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Chinese Science Bulletin 2005年第S1期50卷 163-170页

作者： zhang dongli & {2. xinhai sinopec exploration & Production research institute, beijing 100083, china College of Geoscience of Yangtze University, Jingzhou 43402., china sinopec exploration & Production {2. institute Beijing China College of Geoscience of Yangtze University Jingzhou China

The mechanism of production increasing for the pinnate horizontal well is analyzed with the simulation technique. It is pointed out that the whole horizontal well-bore spreading widely and evenly in coal layers makes the stratum pressure drop evenly and fast, which increases the chance of desorption and diffusion and area controlled. This is the basic reason that the pinnate horizontal well can increase production. How such stratum parameters as permeability, Langmuir constants and adsorption time constant affect the gas production for the pinnate horizontal well is also studied with numerical simulations. Either for the vertical well or the pinnate horizontal well, bigger stratum permeability, steeper relative permeability curve, smaller residual gas saturation, higher gas content and stratum pressure are more favorable for gas production increasing. Langmuir constants decide the change of desorption quantity and influence the gas production through changing the extent of steep of isothermal adsorption curves in the pressure dropping area. The adsorption time constant only influences the time that gas production arrives at the maximum value for the vertical well, but it almost has no influence on the gas production for the pinnate horizontal well because the equivalent adsorption time constant is reduced.

关键词： coalbed gas pinnate horizontal well mechanism numerical simulation sensitivity effect.

Stretchable poly[2.rotaxane elastomers

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Fundamental research 2024年第2期4卷 300-306页

作者： Kai Liu xinhai zhang Dong Zhao Ruixue Bai Yongming {2. Xue Yang Jun Zhao Hao zhang Wei Yu Xuzhou Yan School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative MoleculesShanghai Key Laboratory of Electrical Insulation and Thermal AgingShanghai Jiao Tong UniversityShanghai 200240China College of Chemistry and Chemical Engineering National Engineering Research Center for Dyeing and Finishing of TextilesDonghua UniversityShanghai 201620China

Mechanically interlocked polymers(MIPs)are promising candidates for the construction of elastomeric materials with desirable mechanical performance on account of their abilities to undergo inherent rotational and translational mechanical movements at the molecular ***,the investigations on their mechanical properties are lagging far behind their structural fabrication,especially for linear polyrotaxanes in ***,we report stretchable poly[2.rotaxane elastomers(PREs)which integrate numerous mechanical bonds in the polymeric backbone to boost macroscopic mechanical ***,we have synthesized a hydroxyfunctionalized[2.rotaxane that subsequently participates in the condensation polymerization with diisocyanate to form *** from the peculiar structural and dynamic characteristics of the poly[2.rotaxane,the representative PRE exhibits favorable mechanical performance in terms of stretchability(∼12.0%),Young’s modulus(2..6 MPa),and toughness(49.5 MJ/m^(3)).Moreover,we present our poly[2.rotaxanes as model systems to understand the relationship between mechanical bonds and macroscopic mechanical *** is concluded that the mechanical properties of our PREs are mainly determined by the unique topological architectures which possess a consecutive energy dissipation pathway including the dissociation of host−guest interaction and consequential sliding motion of the wheel along the axle in the[2.rotaxane motif.

关键词： Polyrotaxanes Mechanically interlocked polymers Mechanically interlocked molecules Dynamic materials Elastomers

Quantitative studies of hydrocarbon loss of the Silurian bitumen sandstone in the Tarim Basin

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Science china Earth Sciences 2008年第S2期51卷 101-107页

作者： JIANG ZhenXue1,2.PANG XiongQi1,2.LIU LuoFu1,2.wang XianDong3,zhang Jun4 & LI HongYi1,2.1 Basin and Reservoir {2. Center,china University of Petroleum,beijing 102.49,china 2.State Key Laboratory of Petroleum Resource and Prospecting,china University of Petroleum,beijing 102.49,china 3 {2. institute of exploration and Development,Daqing Oilfield Company Ltd,Daqing 163712.china 4 Petroleum exploration and Production institute of sinopec,beijing 100083,china Basin and Reservoir research Center China University of Petroleum Beijing China State Key Laboratory of Petroleum Resource and Prospecting China University of Petroleum Beijing China research institute of {2. and Development Daqing Oilfield Company Ltd Daqing China Petroleum exploration and Production institute of {2. Beijing China

The evolution of Tarim Basin experienced several tectonic movements,of which Caledonian movement caused a serious damage to reservoirs of Silurian. The earlier reservoirs size and the later hydrocarbon loss are two key factors to exploration prospect of Silurian. On the basis of net thickness of bituminous sandstone and recovery coefficient of crude oil converting to bitumen,the scale of the hydrocarbon loss of palaeo-accumulation in bitumen sandstone of Silurian was calculated (86.30×108t). The deter-mination of net thickness of bitumen sandstone was completed mainly by several methods,such as physical property demarcation,observing lithology,grains with oil inclusion (GOI) technology,and quantitative grains fluorescence (QGF) technology. The samples of black sandstone and white sand-stone were collected and compared by means of the methods mentioned above. The results showed that there was little hydrocarbon,or none,in the white sandstone. The recovery coefficient was ob-tained by the analyses of plentiful physical parameters of crude oil and bitumen sandstone,based on the hypothesis that nonhydrocarbon compounds and bitumen were invariable in the process of bitu-men forming. The calculated result,which is more scientific and actual,indicates the exploration pros-pect is more promising in Silurian of the Tarim Basin.

关键词： Tarim Basin Silurian bitumen sandstone hydrocarbon loss quantitative research recovery coefficient

Study on Preparation and Application of Ti/Si Complex Zeolite

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china Petroleum Processing & Petrochemical Technology 2003年第3期5卷 49-52页

作者： zhang Baoji wang Xieqing({2. research institute of Petroleum Processing, beijing 100083) sinopec Res. Inst. of Petroleum Processing Beijing 100083 China

A Ti/Si complex zeolite has been prepared. X-ray diffraction and infrared spectrometry study has shown that two structures, namely the ZSM-5 and MCM-41, exist in the sample. BET tests have revealed that the complex zeolite contains regular mesopores of 2.6 nm. Ultraviolet spectrometry analysis has shown that the Ti species exist in the zeolite skeleton in the form of tetra-coordinate valence. The Ti/Si complex zeolite (TS-1/Ti-MCM-41) has apparently improved catalytic activity with respect to the macromolecular organic compound oxidation as compared to individual components of either Ti or Si containing zeolites (TS- 1 and Ti-MCM-41).

关键词： Ti/Si zeolite complex macromolecular organic compound catalysis oxidation

A deep learning framework for suppressing prestack seismic random noise without noise-free labels

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Energy Geoscience 2024年第3期5卷 261-274页

作者： Han wang Jie zhang Petroleum exploration and Production research {2. SINOPECBeijing100083China Geophysical research institute School of Earth and Space SciencesUniversity of Science and Technology of ChinaHefeiAnhui230026China

Random noise attenuation is significant in seismic data *** deep learning-based denoising methods have been widely developed and applied in recent *** practice,it is often time-consuming and laborious to obtain noise-free data for supervised ***,we propose a novel deep learning framework to denoise prestack seismic data without clean labels,which trains a high-resolution residual neural network(SRResnet)with noisy data for input and the same valid data with different noise for *** valid signals in noisy sample pairs are spatially correlated and random noise is spatially independent and unpredictable,the model can learn the features of valid data while suppressing random *** data targets are generated by a simple conventional method without fine-tuning *** initial estimates allow signal or noise leakage as the network does not require clean *** Monte Carlo strategy is applied to select training patches for increasing valid patches and expanding training *** learning is used to improve the generalization of real data *** synthetic and real data tests perform better than the commonly used state-of-the-art denoising methods.

关键词： Data processing Denoising Signal processing Seismics Deep learning

Elucidation of the last steps of photo-ammonification:analytical method development and mechanism elucidation

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Frontiers of Environmental Science & Engineering 2024年第8期18卷 101-106页

作者： Yingjing Miao Hui wang Chunpeng Yang Ruochun zhang Hao zhang Peizhe Sun School of Environmental Science and Engineering Tianjin UniversityTianjin 300072China sinopec research {2. of Petroleum Processing Co. Ltd.Beijing 100083China School of Earth System Science Tianjin UniversityTianjin 300072China

The mechanisms underlying the photo-ammonification of nitrogenous organic compounds(NOCs)remain unclear,partly due to the analytical challenges of small NOC *** study introduced a simple methodology for accurately and simultaneously quantifying multiple small NOCs during ammonification *** developed method employed phenyl isothiocyanate as derivatization reagents,followed by high-performance liquid chromatography analysis to measure primary and secondary amines,amides,as well as NH4+over variable photo-ammonification *** our experimental setup,vacuum ultraviolet(VUV)irradiation serves as the controlled reaction environment to simulate harsh photo-ammonification *** NOCs,including pyridine,N,N-dimethylformamide,and acrylonitrile,were chosen due to their structural diversity and environmental relevance as model *** method was able to achieve excellent nitrogen mass balance,and revealed that the last steps of photo-ammonification involved oxidation of nitrogen-adjacent carbon to amide followed by the cleavage of N-C *** novel method may also help quantitative investigation of nitrogen transformations in different environmental contexts.

关键词： Ammonification NOCs Amines Nitrogen mass balance

A NEW CALCULATION METHOD FOR GAS-WELL LIQUID LOADING CAPACITY

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Journal of Hydrodynamics 2010年第6期22卷 823-828页

作者： wang Yi-wei zhang Shi-cheng YAN Jin CHEN Wen-bin Ministry of Education Key Laboratory of Petroleum Engineering China University of Petroleum Beijing 102249 Petroleum exploration and Production research {2. S1NOPEC Beijing 100083 China Sinochem Petroleum Exploitation and Production Co. Ltd Beijing 100031 china

This article proposes a new model for calculating the gas-well liquid loading capacity, which is critical to an accurate prediction of gas well production. Based on analysis of flow regime during the gas well production with water, which is regarded as many single particles in the model, with the shape of particles being assumed as disk-like ellipsoid instead of traditional sphere and changing according to the forces exerted on them, the influences of non-Darcy flow, compressibility, and non-sphere shape on friction factor are analyzed. The differences between the new model and other models are discussed and a new formula for calculating the critical flow rate is obtained. The calculation results and a comparison with other two models show that the new model is more consistent with the actual situation and is practical.

关键词： gas well accumulated liquid drag factor critical flow rate

Experimental study of the influencing factors and mechanisms of the pressure-reduction and augmented injection effect by nanoparticles in ultra-low permeability reservoirs

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Petroleum Science 2024年第3期21卷 1915-1927页

作者： Pan wang Yu-Hang Hu Liao-Yuan zhang Yong Meng Zhen-Fu Ma Tian-Ru wang Zi-Lin zhang Ji-Chao Fang Xiao-Qiang Liu Qing You Yan zhang beijing Key Laboratory of Unconventional Natural Gas Geological Evaluation and Development Engineering China University of Geosciences(Beijing)Beijing100083China School of Energy Resources China University of Geosciences(Beijing)Beijing100083China Petroleum Engineering Technology research institute Sinopec Shengli Oilfield CompanyDongying257000ShandongChina Hekou Oil Production Plant Sinopec Shengli Oilfield CompanyDongying257200ShandongChina Petroleum exploration and Production research {2. SINOPECBeijing102206China CNPC Engineering Technology R&D Company Limited Beijing102206China

Nanoparticles(NPs)have gained significant attention as a functional material due to their ability to effectively enhance pressure reduction in injection processes in ultra-low permeability *** are typically studied in controlled laboratory conditions,and their behavior in real-world,complex environments such as ultra-low permeability reservoirs,is not well understood due to the limited scope of their *** study investigates the efficacy and underlying mechanisms of NPs in decreasing injection pressure under various injection conditions(2.—85℃,10—2. MPa).The results reveal that under optimal injection conditions,NPs effectively reduce injection pressure by a maximum of 2..77%in core *** pressure reduction rate is found to be positively correlated with oil saturation and permeability,and negatively correlated with temperature and ***,particle image velocimetry(PIV)experiments(2.℃,atmospheric pressure)indicate that the pressure reduction is achieved by NPs through the reduction of wall shear resistance and wettability *** work has important implications for the design of water injection strategies in ultra-low permeability reservoirs.

关键词： Nanoparticle Pressure reduction Augmented injection Ultra-low permeability reservoir

Remaining oil distribution characteristics in an oil reservoir with ultra-high water-cut

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Energy Geoscience 2024年第1期5卷 219-223页

作者： Hongmin Yu Youqi wang Li zhang Qingxin zhang Zhenhai Guo Benzhe wang Tao Sun sinopec Petroleum exploration and Development {2. institute Beijing100083China Shengli Oil Production Plant SINOPEC Shengli Oilfield BranchDongyingShandong257051China

An accurate mapping and understanding of remaining oil distribution is very important for water control and stabilize oil production of mature oilfields in ultra-high water-cut ***,the Tuo-2. Fault Block of the Shengtuo Oilfield has entered the stage of ultra-high water cut(97.2.).Poor adaptability of the well pattern,ineffective water injection cycle and low efficiency of engineering measures(such as workover,re-perforation and utilization of high-capacity pumps)are the significant problems in the ultra-high water-cut *** order to accurately describe the oil and water flow characteristics,relative permeability curves at high water injection multiple(injected pore volume)and a semiquantitative method is applied to perform fine reservoir simulation of the Sand group 3e7 in the *** accurate reservoir model is built and history matching is *** distribution characteristics of remaining oil in lateral and vertical directions are quantitatively simulated and *** results show that the numerical simulation considering relative permeability at high injection multiple can reflect truly the remaining oil distribution characteristics after water flooding in an ultrahigh water-cut *** distribution of remaining oil saturation can be mapped more accurately and quantitatively by using the‘four-points and five-types’classification method,providing a basis for potential tapping of various remaining oil types of oil reservoirs in late-stage of development with high water-cut.

关键词： Ultra-high water-cut High water injection multiple Four-points and five-types Numerical simulation Remaining oil distribution

Deformation characteristics and analog modeling of transtensional structures in the Dongying Sag,Bohai Bay Basin

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Frontiers of Earth Science 2024年第1期18卷 227-241页

作者： Dawei DONG Li ZHAO Weizhong zhang Jiyan LI Ruixiang zhang Jianlei YANG Guangzeng {2. Shandong institute of Petroleum and Chemical Technology Dongying 257061China College of Resources and Environment Shandong Agriculture UniversityTai᾽an 271018China Geophysical research institute of Shengli Oilfield Branch Company SINOPECDongying 257022China research institute of Petroleum {2.&Development Shengli Oilfield CompanySINOPECDongying 257000China College of Marine Geosciences Ocean University of ChinaQingdao 266100China

Hydrocarbon exploration in the Dongying Sag is constrained by the development of many Cenozoic transtensional structures with complex patterns and dynamic *** study uses seismic interpretation and analog modeling to investigate these transtensional *** results include dividing these transtensional structures into boundary fault,oblique rifting,and deep strike-slip fault controlled structures,according to the relationships between main and secondary *** developed in the steep slope zone,the central sag zone,and the slope zone,*** profile,the transtensional structures formed appear to be semi-flower-like,step-like,or *** plan-view,they appear to be broom-like,soft-linked,or en-echelon ***,these transtensional structures are controlled by the oblique normal slip of boundary faults,by the oblique extension of sub-sags,and by the later extension of deep strike-slip *** geometric deformation of these transtensional structures is controlled by the angles between the regional extension direction and the strike of boundary faults,deep faults,or sub-sags,where a larger angle corresponds to less developed transtensional ***,the transtensional structures in the Dongying Sag were created by multi-phase and multi-directional extensions in the Cenozoic—which is also controlled by pre-existing *** strike of newborn secondary faults was determined by the regional extension direction and pre-existing structures.

关键词： transtensional structure seismic interpretation analogue modeling dynamic mechanism Dongying Sag