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Changes in filtration and capacitance properties of highly porous reservoir in underground gas storage:CT-based and geomechanical modeling

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第8期16卷 2982-2995页

作者： Valerii Khimulia Vladimir Karev yury Kovalenko Svyatoslav Barkov Ishlinsky Institute for Problems in Mechanics RAS Moscow119526Russia

The paper presents the results of comprehensive studies of filtration and capacitance properties of highly porous reservoir rocks of the aquifer of an underground gas storage *** geomechanical part of the research included studying the dependence of rock permeability on the stress-strain state in the vicinity of the wells,and physical modeling of the implementation of the method of increasing the permeability of the wellbore zone-the method of directional unloading of the *** digital part of the research included computed tomography(CT)-based computer analysis of the internal structure,pore space characteristics,and filtration properties before and after the *** to the results of physical modeling of deformation and filtration processes,it is found that the permeability of rocks before fracture depends on the stress-strain state insignificantly,and this influence is ***,when downhole pressure reaches 7-8 MPa,macrocracks in the rock begin to grow,accompanied by irreversible permeability ***,geodesic tortuosity and permeability values were obtained based on digital studies and numerical modeling.A weak degree of transversal anisotropy of the filtration properties of rocks was *** on the analysis of pore size distribution,pressure field and flow velocities,high homogeneity and connectivity of the rock pore space is *** absence of pronounced changes in pore space characteristics and pore permeability after non-uniform triaxial loading rocks was *** the basis of geometrical analysis of pore space,the reasons for weak permeability anisotropy were *** filtration-capacitance properties obtained from the digital analysis showed very good agreement with the results of field and laboratory *** physical modeling has confirmed the efficiency of application of the directional unloading method for the reservoir under *** necessary parameters of its application were calcu

关键词： Permeability anisotropy Reservoir porosity Rocks computed tomography(CT) Digital core analysis Filtration flow numerical modeling

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Polyelectrolyte Complexes between Hyperbranched and Linear Polysaccharides: Fucoidan/Chitosan

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Chinese Journal of Polymer Science 2024年第4期42卷 468-479页

作者： Ekaterina R.Gasilova Daria N.Poshina Aleksandra O.Sitnikova Natalia N.Saprykina yury A.Skorik Institute of Macromolecular Compounds of the Russian Academy of Sciences Bolshoi VO 31St.Petersburg199004Russian Federation

Polyelectrolyte complexes(PECs)of hyperbranched(HB)and linear polysaccharides are promising as more effective encapsulation agents compared to PECs formed by linear *** investigated the PECs between the HB anionic polysaccharide fucoidan(FUC)and the cationic linear polysaccharide chitosan(CS).The FUC had a molecular weight(MW)of 30×*** PECs were prepared in three solvents(water,0.01 and 0.1 mol/L acetic acid)with CS of MW of 15,110 and 170 kDa,and deacetylation degrees(DDA)of 70%and 97%.The structures of the PECs and the initial FUC were investigated by multi-angle static and dynamic light *** the FUC contained 18 wt%of—OSO3 groups and 5 wt%of uronic acid units,it was a“strong-weak”copolyanion,so the HB macromolecules of the FUC formed nanogel particles in 0.1 mol/L AcOH and open branched structures in water,as confirmed by the Kratky *** mixing the solutions of original components,the PEC structures underwent an equilibration period,the duration of which increased with the MW of *** the charge stoichiometry was approached,the PECs shrank;the fractal dimension approached unity,indicating the side-by-side packing of adjacent FUC branches with the help of *** aggregation in the vicinity of the charge compensation was hardly observed,as it occurred in a very narrow *** PEC content at theζ-potential inversion depended on solvents’pH and the DDA of *** the extreme case of core-shell PECs in 0.1 mol/L AcOH,obtained by mixing FUC nanogels with the solutions of high MW CS of 97%DDA,the protruding tails of CS formed a positively charged shell in the whole range of FUC content(10 wt%

关键词： Polyelectrolyte complexes Chitosan Hyperbranched fucoidan Light scattering

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Peculiarities of Ethylene Polymerization Reactions with Bis(imino)pyridyl Complexes of CoCl_(2) and FeCl_(2)

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Chinese Journal of Polymer Science 2024年第4期42卷 492-500页

作者： Laura A.Rishina yury V.Kissin Svetlana S.Lalayan Artem A.Antonov Vadim G.Krasheninnikov Alexander A.Gulin N.N.Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences4 Kosygin St.Moscow119991Russia Department of Chemistry and Chemical Biology RutgersThe State University of New Jersey123 Bevier Rd.PiscatawayNJ08854USA Boreskov Institute of Catalysis Russian Academy of Sciences5 Lavrentieva Prosp.Novosibirsk630090Russia

The article describes ethylene polymerization reactions with transition metal catalysts based on complexes of CoCl_(2) and FeCl_(2) with an N,N,N-tridentate ligand 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine. The complexes are converted into polymerization catalysts by reacting them either with polymethylalumoxane (MAO) or with a combination of Al(C2H5)2Cl and Mg(C4H9)2 at an [Al]:[Mg] ratio of ~3. Both MAO-activated complexes readily polymerize ethylene at 35 ℃ with the formation of linear, low molecular weight polymers with a narrow molecular weight distribution. The same complexes, when activated with the Al(C2H5)2Cl-Mg(C4H9)2 combination, form multi-center catalysts and generate polyethylenes with a broad molecular weight distribution.

关键词： Ethylene polymerization Bis(imino)pyridyl complexes of CoCl_(2)and FeCl_(2) Molecular-weight distribution Polymer chain structure

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Catalytic co-combustion of biomass and brown coal in a fluidized bed:Economic and environmental benefits

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Journal of Environmental Sciences 2024年第6期140卷 24-36页

作者： yury V.Dubinin Nikolay A.Yazykov Petr M.Yeletsky Roman B.Tabakaev Aleksandra I.Belyanovskaya Vadim A.Yakovlev Federal Research Center Boreskov Institute of Catalysis SB RAS Lavrentiev Ave.5Novosibirsk630090Russia University of Tyumen Volodarskogo str.6Tyumen625003Russia

The work is devoted to the study of combustion of brown coal,pine sawdust,and their mixtures in a fluidized bed of catalyst at 600-750℃.It is shown that an increase in the content of sawdust in a mixture with brown coal leads to an increase in the burnout degree of solid fuel from 94.4%to 99.9%,while the emission of greenhouse gases in the form of CO_(2)CO and NOxis reduced(CO_(2)from the biomass is not included in the balance).The high content of alkaline earth metal oxides(CaO and MgO)in the mineral part of brown coal,sawdust,and their mixtures eliminates the emission of sulfur oxides and the slagging of heat-exchange surfaces during the combustion in a fluidized bed of *** optimal temperature,when the highest burnout degree of the above fuels is achieved in the combustion is 750℃.It is also shown that the increase in temperature and the content of sawdust in the composition of the fuel mixtures has a positive effect on the economic and environmental process indicators.

关键词： Co-combustion Fluidized catalyst bed Biomass Coal Economic effect Environmental impact

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On the Proof of the Contradiction of Set Theory

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Advances in Pure Mathematics 2024年第3期14卷 139-159页

作者： yury M. Volin Mountain View USA

The article is devoted to proving the inconsistency of set theory arising from the existence of strange trees. All steps of the proof rely on common informal set-theoretic reasoning, but they take into account the prohibitions that were introduced into axiomatic set theories in order to overcome the difficulties encountered by the naive Cantor set theory. Therefore, in fact, the article is about proving the inconsistency of existing axiomatic set theories, in particular, the ZFC theory.

关键词： Set Theory Inconsistency Tree Strange Tree Through Way Almost through Way Isomorphism Almost Isomorphism Isomorphism Tree Place Plane Superposition of Trees on the Place Plane Disposition of Trees on the Place Plane

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肥皂性能的评定方法(一)

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中国洗涤用品工业 2016年第4期 65-70页

作者： yury yarovoy Albert J.Post 刘伟毅美国康涅狄格州特朗布尔联合利华研究所上海制皂有限公司

研究了全球肥皂厂家或研发实验室采用的评定方法,这些评定的目的是为了确保其满足生产标准,并最终保证消费者对他们购买到的肥皂产品感到满意。一般来说,评定方法包括分析化学检测(评定原材料和成品)、材料学法(评定产品结构)以及消费... 详细信息

研究了全球肥皂厂家或研发实验室采用的评定方法,这些评定的目的是为了确保其满足生产标准,并最终保证消费者对他们购买到的肥皂产品感到满意。一般来说,评定方法包括分析化学检测(评定原材料和成品)、材料学法(评定产品结构)以及消费者可见属性的直接测试(例如泡沫、湿皂触感和磨损率)。这些检测可在实验室中进行或通过消费者评估进行。

关键词：肥皂检测方法泡沫评定磨损率触感香料湿裂

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肥皂性能的评定方法(二)

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中国洗涤用品工业 2016年第6期 63-69页

作者： yury yarovoy Albert J.Post 刘伟毅(译) 张育新(校) 美国康涅狄格州特朗布尔联合利华研究所上海制皂有限公司

关键词：肥皂检测方法泡沫评定磨损率触感香料湿裂

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Apolipoprotein A-I binding protein-mediated neuroprotection in glaucomatous neuroinflammation and neurodegeneration

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Neural Regeneration Research 2025年第5期20卷 1414-1415页

作者： Sinwoo Hwang Seunghwan Choi Soo-Ho Choi Keun-Young Kim yury I.Miller Won-Kyu Ju Hamilton Glaucoma Center and Shiley Eye Institute The Viterbi Family Department of OphthalmologyUniversity of California San DiegoLa JollaCAUSA Department of Medicine University of California San DiegoLa JollaCAUSA National Center for Microscopy and Imaging Research Department of NeurosciencesUniversity of California San DiegoLa JollaCAUSA

Glaucoma is a multifactorial eye disorder that can cause vision loss and irreversible blindness,affecting individ uals aged 40 to 80 yea rs *** to the aging population,it is expected that the number of people affected by glaucoma will surpass 111 million by 2040 as the disease becomes more *** primarily contributes to optic nerve axon loss and the progressive degeneration of retinal ganglion cells (RGCs),subsequently leading to vision impairment.

关键词： irreversible pass primarily

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Monolithic integrated MXene supercapacitors may power future electronics

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National Science Review 2023年第3期10卷 54-55页

作者： yury Gogotsi A. J. Drexel Nanomaterials Institute and Department of Materials Science and EngineeringDrexel University

Electrolytic capacitors and batteries are the largest components in portable *** they be replaced by fully integrated devices capable of performing functions ranging from energy storage to AC line-filtering and providing power pulses for communication?Wearable,flexible,transparent and epidermal electronics,micro-robots,and Internet of Things devices,will all require compact energy storage solutions.

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The effect of growth conditions on the relationship between fine root and foliage biomass

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Journal of Forestry Research 2022年第5期33卷 1585-1591页

作者： yury Karpechko Anna Karpechko Andrej Tuyunen Forest Research Institute of the Karelian Research Centre of the Russian Academy of Sciences 11 Pushkinskaya St.PetrozavodskKareliaRussia 185910

This article examines the physiological relationships between fine roots and foliage, and how their biomass ratio correlates with changes in stand quality class. The biomass of fine roots ≤ 3 mm in diameter of spruce stands in the Republic of Karelia (Northwest Russia) was determined by the soil monolith method. Foliage biomass was calculated using a previously designed technique from the standing stock, average height and quality class of the stand. A relation between fine-root: foliage biomass ratio and stand quality class (representing soil fertility) has been established. The closest correlation between fine-root: foliage biomass ratio and stand quality based on soil fertility was for the 1-2 mm root fraction. Analysis of the water flux balance in the trees revealed a correlation between fine-root: foliage ratio and the ratio of the specific volume of transpiration by the stand to the specific volume of water uptake from the soil by roots. Theoretical explanations for the decrease in fine-root: foliage biomass ratios with increasing stand quality class are offered.

关键词： Fine-root biomass Foliage biomass Stand quality class Soil fertility

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