience instability and large shear *** mechanism for amplification of post-liquefaction deformation under surface wave load is also explained via element tests and theoretical *** shows that surface wave–shear wave coupling can induce asymmetrical force and resistance in sand,resulting in asymmetrical accumulation of deformation,which is amplified by liquefaction.A constitutive model,referred to as CycLiq,is formulated to capture the large deformation of sand considering water absorption in shearing and seismic wave conditions,along with its numerical implementation *** model is comprehensively calibrated based on various types of element tests and validated against centrifuge shaking table tests in the liquefaction experiments and analysis projects(LEAP).The model,along with various numerical analysis methods,is adopted in the successful simulation of water absorption in shearing and Rayleigh wave-shear wave coupling induced large liquefaction ***,the model is applied to high-performance simulation fo

关键词： Liquefaction Sand Large deformation Water absorption in shearing Surface wave Rayleigh wave-shear wave coupling

Combustion characteristics of millimeter-sized aluminum particles in fluidized bed under various O_(2)/CO_(2)/H_(2)O atmospheres Author links open overlay panel

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Particuology 2024年第8期91卷 315-322页

作者： Jialing Zhou rui zhang Dong Liu Key Laboratory of Thermal Control of Electronic Equipment Ministry of Industry and Information TechnologyNanjing210094China Advanced Combustion Laboratory School of Energy and Power EngineeringNanjing University of Science and TechnologyNanjing210094China

Aluminum is an attractive alternative fuel,but it burns very inefficiently due to the formation of a dense Al_(2)O_(3)layer which prevents O_(2)from diffusion to the surface of Al *** previous experiments,the combustion of millimeter-sized Al(mAl)particles in the fluidized bed has achieved a substantial increase in the combustion efficiency,but further improvements are still *** this study,the effects of reaction atmosphere on the fluidized combustion of mAl particles were *** experiments with different O_(2)/H_(2)O/CO_(2)concentrations were *** experimental results indicate that the combustion efficiency of mAl particles in fluidized bed increases as the mole fraction of O_(2),H_(2)O or CO_(2)increases,and the highest combustion efficiency can reach 38.7%.After the analysis of the oxide film on the surface of aluminum particles,it was found that it is easier to generate the unstableθ-Al_(2)O_(3)under CO_(2)atmosphere,and it is easier to generate the unstableγ-Al_(2)O_(3)andθ-Al_(2)O_(3)under H_(2)O *** unstable Al_(2)O_(3)film is more likely to be abraded in the fluidized bed,which leads to the effective improvement of the combustion efficiency.

关键词： Al combustion Fluidized bed Atmosphere Combustion efficiency

Hollow FeCoNiAl microspheres with stabilized magnetic properties for microwave absorption

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Nano Research 2024年第3期17卷 2079-2087页

作者： Linhe Yu Gangjie Lian Guozhen Zhu Sue Ren Yanfang Du Xuhui xiong rui Chen Jincang zhang Wenbin You Renchao Che Institute of Advanced Materials College of Chemistry and Chemical EngineeringJiangxi Normal UniversityNanchang 330022China Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative MaterialsAcademy for Engineering&TechnologyFudan UniversityShanghai 200438China Zhejiang Laboratory Hangzhou 311100China Capital Aerospace Machinery Corporation Limited Beijing 100000China AECC Beijing Institute of Aeronautical Materials Beijing 100095China International Center for Quantum and Molecular Structures Materials Genome InstitutePhysics DepartmentShanghai UniversityShanghai 200444China

Development of high-performance microwave absorption materials(MAM)with stabilized magnetic properties at high temperatures is specifically essential but remains ***,the Snoke's limitation restrains the microwave absorption(MA)property of magnetic *** alloy components is considered an effective way to solve the aforementioned ***,a hollow medium-entropy FeCoNiAl alloy with a stable magnetic property is prepared via simple spray-drying and two-step annealing for efficient *** exhibited an ultrabroad effective absorption band(EAB)of 5.84 GHz(12.16–18 GHz)at a thickness of just 1.6 mm,revealing an excellent absorption ***,the MA mechanism of FeCoNiAl is comprehensively investigated via off-axis ***,the electromagnetic properties,antioxidant properties,and residual magnetism at high temperatures of FeCoNiAl alloys are summarized in detail,providing new insights into the preparation of MAM operating at elevated temperatures.

关键词： microwave absorption hollow structure magnetic stability multiple microwave absorption mechanism