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Hydrogen storage thermodynamics and kinetics of as-cast Ce-Mg-Ni-based alloy

Journal of Iron and Steel Research International 2024年第3期31卷 752-766页

作者： Yan qi Xin zhang Jun Li Dong-liang Zhao Shi-hai Guo Yang-huan zhang Department of Functional Material Research Central Iron and Steel Research InstituteBeijing 100081China China Rare Earth New Material(Weishan)Co..Ltd. Jining 277600ShandongChina Collaborative Innovation Center of Integrated Exploitation of Bayan Obo Multi-Metal Resources Inner Mongolia University of Science and TechnologyBaotou 014010Inner MongoliaChina

The reaction kinetics of alloys based on magnesium are known to be greatly improved by the partial substitution of Mg with rare earths and transition metals,particularly *** enhanced superficial hydrogen dissociation rate,the weakened Mg-H bond and the lower activation energy following element replacement are thought to be related to the better *** experimental alloys Ce5Mg_(95-x)Ni_(x)(x=5,10,15)were smelted by the vacuum induction *** phase transformation and structural evolution of experimental alloys before and after reaction with hydrogen were char-acterized by X-ray diffraction,scanning electron microscopy and transmission electron *** cast specimens contain CeMg_(12),Mg and Mg_(2)Ni phases,and the increase in Ni content results in an obvious growth of Mg_(2)Ni *** isothermal and non-isothermal hydrogenation and dehydrogenation kinetics of the experimental specimens were investi-gated using the Sievert apparatus,differential scanning calorimetry and thermal gravimetric *** activation energy may be calculated using the Arrhenius and Kissinger *** experimental alloys have been shown to have good activation properties,with a reversible hydriding and dehydriding capacities of around 5.0 wt.%in the first *** initial dehydrogenation temperature of MgH_(2) decreases from 557.5 to 537.7 K with changing Ni content from 5 to 15 at.%.The dehydrogenation activation energy also reduces from 77.09 to 62.96 kJ/mol,which explains the improved hydrogen storage performance caused by Ni *** can be shown that the impact of Ni on the decomposition enthalpy of MgH_(2) is quite modest,with the absolute enthalpy(ΔHr)only decreasing from 78.48 to 76.15 kJ/mol.

关键词： Mg-based alloy Ni content Hydrogen storage kinetics Thermodynamic property Activation energy

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A facile strategy to construct MOF-based nanocatalyst with enhanced activity and selectivity in oxytetracycline degradation

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Nano Research 2024年第7期17卷 5863-5871页

作者： Yanjing Ke Jiaxing zhang Xin Peng Zhiyi zhang Xu Wang Wei qi Mengfan Wang School of Life Sciences Faculty of MedicineSchool of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China The Co-Innovation Centre of Chemistry and Chemical Engineering of Tianjin Tianjin 300072China Tianjin Key Laboratory of Membrane Science and Desalination Technology Tianjin 300350China

Recently,many efforts have been dedicated to construct artificial catalysts with enzyme-like ***,it is still a big challenge to endow artificial catalysts with specific substrate *** this study,we developed a facile strategy to construct a MIL-53(Fe)-based nanocatalyst with designable selectivity in the degradation of oxytetracycline(OTC).Through the Fe–O–P conjunction,oxytetracycline aptamer(OA)can be easily anchored on MIL-53(Fe)to provide the specific site for OTC *** verified that the obtained MIL-53(Fe)-Apt nanocatalyst displayed enhanced catalytic ability in the degradation of OTC,whereas obvious suppression toward other substrate *** performance therefore brings about an anticipated selectivity toward ***,we highlighted that the configuration of aptamers on MIL-53(Fe)can be modulated through varying conjunction ***–function analysis revealed that aptamer configuration affects the local concentration of substrate around catalytic site,which thus decides the catalytic performance toward *** work presented a facile and promising strategy for developing artificial catalysts with designable selectivity.

关键词： MIL-53(Fe) aptamer Fe-O-P catalytic selectivity oxytetracycline

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Identification of fangchinoline as a broad-spectrum enterovirus inhibitor through reporter virus based high-content screening

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Virologica Sinica 2024年第2期39卷 301-308页

作者： qiu-Yan zhang Jia-qi Li qi Li Yang zhang Zhe-Rui zhang Xiao-Dan Li Hong-qing zhang Cheng-Lin Deng Feng-Xia Yang Yi Xu Bo zhang The Joint Center of Translational Precision Medicine Department of Infections and DiseasesGuangzhou Institute of PediatricsGuangzhou Women and Children's Medical CenterGuangzhou510623China Key Laboratory of Special Pathogens and Biosafety Wuhan Institute of VirologyCenter for Biosafety Mega-ScienceChinese Academy of SciencesWuhan430071China University of Science and Technology of China Department of Life Sciences and MedicineHefei230026China Hunan Normal University School of MedicineChangsha410081China

Hand,foot,and mouth disease(HFMD)is a common pediatric illness mainly caused by enteroviruses,which are important human ***,there are no available antiviral agents for the therapy of enterovirus *** this study,an excellent high-content antiviral screening system utilizing the EV-A71-eGFP reporter virus was *** this screening system,we screened a drug library containing 1042 natural compounds to identify potential EV-A71 ***(FAN),a bis-benzylisoquinoline alkaloid,exhibits potential inhibitory effects against various enteroviruses that cause HFMD,such as EV-A71,CV-A10,CV-B3 and *** investigations revealed that FAN targets the early stage of the enterovirus life *** the selection of FAN-resistant EV-A71 viruses,we demonstrated that the VP1 protein could be a potential target of FAN,as two mutations in VP1(E145G and V258I)resulted in viral resistance to *** research suggests that FAN is an efficient inhibitor of EV-A71 and has the potential to be a broad-spectrum antiviral drug against human enteroviruses.

关键词： Hand,foot,and mouth disease(HFMD) Enterovirus EV-A71 High-content screening Fangchinoline(FAN)

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Microstructure and Mechanical Property of Mg‑13Gd‑0.2Ni Alloy Processed by Extrusion and Aging

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Acta Metallurgica Sinica(English Letters) 2024年第8期37卷 1367-1376页

作者： Hang zhang Jiaying Zhao Rongguang Li Boshu Liu Shanshan Li Sha Sha Yuehong zhang man Xu Yan Tang School of Mechanical and Power Engineering Shenyang University of Chemical TechnologyShenyang 110142China Instrumental Analysis Center Shenyang University of Chemical TechnologyShenyang 110142China

In this work,a good combination of strength and ductility is achieved in a Mg-13Gd-0.2Ni alloy by conventional extrusion and following aging *** aged Mg-13Gd-0.2Ni alloy exhibits a yield strength(YS)of 363 MPa,an ultimate tensile strength(UTS)of 433 MPa,and an elongation of 11.9%.The aged Mg-13Gd-0.2Ni alloy contains a microstructure with a 95%proportion of dynamically recrystallized(DRXed)grains with a micron size,weak texture,and a high number density of prismaticβ′precipitates within *** bulk compounds enriched with Ni element which are mainly formed during casting and stable in the extruded and aged *** dynamic compounds are formed during extrusion,and a high density of prismaticβ′precipitates are formed during *** high density of prismaticβ′precipitates results in a significant increase in the strength of the Mg-13Gd-0.2Ni alloy,and the YS and UTS are increased by 153 and 136 MPa,*** high proportion of DRXed grains with a weak texture contributes mainly to the high ductility and the fine compounds with a low density at grain boundaries formed during aging have no significant adverse effect on ductility of the aged Mg-13Gd-0.2Ni *** findings for the novel Mg-Gd-Ni alloy can provide guidance for the design of wrought Mg alloys with superior mechanical properties.

关键词： Mg-Gd-Ni alloy Extrusion Aging Strength Ductility

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无线传感器网络中蒙特卡洛定位算法的研究

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计算机科学 2018年第12期45卷 77-80,116页

作者：张绮曼张颖上海海事大学信息工程学院上海201306

在无线传感器网络的节点定位领域,常用的以蒙特卡洛为基础的定位算法均存在定位误差大、采样效率低的问题。为了提高无线传感器网络中针对移动节点的采样效率和定位精确度,文中采用马尔科夫链进行抽样,提出了一种基于蒙特卡洛的改进算... 详细信息

在无线传感器网络的节点定位领域,常用的以蒙特卡洛为基础的定位算法均存在定位误差大、采样效率低的问题。为了提高无线传感器网络中针对移动节点的采样效率和定位精确度,文中采用马尔科夫链进行抽样,提出了一种基于蒙特卡洛的改进算法。该算法在蒙特卡洛算法的基础上,结合马尔科夫链采集节点样本,随后对其进行过滤,再通过对得到的节点位置值进行加权计算,得到节点的准确位置。仿真实验结果表明,通过该算法得到的节点定位误差低于其他算法,提高了采样效率以及对移动节点的定位准确率。

关键词：无线传感器网络蒙特卡洛算法马尔科夫链移动节点定位

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Heterointerface engineering of rhombic Rh nanosheets confined on MXene for efficient methanol oxidation

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Journal of Energy Chemistry 2024年第6期93卷 419-428,I0011页

作者： qi zhang Quanguo Jiang Xiang Yang Chi zhang Jian zhang Lu Yang Haiyan He Guobing Ying Huajie Huang College of Materials Science and Engineering Hohai UniversityNanjing 210098JiangsuChina New Energy Technology Engineering Lab of Jiangsu Province College of ScienceNanjing University of Posts&Telecommunications(NUPT)Nanjing 210023JiangsuChina School of Materials Science and Engineering Southeast UniversityNanjing 211100JiangsuChina

Although metallic rhodium(Rh)is regarded as a promising platinum-alternative anode catalyst of direct methanol fuel cell(DMFC),the conventional"particle-to-face"contact model between Rh and matrix largely limits the overall electrocatalytic performance due to their insufficient cooperative ***,we report a controllable and robust heterointerface engineering strategy for the bottom-up fabrication of rhombic Rh nanosheets in situ confined on Ti_3C_(2)T_x MXene nanolamellas(Rh NS/MXene)via a convenient stereoassembly *** unique design concept gives the resulting 2D/2D Rh NS/MXene heterostructure intriguing textural features,including large accessible surface areas,strong"face-toface"interfacial interactions,homogeneous Rh nanosheet distribution,ameliorative electronic structure,and high electronic *** a consequence,the as-prepared Rh NS/MXene nanoarchitectures exhibit exceptional electrocatalytic methanol oxidation properties in terms of a large electrochemically active surface area of 126.2 m~2 g_(Rh)~(-1),a high mass activity of 1056.9 mA mg_(Rh)-~1,and a long service life,which significantly outperform those of conventional particle-shaped Rh catalysts supported by carbon black,carbon nanotubes,reduced graphene oxide,and MXene matrixes as well as the commercial Pt nanoparticle/carbon black and Pd nanoparticle/carbon black catalysts with the same noble metal loading *** functional theory calculations further demonstrate that the direct electronic interaction at the well-contacted 2D/2D heterointerfaces effectively enhances the adsorption energy of Rh nanosheets and induces a left shift of the d-band center,thereby making the Rh NS/MXene configuration suffer less from CO *** work highlights the importance of rational heterointerface design in the construction of advanced noble metal/MXene electrocatalysts,which may provide new avenues for developing the next-generation DMFC devices.

关键词： Rhodium nanosheet Ti_(3)C_(2)T_(x)MXene Heterointerface Electrocatalyst Fuel cell

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Recent advances in living cell nucleic acid probes based on nanomaterials for early cancer diagnosis

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Asian Journal of Pharmaceutical Sciences 2024年第3期19卷 22-40页

作者： Xuyao Liu qi Shi Peng qi Ziming Wang Tongyue zhang Sijia zhang Jiayan Wu Zhaopei Guo Jie Chen qiang zhang Department of Thyroid Surgery General Surgery CenterThe First Hospital of Jilin UniversityChangchun 130021China Key Laboratory of Polymer Ecomaterials Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China

The early diagnosis of cancer is vital for effective treatment and improved prognosis. Tumor biomarkers, which can be used for the early diagnosis, treatment, and prognostic evaluation of cancer, have emerged as a topic of intense research interest in recent years. Nucleic acid, as a type of tumor biomarker, contains vital genetic information, which is of great significance for the occurrence and development of cancer. Currently, living cell nucleic acid probes, which enable the in situ imaging and dynamic monitoring of nucleic acids, have become a rapidly developing field. This review focuses on living cell nucleic acid probes that can be used for the early diagnosis of tumors. We describe the fundamental design of the probe in terms of three units and focus on the roles of different nanomaterials in probe delivery.

关键词： Nucleic acid Nanomaterials In situ detection Living cell Early cancer diagnosis

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Laser-upgraded coal tar for smart pavements in road and bridge monitoring applications

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Microsystems & Nanoengineering 2024年第2期10卷 231-239页

作者： Jincai Huang man zhang Haoyun He qingang Li Yixin Zhao qiulin Tan Xining Zang Department of Mechanical Engineering Tsinghua UniversityBeijing100084China State Key Laboratory of Clean and Efficient Turbomachinery Power Equipment Department of Mechanical EngineeringTsinghua UniversityBeijing100084China Key Laboratory for Advanced Materials Processing Technology Ministry of EducationBeijing100084China Science and Technology on Electronic Test and Measurement Laboratory North University of ChinaTaiyuan030051China School of Energy and Mining Engineering China University of Mining and Technology(Beijing)Beijing100083China

The implementation of an intelligent road network system requires many sensors for acquiring data from roads,bridges,and vehicles,thereby enabling comprehensive monitoring and regulation of road *** this large number of required sensors,the sensors must be cost-effective,dependable,and environmentally ***,we show a laser upgrading strategy for coal tar,a low-value byproduct of coal distillation,to manufacture flexible strain-gauge sensors with maximum gauge factors of 15.20 and 254.17 for tension and compression ***,we completely designed the supporting processes of sensor placement,data acquisition,processing,wireless communication,and information decoding to demonstrate the application of our sensors in traffic and bridge vibration *** novel strategy of using lasers to upgrade coal tar for use as a sensor not only achieves the goal of turning waste into a resource but also provides an approach to satisfy large-scale application requirements for enabling intelligent road networks.

关键词： gauge bridge smart

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返乡抑或留城:农民工劳动力供求结构分析

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华南农业大学学报（社会科学版） 2023年第3期22卷 57-68页

作者：艾慧张曼琦上海大学经济研究中心上海200433

常住与户籍人口城镇化率的差距拉大及农民工回流表明:农民工市民化政策目标与效果存在差距。上述问题与农民工就业结构、空间配置紧密相关:第一,需求层面:存在农民工就业结构性失衡;城市扩张强化对农民工的劳动力需求,但面临学历错位。... 详细信息

常住与户籍人口城镇化率的差距拉大及农民工回流表明:农民工市民化政策目标与效果存在差距。上述问题与农民工就业结构、空间配置紧密相关:第一,需求层面:存在农民工就业结构性失衡;城市扩张强化对农民工的劳动力需求,但面临学历错位。第二,供给层面:从农民工根本利益出发,对定居意愿、用益物权和住房性质进行Probit计量分析发现:拥有土地承包权和宅基地使用权对定居意愿呈负向影响,土地流转、在城市拥有住房或正规性租房均有正向影响。住房性质(购房/自建房与租房)对用益物权的影响具有调节作用。第三,供求综合分析:就业错位和学历错位影响其城市收入,政策错位可能降低户籍吸引力从而影响迁移意愿,弱化定居意愿的因素占主导。应加强农民工就业技能培训,加强城市尤其是县域的住房保障及公共服务供给,尽快扭转三大错位,推进市民化与助力乡村振兴并进。

关键词：农民工劳动力供求定居意愿结构性错位

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Sulfur and carbon co-doped g-C_(3)N_(4)microtubes with enhanced photocatalytic H2 production activity

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Frontiers in Energy 2024年第1期18卷 110-121页

作者： Yang GE Quanhao SHEN qi zhang Naixu LI Danchen LU Zhaoming zhang Zhiwei FU Jiancheng ZHOU School of Chemistry and Chemical Engineering Southeast UniversityNanjing 211189China Shangdong Yellow Triangle Biotechnology Industry Research Institute Co. Ltd.Dongying 257091China Xuzhou B&C Chemical Co. Ltd.Xuzhou 221300China

Metal-free graphitic carbon nitride(g-C_(3)N_(4))has captured significant attention as a low-cost and efficient hydrogen production photocatalyst *** regulating the microstructure and accelerating the separation of photogenerated carriers remain crucial strategies for promoting the photocatalytic performance of this ***,a novel sulfur–carbon co-doped g-C_(3)N_(4)(SCCN)hierarchical microtubules filled with abundant nanosheets inside by thermal polymerization is *** nanosheets create abundant pores and cavities inside the SCCN microtubes,thereby increasing the specific surface area of g-C_(3)N_(4)and providing sufficient reactant attachment ***,the hierarchical structure of SCCN microtubules strengthens the reflection and scattering of light,and the utilization of visible light is favorably *** importantly,co-doping S and C has greatly improved the photocatalytic performance of graphitic carbon nitride,optimized the band gap structure and enhanced the photogenerated carrier ***,the SCCN exhibits a remarkable photocatalytic H_(2)evolution rate of 4868μmol/(g·h).This work demonstrates the potential of multi-nonmetal doped g-C_(3)N_(4)as the ideal photocatalyst for H2 evolution.

关键词： carbon nitride photocatalysis hydrogen production

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