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Experimental aspects of ^(14)N overtone RESPDOR solid-state NMR spectroscopy under MAS beyond 60 kHz

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Magnetic Resonance Letters 2024年第1期4卷 40-49页

作者： Yutaro Ogaeri yusuke Nishiyama JEOL Ltd. AkishimaTokyo196-8558Japan

Nitrogen-14(^(14)N)overtone(OT)spectroscopy under fast magic angle spinning(MAS)conditions(>60 kHz)has emerged as a powerful technique for observing correlations and distances between ^(14)N and ^(1)H,owing to the absence of the first-order quadrupolar broad*** addition,^(14)N^(OT) allows selective manipulation of ^(14)N nuclei for each *** extensive theoretical and experimental studies,the spin dynamics of ^(14)N^(OT) remains under *** this study,we conducted experimental investigations to assess the spin dynamics of ^(14)N^(OT) using the rotational-echo saturation-pulse double-resonance(RESPDOR)sequence,which monitors population transfer induced by a^(14)N^(OT) *** ^(14)N^(OT) spin dynamics is well represented by a model of a two-energy-level *** spin-1/2,the maximum excitation efficiency of ^(14)N^(OT) coherences of powdered solids,denoted by p,depends on the radiofrequency field(rf-field)strength due to orientation dependence of effective nutation fields even when pulse lengths are *** is also found that the p factor,contributing to the ^(14)N^(OT) spin dynamics,is nearly independent of the B0 ***,the filtering efficiency of RESPDOR experiments exhibits negligible dependence on B0 when the ^(14)N^(OT) pulse length is *** study also identifies the optimal experimental conditions for ^(14)N^(OT)/^(1)H RESPDOR correlation experiments.

关键词： ^(14)N Overtone RESPDOR ^(14)N/^(1)H correlation Solid-state NMR Fast MAS

Peculiar Concentration Dependence of H/D Exchange Reaction in 1-Butyl-3-methylimidazolium Tetrafluoroborate-D<sub>2</sub>O Mixtures

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Open Journal of Physical Chemistry 2011年第3期1卷 70-76页

作者： Hiroshi Abe Naohiro Hatano yusuke ima Souichi Ohta Akio Shimizu Yukihiro Yoshimura 不详

We have investigated the H/D exchange reaction between heavy water and an ionic liquid, 1-butyl-3-methyl-imidazolium tetrafluoroborate ([bmim][BF4]), throughout the whole concentration region as a function of D2O mol% at room temperature. We expected that the extent of the H/D reaction would increase linearly with increasing content of D2O, but the results show an extended N-shaped behavior having a small maximum at around 40 mol% and the reaction becomes very slow at a specific concentration around 80 mol%. We found that this non-linear concentration dependence correlates with the pD dependence of the solutions.

关键词： H/D Exchange Reaction pD NMR Ionic Liquid

Assessing efficacy of standard impregnation techniques on die-cast aluminum alloys using X-ray micro-CT

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China Foundry 2024年第3期21卷 276-286页

作者： Ajith Bandara Koichi Kan Katanaga yusuke Natsuto Soga Akifumi Koike Toru Aoki Hamamatsu TSC Chuo Hatsumei Institute322 lida-choMinami-kuHamamatsu435-0028Japan Graduate School of Medical Photonics ShizuokaUniversityJohoku 3-5-1HamamatsuShizuoka432-8561Japan ANSeeN Inc Johoku 3-5-1HamamatsuShizuoka432-8561Japan Research Institute of Electronics ShizuokaUniversityJohoku 3-5-1HamamatsuShizuoka432-8561Japan

Utilizing lightweight Al alloys in various industrial applications requires achieving precise pressure tightness and leak *** pressure impregnation(VPI)with thermosetting polymers is commonly used to address leakage defects in die-cast Al *** this study,the efficacy of the VPI technique in sealing alloy parts was investigated using a combination of nondestructive micro X-ray computed tomography(micro XCT)and a standard leak *** results demonstrate that the commonly used water leak test is insufficient for determining the sealing ***,micro XCT shows distinct advantages by enabling more comprehensive *** reveals the presence of a low atomic number impregnates sealant within casting defects,which has low grey contrast and allows for visualizing primary leakage paths in *** effective atomic number of impregnated resin is 6.75 and that of Al alloy is 13.69 by dual-energy X-ray *** research findings will contribute to enhancing the standard VPI process parameters and the properties of impregnating sealants to improve quality assurance for impregnation in industrial metals.

关键词： nondestructive testing Al alloy die-casting vacuum pressure impregnation micro X-ray computed tomography duel-energy X-ray CT

Comment on:Recurrence after spontaneous separation of epiretinal membrane in a young woman:a case report

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International Journal of Ophthalmology(English edition) 2024年第4期17卷 783-784页

作者： yusuke Kameda Yutaka Kaneko Karin Ishinabe Nichika Fukuoka Yotsuya-sanchome Ekimae Eye Clinic Tokyo 160-0004Japan Department of Ophthalmology and Visual Sciences Yamagata University Faculty of MedicineYamagata 990-9585Japan

Dear Editor,Herein,we provide a commentary on the recently published article by Zeng QZ and Yu WZ[1].This case report provides interesting novel insights into the recurrence of epiretinal membrane(ERM)following self-separation in a young *** addition to the study,we have been investigating spontaneous ERM release for many years and have recently published a related paper[2].

关键词： separation young release

Hyperacute experimental model of rat lung transplantation using a coronary shunt cannula

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World Journal of Transplantation 2024年第2期14卷 155-161页

作者： Munehisa Takata yusuke Tanaka Daisuke Saito Shuhei Yoshida Isao Matsumoto Department of Thoracic Surgery Kanazawa UniversityKanazawa 920-8641IshikawaJapan

BACKGROUND Lung transplantation is a well-established treatment of end-stage lung disease.A rodent model is an inexpensive way to collect biological data from a living model after lung ***,mastering the surgical technique takes time owing to the small organ *** To conduct rat lung transplantation using a shunt cannula(SC)or modified cannula(MC)and assess their *** Rat lung transplantation was performed in 11 animals in the SC group and 12 in the MC *** devised a method of rat lung transplantation using a coronary SC for coronary artery bypass surgery as an anastomosis of pulmonary arteri-ovenous vessels and *** same surgeon performed all surgical proce-dures in the donor and recipient rats without using a magnifying *** success rate of lung transplantation,operating time,and PaO2 values were com-pared after 2-h reperfusion after *** Ten and 12 lungs were successfully transplanted in the SC and MC groups,*** the SC group,one animal had cardiac arrest within 1 h after reperfusion owing to bleeding during pulmonary vein *** opera-ting time for the removal of the heart-lung block from the donor and preparation of the left lung graft was 26.8±2.3 and 25.7±1.3 min in the SC and MC groups,respectively(P=0.21).The time required for left lung transplantation in the recipients was 37.5±2.8 min and 35.9±1.4 min in the SC and MC groups,respectively(P=0.12).PaO2 values at 2 h after reperfusion were 456.2±25.5 and INTRODUCTION Lung transplantation is a well-established treatment of end-stage lung *** immune and non-immune mech-anisms in lung transplantation are highly complex,and post-transplant complications such as infections and primary and chronic lung allograft dysfunction must be reduced to improve ***,there is a need for immunological and pathophysiological analyses using animal lung transplantation *** rat lung transplantation model was f

关键词： Lung transplantation Rat Shunt cannula Modified cannula Reperfusion

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应对热电材料人工智能领域的大数据挑战

Science China Materials 2024年第4期67卷 1173-1182页

作者：贾雪 Alex Aziz yusuke Hashimoto 李昊 Advanced Institute for Materials Research(WPI-AIMR) Tohoku UniversitySendai 980-8577Japan Tohoku Forum for Creativity Tohoku UniversitySendai 980-8577Japan

人工智能的发展正在改变材料科学领域.然而,大规模材料数据集中存在错误数据以及利用机器学习预测与温度相关的性质时出现过拟合等挑战.本文以热电材料为例,首先采取一系列合理的方法删除问题数据,从Starrydata2数据库中获得包括7295种... 详细信息

人工智能的发展正在改变材料科学领域.然而,大规模材料数据集中存在错误数据以及利用机器学习预测与温度相关的性质时出现过拟合等挑战.本文以热电材料为例,首先采取一系列合理的方法删除问题数据,从Starrydata2数据库中获得包括7295种成分在不同温度下的92,291个数据.然后,提出了一种基于成分的交叉验证方法避免过拟合.进而,使用梯度提升决策树方法构建了机器学习模型,并获得了显著的R2.最后,使用该模型对Materials Project数据库中的材料进行评估,Ge2Te5As2和Ge3(Te3As)2表现出较高的zT值.理论计算得到n型和p型Ge2Te5As2的最大zT值为1.98和2.12,n型和p型Ge3(Te3As)2的最大zT值为0.58和0.74,表明它们是有潜力的热电材料.本工作提出了一个处理和克服材料科学中的人工智能大数据挑战的示例.

关键词：人工智能大数据机器学习过拟合热电材料材料数据数据库温度相关

Superconducting joints using reacted multifilament MgB_(2)wires:A technology toward cryogen-free MRI magnets

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Journal of Magnesium and Alloys 2024年第1期12卷 159-170页

作者： Dipak Patel Akiyoshi Matsumoto Hiroaki Kumakura Yuka Hara Toru Hara Minoru Maeda Hao Liang yusuke Yamauchi Seyong Choi Jung Ho Kim Md Shahriar A.Hossain School of Mechanical and Mining Engineering The University of QueenslandSt LuciaQueensland 4072Australia National Institute for Materials Science(NIMS) 1-2-1 SengenTsukubaIbaraki 305-0047Japan Department of Electrical Engineering and Kangwon High Magnetic Field Center Institute of Quantum Convergence TechnologyKangwon National UniversityGangwon 24341Republic of Korea Australian Institute for Bioengineering and Nanotechnology(AIBN) The University of QueenslandSt LuciaQueensland 4072Australia Department of Materials Process Engineering Graduate School of EngineeringNagoya UniversityNagoyaAichi 464-8603Japan Institute for Superconducting and Electronic Materials Australian Institute for Innovative MaterialsUniversity of WollongongNorth WollongongNew South Wales 2500Australia

The development of superconducting joining technology for reacted magnesium diboride(MgB_(2))conductors remains a critical challenge for the advancement of cryogen-free MgB_(2)-based magnets for magnetic resonance imaging(MRI).Herein,the fabrication of superconducting joints using reacted carbon-doped multifilament MgB_(2)wires for MRI magnets is *** achieve successful superconducting joints,the powder-in-mold method was employed,which involved tuning the filament protection mechanism,the powder compaction pressure,and the heat treatment *** fabricated joints demonstrated clear superconducting-to-normal transitions in self-field,with effective magnetic field screening up to 0.5 T at 20 *** evaluate the interface between one of the MgB_(2)filaments and the MgB_(2)bulk within the joint,serial sectioning was conducted for the first time in this type of superconducting *** serial sectioning revealed space formation at the interface,potentially caused by the volume shrinkage associated with the MgB_(2)formation or the combined effect of the volume shrinkage and the different thermal expansion coefficients of the MgB_(2)bulk,the filament,the mold,and the sealing *** findings are expected to be pivotal in developing MgB_(2)superconducting joining technology for MRI magnet applications through interface engineering.

关键词： Mg B2 superconducting joint MgB_(2)conductor MRI applications Cryogen-free magnet Persistent-mode operation

A dynamic database of solid-state electrolyte(DDSE)picturing all-solid-state batteries

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Nano Materials Science 2024年第2期6卷 256-262页

作者： Fangling Yang Egon Campos dos Santos Xue Jia Ryuhei Sato Kazuaki Kisu yusuke Hashimoto Shin-ichi Orimo Hao Li Advanced Institute for Materials Research(WPI-AIMR) Tohoku UniversitySendai980-8577Japan Key Laboratory of Radiation Physics and Technology Ministry of EducationCollege of PhysicsSichuan UniversityChengdu610065People's Republic of China Institute for Materials Research(IMR) Tohoku UniversitySendai980-8577Japan Tohoku Forum for Creativity Tohoku UniversitySendai980-8577Japan

All-solid-state batteries(ASSBs)are a class of safer and higher-energy-density materials compared to conventional devices,from which solid-state electrolytes(SSEs)are their essential *** date,investigations to search for high ion-conducting solid-state electrolytes have attracted broad ***,obtaining SSEs with high ionic conductivity is challenging due to the complex structural information and the less-explored structure-performance *** provide a solution to these challenges,developing a database containing typical SSEs from available experimental reports would be a new avenue to understand the structureperformance relationships and find out new design guidelines for reasonable ***,a dynamic experimental database containing>600 materials was developed in a wide range of temperatures(132.40–1261.60 K),including mono-and divalent cations(e.g.,Li^(+),Na^(+),K^(+),Ag^(+),Ca^(2+),Mg^(2+),and Zn^(2+))and various types of anions(e.g.,halide,hydride,sulfide,and oxide).Data-mining was conducted to explore the relationships among different variates(e.g.,transport ion,composition,activation energy,and conductivity).Overall,we expect that this database can provide essential guidelines for the design and development of high-performance SSEs in ASSB *** database is dynamically updated,which can be accessed via our open-source online system.

关键词： Solid-state electrolyte(SSE) All-solid-state battery(ASSB) Ionic conductivity Dynamic database Machine learning

应对热电材料人工智能领域的大数据挑战（英文）

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Science China Materials 2024年

作者：贾雪 Alex Aziz yusuke Hashimoto 李昊 Tohoku Forum for Creativity Tohoku University Advanced Institute for Materials Research (WPI-AIMR) Tohoku University

人工智能的发展正在改变材料科学领域.然而,大规模材料数据集中存在错误数据以及利用机器学习预测与温度相关的性质时出现过拟合等挑战.本文以热电材料为例,首先采取一系列合理的方法删除问题数据,从Starrydata2数据库中获得包括7295种...

人工智能的发展正在改变材料科学领域.然而,大规模材料数据集中存在错误数据以及利用机器学习预测与温度相关的性质时出现过拟合等挑战.本文以热电材料为例,首先采取一系列合理的方法删除问题数据,从Starrydata2数据库中获得包括7295种成分在不同温度下的92,291个数据.然后,提出了一种基于成分的交叉验证方法避免过拟合.进而,使用梯度提升决策树方法构建了机器学习模型,并获得了显著的R2.最后,使用该模型对Materials Project数据库中的材料进行评估,Ge2Te5As2和Ge3(Te3As)2表现出较高的zT值.理论计算得到n型和p型Ge2Te5As2的最大zT值为1.98和2.12, n型和p型Ge3(Te3As)2的最大zT值为0.58和0.74,表明它们是有潜力的热电材料.本工作提出了一个处理和克服材料科学中的人工智能大数据挑战的示例.

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