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Superconducting joints using reacted multifilament MgB_(2)wires:A technology toward cryogen-free MRI magnets

Journal of Magnesium and Alloys 2024年第1期12卷 159-170页

作者： Dipak Patel Akiyoshi Matsumoto Hiroaki Kumakura Yuka Hara Toru Hara Minoru Maeda Hao Liang yusuke yamauchi Seyong Choi Jung Ho Kim Md Shahriar A.Hossain School of Mechanical and Mining Engineering The University of QueenslandSt LuciaQueensland 4072Australia National Institute for Materials Science(NIMS) 1-2-1 SengenTsukubaIbaraki 305-0047Japan Department of Electrical Engineering and Kangwon High Magnetic Field Center Institute of Quantum Convergence TechnologyKangwon National UniversityGangwon 24341Republic of Korea Australian Institute for Bioengineering and Nanotechnology(AIBN) The University of QueenslandSt LuciaQueensland 4072Australia Department of Materials Process Engineering Graduate School of EngineeringNagoya UniversityNagoyaAichi 464-8603Japan Institute for Superconducting and Electronic Materials Australian Institute for Innovative MaterialsUniversity of WollongongNorth WollongongNew South Wales 2500Australia

The development of superconducting joining technology for reacted magnesium diboride(MgB_(2))conductors remains a critical challenge for the advancement of cryogen-free MgB_(2)-based magnets for magnetic resonance imaging(MRI).Herein,the fabrication of superconducting joints using reacted carbon-doped multifilament MgB_(2)wires for MRI magnets is reported.To achieve successful superconducting joints,the powder-in-mold method was employed,which involved tuning the filament protection mechanism,the powder compaction pressure,and the heat treatment condition.The fabricated joints demonstrated clear superconducting-to-normal transitions in self-field,with effective magnetic field screening up to 0.5 T at 20 K.To evaluate the interface between one of the MgB_(2)filaments and the MgB_(2)bulk within the joint,serial sectioning was conducted for the first time in this type of superconducting joint.The serial sectioning revealed space formation at the interface,potentially caused by the volume shrinkage associated with the MgB_(2)formation or the combined effect of the volume shrinkage and the different thermal expansion coefficients of the MgB_(2)bulk,the filament,the mold,and the sealing material.These findings are expected to be pivotal in developing MgB_(2)superconducting joining technology for MRI magnet applications through interface engineering.

关键词： Mg B2 superconducting joint MgB_(2)conductor MRI applications Cryogen-free magnet Persistent-mode operation

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Porous Metal Nanocrystal Catalysts:Can Crystalline Porosity Enable Catalytic Selectivity?

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CCS Chemistry 2022年第6期4卷 1829-1842页

作者： Xiaowen Min Hao Lv yusuke yamauchi Ben Liu Key Laboratory of Green Chemistry and Technology of the Ministry of Education College of ChemistrySichuan UniversityChengdu 610064 Australian Institute for Bioengineering and Nanotechnology(AIBN) School of Chemical EngineeringThe University of QueenslandBrisbaneQLD 4072 JST-ERATO yamauchi Materials Space-Tectonics Project International Research Centre for Materials Nanoarchitechtonics(WPI-MANA)National Institute for Materials Science(NIMS)TsukubaIbaraki 305-0044

Catalytic selectivity is a central issue in the efficiency of catalytic processes.A large number of strategies have been developed to improve the catalytic selectivity of metal catalysts at the atomic and molecular levels,for instance,alloying secondary elements,fabricating metal-support interactions,and introducing surface ligands.Recently,macro/mesoscopic pores and cavities have been demonstrated as an alternative route to promote catalytic selectivity of metal nanocrystal catalysts.The promotion effects of continuous crystalline porosity include(1)more catalytically active sites that accelerate the favorable catalytic routes to targeted products,(2)confined spaces that increase the retention time of key intermediates and remarkably promote the selective catalysis toward desired products,and(3)an optimized electronic structure and coordination environment of active metal sites that tailor the reaction trends of selective catalysis toward desired products.In this minireview,we summarize recent advances in porosity-enabled catalytic selectivity of metal nanocrystal catalysts with focused discussions of CO_(2) reduction electrocatalysis and selective hydrogenation reactions.The mechanisms that allow for the continuous porosity that enables the catalytic selectivity of metal nanocrystal catalysts are discussed in detail.We end this minireview by proposing current challenges and offering future opportunities in this research field.

关键词： porous metal continuous crystalline porosity structural synergy confinement catalytic selectivity

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Metal−Organic Frameworks:A Robust Platform for Creating Nanoarchitectured Carbon Materials

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Accounts of Materials Research 2022年第4期3卷 426-438页

作者： Chaohai Wang Yiyuan Yao Jiansheng Li yusuke yamauchi Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse Key Laboratory of New Membrane MaterialsMinistry of Industry and Information TechnologySchool of Environmental and Biological EngineeringNanjing University of Science and TechnologyNanjing 210094People’s Republic of China Australian Institute for Bioengineering and Nanotechnology(AIBN) The University of QueenslandBrisbaneQueensland 4072Australia International Center for Materials Nanoarchitectonics(WPI-MANA) National Institute for Materials Science(NIMS)TsukubaIbaraki 305-0044Japan

CONSPECTUS:Nanoporous carbon(NPC)materials with various architectures have attracted considerable attention because of their distinctive properties and great application potential in environmental remediation,energy conversion and storage,advanced sensors,and other applications.Traditional methods for the synthesis of NPCs,for example,the pyrolysis of natural products or polymers,template-assisted synthesis,and using deep-eutectic solvents,always involve toxic precursors and complex procedures,which greatly hinder further applications.Therefore,it is highly desirable to explore simple and feasible ways to prepare NPCs.Furthermore,to improve the performance and extend the application fields of NPCs,efficient strategies should be developed to regulate the components at the atomic level and construct multidimensional architectures.

关键词： synthesis pyrolysis hinder

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Photo-enhanced rechargeable high-energy-density metal batteries for solar energy conversion and storage

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Nano Research Energy 2022年第1期1卷 22-42页

作者： Hairong Xue Hao Gong yusuke yamauchi Takayoshi Sasaki Renzhi Ma International Center for Materials Nanoarchitectonics(WPI-MANA) National Institute for Materials Science(NIMS)1-1 NamikiTsukubaIbaraki 305-0044Japan Department of Chemistry and Materials Science College of ScienceNanjing Forestry UniversityNanjing 210037China Australian Institute for Bioengineering and Nanotechnology(AIBN)and School of Chemical Engineering The University of QueenslandBrisbaneQueensland 4072Australia JST-ERATO yamauchi Materials Space-Tectonics Project National Institute for Materials Science(NIMS)1-1 NamikiTsukubaIbaraki 305-0044Japan

Solar energy is considered the most promising renewable energy source.Solar cells can harvest and convert solar energy into electrical energy,which needs to be stored as chemical energy,thereby realizing a balanced supply and demand for energy.As energy storage devices for this purpose,newly developed photo-enhanced rechargeable metal batteries,through the internal integration of photovoltaic technology and high-energy-density metal batteries in a single device,can simplify device configuration,lower costs,and reduce external energy loss.This review focuses on recent progress regarding the working principles,device architectures,and performances of various closed-type and open-type photo-enhanced rechargeable devices based on metal batteries,including Li/Zn-ion,Li-S,and Li/Zn-I_(2),and Li/Zn-O_(2)/air,Li-CO_(2),and Na-O_(2) batteries.In addition to provide a fundamental understanding of photo-enhanced rechargeable devices,key challenges and possible strategies are also discussed.Finally,some perspectives are provided for further enhancing the overall performance of the proposed devices.

关键词： Solar energy photo-electrochemistry rechargeable batteries metal batteries energy conversion and storage high energy density

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Recent progress in MgB_(2)superconducting joint technology

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镁合金学报(英文) 2023年第7期11卷 2217-2229页

作者： Hao Liang Dipak Patel Mahboobeh Shahbazi Andrzej Morawski Daniel Gajda Matt Rindfleisch Richard Taylor yusuke yamauchi Md Shahriar A.Hossain School of Mechanical and Mining Engineering The University of QueenslandSt LuciaQueensland 4072Australia QUT Centre for Materials Science and School of Chemistry and Physics Queensland University of TechnologyBrisbaneQueensland 4001Australia Institute of High Pressure Physics Polish Academy of Sciences(PAS)Sokolowska 29/37Warsaw 01-142Poland Institute of Low Temperature and Structure Research Polish Academy of Sciences(PAS)Okólna 2Wrocław 50-422Poland Hyper Tech Research Inc.539 Industrial Mile RdColumbusOhio 43228USA Applied Superconductivity Laboratory Queensland University of TechnologyBrisbaneQueensland 4001Australia Australian Institute for Bioengineering and Nanotechnology(AIBN) The University of QueenslandSt LuciaQueensland 4072Australia Department of Materials Process Engineering Graduate School of EngineeringNagoya UniversityFuro-choChikusa-kuNagoya 464-8603Japan The Commonwealth Scientific and Industrial Research Organisation(CSIRO) LindfieldNew South Wales 2070Australia

Magnesium diboride(MgB_(2))magnets have the potential to be the next-generation liquid-helium-free magnet for magnetic resonance imaging(MRI)application due to their relatively high superconducting transition temperature,high current density and low raw material cost compared with current commercial niobium-titanium(Nb-Ti)magnets.A typical superconducting magnet includes several coils.To produce an ultra-stable magnetic field for imaging in MRI,a superconducting electromagnet operating in a persistent mode is crucial.Superconducting coils of the electromagnet in MRI are short-circuited to operate in the persistent mode by connecting coils with superconducting joints.Per-sistent joints have been demonstrated for in-situ and ex-situ wires of both mono-and multi-filamentary structures,made predominantly by PIT techniques similar to those used in wire production.To realise further engagement of MgB_(2)in MRI applications,enhancing the performance of MgB_(2)superconducting joints is essential.This literature review summarises research and development on MgB_(2)superconducting joining technology.

关键词： MgB_(2) Superconducting joints Persistent-mode magnets MRI application Field-decay measurement

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Cobalt phthalocyanine-based conjugated polymer as efficient and exclusive electrocatalyst for CO_(2) reduction to ethanol

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Materials Reports(Energy) 2023年第1期3卷 100-106,I0004页

作者： Dong Jiang Ran Bu Wei Xia Yichen Hu Mengchen Zhou Enqing Gao Toru Asahi yusuke yamauchi Jing Tang School of Chemistry and Molecular Engineering Shanghai Key Laboratory of Green Chemistry and Chemical ProcessesEast China Normal UniversityShanghai200062China Department of Life Science&Medical Bioscience School of Advanced Science and EngineeringWaseda University2-2 Wakamatsu-choShinjukuTokyo 162-8480 Japan International Center for Materials Nanoarchitectonics(WPI-MANA) National Institute for Materials Science(NIMS)1-1 NamikiTsukuba305-0044IbarakiJapan Australian Institute for Bioengineering and Nanotechnology(AIBN) The University of QueenslandBrisbane4072QueenslandAustralia Institute of Eco-Chongming Shanghai202162China

Electrocatalytic conversion of carbon dioxide to high value-added chemicals is a promising method for solving the energy crisis and global warming.Electrochemical active metal-containing conjugated polymers have been widely studied for heterogeneous carbon dioxide reduction.In the present contribution,we designed and synthesized a stable cobalt phthalocyanine-based conjugated polymer,named CoPPc-TFPPy-CP,and also explored its electro-catalytic application in carbon dioxide reduction to liquid products in an aqueous solution.In the catalyst,cobalt phthalocyanine acts as building blocks connected with 1,3,6,8-tetrakis(4-formyl phenyl)pyrenes via imine-linkages,leading to mesoporous formation polymers with the pore size centered at 4.1nm.And the central co-balt atoms shifted to a higher oxidation state after condensation.With these chemical and structural natures,the catalyst displayed a remarkable electrocatalytic CO_(2) reduction performance with an ethanol Faradaic efficiency of 43.25%at-1.0V vs RHE.While at the same time,the electrochemical reduction process catalyzed by cobalt phthalocyanine produced only carbon monoxide and hydrogen.To the best of our knowledge,CoPPc-TFPPy-CP is the first example among organic polymers and metal-organic frameworks that produces ethanol from CO_(2) with a remarkable selectivity.

关键词： Cobalt phthalocyanine based conjugated polymer Carbon dioxide electroreduction Liquid products Ethanol

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Photovoltaic-powered supercapacitors for driving overall water splitting:A dual-modulated 3D architecture

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Carbon Energy 2022年第6期4卷 1262-1273页

作者： Zixu Sun Lijuan Sun See Wee Koh Junyu Ge Jipeng Fei Mengqi Yao Wei Hong Shude Liu yusuke yamauchi Hong Li Key Lab for Special Functional Materials of Ministry of Education National and Local Joint Engineering Research Center for High-Efficiency Display and Lighting TechnologyCollaborative Innovation Center of Nano Functional Materials and ApplicationsSchool of Materials Science and EngineeringHenan UniversityKaifengPeople's Republic of China School of Mechanical and Aerospace Engineering Nanyang Technological UniversitySingaporeSingapore School of Electronic and Information Zhongyuan University of TechnologyZhengzhouPeople's Republic of China JST-ERATO yamauchi Material Space-Tectonics Project National Institute for Materials Science(NIMS)TsukubaIbarakiJapan Australian Institute for Bioengineering and Nanotechnology(AIBN) The University of QueenslandBrisbaneQueenslandAustralia

Due to the growing demand for clean and renewable hydrogen fuel,there has been a surge of interest in electrocatalytic water-splitting devices driven by renewable energy sources.However,the feasibility of self-driven water splitting is limited by inefficient connections between functional modules,lack of highly active and stable electrocatalysts,and intermittent and unpredictable renewable energy supply.Herein,we construct a dualmodulated three-dimensional(3D)NiCo_(2)O_(4)@NiCo_(2)S_(4)(denoted as NCONCS)heterostructure deposited on nickel foam as a multifunctional electrode for electrocatalytic water splitting driven by photovoltaic-powered supercapacitors.Due to a stable 3D architecture configuration,abundant active sites,efficient charge transfer,and tuned interface properties,the NCONCS delivers a high specific capacity and rate performance for supercapacitors.A twoelectrode electrolyzer assembled with the NCONCS as both the anode and the cathode only requires a low cell voltage of 1.47 V to achieve a current density of 10 mA cm^(−2) in alkaline electrolyte,which outperforms the state-of-the-art bifunctional electrocatalysts.Theoretical calculations suggest that the generated heterointerfaces in NCONCS improve the surface binding capability of reaction intermediates while regulating the local electronic structures,which thus accelerates the reaction kinetics of water electrolysis.As a proof of concept,an integrated configuration comprising a two-electrode electrolyzer driven by two series-connected supercapacitors charged by a solar cell delivers a high product yield with superior durability.

关键词： hybrid energy systems interface engineering morphology control solar-to-hydrogen trifunctional electrode

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Size control and electronic manipulation of Ru catalyst over B,N codoped carbon network for high-performance hydrogen evolution reaction

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Nano Research 2023年第5期16卷 6212-6219页

作者： Shuai Xu Mang Niu Guowei Zhao Shujun Ming Xingyun Li Qilong Zhu Liang-Xin Ding Minjun Kim Asma A.Alothman Mohammed Sheikh Saleh Mushab yusuke yamauchi Institute of Materials for Energy and Environment Institute of Biochemical EngineeringCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071China Hubei Key Laboratory of Processing and Application of Catalytic materials Huanggang Normal UniversityHuanggang 438000China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of Sciences(CAS)Fuzhou 350002China Guangdong Provincial Key Lab of Green Chemical Product Technology School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510640China Australian Institute for Bioengineering and Nanotechnology(AIBN)and School of Chemical Engineering The University of QueenslandBrisbaneQueensland 4072Australia Department of Chemistry College of ScienceKing Saud UniversityRiyadh 11451Saudi Arabia

Exploring highly efficient Pt-free catalysts for hydrogen evolution reaction(HER)is of great importance for hydrogen(H2)production.Herein,a novel HER electrocatalyst having abundant ultra-small(2–3 nm)Ru electronically confined by a B,N codoped polar carbon surface(Ru/(B-N)-PC)was constructed.The Ru/(B-N)-PC catalyst exhibits a low overpotential of 15 mV at the current density of 10 mA·cm^(−2),a low Tafel slope of 22.6 mV·dec^(−1),superior durability,which outperforms the benchmark Pt/C catalyst.Both experimental characterizations and theory calculations suggest that an electron communication established between B,N co-doped carbon surface and ultra-small Ru nanoparticles with electrons transferred from N atoms to Ru and backtransferred from Ru to B atoms,which exerts a moderate electronic modification of Ru.This,in turn,affords a modest H adsorption energy and a lower H2O dissociation barrier,leading to the high-performance hydrogen evolution reaction.The work provides meaningful insight into the size control and electronic modulation of Ru catalyst for intrinsic HER activity improvement.

关键词： hydrogen evolution reaction Ru catalyst carbon support doping

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Spatial-controlled etching of coordination polymers

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Chinese Chemical Letters 2021年第2期32卷 635-641页

作者： Qi Dang Yucen Li Wei Zhang Yusuf Valentino Kaneti Ming Hu yusuke yamauchi School of Physics and Electronic Science.East China Normal University Shanghai 200241China International Center for Materials Nanoarchitectonics(MANA) National Institute for Materials Science(NIMS)Ibaraki 305-0044Japan School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology(A1BN) The University of QueenslandQueensland 4072Australia Department of Plant and Environmental New Resources Kyung Hee University.Gyeonggi-do 446-701South Korea

Nanoarchitectonics provide versatile opportunities for modifying the properties of coordination polymers(CP) other than molecular engineering.Spatial-controlled etching focuses on the controlled disassembly of the frameworks.The etching method provides an excellent opportunity for tailoring the properties and functions of the CPs.Here,we discuss the mechanism for controlled etching of the CPs and summarized the two main strategies utilized so far.Several examples are illustrated to demonstrate recent developments in this area.Moreover,advantages of the etched CPs are summarized in several important applications,including energy storage,catalysis and nanomedicine.

关键词： Coordination polymer Metal-organic frameworks Etching Hollow structure Sodium ion battery Catalysis Nanomedicine

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Superior electrocatalytic activity of mesoporous Au film templated from diblock copolymer micelles

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Nano Research 2016年第6期9卷 1752-1762页

作者： Cuiling Lil Bo Jiang Hungru Chen Masataka Imura Liwen Sang Victor Malgras Yoshio Bando Tansir Ahamad Saad M. Atshehri Satoshi Tominaka yusuke yamauchi World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA) National Institute for Materials Science (NIMS) I- 1 Namiki Tsukuba Ibaraki 305-0044 Japan Faculty of Science and Engineering Waseda University 3-4-10kubo Shinjuku Tokyo 169-8555 Japan Department of Chemistry University of Bath Bath BA2 7AY UK Department of Chemistry College of Science King Saud University Riyadh 11451 Saudi Arabia

Mesoporous Au films consisting of a network of interconnected Au ligaments around ultra-large pores were found to exhibit a promising electrocatalytic activity towards sluggish reactions. Mesoporous Au films with pore sizes up to 25 nm were successfully fabricated using a polymeric micelle approach. A superior catalytic activity of the mesoporous Au films towards methanol oxidation was confirmed, which was thoroughly analyzed and compared with that of other Au materials. An intrinsic investigation on the high catalytic activity revealed that the superior performance of the as-prepared mesoporous Au film was related to its unique atomic structures around the mesopores with well- crystallized facets and several step/kink sites on the Au surfaces. These findings showcase a strategic and feasible design for preparing highly active Au-based catalysts that could be used as promising candidates in electrocatalytic applications.

关键词： block copolymers mesoporous materials mesoporous metals gold electrocatalysts

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