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Precipitation of multi-type nano-quasicrystals in a Mg-zn-Y alloy

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Journal of Magnesium and Alloys 2024年第3期12卷 997-1008页

作者： W.z.Wang X.z.zhou l.F.zhang H.Q.Ye z.Q.Yang Shenyang National laboratory for Materials Science Institute of Metal ResearchChinese Academy of ScienceShenyang 110016China Ji Hua laboratory Foshan 528251China Foshan University Foshan 528231China

Mg-6zn-1Y(at.%)ribbons with strengthening precipitates of multi-type nanoquasicrystals were prepared by melt-spinning followed by aging *** evolution of the rapidly solidified ribbons during isothermal aging was comprehensively studied using various electron microscopy *** new kinds of decagonal quasicrystals were formed in aged ribbons,in addition to precipitation of nanometer icosahedral ***-resolution observations reveal that both decagonal quasicrystals can be modeled by quasiperiodic tiling with decagonal clusters of 2.5 nm in diameter,but overlap of neighboring clusters in both decagonal quasicrystals is different from the Gummelt model observed in other quasicrystals.A shell composed of complex laves Mg-zn domains was formed surrounding each decagonal quasicrystal precipitate upon prolonged *** addition,all kinds of nanoprecipitates exhibit excellent structure and size stability at 573 *** findings may have implications for not only fundamental studies about quasicrystals,but also microstructural manipulation of high-performance Mg alloys.

关键词： Quasicrystal Mg alloys Rapid solidification Scanning-transmission electron microscopy.

Decorating crystalline YFe_(2-x)Al_(x) on the Mg_(60)la_(10)Ni_(20)Cu_(10) amorphous alloy as “hydrogen pump” to realize fast de/hydrogenation

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Journal of Materials Science & Technology 2024年第6期173卷 72-79页

作者： l.J.Huang H.Wang l.z.Ouyang M.zhu H.J.lin School of Materials Science and Engineering Key Laboratory of Advanced Energy Storage Materials of Guangdong ProvinceSouth China University of TechnologyGuangzhou 510641China Institute of Advanced Wear&Corrosion Resistance and Functional Materials Jinan UniversityGuangzhou 510632China

Mg-based amorphous alloys are one of the potential hydrogen storage materials but suffer from sluggish dehydrogenation/hydrogenation(de/hydrogenation)*** this work,as a new strategy,a hydrogen pump is built on the surface of amorphous alloys to solve this *** milling crystalline YFe_(2-x)Al_(x) hydrogen storage alloy with Mg_(60)la_(10)Ni_(20)Cu_(10) amorphous alloy,fine crystalline particles were seeded on amorphous alloy powder to form a“strawberry”*** to the TEM observation,a metallurgical bonding boundary formed between the Mg-based amorphous matrix and the Y-Fe-Al crystalline *** microstructure and de/hydrogenation kinetics investigation,the“hydrogen pump”effect of the seeded crystalline alloy was confirmed,which makes it much easier for the hydrogen to dissociate on and diffuse through the surface of the Mg-based amorphous *** such effect,the H absorption rate of Mg_(60)la_(10)Ni_(20)Cu_(10) amorphous alloy became almost eight times faster and it absorbs ~2.8 wt.% in 1 h at 130℃ under 4.5 MPa-H_(2).Further,fast hydrogenation can even achieve at 70℃ and the low-temperature dehydrogenation kinetics of the amorphous hydride can be also greatly *** present work proves that surface modification is of great importance for obtaining Mg-based amorphous alloy with ideal hydrogen storage performance.

关键词： Hydrogen storage Mg-based amorphous alloy Hydrogen pump Composite structure

Rational design of AgGaS/znS/znS quantum dots with a near-unity photoluminescence quantum yield via double shelling scheme

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Journal of Materials Science & Technology 2024年第2期169卷 235-242页

作者： H.X.lu H.liu z.z.Fu Y.Y.Chen H.Q.Dai z.Hu W.l.zhang R.Q.Guo Institute for Electric light Sources School of Information Science and TechnologyFudan UniversityShanghai 200433China Institute of Future lighting Academy for Engineering and TechnologyFudan UniversityShanghai 200433China Yiwu Research Institute of Fudan University YiwuZhejiang 322000China zhongshan-Fudan Joint Innovation Center Zhongshan 528437China

In this study,a two-step method was used to synthesize highly luminescent AgGaS/znS/znS quantum dots(QDs).In the first step,an inner znS shell was formed via a one-pot method,which resulted in a smaller lattice mismatch between the AgGaS core and the outer znS shell,thereby facilitating the formation of a thick outer *** the two-step shelling process,the synthesized AgGaS/znS/znS QDs showed an excellent photoluminescence quantum yield(PlQY)of 96.4.with a peak wavelength of 508 nm,repre-senting the highest PlQY reported thus far for AgGaS ***,the effect of halogen ions in zn precursors on the shelling process was *** was proposed that the capacity of halogen ions to coordinate with the QDs influenced the balance between zn cation diffusion and znS shelling ***,the znS shelling reaction was dominant when znCl_(2)was employed,while zn cation diffusion was the dominant process under the I^(−)-rich *** work provides insights into the interfacial restructuring during the znS shelling and offers a clear map for the tailored synthesis of core/shell QDs.

关键词： AgGaS Quantum dots Photoluminescence Core/shell Alloyed core/shell interface

A multi-sensor appiproach to calving detection

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Information Processing in Agriculture 2024年第1期11卷 45-64页

作者： Anita z.Chang David l.Swain Mark G.Trotter Institute for Future Farming Systems School of HealthMedicaland Applied SciencesCentral Queensland UniversityRockhamptonQueensland 4700Australia

The advent of remote livestock monitoring systems provides numerous possibilities for improving on-farm productivity,efficiency,and *** potential application for these systems is for the detection of calving *** study describes the integration of data from multiple sensor sources,including accelerometers,global navigation satellite systems(GNsS),an accelerometer-derived rumination algorithm,a walk-over-weigh unit,and a weather station for parturition detection using a support vector machine *** best performing model utilised data from GNsS,the ruminating algorithm,and weather stations to achieve 98.6%accuracy,with 88.5%sensitivity and 100%*** topranking features of this model were primarily GNSS *** study provides an overview as to how various sensor systems could be integrated on-farm to maximise calving detection for improved production and welfare outcomes.

关键词： Accelerometer GNSS GPS Rumination Sensor WOW

Prediction of the undrained shear strength of remolded soil with non-linear regression,fuzzy logic,and artificial neural network

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Journal of Mountain Science 2024年第9期21卷 3108-3122页

作者： YÜNKÜl Kaan KARAÇOR Fatih GÜRBÜz Ayhan BUDAK TahsinÖmür Department of Civil Engineering Faculty of Engineering and ArchitectureTokat Gaziosmanpaşa UniversityTokat 60100Türkiye Department of Civil Engineering Faculty of Engineering and ArchitectureKafkas UniversityKars 36000Türkiye Department of Civil Engineering Faculty of EngineeringGazi UniversityAnkara 06570Türkiye Ministry of Youth and Sports Ankara 06090Türkiye

This study aims to predict the undrained shear strength of remolded soil samples using non-linear regression analyses,fuzzy logic,and artificial neural network modeling.A total of 1306 undrained shear strength results from 230 different remolded soil test settings reported in 21 publications were collected,utilizing six different measurement *** water content,plastic limit,and liquid limit were used as input parameters for fuzzy logic and artificial neural network modeling,liquidity index or water content ratio was considered as an input parameter for non-linear regression *** non-linear regression analyses,12 different regression equations were derived for the prediction of undrained shear strength of remolded ***-Forward backpropagation and the TANSIG transfer function were used for artificial neural network modeling,while the Mamdani inference system was preferred with trapezoidal and triangular membership functions for fuzzy logic *** experimental results of 914.tests were used for training of the artificial neural network models,196 for validation and 196 for *** was observed that the accuracy of the artificial neural network and fuzzy logic modeling was higher than that of the non-linear regression ***,a simple and reliable regression equation was proposed for assessments of undrained shear strength values with higher coefficients of determination.

关键词： Undrained shear strength liquidity index Water content ratio Non-linear regression Artificial neural networks Fuzzy logic

Effect of Al_(2)O_(3)on the Mechanical Properties of(B_(4.C+Al_(2)O_(3))/Al Neutron Absorbing Materials

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Acta Metallurgica Sinica(English letters) 2024年第8期37卷 1411-1420页

作者： J.X.Cai B.M.Shi N.li Y.liu z.G.zhang Y.N.zan Q.z.Wang B.l.Xiao z.Y.Ma Shi‑Changxu Innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China Key laboratory of Nuclear Materials and Safety Assessment Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China Nuclear Equipment Division Beijing Institute of Nuclear EngineeringChina Nuclear Power Engineering Co.Ltd.Beijing 100840China Department of Materials Science School of Mechanical EngineeringShenyang UniversityShenyang 110044China

B_(4.C/Al composites are widely utilized as neutron absorbing materials for the storage and transportation of spent nuclear *** order to improve the high-temperature mechanical properties of B_(4.C/Al composites,in-situ nano-Al_(2)O_(3)was introduced utilizing oxide on Al powder *** this study,the Al_(2)O_(3)content was adjusted by utilizing spheroid Al powder with varying diameters,thereby investigating the impact of Al_(2)O_(3)content on the tensile properties of(B_(4.C+Al_(2)O_(3))/Al *** was found that the pinning effect of Al_(2)O_(3)on the grain boundaries could hinder the recovery of dislocations and lead to dislocation accumulation at high *** the result,with the increase in Al_(2)O_(3)content and the decrease in grain size,the high-temperature strength of the composites increased *** finest Al powder used in this investigation had a diameter of 1.4.m,whereas the resultant composite exhibited a maximum strength of 251 MPa at room temperature and 133 MPa at 350℃,surpassing that of traditional B_(4.C/Al composites.

关键词： Al matrix composites Neutron absorbing materials (B_(4.C+Al_(2)O_(3))/Al composites High-temperature strength

A DiscreteMulti-Objective Squirrel Search Algorithm for Energy-Efficient Distributed Heterogeneous Permutation Flowshop with Variable Processing Speed

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Computers, Materials and Continua 2024年第1期81卷 1757-1787页

作者： zeng l. Ding z. Shi J. Wang S. School of Electrical and Electronic Engineering Hubei University of Technology Wuhan 430068 China Hubei Key laboratory for High-Efficiency Utilization of Solar Energy and Operation Control of Energy Storage System Hubei University of Technology Wuhan 430068 China Xiangyang Industrial Institute of Hubei University of Technology Xiangyang 441100 China

In the manufacturing industry, reasonable scheduling can greatly improve production efficiency, while excessive resource consumption highlights the growing significance of energy conservation in production. This paper studies the problem of energy-efficient distributed heterogeneous permutation flowshop problem with variable processing speed (DHPFSP-VPS), considering both theminimum makespan and total energy consumption (TEC) as objectives. A discrete multi-objective squirrel search algorithm (DMSSA) is proposed to solve the DHPFSPVPS. DMSSA makes four improvements based on the squirrel search algorithm. Firstly, in terms of the population initialization strategy, four hybrid initialization methods targeting different objectives are proposed to enhance the quality of initial solutions. Secondly, enhancements are made to the population hierarchy system and position updating methods of the squirrel search algorithm, making it more suitable for discrete scheduling problems. Additionally, regarding the search strategy, six local searches are designed based on problem characteristics to enhance search capability. Moreover, a dynamic predator strategy based on Q-learning is devised to effectively balanceDMSSA's capability for global exploration and local exploitation. Finally, two speed control energy-efficient strategies are designed to reduce TEC. Extensive comparative experiments are conducted in this paper to validate the effectiveness of the proposed strategies. The results of comparing DMSSA with other algorithms demonstrate its superior performance and its potential for efficient solving of the DHPFSP-VPS problem. © 2024.The Authors. Published by Tech Science Press.

关键词： Distributed heterogeneous permutation flowshop problem energy-efficient squirrel search algorithm muli-objective optimization variable processing speed

Discovery of new MAX-phase-like layered ternary carbide V_(8)P_(6)C:Crystal structure,thermal expansion,and elastic properties

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Journal of Materials Science & Technology 2024年第7期174卷 55-62页

作者： H.X.Chen l.Sheng z.l.zhang X.C.Wen D.l.Yang X.Y.Ye P.Q.Dai School of Materials Science and Engineering Fujian University of TechnologyFuzhou 350118China Beijing Synchrotron Radiation Facility Institute of High Energy PhysicsChinese Academy of ScienceBeijing 100049China Fujian Provincial Key laboratory of Advanced Materials Processing and Application Fuzhou 350118China State Key laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China

Due to the laminated structure,MAX phases and MAX-phase-like compounds possess outstanding dam-age tolerance capability with good thermal/electrical conductivity and other charming functional prop-erties,showing a bright future for structural-functional ***,a new MAX-phase-like ternary car-bide V_(8)P_(6)C with layered characteristics was *** to the alternate stacking of hexagonal-arranged M/A/X atom layers in MAX phases,V_(8)P_(6)C has a layered structure formed by a repeated stacking of the slabs consisting of V_(6)C-octahedrons and VP 6-distorted-octahedrons in three-atomic layers *** thermal expansion anisotropy was revealed,with the thermal expansion coefficients(TECs)along a-axis,c-axis,and the average value,equal toα_(a)=8.55(5)μK^(−1),α_(c)=10.23(5)μK^(−1),andα_(l)=9.14.5)μK^(−1),*** dilation along the c-axis was mainly dominated by out-plane V-P bonds be-tween layered *** to the pressure-dependent lattice parameters,the polycrystalline bulk modulus(B_(0)=185(9)GPa)and high compressibility anisotropy factor(B_(a)/B_(c)=1.64.was ***-while,the second-order elastic constants were calculated,and the elastic moduli,E=303 GPa,B=198 GPa,G=122 GPa,andν=0.24.,were *** the weak connection between layer slabs by out-plane V1-P bond was revealed by the bond stiffness model,with a bond stiffness close to the M-A bond in MAX ***,good damage tolerance capability was predicted according to Paugh’s ratio(G/B=0.616)and Cauchy pressure(P_(a)=0 GPa,P_(c)=-7.5 GPa),even better than those of typical MAX *** discovery of V_(8)P_(6)C provides a new member of MAX-phase-like damage-tolerant ceramic with relatively low density,moderate thermal expansion,and anisotropic compressibility,and the unique lay-ered structure is inspiring for exploring new layered ternary ceramics.

关键词： New ternary carbide MAX phase Thermal expansion Elastic constants Anisotropy

Reactive destabilization and bidirectional catalyzation for reversible hydrogen storage of liBH_(4. by novel waxberry-like nano-additive assembled from ultrafine Fe_(3)O_(4. particles

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Journal of Materials Science & Technology 2024年第6期173卷 63-71页

作者： S.Wang M.H.Wu Y.Y.zhu z.l.li Y.X.Yang Y.z.l. H.F.liu M.X.Gao Department of Material Science Shenzhen MSU-BIT UniversityShenzhen 518172China State Key laboratory of Silicon and Advanced Semiconductor Materials&School of Materials Science and Engineering Zhejiang UniversityHangzhou 310027China Institute of Resources Utilization and Rare Earth Development State Key Laboratory of Rare Metals Separation and Comprehensive UtilizationGuangdong Provincial Key Laboratory of Rare Earth Development and ApplicationGuangdong Academy of SciencesGuangzhou 510650China Institute of Science and Technology for New Energy Xi’an Technological UniversityXi’an 710021China National Supercomputing Center in Shenzhen Shenzhen 518055China

liBH_(4. containing 18.5 wt.%H_(2) is an attractive high-capacity hydrogen storage material,however,it suffers from high operation temperature and poor ***,a novel and low-cost bifunctional additive,waxberry-like Fe_(3)O_(4. secondary nanospheres assembled from ultrafine primary Fe_(3)O_(4. nanoparticles,is synthesized,which exhibits significant destabilization and bidirectional catalyzation towards(de)hydrogenation of liBH_(4..With an optimized addition of 30 wt.% waxberry-like Fe_(3)O_(4.,the system initiated dehydrogenation below 100℃ and released a total of 8.1 wt.%H_(2) to 4.0℃.After 10 cycles,a capacity retention of 70% was achieved,greatly superior to previously reported oxides-modified *** destabilizing and catalyzing mechanisms of waxberry-like Fe_(3)O_(4. on liBH_(4. were systematically analyzed by phase and microstructural evolutions during dehydrogenation and hydrogenation cycling as well as density functional theory(DFT)*** present work provides new insights in developing advanced nano-additives with unique structural and multifunctional designs towards liBH4.hydrogen storage.

关键词： liBH_(4. Hydrogen storage Waxberry-like Fe_(3)O_(4. Destabilization Catalysis