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Vitrification cryopreservation of ligaments based on zwitterionic betaine

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Chinese Journal of Chemical Engineering 2024年第8期72卷 1-9页

作者： Liming zhang Xinmeng Liu Haoyue Li Lei zhang Department of Biochemical Engineering Frontier Science Center for Synthetic Biology and Key Laboratory of Systems Bioengineering(MOE)School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300350China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China

Ligament cryopreservation enables a prolonged shelf life of allogeneic ligament grafts,which is fundamentally important to ligament ***,conventional cryopreservation techniques fail to eliminate the damage caused by ice crystal growth and the toxicity of cryopreservation agents(CPAs).Here,we report a novel CPA vitrification formulation primarily composed of betaine for ligament *** optimization was conducted on the methods for vitrification and rewarming,as well as the loading and unloading conditions,based on the critical cooling rate(CCR),critical warming rate(CWR),and permeation properties of the *** biomechanical and histological level tests,we demonstrate the superior performance of our method in ligament *** 30 days of vitrification cryopreservation,parameters such as the Young's modulus,tensile stress,denaturation temperature,and glycosaminoglycans content of the ligament remained essentially *** work pioneers the application of ice-free cryopreservation for ligament and holds great potential for improving the long-term storage of ligament,providing valuable insights for future cryopreservation technique development.

关键词： Ligament Betaine Vitrification Cryopreservation

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Three-dimensional porous bimetallic metal–organic framework/gelatin aerogels: A readily recyclable peroxymonosulfate activator for efficient and continuous organic dye removal

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Chinese Journal of Chemical Engineering 2024年第7期71卷 193-202页

作者： Wenlong Xiang Xian zhang Rou Xiao Yanhui zhang College of Chemistry Chemical Engineering and EnvironmentFujian Province Key Laboratory of Morden Analytical Science and Separation TechnologyMinnan Normal UniversityZhangzhou 363000China Fujian Provincial University Key Laboratory of Pollution Monitoring and Control Minnan Normal UniversityZhangzhou 363000China

As promising catalysts for the degradation of organic pollutants,metal–organic frameworks(MOFs)often face limitations due to the particle agglomeration and challenging recovery in liquid-catalysis application,stemming from their powdery *** macroscopic structures from pulverous MOF is thus of great importance for broadening their practical *** this study,three-dimensional porous MOF aerogel catalysts were successfully fabricated for degrading organic dyes by activating peroxymonosulfate(PMS).MOF/gelatin aerogel(MOF/GA)catalysts were prepared by directly integrating bimetallic FeCo-BDC with gelatin solutions,followed by freeze-drying and low-temperature *** FeCo-BDC-0.15/GA/PMS system exhibited remarkable performance in degrading various organic dyes,eliminating 99.2%of rhodamine B within a mere 5 *** to the GA/PMS system,there was over a 300-fold increase in the reaction rate ***,high removal efficiency was maintained across varying conditions,including different solution pH,co-existing inorganic anions,and natural water *** trapping experiments and electron paramagnetic resonance analysis revealed that the degradation involved radical(SO_(4)^(-)·)and non-radical routes(^(1)O_(2)),of which ^(1)O_(2) was ***,even after a continuous 400-min reaction in a fixed-bed reactor at a liquid hourly space velocity of 27 h^(-1),the FeCo-BDC/GA composite sustained a degradation efficiency exceeding 98.7%.This work presents highly active MOF-gelatin aerogels for dye degradation and expands the potential for their large-scale,continuous treatment application in organic dye wastewater management.

关键词： Catalyst Environment Wastewater Metal–organic framework Gelatin aerogel Peroxymonosulfate

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Carbon nanotubes and hexagonal boron nitride nanosheets co-filled ethylene propylene diene monomer composites:Improved electrical property for cable accessory applications

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High Voltage 2024年第3期9卷 546-555页

作者： Tiandong zhang Huiduo Xu Chuanxian Dai Changhai zhang Yongquan zhang Qingguo Chi School of Electrical and Electronic Engineering Harbin University of Science and TechnologyHarbinChina

Rubber-based composites based on ethylene propylene diene monomer(EPDM)with excellent non-linear electrical conductivity are preferred to serve as reinforced insu-lation in cable accessories,which can self-adaptively regulate electric field distribution and avoid electric field concentration due to the non-linear *** conductive carbon nanotubes(CNT)are filled into EPDM to improve the non-linear conductivity,while the insulating hexagonal boron nitride nanosheets(h-BN)are used to reconcile the electric breakdown *** results show that with the increase of CNT loading content,the non-linear conductivity of CNT/h-BN/EPDM com-posites becomes more prominent,accompanying the decrease of threshold field strength and increase of non-linear ***,the electric breakdown strength of CNT/h-BN/EPDM composites seriously deteriorates due to the increase of CNT content and *** incorporating 10 wt.%h-BN into the com-posites,the reduction percentage of breakdown strength can be significantly lowered,which is 19.95%of neat EPDM and 13.74%of CNT/h-BN/EPDM composites at 70℃,*** COMSOL Multiphysics simulation results demonstrate that using the CNT/h-BN/EPDM composite as the reinforced insulation can eliminate the electric field concentration of the cable accessory as well as enable the cable accessory with good lightning shock resistance.

关键词： composites hexagonal boron

Distributed adaptive prescribed-time orbit containment control for satellite cluster flight

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Chinese Journal of Aeronautics 2024年第8期37卷 342-357页

作者： Tingting zhang Shijie zhang Huayi LI Xiangtian ZHAO Research Center of Satellite Technology Harbin Institute of TechnologyHarbin 150080China State Key Laboratory of Networking and Switching Technology Beijing University of Posts and TelecommunicationsBeijing 100876China

The distributed prescribed-time orbit containment control for the satellite cluster flight with multiple dynamic leaders is *** directed information communication topology between followers is taken into account in the overall *** the satellite mass is assumed to be constant,a distributed prescribed-time orbit containment controller is,firstly,presented to drive the followers into the dynamic convex hull produced by multiple ***,the parameter uncertainty is considered,and a prescribed-time sliding mode estimator is introduced to estimate the desired velocity of each *** on the estimated state,a novel distributed adaptive prescribed-time orbit containment control scheme is *** Lyapunov stability theory is utilized to prove the prescribed-time stability of the closed-loop ***,several numerical simulations and comparison of different control methods are provided to verify the effectiveness and superiority of the proposed control method.

关键词： Satellite cluster Orbit containment control Prescribed-time control Parameter uncertainty Directed communication graph

Elliptical encirclement control capable of reinforcing performances for UAVs around a dynamic target

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Defence Technology（防务技术） 2024年第2期32卷 104-119页

作者： Fei zhang Xingling Shao Yi Xia Wendong zhang National Key Laboratory for Electronic Measurement Technology School of Instrument and ElectronicsNorth University of ChinaTaiyuan030051China

Most researches associated with target encircling control are focused on moving along a circular orbit under an ideal environment free from external ***,elliptical encirclement with a time-varying observation radius,may permit a more flexible and high-efficacy enclosing solution,whilst the non-orthogonal property between axial and tangential speed components,non-ignorable environmental perturbations,and strict assignment requirements empower elliptical encircling control to be more challenging,and the relevant investigations are still *** this line,an appointed-time elliptical encircling control rule capable of reinforcing circumnavigation performances is developed to enable Unmanned Aerial Vehicles(UAVs)to move along a specified elliptical path within a predetermined reaching *** remarkable merits of the designed strategy are that the relative distance controlling error can be guaranteed to evolve within specified regions with a designer-specified convergence ***,wind perturbations can be online counteracted based on an unknown system dynamics estimator(USDE)with only one regulating parameter and high computational *** tool demonstrates that all involved error variables are ultimately limited,and simulations are implemented to confirm the usability of the suggested control algorithm.

关键词： Elliptical encirclement Reinforced performances Wind perturbations UAVs

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New structure transistors for advanced technology node CMOS ICs

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National Science Review 2024年第3期11卷 24-41页

作者： Qingzhu zhang Yongkui zhang Yanna Luo Huaxiang Yin Integrated Circuit Advanced Process R&D Center Institute of Microelectronics of Chinese Academy of Sciences(IMECAS) State key Lab of Fabrication Technologies for Integrated Circuits Institute of Microelectronics of Chinese Academy of Sciences School of Integrated Circuits University of Chinese Academy of Sciences

Over recent decades, advancements in complementary metal-oxide-semiconductor integrated circuits(ICs)have mainly relied on structural innovations in transistors. From planar transistors to the fin field-effect transistor(FinFET) and gate-all-around FET(GAAFET), more gate electrodes have been added to three-dimensional(3D) channels with enhanced control and carrier conductance to provide higher electrostatic integrity and higher operating currents within the same device footprint. Beyond the 1-nm node, Moore's law scaling is no longer expected to be applicable to geometrical shrinkage. Vertical transistor stacking, e.g. in complementary FETs(CFET), 3D stack(3DS) FETs and vertical-channel transistors(VFET), for enhanced density and variable circuit or system design represents a revolutionary scaling approach for sustained IC development. Herein, innovative works on specific structures, key process breakthroughs, shrinking cell sizes and design methodologies for transistor structure research and development are reviewed. Perspectives on future innovations in advanced transistors with new channel materials and operating theories are also discussed.

关键词： transistor CMOS GAAFET CFET 3DS FET

Coupled simulation of fluid-particle interaction for large complex granules:A resolved CFD-DEM method for modelling the airflow in a vertical fixed bed of irregular sinter particles

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Particuology 2024年第7期90卷 292-306页

作者： Chengzhi Li Yu zhang Jiahe Shen Wei zhang The State Key Laboratory of Refractories and Metallurgy Wuhan University of Science and TechnologyWuhan 430081China Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education Wuhan University of Science and TechnologyWuhan 430081China School of Transportation and Logistics Engineering Wuhan University of TechnologyWuhan 430063China Centre for Bulk Solids and Particulate Technologies The University of NewcastleCallaghan NSW 2308Australia

A resolved CFD-DEM method is proposed to simulate the fluid-particle interaction for large complex *** airflow in a vertical sinter fixed bed is numerically studied using this *** multi-sphere clumped method is used to create irregular sinter particles in *** immersed boundary method and dynamic cell refinement are applied to describe the fluid flow around particles with higher resolution,by which the fluid-particle interaction can be simulated more *** simulation results presented the packing voidage distributions and the airflow fields in the sinter beds of different single and mixed particle size *** bed pressure drops were simulated and the results were compared with the corresponding experimental *** good agreement indicated that the proposed resolved CFD-DEM method is an effective tool to model the fluid-particle interaction for irregular large granules in the gas-solid multi-phase systems.

关键词： Resolved CFD-DEM method Irregular sinter particles Multi-sphere clumped method Immersed boundary method Dynamic cell refinement

Multi-user reinforcement learning based task migration in mobile edge computing

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Frontiers of Computer Science 2024年第4期18卷 161-173页

作者： Yuya CUI Degan zhang Jie zhang Ting zhang Lixiang CAO Lu CHEN Tianjin Key Lab of Intelligent Computing and Novel Software Technology Tianjin University of TechnologyTianjin 300384China School of Internet of Things Engineering Jiangsu Vocational College of Information TechnologyWuxi 214153China School of Electronic and Information Engineering Beijing Jiaotong UniversityBeijing 100044China School of Sports Economics and Management Tianjin University of SportTianjin 301617China

Mobile Edge Computing(MEC)is a promising *** service migration is a key technology in *** order to maintain the continuity of services in a dynamic environment,mobile users need to migrate tasks between multiple servers in real *** to the uncertainty of movement,frequent migration will increase delays and costs and non-migration will lead to service ***,it is very challenging to design an optimal migration *** this paper,we investigate the multi-user task migration problem in a dynamic environment and minimizes the average service delay while meeting the migration *** order to optimize the service delay and migration cost,we propose an adaptive weight deep deterministic policy gradient(AWDDPG)*** distributed execution and centralized training are adopted to solve the high-dimensional *** show that the proposed algorithm can greatly reduce the migration cost and service delay compared with the other related algorithms.

关键词： mobile edge computing mobility service migration deep reinforcement learning deep deterministic policy gradient

Breakthrough of Carbon-Ash Recalcitrance in Hydrochar via Molten Carbonate:Engineering Mineral-Rich Biowaste Toward Sustainable Platform Carbon Materials

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Engineering 2024年第5期36卷 167-177页

作者： Zihan Wang Leli zhang Yuanhui zhang Zhidan Liu Laboratory of Environment-Enhancing Energy(E2E) Key Laboratory of Agricultural Engineering in Structure and EnvironmentMinistry of AgricultureCollege of Water Resources and Civil EngineeringChina Agricultural UniversityBeijing 100083China Department of Agricultural and Biological Engineering University of Illinois at Urbana-ChampaignUrbanaIL 61801USA

The function-led design of porous hydrochar from mineral-rich biowaste for environmental applications inevitably suffers from carbon-ash ***,a method to alter the original carbon skeleton with ash remains elusive and hinders the availability of ***,we propose a facile strategy for breaking the rigid structure of carbon-ash coupled hydrochar using phase-tunable molten carbonates.A case system was designed in which livestock manure and NaHCO3 were used to prepare the activated hydrochar,and NH3 served as the target *** to the redox effect,we found that organic fractions significantly advanced the melting temperature of Na2CO3 below 800℃.The Na species steadily broke the carbon-ash interaction as the thermal intensity increased and transformed inorganic constituents to facilitate ash dissolution,rebuilding the hydrochar skeleton with abundant hierarchical channels and active defect *** surface polarity and mesopore distribution collectively governed the five cycles NH3 adsorption attenuation *** hydrochar delivered favorable potential for application with a maximum overall adsorption capacity of 100.49 mg·g^(-1).Integrated spectroscopic characterization and theoretical computations revealed that incorporating NH3 on the carbon surface could transfer electrons to chemisorbed oxygen,which promoted the oxidation of pyridine-N during *** work offers deep insight into the structure function correlation of hydrochar and inspires a more rational design of engineered hydrochar from high-ash biowaste.

关键词： Hydrochar Livestock manure Ammonia adsorption Deashing Oxygen activation