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Recent development of chemically complex metallic glasses: from accelerated compositional design, additive manufacturing to novel applications

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Materials Futures 2022年第1期1卷 9-31页

作者： J Y zhang z Q zhou z b zhang M H Park Q Yu z Li J Ma A D Wang H G Huang M Song b S Guo Q Wang Y Yang Department of Mechanical Engineering College of EngineeringCity University of Hong KongKowloon TongKowloonHong KongPeople’s Republic of China Shenzhen Key Laboratory of High Performance Nontraditional Manufacturing College of Mechatronics and Control EngineeringShenzhen UniversityShenzhenGuangdong 518060People’s Republic of China School of Materials Science and Engineering Dongguan University of TechnologyDongguanGuangdong 523808People’s Republic of China Institute of Materials China Academy of Engineering PhysicsJiangyouSichuan 621907People’s Republic of China State Key Laboratory of Powder Metallurgy Central South UniversityChangshaHunan 410083People’s Republic of China Institute of Advanced Wear&Corrosion Resistant and Functional Materials Jinan UniversityGuangzhouGuangdong 510632People’s Republic of China Institute of Materials Laboratory for MicrostructuresShanghai UniversityShanghai 200444People’s Republic of China Department of Materials Science and Engineering College of EngineeringCity University of Hong KongKowloon TongKowloonHong KongPeople’s Republic of China Department of Advanced Design and System Engineering College of EngineeringCity University of Hong KongKowloon TongKowloonHong KongPeople’s Republic of China

Metallic glasses(MGs)or amorphous alloys are an important engineering material that has a history of research of about 80–90 *** different fast cooling methods were developed for multi-component MGs between 1960s and 1980s,1990s witnessed a surge of research interest in the development of bulk metallic glasses(bGMs).Since then,one central theme of research in the metallic-glass community has been compositional design that aims to search for MGs with a better glass forming ability,a larger size and/or more interesting properties,which can hence meet the demands from more important *** this review article,we focus on the recent development of chemically complex MGs,such as high entropy MGs,with new tools that were not available or mature yet until recently,such as the state-of-the-art additive manufacturing technologies,high throughput materials design techniques and the methods for big data analyses(*** learning and artificial intelligence).We also discuss the recent use of MGs in a variety of novel and important applications,from personal healthcare,electric energy transfer to nuclear energy that plays a pivotal role in the battle against global warming.

关键词： metallic glasses amorphous alloys alloy design additive manufacturing machine learning high throughput materials design

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The Impact of Subclinical Ketosis on Mastitis by Changes of Antioxygen Function and Immunity in Dairy Cows

The Impact of Subclinical Ketosis on Mastitis by Changes of ...

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中国畜牧兽医学会家畜内科学分会第七届代表大会暨学术研讨会

作者： J.X.Xue~(a,b),K.C zhang~(a,b),K.H.Huang~b,D.N.Miao~c, z.z.zhang~(a,b),R.H.zhang~a (a.Shanghai Institute of Dairy Science,Shanghai 200436,china b.College of Veterinary Medicine,Nanjing Agricultural University,Nanjing 210095,china c.Institute of Animal Husbandry and Veterinary Sciences,Shanghai Academy of Agricultural Sciences,Shanghai 201106,China )

69 subclinical ketosis cows were chosen from 156 holstein cows as the test group (1.0mmol/L200,000/mL) were asepses collected separately for the isolation and indentification of mastitis pathogens.12 cows(SCC 0.05 ). ... 详细信息

69 subclinical ketosis cows were chosen from 156 holstein cows as the test group (1.0mmol/Lbutyric acidbutyric acid200,000/mL) were asepses collected separately for the isolation and indentification of mastitis pathogens.12 cows(SCCbut the difference was not significant(P> 0.05 ). Mastitis in test group was mainly onset during the third to sixth week after parturition,while the control group mainly onset during fifth to eighth week after *** mainly occured one to three weeks later than subclinical ketosis,and the proportion that outbreak in the three weeks was 73.33%.There was no difference on the composition of mastitis pathogen(P>0.05). The level of T-AOC in the serum of test group was significantly lower than control group(Pbut the levels of GSH-PX,MDA and NO in the serum of test group was significantly increased(Pbetween plasma ACAC and bHbA levels(Pbe significantly positive(Pbetween NO level and ACAC level(Pbe significantly negative(Pblood cell count,the number of neutrophils and lymphocyte,the rate of phagocytosis and the chemotactic index of neutrophils in the blood of the subclinical ketosis cows were signi

关键词： subclinical ketosis mastitis antioxygen function Immunological function dairy cows

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A none quilibrium model for spray evaporation desalination

A none quilibrium model for spray evaporation desalination

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第十七届全国化学热力学和热分析学术会议

作者： H.L.Qian F.W.Wu z.zhou z.b.zhang C.Liu X.H.Lu Department of Pharmaceutical Engineering China Pharmaceutical University School of Chemistry and Chemical Engineering Nanjing Tech University School of Chemistry and Chemical Engineering Nanjing University

A general thermodynamic model is developed by combining organically the nonequilibrium thermodynamic analysis with the simulation of spray evaporation desalination processes. The model is capable of both simulating spray evaporation desalination processes and analyzing energy consumptions of the processes. The simulation results show that the structure parameters, physical property, operation parameters have significant influences on the entropy generation rate(EGR), and the nonequilibrium thermodynamic analysis is a potential tool to optimize the spray evaporation desalination operation and design. It is also found that the 1atomization effect of pressure-jet atomizers is lower than that of plain-jet airblast atomizers under the same condition.

关键词： spray evaporation desalination nonequilibrium thermodynamics entropy generation rate

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Depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 335-345页

作者： Feng zhang Chenyang zhang Linlin Wu Wei Sun Hongliang zhang Jianhua Chen Yong Pei Songjiang Li Engineering Research Center of Ministry of Education for Carbon Emission Reduction in Metal Resource Exploitation and Utilization Hunan International Joint Research Center for Efficient and Clean Utilization of Critical Metal Mineral ResourcesSchool of Minerals Processing and BioengineeringCentral South UniversityChangsha 410083China State Key Laboratory of Mineral Processing Beijing General Research Institute of Mining&MetallurgyBeijing 100160China Hunan Provincial Key Laboratory of Micro&Nano Materials Interfaces Science College of Chemistry and Chemical EngineeringCentral South UniversityChangsha 410083China School of Resources Environment and MaterialsGuangxi UniversityNanning 530004China Department of Chemistry Xiangtan UniversityXiangtan 411105China China Railway Resource Group Co.Ltd Beijing 102300China

The depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite still lacked in-depth ***,the depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite was further systematically investigated with experiments and density functional theory(DFT)*** X-ray photoelectric spectroscopy(XPS)results,DFT calculation results,and frontier molecular orbital analysis indicated that sulfite ions were difficult to be adsorbed on sphalerite surface,suggesting that sulfite ions achieved depression effects on sphalerite through other non-adsorption ***,the oxygen content in the surface of sphalerite treated with sulfite ions in creased,which enhanced the hydrophilicity of the sphalerite and further increased the difference in hydrophilicity between sphalerite and ***,sulfite ions were chelated with lead ions to form PbSO_(3)in *** hydrophilic PbSO_(3)was more easily adsorbed on sphalerite than *** interaction between sulfite ions and lead ions could effectively inhibit the activation of *** addition the UV spectrum showed that after adding sulfite ions,the peak of perxanthate in the sphalerite treated xanthate solution was significantly stronger than that in the galena with xanthate solution,indicating that xanthate interacted more readily with sulfite ions and oxygen mo lecules within the sphalerite system,leading to the formation of ***,sulfite ions hardly depressed the flotation of ga lena and could promote the flotation of galena to some *** study deepened the understanding of the depression mechanism o sulfite ions on sphalerite and Pb^(2+)activated sphalerite.

关键词： sphalerite galena sulfite ion density functional theory depression mechanism

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The specimen preparation methods for nanoindentation testing of biomaterials:a review

The specimen preparation methods for nanoindentation testing...

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2007亚洲光电子会议纳米光子学/纳米结构/纳米计量学分会场

作者： J.Y.Sun a,J.Tong a,z.J.zhang b aKey Laboratory of Terrain-Machine bionics Engineering(Ministry of Education,China)and bCollege of biological and Agricultural Engineering,Jilin University College of Mechanical Science and Engineering,Jilin University Changchun,Jilin Province,China

Nanoindenter provides an approach for assessing mechanical properties in micro-electronics devices and films based on quantitative,controlled nanoindentation of surfaces,with the convenience of modern *** is also suitable to measure mechanical properties of *** for biomaterial testing in bone and dentin was widely *** some studies of nanoindentation properties in insect were carried *** the surface roughness of natural biomaterials problem should not to be ignored in nanoindentation *** surface roughness will critically affect the precision of result of nanoindentation testing and caused error *** this paper,the biomaterials specimen preparation methods for nanoindentation testing will be reviewed.

关键词： specimen preparation,nanoindentation,biomaterials

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Effects of carbon content on the microstructure and tensile properties of a low-density steel

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 391-401页

作者： Yongxuan Shang Mingyu Fan Shuyong Jiang zhongwu zhang Key Laboratory of Superlight Materials and Surface Technology Ministry of EducationCollege of Materials Science and Chemical EngineeringHarbin Engineering UniversityHarbin 150001China State Key Laboratory of Metal Material for Marine Equipment and Application Iron&Steel Research Institute of Ansteel Group CorporationAnshan 114009China

Carbon can change the phase components of low-density steels and influence the mechanical *** this study,a new method to control the carbon content and avoid the formation ofδ-ferrite by decarburization treatment was *** microstructural changes and mechanical characteristics with carbon content induced by decarburization were systematically ***-Jaoul(C-J)analysis was employed to examine the work hardening characteristics during the tensile *** decarburization by heat treatments,the carbon content within the austenite phase decreased,while Mn and Al were almost unchanged;this made the steel with full austenite transform into the austenite and ferrite dual ***,(Ti,V)C carbides existed in both matrix phase and the mole fraction almost the *** addition,the formation of other carbides *** loss induced a decrease in strength due to the weakening of the carbon solid *** the steel with the single austinite,the deformation mode of austenite was the dislocation planar glide,resulting in the formation of *** the dual-phase steel,the deformation occurred by the dislocation planar glide of austenite first,with the increase in strain,the cross slip of ferrite took place,forming dislocation cells in *** the late stage of deformation,the work hardening of austinite increased rapidly,while that of ferrite increased slightly.

关键词： low-density steels carbon content decarburization strengthening mechanisms work hardening behavior

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Synergistically enhanced ORR and HER performance on Co-N-C coupled in-situ generated PtCo intermetallic

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Journal of Energy Chemistry 2025年第1期100卷 721-729页

作者： Guanyu Luo Min Song Lulu An Xiao Huang Qian zhang Chenhao zhang Tao Shen Shuang Wang Deli Wang Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology) Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology

Integrating multi-scale sites in a composite catalyst is vital to realize efficient ***,a synergistic composite catalyst consisting of Co atomic sites and in-situ generated PtCo intermetallic compounds （IMCs）(o-PtCo@CoNC) is proposed through Co pre-anchoring and subsequent impregnation-reduction *** loading of Co atoms provides a chance for in-situ generating PtCo ordered intermetallic *** remaining Co single atoms and PtCo IMCs construct synergistic electrocatalytic *** from the ordered structure,synergistic effect of Pt Co IMCs and Co single atoms,o-PtCo@CoNC exhibits excellent electrocatalytic performance for oxygen reduction reaction （ORR） and hydrogen evolution reaction （HER） with mass activity of 1.21 A mgPt-1（at 0.9 V） and5.70 A mgPt-1（at an overpotential of 100 mV）,***,o-PtCo@CoNC delivers negligible loss of half-wave potential and overpotential during long-term stability test in acid solutions,with 13 mV decay after 50,000 potential cycles for ORR and a 2.7 mV decay after 20,000 potential cycles for *** integration strategy of single-atomic sites coupled IMCs paves the way for enhancing the activity and durability of Pt-based electrocatalysts.

关键词： Electrolytic reduction

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Strain-induced formation of a gradient nanostructured surface layer on an ultrahigh strength bearing steel

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Journal of Materials Science & Technology 2018年第9期34卷 1676-1684页

作者： K.zhang z.b.Wang Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of SciencesShenyang 110016 China University of Chinese Academy of Sciences Beijing 100049 China

In the present work, an ultrahigh strength bearing steel（AISI 52100） was subjected to surface mechanical rolling treatment（SMRT） at room temperature. Microstructural observations showed that martensitic laths, twins and cementite particles in the initial microstructure underwent distinct plastic strains and were gradually refined into nanostructures. Consequently, a gradient nanostructured（GNS） surface layer with a mean grain size of -24 nm at the top surface was obtained on the bearing steel, resulting in an increment of -20% in the surface hardness. Analyses based on microstructural evolution, phase constitution and in-depth hardness distribution revealed a mechanically induced formation mechanism of the GNS surface layer. The multiple surface severe plastic deformation under fine lubrication and cooling during SMRT contributed to the formation of a thick hardened surface layer on the bearing steel.

关键词： Gradient nanostructured Ultrahigh strength bearing steel Plastic deformation Martensite Surface mechanical rolling treatment

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A practical model for efficient anti-fatigue design and selection of metallic materials:Ⅰ.Model building and fatigue strength prediction

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Journal of Materials Science & Technology 2021年第11期70卷 233-249页

作者： R.Liu P.zhang z.J.zhang b.Wang z.F.zhang Laboratory of Fatigue and Fracture for Materials Shi-changxu Innovation Center for Advanced MaterialsInstitute of Metal ResearchChinese Academy of Sciences72 Wenhua RoadShenyang 110016China

The high cost and low efficiency of fatigue tests are bottleneck problem for the anti-fatigue design of metallic *** this problem,a theoretical fatigue model is proposed in this study,the possible applications have also been *** results would be introduced in two serial papers,in which the first paper focuses on the model building and the applications on fatigue strength prediction;the second paper put emphasis on the influencing factors of the model parameters and the applications on fatigue strength *** this first paper,a theoretical model is proposed considering both the strength and plastic restrictions of fatigue *** the model builds up a brief relationship among yield strength(Y),tensile strength(T)and fatigue strength(F),it is named as the Y-T-F *** the verification with fatigue strength data covering various kinds of metallic materials and loading conditions,this Y-T-F model exhibits both generality and *** the Y-T-F model,the efficient fatigue strength prediction could be conducted by brief linear fitting and calculation,just through yield strength,tensile strength and several known fatigue strength ***,through its deduced Y-F model,the analytical formula of fatigue strength continuously changing with materials strengthening can be obtained,as well as the maximum value of fatigue strength and corresponding critical yield *** summary,the Y-T-F model would be useful for reducing the fatigue tests,thus providing new possibilities on the efficient anti-fatigue design and selection of metallic materials.

关键词： Yield strength Tensile strength Plasticity Fatigue strength Anti-fatigue design

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Targeting Epac2 and GluA3-containing AMPARs:a novel therapeutic strategy for Alzheimer's disease

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Neural Regeneration Research 2025年第11期20卷 3223-3224页

作者： Tong zhang Martina Schmidt Department of Molecular Pharmacology Groningen Research Institute of PharmacyUniversity of GroningenGroningenThe Netherlands School of Pharmacy Tianjin Medical UniversityTianjinChina

Alzheimer's disease(AD)is a neurodegenerative disease that manifests progressive decline in memory and *** the early stage of AD,memory retrieval is impaired preceding memory acquisition and consolidation(Roy et al.,2016).Prior to the onset of symptoms,pathological amyloid-β(Aβ)plagues and tau protein tangles accumulate in extracellular and intracellular spaces,respectively,leading to *** these hallmark pathologies,Aβ is proposed to be the primary etiology by triggering a cascade of pathogenic events,including neuroinflammation,oxidative stress,tau hyperphosphorylation,synaptic/neuronal dysfunction,and neuronal death(zhang et al.,2023b).

关键词： Alzheimer impaired Aβ

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