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Calculating model of mass action concentrations for Ag-Au-Cu melts

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Rare Metals 2002年第1期21卷 43-47页

作者： zhang jian metallurgy school, university of Science and {2. beijing, beijing 100083, china metallurgy school University of Science and Technology Beijing 北京 100083

Based on phase diagrams and measured activities, the calculatingmodel of mass action concentrations for het- erogeneous meltsAg-Au-Cu was formulated. Calculated results agree with the improvedresults of recent research work, Showing that the model formulatedcan reflect the structural characteristics of these melts. In thismodel, without the help Of any empirical parameters, only threeequilibrium constants are used, hence it is simple, lear, andfavorable to the sim- Plification of calculation.

关键词： activity mass action concentration eutectic Solid solution

Calculating Model of Mass Action Concentrations for Mn-C Melts and Optimization of Thermodynamic Parameters

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International Journal of Minerals,metallurgy and Materials 1998年第4期12卷 208-211页

作者： jian zhang({2. school, university of Science and technology beijing, beijing 100083, china) metallurgy school University of Science and Technology Beijing Beijing 100083 China

Based on the phase diagram, the coexistence theory of the metallic melt structure involving compoundformation and the regularity of melts containing saturated phase, a calculating model of mass action concentrationsfor Mn-C melts was formulated. According to the activities (or activity coefficients AM. and γc.), obtained by theUnified Interaction Parameter Model (UIPM), the thermodynamic parameters G and G at higher temperatures (162.～1873 K) were optimized by the repeated try and error method. It is testified that G G(873～12.3 K) and G (2.8～162. K), obtained at lower temperatures, can also be used at the above-mentionedhigher temperatures. The calculated N. and N agree well with ac. and ac obtained by UIPM. This result showsthat the deduced model can reflect the structural reality of Mn-C melts.

关键词： Mn-C melts activity coexistence theory mass action concentration

Calculating Models of Mass Action Concentrations for Ni-Mn and Co-Mn Melts and Optimization of Their Thermodynamic Parameters

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International Journal of Minerals,metallurgy and Materials 2000年第4期14卷 246-250页

作者： jian zhang ({2. school, university of Science and technology beijing, beijing 100083, china) metallurgy school University of Science and Technology Beijing Beijing 100083 China

According to phase diagrams, measured activities as well as the coexistence theory of motallic melts structure involving compound formation, the calculating models of mass action concentrations for Ni-Mn and Co-Mn melts are formulated and their thermodynamic parameters are optimized. As a result, the calculated mass action concentrations agree well with the corresponding measured activities, showing that these models can reflect the structural characteristics of both Ni-Mn and Co-Mn melts.

关键词： activity metallic melts coexistence theory mass action concentration

Calculating Models of Mass Action Concentrations for Fe-P and Cr-P Melts and Optimization of Their Thermodynamic Parameters

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International Journal of Minerals,metallurgy and Materials 1999年第3期13卷 174-177页

作者： jian zhang({2. school, university of Science and technology beijing, beijing 100083, china) metallurgy school University of Science and Technology Beijing Beijing 100083 China

Based on the phase diagrams, reliable reference experimental data and the coexistence theory of metallic melts structure involving compound formation, calculating models of mass action concentrations for Fe-P and Cr-P melts have been formulated. At the same time, some of their thermodynamic parameters have been optimized. The calculated results not only agree well with the measuredvalues, but also obey the mass action law rigorously, this in turn shows that these models can reflect the structural characteristics of corresponding melts.

关键词： activity phase diagram coexistence theory mass action concentration

A Back Look on the Binary Phase Diagrams of Metals from the Mass Action Law and the Coexistence Theory of Metallic Melts

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Journal of university of Science and technology {2. 2001年第1期8卷 15-19页

作者： jian zhang {2. school, university of Science and technology beijing, beijing 100083, china Univ Sci & Technol beijing Met Sch Beijing 100083 Peoples R China

According to the mass action law and the coexistence theory of metallic melts, the mass action concentrations of Cu-Mg, Bi-Tl and Ni-Al melts involving compound formation have been calculated. The calculated results show that, except the ultimate case of pure element, when two elements are present in the melts, all structural units (atoms and molecules) without exception will be present in the melts, i.e., their concentrations may change from great to small, but they will not vanish into nothing, and only under such conditions, the calculated results both agree with practice and obey the law of mass action. In view of that over considerable wide composition range, the activities of both elements of the three solid binary alloys mentioned above have been measured, this seems in contradiction with the present relevant phase diagrams, in which the structural units are determined by composition range, so the latter needs further investigation and consideration.

关键词： activity phase diagram the mass action law the coexistence theory

Calculation Models of Mass Action Concentrations for Metallic Melts Involving Monotectic

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Journal of university of Science and technology {2. 2001年第4期8卷 248-253页

作者： jian zhang {2. school, university of Science and technology beijing, beijing 100083, china Univ Sci & Technol beijing Met Sch Beijing 100083 Peoples R China

Based on the phase diagrams, measured activities as well asDeltaG(m) and DeltaG(xs), calculating models of mass action concentrations for metallic melts involving monotectic have been formulated. The calculated results agree with practice on the whole, showing that the models deduced generally can reflect the structural characteristics of these melts. The metastable compounds formed in the melts are of the types A(2.B(3), AB(2., A(2.B(3) or AB and A(2.B(3)+AB etc..

关键词： metallic melts monotectic activity mass action concentration

Carbon Solubility and Mass Action Concentrations of Fe-Cr-C Melts

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International Journal of Minerals,metallurgy and Materials 2000年第2期14卷 86-91页

作者： Jtan zhang(metallurgy {2., university of Science and technology beijing, beijing 100083, china) metallurgy school University of Science and Technology Beijing Beijing 100083 China

An empirical equation of carbon solubility in Fe-Cr-C melts is regressed based on the experimental data from references. Acalculating model of mass action concentrations for these melts is formulated on the basis of the coexistence theory of metaIlic melts in-volving compound formation, the phase diagram of Cr-C system as well as thermodynamic data of Fe-Cr-C melts. According to the mod-el, the standard Gibbs free energies of formation of CrC and Cr3C2.are obtained. Satisfactory agreement between the calculated and me-asured values shows that the model can reflect the structural characteristics of Fe-Cr-C melts.

关键词： activity, coexistence theory mass action concentration saturated state

Calculating Model of Mass Action Concentrations for Fe-Cr-P Melts and Optimization of Thermodynamic Parameters

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International Journal of Minerals,metallurgy and Materials 1999年第1期13卷 11-14页

作者： jian zhang ({2. school, university of Science and technology Beliing, beijing 100083, china) metallurgy school University of Science and Technology Beijing Beijing 100083 China

According to the results of research on the thermodynamic propelles of Fe-Cr, Fe-P and Cr-P melts, the measured achvihes of Fe-Cr-P melts from reference sources as well as the coexistence theory of metallic melts structure involving compound formation, a calculating model of the mass action concentrations for Fe-Cr-P melts has been formulated and some of its thermodynamic parameters have been optimized. The calculated mass action concentrations agree with the measured achvities, which shows that this model can reflect the structural reality of Fe-Cr-P melts.

关键词： activity dephosphorization of stainless steel, coexistence theory mass action concentration

Thermodynamic Properties of Mn-P and Fe-Mn-P Melts

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International Journal of Minerals,metallurgy and Materials 2000年第1期14卷 10-13页

作者： jian zhang Rong Zhu {2. school, university of Science and technology beijing, beijing 100083, china Univ Sci & Technol beijing Met Sch Beijing 100083 Peoples R China

Based on the phase diagrams and the coexistence theory of metallic melts structure involving compound formation, the cal- culating models of mass action concentrations for Mn-P and Fe-Mn-P melts have been formulated. The calculated mass action concen- trations agree well with the corresponding measured activities, this in turn shows that the deduced models can reflect the structural char- acteristics of the melts concerned and there isn't any saturation of phosphorus in both melts.

关键词： activity dephosphorization the coexistence theory mass action concentration