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Improving high-temperature mechanical properties of cast CrFeCoNi high-entropy alloy by highly thermostable in-situ precipitated carbides

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Journal of Materials Science & technology 2021年第13期72卷 29-38页

作者： X.W.Liu N.Gao J.zheng Y.Wu Y.Y.zhao Q.Chen W.zhou S.z.Pu W.M.Jiang z.t.fan State Key Laboratory of Materials Processing and Die&Mould technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan430074China Institute of Nuclear Physics and Chemistry China Academy of Engineering PhysicsMianyang 621999China State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing 100083China School of Materials Engineering Purdue UniversityWest LafayetteIN 47907USA Southwest technology and Engineering Research Institute Chongqing 400039China Center for Electron Microscopy Wuhan UniversityWuhan 430072China

the Cr Fe Co Ni high-entropy alloy(HEA)exhibits excellent mechanical properties at lower temperatures due to its low stacking-fault energy,however,its medium-and high-temperature strengths are still insufficient.In consideration of the potential diversified applications,more strengthening approaches except for the previously proposed L12 phase hardening deserve further exploration due to its rapid coarsening tendency at high temperatures.Here,we achieved significant high-temperature strengthening of the cast Cr Fe Co Ni HEA by in-situ precipitation of highly thermostable carbides.Alloys with 0.5 at.%and 1 at.%niobium and carbon were prepared by simple casting processes,i.***.drop cast,solute solution and aging.A highly thermostable microstructure was formed,which comprises very coarse grains accompanied with extensive thermostable carbide precipitates embedded,including submicrometer coherent Nb C particles in grain interiors and intergranular coherent M_(23)C_(6)carbides.this high thermostability of microstructure,which is beneficial for the high-temperature loading,is ascribed to the synergy of lacking growth driving force and zenner pinning effect by the carbides.tensile properties tested at 673,873 and1073 K show that the yield strength and ultimate tensile strength are significantly increased by Nb/C doping,along with the elongation escalation at higher temperatures.the strengthening is mainly due to the precipitation hardening of carbide particles.

关键词： High-entropy alloy Carbides Precipitation High-temperature property Strengthening

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tailoring grain growth and solid solution strengthening of single-phase CrCoNi medium-entropy alloys by solute selection

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Journal of Materials Science & technology 2020年第19期54卷 196-205页

作者： G.W.Hu L.C.zeng H.Du X.W.Liu Y.Wu P.Gong z.t.fan Q.Hu E.P.George Key Laboratory of Metallurgical Equipment and Control technology Ministry of EducationWuhan University of Science and TechnologyWuhan 430081China Hubei Key Laboratory of Mechanical transmission and Manufacturing Engineering Wuhan University of Science and TechnologyWuhan 430081China State Key Laboratory of Materials Processing and Die&Mould technology Huazhong University of Science and TechnologyWuhan 430074China State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing 100083China Institute of Applied Physics Jiangxi Academy of SciencesNanchang 330029China Oak Ridge National Laboratory Materials Science and Technology DivisionOak RidgeTN37831USA Department of Materials Science and Engineering University of TennesseeKnoxvilleTN37996USA

In the present study,we selected solutes to be added to the Cr Co Ni medium-entropy alloy(MEA)based on the mismatch of self-diffusion activation energy(SDQ)between the alloying elements and constituent elements of the matrix,and then investigated their grain growth behavior and mechanical properties.Mo and Al were selected as the solutes for investigation primarily because they have higher and lower SDQ,respectively,than those of the matrix elements;a secondary factor was their higher and lower shear modulus.their concentrations were fixed at 3 at.%each because previous work had shown these compositions to be single-phase solid solutions with the face-centered cubic structure.three alloys were produced by arc melting,casting,homogenizing,cold rolling and annealing at various temperatures and times to produce samples with different grain sizes.they were(a)the base alloy Cr Co Ni,(b)the base alloy plus 3 at.%Mo,and(c)the base alloy plus 3 at.%Al.the activation energies for grain growth of the Cr Co Ni,Cr Co Ni-3Mo and CrCo Ni-3Al MEAs were found to be^251,~368 and^219 k J/mol,respectively,consistent with the notion that elements with higher SDQ(in this study Mo)retard grain growth(likely by a solute-drag effect),whereas those with lower values(Al)accelerate grain growth.the roomtemperature tensile properties show that Mo increases the yield strength by^40%but Al addition has a smaller strengthening effect consistent with their relative shear moduli.the yield strength as a function of grain size for the three single-phase MEAs follows the classical Hall-Petch relationship with much higher slopes(>600 MPaμm-0.5)than traditional solid solutions.this work shows that the grain growth kinetics and solid solution strengthening of the Cr Co Ni MEA can be tuned by selecting solute elements that have appropriate diffusion and physical properties.

关键词： Medium and high entropy alloys Solute-drag effect Microstructure Grain growth kinetics Solid solution strengthening

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ADAM8 inactivation retards intervertebral disc degeneration in mice

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Genes & Diseases 2024年第3期11卷 91-94页

作者： zuozhen tian Frances S.Shofer Mingyue fan Alec z.Sandroni Lutian Yao Lin Han Ling Qin Motomi Enomoto-lwamoto Yejia zhang Department of Physical Medicine&Rehabilitation Perelman School of MedicineUniversity of PennsylvaniaPhiladelphiaPA19146USA Department of Emergency Medicine Perelman School of MedicineUniversity of PennsylvaniaPhiladelphiaPA 19104USA Department of Orthopedic Surgery Perelman School of MedicineUniversity of PennsylvaniaPhiladelphiaPA 19104USA School of Biomedical Engineering Science&Health SystemsDrexel UniversityPhiladelphiaPA 19104USA Department of Orthopedics/Sports Medicine and Joint Surgery the First Hospital of China Medical UniversityShenyangLiaoning 110001China Department of Orthopedics University of Maryland School ofMedicineBaltimoreMD21201USA Section of Rehabilitation Medicine Corporal Michael J.Crescenz Veterans Affairs Medical CenterPhiladelphiaPA 19104USA

ADAM8 has been identified as the fibronectin-cleaving enzyme in human degenerative intervertebral disc(IVD)tissues.^(1)Increase of the active form of ADAM8 and its cleavage product,fibronectin fragment,correlated with an increased degree of IVD degeneration.1 Furthermore,fibronectin fragments have been shown to accelerate the progression of IVD degeneration.^(2)these findings suggest that ADAM8 may play a role in degenerative disc disease,a clinical problem with tremendous socioeconomic burdens in the United States.

关键词： ADAM8 degeneration intervertebral

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Decoding human brain functions: Multi-modal, multi-scale insights

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the Innovation 2024年第1期5卷 17-18页

作者： Camilla t.Erichsen Deying Li Lingzhong fan Sino-Danish Center University of Chinese Academy of SciencesBeijing 100190China Brainnetome Center Institute of AutomationChinese Academy of SciencesBeijing 100190China Core Centre for Molecular Morphology Section for Stereology and MicroscopyDepartment of Clinical MedicineAarhus University8200 Aarhus NDenmark School of Health and Life Sciences University of Health and Rehabilitation SciencesQingdao 266000China

Unraveling the intricate relationship between the structure and function of the human brain remains a central and unresolved question in neuroscience.Ethical considerations impose significant constraints on invasive techniques in human neuroscience research.Consequently,knowledge about human brain function often relies on animal models to provide valuable discoveries and insights.However,caution is warranted,as findings from animal studies may not always be directly translatable to humans,especially when investigating higher cognitive functions.

关键词： functions insight modal

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traveling wave solutions of the nonlinear Gilson-Pickering equation in crystal lattice theory

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Journal of Ocean Engineering and Science 2024年第1期9卷 40-49页

作者： A.t.Nguyen O.Nikan z.Avazzadeh Division of Applied Mathematics Science and Technology Advanced InstituteVan Lang UniversityHo Chi Minh CityVietnam Faculty of technology Van Lang UniversityHo Chi Minh CityVietnam School of Mathematics Iran University of Science and TechnologyNarmakTehranIran Department of Applied Mathematics Xi’an Jiaotong-Liverpool UniversitySuzhou 215123China

this paper focuses on obtaining the traveling wave solutions of the nonlinear Gilson-Pickering equa-tion(GPE),which describes the prorogation of waves in crystal lattice theory and plasma physics.the solution of the GPE is approximated via the finite difference technique and the localized meshless radial basis function generated finite difference.the association of the technique results in a meshless approach that does not require linearizing the nonlinear terms.At the first step,the PDE is converted to a system of nonlinear ODEs with the help of the radial kernels.In the second step,a high-order ODE solver is adopted to discretize the nonlinear ODE system.the global collocation techniques pose a considerable computationl burden due to the calculation of the dense algebraic system.the proposed method approx-imates differential operators over the local support domain,leading to sparse differentiation matrices and decreasing the computational burden.Numerical results and comparisons are provided to confirm the efficiency and accuracy of the method.

关键词： Nonlinear Gilson–Pickering equation Soliton wave solutions Meshless technique RBF LRBF-FD Optimal shape parameter

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Soliton resolution and asymptotic stability of N-solutions for the defocusing Kundu–Eckhaus equation with nonzero boundary conditions

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Communications in theoretical Physics 2024年第1期76卷 1-6页

作者： Engui fan Yanxi zhang School of Mathematical Sciences and Key Laboratory of Mathematics for Nonlinear Science Fudan UniversityShanghai200433China tianjin Xinhua High School No.99 machang RoadTianjin300204China

In this paper,we address interesting soliton resolution,asymptotic stability of N-soliton solutions and the Painleve asymptotics for the Kundu-Eckhaus(KE)equation with nonzero boundary conditions iq_(t)+q_(xx)-2(l|q|^(2)-1)q+4β^(2)(lql^(4)-1)q+4iβ(lql^(2))_(x)q=0,q(x,0)=q_(0)(x)-±1,x→±∞.the key to proving these results is to establish the formulation of a Riemann-Hilbert(RH)problem associated with the above Cauchy problem and find its connection with the RH problem of the defocusing NLS equation.With the■-steepest descent method and the results of the defocusing NLS equation,we find complete leading order approximation formulas for the defocusing KE equation on the whole(x,t)half-plane including soliton resolution and asymptotic stability of N-soliton solutions in a solitonic region,zakharov-Shabat asymptotics in a solitonless region and the Painlevéasymptotics in two transition regions.

关键词： defocusing Kundu-Eckhaus equation Riemann-Hilbert problems steepest descent method soliton resolution asymptotic stability Painleve transcendents

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Spatiotemporal mapping of(ultra‐)mafic magmatic mine areas:Implications of economic and political realities in China

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Deep Underground Science and Engineering 2024年第1期3卷 91-102页

作者： Heling Li Liang tang tim t.Werner zhengmeng Hou fan Meng Jingjing Li College of Earth Sciences Chengdu University of TechnologyChengduChina Institute of Subsurface Energy Systems Clausthal University of TechnologyClausthal ZellerfeldGermany School of Geography Earth and Atmospheric SciencesFaculty of ScienceThe University of MelbourneMelbourneVictoriaAustralia

the spatiotemporal extension/expansion of mine areas is affected by multiple factors.So far,very little has been done to examine the interaction between mine areas and political or economic realities.the(ultra‐)mafic magmatic mines in China played a specific role in supporting national development and providing an ideal research subject for monitoring their interrelationship.In this study,remote sensing and mining‐related GIS data were used to identify and analyze 1233(ultra‐)mafic magmatic mine area polygons in China,which covered approximately 322.96 km2 of land and included a V–ti–Fe mine,a copper–nickel mine,a chromite mine,an asbestos mine,and a diamond mine.It was found that(1)the areal expansion of mines is significantly related to the mine types,perimeter,topography,and population density.(2)the mine area variation also reflects market and policy realities.the temporal expansion of the mine area from 2010 to 2020 followed an S‐shaped pattern(with the turning point occurring in 2014),closely related to iron overcapacity and tightened mining policies.(3)the complexity(D)of the mine area may reflect mine design and excavation practices.to be specific,lower D indicates early‐stage or artisanal/small‐scale mining,whereas higher D represents large‐scale mining.this study demonstrates that the detailed mapping of mine land can serve as an indicator to implement miningrelated market and policy changes.the(ultra‐)mafic mines area data set can be accessed at https://***/record/7636616#.Y-p0uXazOa0.

关键词： complexity mine area mining and socioeconomic interaction spatiotemporal distribution (ultra‐)mafic magmatic mine

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Construction of 2D/2D ti_(3)C_(2)t_(x)MXene/CdS heterojunction with photothermal effect for efficient photocatalytic hydrogen production

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Journal of Materials Science & technology 2024年第4期171卷 1-9页

作者： t.Y.Huang z.Yang S.Y.Yang z.H.Dai Y.J.Liu J.H.Liao G.Y.zhong z.J.Xie Y.P.fang S.S.zhang Key Laboratory for Biobased Materials and Energy of Ministry of Education Guangdong Laboratory for Lingnan Modern AgricultureCollege of Materials and EnergySouth China Agricultural UniversityGuangzhou 510643China School of Physics and Optoelectronics South China University of TechnologyGuangzhou 510640China School of Chemical Engineering and Energy technology Guangdong Provincial Key Laboratory of Distributed Energy SystemsDongguan University of TechnologyDongguan 523808China

the insensitivity of semiconductors to visible and infrared light is a key constraint on the utilization of light energy in photocatalytic reactions.Constructing photocatalysts with full-spectrum absorption through surface engineering is an effective approach to fully harnessing light energy in semiconductor materials.Herein,a novel stable ti_(3)C_(2)t_(x)MXene/CdS heterojunction catalyst is obtained by in-situ epitaxial growth of two-dimensional(2D)CdS nanosheets on 2D MXene interface via a solvothermal method.the exceptional light absorption properties of MXene confer outstanding full-spectrum driven photocat-alytic hydrogen evolution capability upon the heterogeneous catalyst.the unique 2D/2D structure effectively mitigated the recombination of photogenerated carriers,enhancing the photocatalytic performance of the catalyst.Moreover,the composite catalyst exhibits a significantly higher surface temperature of 80.4℃under visible light irradiation at an intensity of 0.1 W/cm^(2),which is 1.84 times higher than that of CdS.Under irradiation of visible and near infrared light,the composite catalyst with photothermal ef-fect demonstrates a remarkable hydrogen evolution rate of 65.4 mmol g^(-1)h^(-1),which is 7.2 times higher than that of CdS catalyst.this study introduces a novel approach for constructing full-spectrum absorption catalysts and expands the application of the photothermal effect in photocatalytic hydrogen evolution research.

关键词： two-dimensional structure Heterostructure Photothermal effect Photocatalyst Hydrogen evolution

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In vitro bench testing using patient-specific 3D models for percutaneous pulmonary valve implantation with Venus P-valve

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中华医学杂志(英文版) 2024年第8期137卷 990-996页

作者： Han Yu Shao zehua Sun zirui Han Yan Xu Hongdang Song Shubo Pan Xiangbin de Jaegere Peter P. t. fan taibing zhang Gejun Department of Cardiology Erasmus MC Rotterdam 3015 GD Netherlands Department of Structure Heart Disease Central China Fuwai Hospital of zhengzhou University zhengzhou Henan 451460 China Children’s Heart Center Department of Anesthesiology Fuwai Hospital Chinese Academy of Medical Sciences Beijing 100037

Background: Due to the wide variety of morphology, size, and dynamics, selecting an optimal valve size and location poses great difficulty in percutaneous pulmonary valve implantation (PPVI). this study aimed to report our experience within vitro bench testing using patient-specific three-dimensional (3D)-printed models for planning PPVI with the Venus P-valve.Methods: Patient-specific 3D soft models were generated using PolyJet printing with a compliant synthetic material in 15 patients scheduled to undergo PPVI between July 2018 and July 2020 in Central China Fuwai Hospital of zhengzhou University.Results: 3D model bench testing altered treatment strategy in all patients (100%). One patient was referred for surgery because testing revealed that even the largest Venus P-valve would not anchor properly. In the remaining 14 patients, valve size and/or implantation location was altered to avoid valve migration and/or compression coronary artery. In four patients, it was decided to change the point anchoring because of inverted cone-shaped right ventricular outflow tract (RVOt) (n = 2) or risk of compression coronary artery (n = 2). Concerning sizing, we found that an oversize of 2-5 mm suffices. Anchoring of the valve was dictated by the flaring of the in- and outflow portion in the pulmonary artery. PPVI was successful in all 14 patients (absence of valve migration, no coronary compression, and none-to-mild residual pulmonary regurgitation [PR]). the diameter of the Venus P-valve in the 3D simulation group was significantly smaller than that of the conventional planning group (36 [2]vs. 32 [4],z = -3.77,P tro testing indicated no need to oversize the Venus P-valve to the degree recommended by the balloon-sizing technique, as 2-5 mm sufficed.

关键词： Heart valve prosthesis implantation Percutaneous pulmonary valve intervention Pulmonary regurgitation In vitro bench testing 3D printing Venus P-valve

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Prediction of subsurface settlement induced by shield tunnelling in sandy cobble stratum

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第1期16卷 192-212页

作者： fan Wang Xiuli Du Pengfei Li Key Laboratory of Urban Security and Disaster Engineering Ministry of EducationBeijing University of TechnologyBeijing100124China

this study focuses on the analytical prediction of subsurface settlement induced by shield tunnelling in sandy cobble stratum considering the volumetric deformation modes of the soil above the tunnel crown.A series of numerical analyses is performed to examine the effects of cover depth ratio(C/D),tunnel volume loss rate(h t)and volumetric block proportion(VBP)on the characteristics of subsurface settle-ment trough and soil volume loss.Considering the ground loss variation with depth,three modes are deduced from the volumetric deformation responses of the soil above the tunnel crown.then,analytical solutions to predict subsurface settlement for each mode are presented using stochastic medium theory.the influences of C/D,h t and VBP on the key parameters(i.e.B and N)in the analytical expressions are discussed to determine the fitting formulae of B and N.Finally,the proposed analytical solutions are validated by the comparisons with the results of model test and numerical simulation.Results show that the fitting formulae provide a convenient and reliable way to evaluate the key parameters.Besides,the analytical solutions are reasonable and available in predicting the subsurface settlement induced by shield tunnelling in sandy cobble stratum.

关键词： Shield tunnelling Sandy cobble stratum Subsurface settlement Volumetric deformation mode Stochastic medium theory

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