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dual-additives enable stable electrode-electrolyte interfaces for long life Li-SPAN batteries

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chinese chemical Letters 2024年第5期35卷 459-465页

作者： zhenqiang guo Huicong yang Qian wei Shengjun xu Guangjian Hu Shuo Bai Feng Li School of materials science and {2. University of Science and Technology of ChinaShenyang 110016China Shenyang National Laboratory for materials science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China department of Biochemistry and Molecular Biology College of Life ScienceChina Medical UniversityShenyang 110122China dalian National Laboratory for clean Energy Dalian 116023China Shenyang King Power technology co. Ltd.Shenyang 110016China

Sulfurized polyacrylonitrile(SPAN)is proposed as a promising cathode material for lithium sulfur ***,the continuous side reactions at the electrolyte-electrode interfaces as well as the slow redox kinetics of SPAN cathode deteriorate the electrochemical *** this study,an electrolyte with dual-additives comprising 2.fluoropyridine(2.FP)and lithium difluorobis(oxalato)phosphate(LidFBOP)was used to improve the performance of Li||SPAN cells.2.FP has a lower lowest occupied molecular orbital energy than that of the solvents in the electrolyte,leading to its prior reduction.A LiF-rich film can be formed on the electrode,effectively improving the stability of the electrolyte-electrode interfaces and prolonging the ***,LidFBOP could form an electrolyte-electrode interface film containing a large amount of Li_(x)PO_(y)F_(z) species,compensating for the kinetic deterioration caused by the lower ionic conductive of LiF formed at the electrolyte-electrode ***,an electrode-interface film with good chemical stability and high Li^(+) transport was established by LiF and Li_(x)PO_(y)F_(z)-rich *** Li||SPAN cell with the electrolyte containing dual-additives demonstrates an excellent capacity retention of 97.5%after 2.0 cycles at 1.0 c,2.℃,comparing to 56.2.capacity retention without ***,the rate capacities of cells with dual-additives can reach 112..1 mAh/g at 5 c,comparing to only 813.5 mAh/g using electrolyte without *** results shown that the dual-additives in electrolyte provide a promising strategy for practical application of lithium sulfur batteries with SPAN cathodes.

关键词： Sulfurized polyacrylonitrile Lithium metal Interface film 2.Fluoropyridine difluorobis(oxalato)phosphate

KINETIc STUdy OF SPINEL LiMn_2._4 SyNTHESIzEd By SOLId rEAcTION wITH SOFT-cHEMIcAL METHOd

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Acta Metallurgica Sinica(English Letters) 2005年第4期18卷 512-518页

作者： c.Q. xu y. w. Tian y. c. zhai z.J. guo z. Q. Huang School of materials and metallurgy Northeastern University Shenyang 110004 China

The differential thermal analysis （dTA） curves were measured at different heating rates in flowing air for studying the synthesis of the spinel LiMn2.3 with Li2.O3 and MnO2. The reaction began at about 503K, and finished at about 873K. The apparent activation energy of Kissinger method was about ***^-1, the reaction orderwas 1.67, the frequency factor was 7.81×10^9, and therefore the dinetic epuation was dδ/dt=A·exp（- E/rT）·（1-δ）^n=7.81×10^9, exp（-12.770/rT）·（l-δ）^1.67 . coats-redfem integral method was used to analyze the dTA curves of the samples at different heating rates, and the calculated apparent activation energy and frequency factor were 112. 13kJ· mol^-1 and 1.18 × 10^9, respectively, rather close to that of Kissinger method. x-ray diffraction （xrd） and scanning electron microscope （SEM） results shown that the synthesized LiMn2.3 possesses pure phase, regular shape and normal particle distribution.

关键词： lithium manganese oxides synthesized kinetics Kissinger method,coats-redfern integral method

Enhancing strength and creep resistance of Mg-Gd-y-zn-zr alloy by substituting Mn for zr

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Journal of Magnesium and Alloys 2019年第3期7卷 388-399页

作者： c.xu T.Nakata G.H.Fan x.w.Li G.z.Tang S.Kamado School of materials science and {2. Harbin Institute of TechnologyHarbin 150001PR China department of Mechanical engineering Nagaoka University of TechnologyNagaoka 940-2188Japan School of material science and {2. Harbin University of Science and TechnologyHarbin 150040PR China

The age-hardening behavior and mechanical properties of the extruded Mg-2.d-1.2.-0.5zn(at.%)alloy with zr or Mn additions were *** results show that Mn added alloy exhibits more remarkable age-hardening response than zr added alloy,which is attributed to the fact that partitioning of Mn into the β'phases,β'precipitates and long period stacking ordered(LPSO)phases leads to the decrement in(G d+y)concentrations in the second phases,facilitating the precipitation during aging *** peak-aged alloys show bimodal microstructure comprising the fine drxed grains with nano-sized β phases pinned at drxed grain boundaries as well as coarse worked grains with strong fiber *** strength and good thermal stability were obtained in both peak-aged Mn and zr added *** the peak-aged Mn added alloy shows higher strength and superior creep resistance due to its denser β'precipitates,thin LPSO phases and γ'precipitates and higher area fraction of worked grains with strong fiber *** 0.2. tensile proof stress and ultimate tensile strength of peak-aged Mn added alloy reach up to 454 MPa and 508 MPa,respectively,with elongation of 3.2.at room *** minimum creep rate of the peak-aged Mn added alloy at 2.0℃/150 MPa is 2.4 × 10^-8 s^-1,which is superior than previously reported extruded Mg-Gd based alloys.

关键词： Magnesium alloys rare earth(rE) Precipitation Mechanical properties creep resistance

The design and performance of Grd onboard the GEcAM satellite

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radiation detection technology and Methods 2022年第1期6卷 43-52页

作者： z.H.An x.L.Sun d.L.zhang S.yang x.Q.Li x.y.wen K.Gong x.H.Liang x.J.Liu y.Q.Liu y.G.Li S.L.xiong y.B.xu Fan zhang x.y.zhao c.cai z.chang G.chen c.chen y.y.du P.y.Feng M.Gao r.Gao d.y.guo J.J.He d.J.Hou c.y.Li G.Li L.Li x.F.Li M.S.Li F.J.Lu H.Lu B.Meng w.x.Peng F.Shi H.wang J.z.wang y.S.wang H.z.wang x.wen S.xiao y.P.xu J.w.yang Q.B.yi S.N.zhang c.y.zhang c.M.zhang Fei zhang y.zhao x.zhou cAS Institute of High Energy PhysicsBeijing 100049China State Key Laboratory of Particle detection and Electronics Beijing 100049China 3 Xiangtan UniversityXiangtan 411105China 4 Beijing Normal UniversityBeijing 110875China xiangtan university Xiangtan 411105China Beijing Normal university Beijing 110875China

Background Each GEcAM satellite payload contains 2. gamma-ray detectors(Grds),which can detect gamma-rays and particles and can roughly localize the Gamma-ray Bursts(GrBs).Grd was designed using lanthanum bromide(LaBr3)crystal as the sensitive material with the rear end coupled with silicon photomultiplier(SiPM)array for *** In aerospace engineering design of Grd,there are many key points to be *** this paper,we present the specific design scheme of Grd,the assembly and the performance test results of *** Based on Monte carlo simulation and experimental test results,the specific schematic design and assembling process of Grd were *** being fully assembled,the Grds were conducted performance tests by using radioactive source and also conducted random vibration *** and conclusion The test results show that all satellite-borne Grds have energy resolutionrequirements of satellite in scientific *** random vibration test shows that Grd can maintain in a stable performance,which meets the requirement of spatial application.

关键词： Lanthanum bromide scintillator SiPM array GEcAM Gamma-ray detector Energy resolution

Effects of Sic Nanoparticle content on the Microstructure and Tensile Mechanical Properties of Ultrafine Grained AA6063-Sic_(np) Nanocomposites Fabricated by Powder metallurgy

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Journal of materials science & {2. 2017年第9期33卷 1023-1030页

作者： x.yao z.zhang y.F.zheng c.Kong M.z.Quadir J.M.Liang y.H.chen P.Munroe d.L.zhang State Key Laboratory of Metal Matrix composites School of Materials Science and EngineeringShanghai Jiao Tong University Electron Microscope Unit University of New South Wales School of materials science and {2. University of New South Wales

Ultrafine grained AA6063-Sicnpnanocomposites with 1, 5 and 10 vol.% Sicnphave been fabricated by a novel powder metallurgy process. This process combines high energy ball milling of a mixture of 6063 alloy granules made from machining chips and Si c nanoparticles and thermomechanical powder consolidation by spark plasma sintering and hot extrusion. The microstructure and tensile mechanical properties of the samples were investigated in detail. Increasing the Si c nanoparticle content from 1 to 10 vol.%,the yield strength and ultimate tensile strength increased from 2.6 and 343 MPa to 545 and 603 MPa respectively, and the elongation to fracture decreased from 10.0%, to 2.3%. As expected, a higher Si c nanoparticle content generates a stronger inhibiting effect to grain growth during the thermomechanical powder consolidation process. Analysis of the contributions of various strengthening mechanisms shows that a higher Si c nanoparticle content leads to a higher contribution from nanoparticle strengthening, but grain boundary strengthening still makes the largest contribution to the strength of the *** the Si c nanoparticle content increased to 10 vol.%, the failure of the nanocomposite was initiated at weakly-bonded interparticle boundaries(IPBs), indicating that with a high flow stress during tensile deformation, the failure of the material is more sensitive to the presence of weakly-bonded IPBs.

关键词： Metal matrix nanocomposite Ultrafine grained material Powder metallurgy Tensile mechanical properties

Proton beams from intense laser-solid interaction:Effects of the target materials

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Matter and radiation at Extremes 2020年第6期5卷 42-47页

作者： y.x.Geng d.wu w.yu z.M.Sheng S.Fritzsche Q.Liao M.J.wu x.H.xu d.y.Li w.J.Ma H.y.Lu y.y.zhao x.T.He J.E.chen c.Lin x.Q.yan Key Laboratory of HEdP of the Ministry of Education CAPTand State Key Laboratory of Nuclear Physics and TechnologyPeking UniversityBeijing 100871China Institute for Fusion Theory and Simulation Department of PhysicsZhejiang University310058 HangzhouChina State Key Laboratory of High Field Laser Physics Shanghai Institute of Optics and Fine Mechanics201800 ShanghaiChina SUPA department of Physics University of StrathclydeGlasgow G40NGUnited Kingdom Key Laboratory for Laser Plasmas(Ministry of Education) School of Physics and AstronomyShanghai Jiao Tong UniversityShanghai 200240China Helmholtz Institut-Jena and Friedrich-Schiller-university D-07743 JenaGermany

we report systematic studies of laser-driven proton beams produced with micrometer-thick solid targets made of aluminum and plastic,*** effects of the target materials are found on the total charge,cutoff energy,and beam spot of protons in the experiments,and these are described well by two-dimensional particle-in-cell simulations incorporating intrinsic material *** is found that with a laser intensity of 8×10^(19) w/cm^(2.,target normal sheath acceleration is the dominant mechanism for both types of *** a plastic target,the higher charge and cutoff energy of the protons are due to the greater energy coupling efficiencies from the intense laser beams,and the larger divergence angle of the protons is due to the deflection of hot electrons during transport in the *** also find that the energy loss of hot electrons in targets of different thickness has a significant effect on the proton cutoff *** consistent results obtained here further narrow the gap between simulations and experiments.

关键词： properties. intense solid

Synthesis,crystal Structure and thermal decomposition mechanism of the complex [Sm(p-BrBA)3bipy·H2.]2.H2.

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Synthesis,Crystal Structure and thermal decomposition mechan...

Status and Strategy of Fusion materials development in china

中国化学会第五届全国结构化学学术会议

作者： H.y.zhang~(1,2. J.J.zhang~(1*) S.L.xu~(1,2. N.ren~3 L.Tian~(1,2. J.H.Bai~4 (1 Experimental center,Hebei Normal university,shijia{2.ang 050016 P.r.china.) (2.college of chemistry& material science,Hebei Normal university,Shijia{2.ang 050016 P.r.china) (3 department of chemistry,Handan college,Handan 056005 P.r.china) 4(department of compute,Hebei Normal college of science and technology,Qinhuangdao,066600 P.r.china)

A binuclear samarium(Ⅲ)complex with p-bromobenzoic acid and 2.2.-bipyridine [Sm(p-SrBA)bipy-HO]·HO has been synthesized and characterized by elemental analysis,UV, Ir and TG-dTG *** structure of the complex was established by single crystal x-ray *** crystallized in triclinic,space group PT with a=8.2.76(7),b=13.3483(10),c= 15.9035(13),α=73.9160(10),β=78.9630(10),γ=74.4770(10),z=1,d=1.947 g·cm,F(000)= *** carboxylate groups are bonded to the samarium ion in two modes:bidentate bridging,

关键词： Samarium complex p-bromobenzoic acid 2.2.-bipyridine crystal structure Thermal decomposition mechanism

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Status and Strategy of Fusion Materials Development in China

Bimeron clusters in chiral antiferromagnets

第十二届反应堆数值计算与粒子输运学术会议

作者： Q.y.Huang~1 y.c.wu~1 J.G.Li~1 F.r.wan~2.J.L.chen~1 G.N.Luo~1 x.Liu~3 J,M,chen~3 z.y.xu~3 x.G.zhou~4 x.Ju~2.y.y.Shan~5 J.N.yu~6 S.y.zhu~6 P.y.zhang~6 J.F.yang~7 x.J.chen~8 S.M.dong~9 (1.Institute of Plasma Physics,chinese Academy of {2.s,Hefei,Anhui,2.0031,china 2.university of {2. and technology Beijing,Beijing 100083,china 3.Southwestern Institute of Physics,chengdu,Sichuan,610041,china 4 National university of defense technology,changsha,Hunan,410073,china 5.Institute of Metal research,chinese Academy of {2.s,Shenyang,Liaoning,110016,china 6.china Institute of Atomic Energy,Beijing,102.13,china 7.xi’an Jiaotong university,xi’an,Shanxi,710049,china 8 china Academy of engineering Physics,Mianyang,Sichuan,62.900,china 9.Shanghai Institute of ceramics,chinese Academy of {2.s,Shahghai,2.0050,china)

The liquid metal and solid ceramic pebble breeder blankets have become the most promising blankets for ITEr-TBMs or dEMO reactors in china and the world due to their potential advantages. In recent years the corresponding research work on fusion reactor materials are mainly focus on structural materials,plasma facing materials and the functional materials for the blanket such as breeder, coating and flow channel insert *** push work on fusion materials and then for the successful application of fusion *** r&d on those materials in the two kinds of blankets is being carried out widely in china,including fabrication and manufacturing techniques,physical/mechanical properties assessment before and after irradiation,joining techniques for structural materials, compatibility evaluation,and the development and verification of the criteria for fusion material *** progress on main r&d activities of fusion reactor materials in china is introduced and prospected in the paper.

关键词： Fusion reactor Blanket materials r&d

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npj computational materials 2020年第1期6卷 270-278页

作者： xiaoguang Li Laichuan Shen yuhao Bai Junlin wang xichao zhang Jing xia Motohiko Ezawa Oleg A.Tretiakov xiaohong xu Michal Mruczkiewicz Maciej Krawczyk yongbing xu richard F.L.Evans roy w.c.hantrell yan zhou School of science and engineering The Chinese University of Hong Kong518172 ShenzhenChina Hefei National Laboratory for Physical sciences at the Microscale Department of PhysicsUniversity of Science and Technology of China230026 HefeiChina research Institute of materials science of Shanxi Normal {2.&collaborative Innovation center for Shanxi Advanced Permanent Magnetic materials and technology 041004 LinfenChina School of Physics and Electronic Information Shanxi Normal University041004 LinfenChina department of Physics University of YorkYork YO105DDUK york-Nanjing International center of Spintronics(yNIcS) Nanjing University210093 NanjingChina department of Applied Physics The University of Tokyo7-3-1 HongoTokyo 113-8656Japan School of Physics The University of New South WalesSydney 2052Australia National university of science and {2.‘MISiS’ Moscow 119049Russia School of chemistry and materials science of Shanxi Normal {2.&Key Laboratory of Magnetic Molecules and Magnetic Information materials of Ministry of Education 041004 LinfenChina Institute of Electrical engineering Slovak Academy of SciencesDúbravskácesta 984104 BratislavaSlovakia centre for Advanced materials Application cEMEA Slovak Academy of SciencesDúbravskácesta 5807/984511 BratislavaSlovakia Faculty of Physics Adam Mickiewicz University in PoznanUniwersytetu Poznanskiego 261-614 PoznanPoland

A magnetic bimeron is an in-plane topological counterpart of a magnetic *** the topological equivalence,their statics and dynamics could be distinct,making them attractive from the perspectives of both physics and spintronic *** this work,we demonstrate the stabilization of bimeron solitons and clusters in the antiferromagnetic(AFM)thin film with interfacial dzyaloshinskii–Moriya interaction(dMI).Bimerons demonstrate high current-driven mobility as generic AFM solitons,while featuring anisotropic and relativistic dynamics excited by currents with in-plane and out-ofplane polarizations,***,these spin textures can absorb other bimeron solitons or clusters along the translational direction to acquire a wide range of Néel topological *** clustering involves the rearrangement of topological structures,and gives rise to remarkable changes in static and dynamical *** merits of AFM bimeron clusters reveal a potential path to unify multibit data creation,transmission,storage,and even topology-based computation within the same material system,and may stimulate spintronic devices enabling innovative paradigms of data manipulations.

关键词： properties topological clusters