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Journal of Environmental Sciences 2002年第2期14卷 204-209页

作者： LI Xiao ming zeng guang-ming CHEN Jian LUN Shi yi Department of Environmental Science and Engineering Hunan UniversityChangsha 410082China School of Biotechnology Wuxi University of Light IndustryWuxi 214036China

The seed sludge originated from a methane fermentation reactor was enriched and acclimated with TA as sole carbon source under nitrate respiration mode first for 6 week, and then can be turned to methane fermentation conditions. After 6 weeks processing, the specific rate of TA degradation under nitrate respiration mode reached 23.8 mgTA/(L·gVSS), more than two times of that under methane fermentation mode 11.4 mg TA/(L·gVSS). The TA reductive cleavers' population density increased about 6 times and 20 times after 30 days and 90 days acclimation. After a total of 90 days for the enrichment and acclimation, the fermentative bacteria which originally existed in the seed sludge nearly disappeared, and instead of them, the TA reductive and cleaving bacteria group was formed in the new consortia, which was confirmed by the MPN counts and roll tube counts. Compared with the control experiment, the acclimation period can be shortened by about 50%.

关键词： acclimation anaerobic sludge enrichment nitrate terephthalic acid (TA)

A novel biosorbent: characterization of the spent mushroom compost and its application for removal of heavy metals

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Journal of Environmental Sciences 2005年第5期17卷 756-760页

作者： CHEN Gui-qiu zeng guang-ming TU Xiang HUANG Guo-he CHEN Yao-ning Department of Environmental Science and Engineering Hunan University Changsha 410082 China

The spent mushroom compost of Lentinus edodes was used as a biosorbent for adsorbing cadmium, lead and chromium from solutions under batch conditions for the first time. Titration of the biomass revealed that it contained at least three types of functional groups. The Fourier transform infrared spectrometry showed that the carboxyl, phosphoryl, phenolic groups were the main groups. The simulated values of pK, and molar quantity were 5.00 and 0.44 mmol/g, 7.32 and 1.38 mmol/g, 10.45 and 1.44 mmol/g, respectively. The biosorption ability increased with pH in acid condition. When 10 mg/L biomass dosage was added in, there was no significant increment of metal uptake. The maximum uptake estimated with the Langmiur isotherm model were 833.33 mg/g for Cd（ Ⅱ ）, 1000.00 mg/g for Pb（ Ⅱ ） and 44.44 mg/g for Cr（ Ⅲ ）, respectively. All the results showed that vast potential sorption capacity was existed in the biomass for adsorbing these three kinds of metals studied.

关键词： spent mushroom compost characterization biosorptlon heavy metals

Prediction of the amount of urban waste solids by applying a gray theoretical model

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Journal of Environmental Sciences 2003年第1期15卷 43-46页

作者： LI Xiao ming, zeng guang ming, WANG ming, LIU Jin jin (Department of Environmental Science and Technology, Hunan University, Changsha 410082, China. Department of Environmental Science and Technology Hunan University Changsha 410082 China

Urban waste solids are now becoming one of the most crucial environmental problems. There are several different kinds of technologies normally used for waste solids disposal, among which landfill is more favorable in China than others, especially for urban waste solids. Most of the design works up to now are based on a roughly estimation of the amount of urban waste solids without any theoretical support, which lead to a series problems. To meet the basic information requirements for the design work, the amount of the urban waste solids was predicted in this research by applying the gray theoretical model GM (1,1) through non linear differential equation simulation. The model parameters were estimated with the least square method (LSM) by running a certain MATALAB program, and the hypothesis test results show that the residual between the prediction value and the actual value approximately comply with the normal distribution N (0,0 21 2), and the probability of the residual within the range (-0 17, 0 19) is more than 95%, which indicate obviously that the model can be well used for the prediction of the amount of waste solids and those had been already testified by the latest two years data about the urban waste solids from Loudi City of China. With this model, the predicted amount of the waste solids produced in Loudi City in the next 30 years is 8049000 ton in total.

关键词： gray theoretical model prediction waste solids

Application of Bayesian regularized BP neural network model for analysis of aquatic ecological data—A case study of chlorophyll-a prediction in Nanzui water area of Dongting Lake

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Journal of Environmental Sciences 2005年第6期17卷 946-952页

作者： XU Min zeng guang-ming XU Xin-yi HUANG Guo-he SUN Wei JIANG Xiao-yun College of Environmental Science and Engineering Hunan University Changsha 410082 China Sino-Canadian Center of Energy and Environment Research University of Regina Regina SK S4S 0A2 Canada

Bayesian regularized BP neural network（BRBPNN） technique was applied in the chlorophyll-α prediction of Nanzui water area in Dongting Lake. Through BP network interpolation method, the input and output samples of the network were obtained. After the selection of input variables using stepwise/multiple linear regression method in SPSS i1.0 software, the BRBPNN model was established between chlorophyll-α and environmental parameters, biological parameters. The achieved optimal network structure was 3-11-1 with the correlation coefficients and the mean square errors for the training set and the test set as 0.999 and 0.000？8426, 0.981 and 0.0216 respectively. The sum of square weights between each input neuron and the hidden layer of optimal BRBPNN models of different structures indicated that the effect of individual input parameter on chlorophyll- α declined in the order of alga amount 〉 secchi disc depth（SD）〉 electrical conductivity （EC）. Additionally, it also demonstrated that the contributions of these three factors were the maximal for the change of chlorophyll-α concentration, total phosphorus（TP） and total nitrogen（TN） were the minimal. All the results showed that BRBPNN model was capable of automated regularization parameter selection and thus it may ensure the excellent generation ability and robustness. Thus, this study laid the foundation for the application of BRBPNN model in the analysis of aquatic ecological data（chlorophyll-α prediction） and the explanation about the effective eutrophication treatment measures for Nanzui water area in Dongting Lake.

关键词： Dongting Lake chlorophyll-a Bayesian regularized BP neural network model sum of square weights

Effect of pyrolysis temperature and hold time on the characteristic parameters of adsorbent derived from sewage sludge

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Journal of Environmental Sciences 2004年第4期16卷 683-686页

作者： ZHAI Yun-bo, WEI Xian-xun, zeng guang-ming (Department of Environmental Science and Engineering,Hunan University, Changsha 410082, China. Department of Environmental Science and Engineering Hunan University Changsha 410082

According to the Doehlert’s matrix method, the adsorbent derived from sewage sludge was prepared through chemical activation under controlling the pyrolysis temperature and hold time. The characteristic parameters including the total yield, adsorption of methylene blue, adsorption of iodine, BET surface area, micro-pore volume are 35%—49%, 16.5—38 mg/g, 285—362 mg/g, 185—359 m2/g, and 0.112—0.224 m3/g, respectively. According to the experimental data, the multi-linear regression method was adopted to fit the relations between the characteristic parameters and influential factors. At final, through optimization method, the optimal adsorbent is obtained when using 62 min as hold time and 1105K as pyrolysis temperature. Under the conditions, the adsorbent was produced and compared the characteristic parameters with model forecast value, the coherence is satisfied.

关键词： adsorbent sewage sludge pyrolysis temperature hold time Doehlert’s matrix

The Effects of Land Use and Landscape Position on Labile Organic Carbon and Carbon Management Index in Red Soil Hilly Region,Southern China

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Journal of Mountain Science 2015年第3期12卷 626-636页

作者： LI Zhong-wu NIE Xiao-dong CHEN Xiao-lin LU Yin-mei JIANG Wei-guo zeng guang-ming College of Environmental Science and Engineering Hunan University Key Laboratory of Environmental Biology and Pollution Control (Hunan University) Ministry of Education State Key Laboratory of Earth Surface Processes and Resource Ecology Beijing Normal University

Labile organic carbon （LOC） and carbon management index （CMI）, which are sensitive factors to the changes of environment, can improve evaluating the effect of land management practices changes on soil quality. The objective of this study was to investigate the effects of land use types and landscape positions on soil quality as a function of L0C and CMI. A field study in a small watershed in the red soil hilly region of southern China was conducted, and soil samples were collected from four typical lands （pine forest （PF） on slope land, barren hill （BH） on slope land, citrus orchard （C0） on terrace land and Cinnarnornum Camphora （CC） on terrace land） at a sampling depth of 20 cm. Soil nutrients, soil organic carbon （SOC）, L0C and CMI were measured. Results showed that the L0C and CMI correlated to not only soil carbon but also soil nutrients, and the values of LOC and CMI in different land use types followed the order CC 〉 PF 〉 CO 〉 BH at the upper- slope, while CO 〉 CC 〉 BH 〉 PF at mid-slope and down-slope. With respect to slope positions, the values of LOC and CMI in all the lands were followed the order： upper-slope 〉 down-slope 〉 mid- slope. As whole, the mean values of LOC and CMI in different lands followed the order CC 〉 CO 〉 PF 〉 BH. High CMI and LOC content were found in the terrace lands with broadleaf vegetations. These results indicated that the terracing and appropriate vegetations can increase the carbon input and lability and decrease soil erosion. However, the carbon pools and CMI in these lands were significantly lower than that in reference site. This suggested that it may require a long time for the soil to return to a high~ quality. Consequently, it is an efficient way to adopt the measures of terracing and appropriate vegetations planting in improving the content of LOC and CMI and controlling water and soil loss in fragile ecosystems.

关键词： Carbon pool index (CPI) Lability index(LI) Non-labile organic carbon (NLOC) Soil organiccarbon (SOC) Soil erosion

Environmental input-output model and its analysis with a focus on the solid waste management sectors

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Journal of Environmental Sciences 2000年第2期12卷 53-58页

作者： zeng, guang-ming Yuan, Xing-Zhong Zhang, Pan-Yue Guo, Huai-Cheng Huang, Gordon Guo-He Hemelaar, L. Environmental Protection Institute Hunan University Changsha 410082 China Environmental Science Center Peking University Beijing 100871 China Faculty of Engineering University of Regina Sask. S4S OA2 Canada Waste Nieuwehaven 201 2801 CW Netherlands

An environmental input output model (EIOM) was introduced to the regional solid waste management sectors, which can reflect the direct and indirect relations between the environment and the regional economy development. Some details about how to use the EIOM was discussed. The EIOM was applied to the Changsha City in China. The example results indicate that much useful information related to the environment and the regional economy development can be gained from the solution of the EIOM. Thus, the EIOM can be used as a useful tool for the sustainable development planning including the solid waste management sectors.

关键词： environmental input\|output model analysis of economy and environment solid waste management

Heavy Metal Accumulation in Plants on Mn Mine Tailings

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Pedosphere 2006年第1期16卷 131-136页

作者： LIU Yun-Guo ZHANG Hui-Zhi zeng guang-ming HUANG Bao-Rong LI Xin College of Environmental Science and Engineering Hunan University Changsha 410082 （China）. Institute of Soil Science Chinese Academy of Sciences Nanjing 210008 （China）

The Xiangtan Manganese (Mn) Mine in the middle of Hunan Province, China, has been mined since 1913 with mine tailings including excavated wastes, wastewater, and smelting wastes. A survey was conducted on the Mn mine tailing soils and eight plants on the Mn mine tailings. The concentrations of soil Mn, Pb, and Cd and the metal-enrichment traits of these eight plants were analyzed simultaneously. Exceptionally high concentrations of these three metals were found in the soils, especially on the tailing dam. Each plant investigated in this study accumulated the three heavy metals, but no hyperaccumulator of these metals was found. However, analysis indicated that Poa pratensis Linn., Gnaphalium affine D. Don, Pteris vittata L., Conyza canadensis (L.) Cronq., and Phytolacca acinosa Roxb. possessed specially good metal-enrichment and metal-tolerant traits. P. pratensis, G. affine, and P. vittata were Pb-tolerant plants; and C. canadensis, P. pratensis, and G. affine were Cd-tolerant plants. P. acinosa had a great tolerance to Mn. and it was a valuable plant for on-site phytoremediation. Phragmites communis Trin. was found to have high metal tolerance and economic benefit as a raw material for paper and should be considered for soil remediation. G. affine and C. canadensis had excessive accumulation of Mn and could be useful in phytoremediation. However, although P. pratensis was a good accumulator, it was not a suitable plant for soil remediation because its biomass was too little.

关键词： heavy metal metal-tolerant plant Mn mine tailings phytoremediation soil

Application of numerical simulation on optimum design of two-dimensional sedimentation tanks in the wastewater treatment plant

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Journal of Environmental Sciences 2003年第3期15卷 346-350页

作者： zeng guang-ming,ZHANG Shuo-fu, QIN Xiao-sheng, HUANG Guo-he, LI Jian-bing (Department of Environmental Science and Engineering of Hunan University, Changsha 410082, China.) Department of Environmental Science and Engineering of Hunan University Changsha 410082

The paper establishes the relationship between the settling efficiency and the sizes of the sedimentation tank through the process of numerical simulation, which is taken as one of the constraints to set up a simple optimum designing model of sedimentation tank. The feasibility and advantages of this model based on numerical calculation are verified through the application of practical case.

关键词： numerical simulation sedimentation tank optimum design

Redistribution of Pb, Zn and Cu Fractions in Tailing Soils Treated with Different Extractants

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Pedosphere 2006年第3期16卷 312-318页

作者： LIU Yun-Guo WANG Xian-Hai zeng guang-ming LI Xin ZHOU Chun-Hua FAN Ting LI Yong-Li YUAN Xin-Zhong Department of Environmental Science and Engineering Hunan University Changsha 410082 （China） Institute of Applied Ecology Chinese Academy of Sciences Shenyang 110016 （China） Graduate School of Chinese Academy of Sciences Beijing 100039 （China）

The efficiency of EDTA, HNO3 and CaCl2 as extractants to remove Pb, Zn and Cu from tailing soils without varying soil pH was investigated with distributions of Pb, Zn and Cu being determined before and after extraction using the sequential extraction procedure of the optimized European Community Bureau of Reference (BCR). Results indicated that EDTA and HNO3 were both effective extracting *** extractability of extractants for Pb and Zn was in the order EDTA > HNO3 > CaCl2, while for Cu it was HNO3 > EDTA > CaCl2. After EDTA extraction, the proportion of Pb, Zn and Cu in the four fractions varied greatly, which was related to the strong extraction and complexation ability. Before and after extraction with HNO3 and CaCl2, the percentages of Pb, Zn and Cu in the reducible, oxidizable and residual fractions changed little compared to the acid-extractable fraction. The lability of metal in the soil and the kinds of extractants were the factors controlling the effects of metal extraction.

关键词： BCR extraction fraction heavy metals redistribution