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Constitutive equation and model validation for a 31 vol.% B_4Cp/6061Al composite during hot compression

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Journal of Materials Science & Technology 2018年第10期34卷 1730-1738页

作者： L. zhou C. Cui q.z. Wang C. Li B.L. Xiao z.Y. Ma Institute of Metal Research Chinese Academy of Sciences Shenyang 110016 China School of Electromechanical and Vehicle Engineering Yantai University Yantai 264005 China School of Mechanical Engineering Shenyang Ligong University Shenyang 110159 China Nuclear and Radiation Safety Center Ministry of Environmental Protection Beijing 100082 China

An accurate constitutive equation is essential to understanding the flow behavior of B4C/A1 compos-ites during the hot deformation. However, the constitutive equations developed previously in literature are generally for low strain rate deformation. In the present work, we modified the general consti-tutive equation and take the high strain rate correction into account. The constitutive equation for a 31 vol.% B4Cp/6061AI composite was constructed based on the flow stresses measured during isothermal hot compression at temperatures ranging from 375 to 525 ℃ and strain rates from 0.01 to 10 s^-1. The experimental flow stresses were corrected by considering temperature-dependent Arrhenius factor. The modified equation was then verified by using DEFORM-3D finite element analysis to simulate the exper-imental hot compression process. The results show that the modified equation successfully predicts flow stress, load-displacement, and the temperature rise. This helps to optimize the hot deformation process, and to obtain desirable properties, such as reduced porosity and homogenous particle distribution in B4C/AI composites.

关键词： Composites B4C/AI Constitutive equation Hot compression Finite element simulation

Viscosity and structure relationship with equimolar substitution of CaO with MgO in the CaO–MgO–Al_(2)O_(3)–SiO_(2)slag melts

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 70-79页

作者： Yong Hou Shuo zhang Jie Dang Jia Guo Hanghang zhou Xuewei Lü College of Materials Science and Engineering Chongqing UniversityChongqing 400044China Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and New Materials Chongqing UniversityChongqing 400044China

Currently,the Al_(2)O_(3)content in the high-alumina slag systems within blast furnaces is generally limited to 16wt%–18.5wt%,making it challenging to overcome this *** most studies that concentrated on managing the MgO/Al_(2)O_(3)ratio or basicity,this paper explored the effect of equimolar substitution of MgO for CaO on the viscosity and structure of a high-alumina CaO-MgO-Al_(2)O_(3)-SiO_(2)slag system,providing theoretical guidance and data to facilitate the application of high-alumina *** results revealed that the viscosity first decreased and then increased with higher MgO substitution,reaching a minimum at 15mol%MgO *** transform infrared spectroscopy(FTIR)results found that the depths of the troughs representing[SiO_(4)]tetrahedra,[AlO_(4)]tetrahedra,and Si-O-Al bending became progressively deeper with increased MgO *** of the Raman spectra showed that the average number of bridging oxygens per Si atom and the X_(q^(3))/X_(q^(2))(X_(q^(i))is the molar fraction of q^(i) unit,and i is the number of bridging oxygens in a[SiO_(4)]tetrahedral unit)ratio increased from 2.30 and 1.02 to 2.52 and 2.14,respectively,indicating a progressive polymerization of the silicate structure.X-ray photoelectron spectroscopy(XPS)results highlighted that non-bridging oxygen content decreased from 77.97mol% to 63.41mol% with increasing MgO concentration,whereas bridging oxygen and free oxygen contents *** analysis demonstrated a gradual increase in the polymerization degree of the tetrahedral structure with the increase in MgO ***,bond strength is another important factor affecting the slag *** occurrence of a viscosity minimum can be attributed to the complex evolution of bond strengths of non-bridging oxygens generated during depolymerization of the[SiO_(4)]and[AlO_(4)]tetrahedral structures by CaO and MgO.

关键词： aluminosilicate viscosity structure spectroscopy

Bioinspired Passive Tactile Sensors Enabled by Reversible Polarization of Conjugated Polymers

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Nano-Micro Letters 2025年第1期17卷 361-377页

作者： Feng He Sitong Chen Ruili zhou Hanyu Diao Yangyang Han Xiaodong Wu School of Mechanical Engineering Sichuan UniversityChengdu 610065People’s Republic of China School of Software Engineering Chongqing University of Posts and TelecommunicationsChongqing 400065People’s Republic of China State Key Laboratory of Polymer Materials Engineering Sichuan UniversityChengdu 610065People’s Republic of China

Tactile perception plays a vital role for the human body and is also highly desired for smart prosthesis and advanced *** to active sensing devices,passive piezoelectric and triboelectric tactile sensors consume less power,but lack the capability to resolve static ***,we address this issue by utilizing the unique polarization chemistry of conjugated polymers for the first time and propose a new type of bioinspired,passive,and bio-friendly tactile sensors for resolving both static and dynamic ***,to emulate the polarization process of natural sensory cells,conjugated polymers(including poly(3,4-ethylenedioxythiophen e):poly(styrenesulfonate),polyaniline,or polypyrrole)are controllably polarized into two opposite states to create artificial potential *** controllable and reversible polarization process of the conjugated polymers is fully in situ ***,a micro-structured ionic electrolyte is employed to imitate the natural ion channels and to encode external touch stimulations into the variation in potential difference *** with the currently existing tactile sensing devices,the developed tactile sensors feature distinct characteristics including fully organic composition,high sensitivity(up to 773 mV N^(−1)),ultralow power consumption(nW),as well as superior *** demonstrations,both single point tactile perception(surface texture perception and material property perception)and two-dimensional tactile recognitions(shape or profile perception)with high accuracy are successfully realized using self-defined machine learning *** tactile sensing concept innovation based on the polarization chemistry of conjugated polymers opens up a new path to create robotic tactile sensors and prosthetic electronic skins.

关键词： Passive tactile sensors Reversible polarization of conjugated polymers Tactile perception Machine learning algorithm Object recognition

Finite Element Prediction of the Thermal Conductivity of GNP/Al Composites

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Acta Metallurgica Sinica(English Letters) 2022年第5期35卷 825-838页

作者： X.S.Yang L.zhou K.Y.Liu z.Y.Liu q.z.Wang B.L.Xiao z.Y.Ma School of Electromechanical and Automotive Engineering Yantai UniversityYantai264005China Shi-Changxu Innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang110016China

A 3 D multi-scale finite element model was developed to predict the effective thermal conductivity of graphene nanoplatelet(GNP)/Al *** factors influencing the effective thermal conductivity of the GNP/Al composites were investigated,including the orientation,shape,aspect ratio,configuration and volume fraction of *** results show that GNPs shape has a little influence on the thermal conductivity of GNP/Al composites,and composites with elliptic GNPs have the highest thermal *** addition,with increasing the aspect ratio of GNPs,the thermal conductivity of GNP/Al composites increases and finally tends to be *** GNPs configuration strongly influences the thermal conductivity of GNP/Al composites,and the thermal conductivity of the composites with layered GNPs is the highest among the five *** effective thermal conductivity is sensitive to volume fraction of ***,when the volume fraction of layered GNPs reaches 1.54%,the thermal conductivity of GNP/Al composites is as high as 400 W/m *** findings of this study could provide a good theoretical basis for designing high thermal conductivity GNP/Al composites.

关键词： Multi-scale finite element model Thermal conductivity GNP/Al composites Shape Aspect ratio Configuration

Recent development of chemically complex metallic glasses: from accelerated compositional design, additive manufacturing to novel applications

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Materials Futures 2022年第1期1卷 9-31页

作者： J Y zhang z.q.zhou z B zhang M H Park q Yu z Li J Ma A D Wang H G Huang M Song B S Guo q Wang Y Yang Department of Mechanical Engineering College of EngineeringCity University of Hong KongKowloon TongKowloonHong KongPeople’s Republic of China Shenzhen Key Laboratory of High Performance Nontraditional Manufacturing College of Mechatronics and Control EngineeringShenzhen UniversityShenzhenGuangdong 518060People’s Republic of China School of Materials Science and Engineering Dongguan University of TechnologyDongguanGuangdong 523808People’s Republic of China Institute of Materials China Academy of Engineering PhysicsJiangyouSichuan 621907People’s Republic of China State Key Laboratory of Powder Metallurgy Central South UniversityChangshaHunan 410083People’s Republic of China Institute of Advanced Wear&Corrosion Resistant and Functional Materials Jinan UniversityGuangzhouGuangdong 510632People’s Republic of China Institute of Materials Laboratory for MicrostructuresShanghai UniversityShanghai 200444People’s Republic of China Department of Materials Science and Engineering College of EngineeringCity University of Hong KongKowloon TongKowloonHong KongPeople’s Republic of China Department of Advanced Design and System Engineering College of EngineeringCity University of Hong KongKowloon TongKowloonHong KongPeople’s Republic of China

Metallic glasses(MGs)or amorphous alloys are an important engineering material that has a history of research of about 80–90 *** different fast cooling methods were developed for multi-component MGs between 1960s and 1980s,1990s witnessed a surge of research interest in the development of bulk metallic glasses(BGMs).Since then,one central theme of research in the metallic-glass community has been compositional design that aims to search for MGs with a better glass forming ability,a larger size and/or more interesting properties,which can hence meet the demands from more important *** this review article,we focus on the recent development of chemically complex MGs,such as high entropy MGs,with new tools that were not available or mature yet until recently,such as the state-of-the-art additive manufacturing technologies,high throughput materials design techniques and the methods for big data analyses(*** learning and artificial intelligence).We also discuss the recent use of MGs in a variety of novel and important applications,from personal healthcare,electric energy transfer to nuclear energy that plays a pivotal role in the battle against global warming.

关键词： metallic glasses amorphous alloys alloy design additive manufacturing machine learning high throughput materials design

STUDY ON THE MECHANISM OF GRAPHITIzATION IN MOLTEN CAST IRON PROMOTED BY ELECTROPULSE DISCHARGE

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Acta Metallurgica Sinica(English Letters) 2004年第6期17卷 790-794页

作者： G.W.Chang J.S.Wang J.z.Wang q.G.Xue O.q.zhou D.q.Cang Dept.Materials＆ChemicalEng. LiaoningInstituteofTechnologyJinzhou121001China SchoolofMetallurgy BeijingUniversityofScience＆Technology.Beijing100083China

From the points of both molten cast iron structure and the appearing ratio of electrons in outer-layer of different atoms, analysis on enhancement mechanism of graphitization ability after processing of the iron by pulse electric discharge has been made, and the theory has been proofed by corresponding experiments. The results show that when the molten cast iron is being processed by pulse electric discharge, both the size of crystal embryos that composed by Fe and C atoms as well as the number of clusters can be reduced, even be separated by such discharging; consequently results in the segre- gation of C atoms in the molten cast iron near the cathode of discharging. The nucleation of graphite in these areas of the iron has been promoted at the discharging temperature; even though such degree has not been reached, the most favorable nucleation conditions of graphite can be at least created. Under the preconditions of not breaking up the graphite crystal embryos, with proper adjustment of discharging frequency, the stronger of the electric field and the longer of the pulsation treatment time are, the more graphitization ability of the molten cast iron is. The theoretical analysis on the above rules consists well with experimental results.

关键词： pulsed electric field molten iron-solution graphitization

RELATIONSHIP AMONG EVAPORATION FLUX OF GROUNDWATER, DEPTH OF WATER TABLE AND NEGATIVE PRESSURE HEAD IN BARE SOIL

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Journal of Hydrodynamics 2000年第4期12卷 52-58页

作者： qian, J.z. zhu, X.Y. zhou, N.q. Li, G.Y. Dep. of Earth Sci. Nanjing Univ. Nanjing 210093 China

Evaporation of ground water is a part of moisture circulation in the field. And it is a main natural form in which water transmits from the ground water to the soil water and atmosphere water. According to the simulated experiments, we study the relationship among the evaporation, depth of groundwater table and negative pressure. By theoretical analysis of the experimental results, the main conclusions are drawn as follows. There are two abrupt points in every q-H curve. The locations of the abrupt points are separately in step with the height of top of the capillary fringe and the height of maximal capillary rise in the soil section. When the depth of water table H is small, the evaporation flux of ground water is large. While the depth of water table exceeds the maximal capillary rise of media in vadose zone, the capillary rise breaks up and evaporation flux of groundwater is small. The water content ratio in ground surface tends to be zero and the surface of soil tends to be drought. These conclusions show that the maximal capillary rise of media in vadose zone is an important value in regulating rational depth of ground water to reduce the evaporation of ground water and to increase effective quantity of water resources. In the meantime, these conclusions are of important theoretical and practical significance to reduce the evaporation of ground water, to prevent and cure the salinization of soil, and to make full use of and protect water resources in the northern plains in China.

关键词： Capillarity Evaporation Soils

STABILITY OF MICROSTRUCTURES DURING COOLING PROCESSES OF Al LIqUID METAL

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中国有色金属学会会刊：英文版 1998年第4期8卷 2-7页

作者： Liu, RS Li, JY zhou, z Dong, KJ Peng, P Xie, q zheng, CX Hunan Univ Dept Phys Changsha 410012 Peoples R China Hunan Univ Dept Chem Changsha 410012 Peoples R China

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关键词： stability microstructure liquid metal rapid cooling computer simulation

One-dimensional non-Darcy flow in a semi-infinite porous media:a multiphase implicit Stefan problem with phases divided by hydraulic gradients

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Acta Mechanica Sinica 2017年第5期33卷 855-867页

作者： G.q.zhou Y.zhou X.Y.Shi State Key Laboratory for Geomechanics and Deep Underground Engineering China University of Mining and Technology School of Mechanics and Civil Engineering China University of Mining and Technology JiangSu Collaborative Innovation Center for Building Energy Saving and Construct Technology

One-dimensional non-Darcy flow in a semi-infinite porous media is investigated. We indicate that the non-Darcy relation which is usually determined from experimental results can always be described by a piecewise linear function, and the problem can be equivalently transformed to a multiphase implicit Stefan problem. The novel feature of this Stefan problem is that the phases of the porous media are divided by hydraulic gradients, not the excess pore water pressures. Using the similarity transformation technique, an exact solution for the situation that the external load increases in proportion to the square root of time is developed. The study on the existence and uniqueness of the solution leads to the requirement of a group of inequalities. A similar Stefan problem considering constant surface seepage velocity is also investigated, and the solution, which we indicate to be uniquely existent under all conditions, is established. Meanwhile, the relation between our Stefan problem and the traditional multiphase Stefan problem is demonstrated. In the end, computational examples of the solution are presented and discussed. The solution provides a useful benchmark for verifying the accuracy of general approximate algorithms of Stefan problems, and it is also attractive in the context of inverse problem analysis.

关键词： Moving boundary problem Stefan problem Analytical solution Non-Darcy flow Soil consolidation