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Fischer-Tropsch Synthesis of the Promoted Co/ZSM-5 Hybrid Catalysts for the Production of Gasoline Range Hydrocarbons

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Modern Research in Catalysis 2014年第3期3卷 99-106页

作者： Suk-Hwan Kang Jae-Hong Ryu Jin-Ho Kim Hyo-Sik Kim Chan-Gi lee yun-jo lee Ki-Won Jun Petroleum Displacement Technology Research Center Korea Research Institute of Chemical Technology (KRICT) Yuseong Daejeon Korea Plant Engineering Center Institute for Advances Engineering (IAE) Yongin-si Korea

Fischer-Tropsch synthesis (FTS) reaction for the direct production of gasoline range hydrocarbons (C5-C9) from syngas was investigated on Ru, Pt, and La promoted Co/ZSM-5 (Si/Al = 25) catalysts. The hybrid catalysts were characterized by BET surface area, XRD, H2-TPR, NH3-TPD and XPS analyses. These physico-chemical properties were correlated with activity and selectivity of the catalysts. The promoted Co/ZSM-5 hybrid catalysts were found to be superior to the unpromoted Co/ZSM-5 catalyst in terms of better C5-C9 selectivity. Pt-Co/ZSM-5 exhibited the highest catalytic activity because of the small cobalt particle size.

关键词： Fischer-Tropsch Synthesis Cobalt Hybrid Catalyst Promoter Gasoline ZSM-5 Syngas

Stevens-johnson syndrome and concurrent hand foot syndrome during treatment with capecitabine:A case report

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World journal of Clinical Cases 2021年第17期9卷 4279-4284页

作者： Ha Rim Ahn Sang-Kyung lee Hyun jo Youn Seok-Kweon yun Il-Jae lee Division of Breast and Thyroid Surgery Department of SurgeryJeonbuk National UniversityJeonju 54907South Korea Research Institute of Clinical Medicine of Jeonbuk National University-Biomedical Research Institute of Jeonbuk National University Hospital Jeonju 54907South Korea Department of Dermatology Jeonbuk National University Medical SchoolJeonju 54907South Korea

BACKGROUND Capecitabine is used in combination with lapatinib as palliative treatment for human epidermal growth factor receptor 2-positive metastatic breast *** most frequently reported adverse events attributed to capecitabine include diarrhea,hyperbilirubinemia,and hand-foot syndrome(HFS).A number of cutaneous adverse events have been attributed to capecitabine,including Stevens-johnson syndrome(SJS)as a rare and potentially life-threatening mucocutaneous *** report the first case involving concurrent SJS and HFS after capecitabine and lapatinib *** SUMMARY A 70-year-old woman with a history of breast cancer treatment visited our hospital for evaluation of painful skin *** weeks earlier,she had been prescribed capecitabine plus lapatinib as treatment for metastatic breast *** subsequently developed worsening erythema and bullae on her palms and soles,as well as reddish macules on her back and chest *** evaluation of the chest wall lesions revealed extensive eosinophilic epidermal necrosis and separation of the epidermis from the *** capecitabine plus lapatinib treatment was discontinued immediately and treatment was started using systemic *** treatment resolved most lesions,although the lesions on her palms and soles required Vaseline gauze dressings,which resulted in ***,we determined that the patient had concurrent SJS and *** the dermatological problems resolved,the patient ultimately died because of multiple organ *** Oral capecitabine treatment carries a risk of both HFS and also life-threatening adverse cutaneous drug reactions,such as SJS.

关键词： Stevens-johnson syndrome Hand-Foot syndrome Palliative treatment Capecitabine Breast neoplasms Case report

joint member angle limits of composite beams and CFT square columns

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journal of Central South University 2013年第1期20卷 199-206页

作者： lee Seung-jo lee Kang-Guk Department of Architecture Chosun College of Science & Technology Research Center for Urban Affair Kyungil University

This work aims to understand the relationship between the member angle limit and the energy ratio for 24 test samples of composite beams and CFT square steel tube columns. This work also compares the formula applicability for member angle limit with the previous test result to provide the basic data for the design of composite beam-CFT column. The evaluation of the member angle limit was performed with concrete compressive strength (fC =22.16 MPa, 30.49 MPa), breadth-to-thickness ratio (B/t=25.0, 33.3, 43.5), and axial capacity ratio (N/N0=0, 0.3, 0.4, 0.5) as the main variables of the test samples. For the relationship between the member angle limit (Ru) and the energy ratio (ES/EC ), the test result shows that the energy ratio becomes lower as the axial capacity ratio and the breadth-to-thickness ratio increase. The energy ratio is lower for the Type B test sample compared with that of Types A and C. For the formula suggested by SATO, the test samples are distributed evenly for comparison between test values and the member angle limit; however, other formulas indicate a deviation. Specifically, for the comparison between R u,cal and R u (Test), Maeda's formula shows severe deviation.

关键词： square steel tube axial capacity ratio member angle limit breadth-to-thickness ratio

Comparison of biochemical characteristics between PAO and DPAO sludges

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journal of Environmental Sciences 2014年第6期26卷 1340-1347页

作者： Hansaem lee Zuwhan yun Research Institute for Environmental Technology and Sustainable Development Korea University Department of Environmental Engineering Korea University

A successful enhanced biological phosphorus removal （EBPR） was observed in both anaerobic- aerobic sequencing batch reactor （An-Ox SBR） to induce growth of phosphorus accumulating organism （PAO） and anaerobic-anoxic （An-Ax） SBR to induce growth of denitrifying PAO （DPAO）. Although the EBPR performance of An-Ox SBR was higher by 11.3% than that of An-Ax SBR, specific phosphorus release rates in the An-Ax SBR （22.8 ± 3.5 mg P/（g ***）） and the An-Ox SBR （22.4 ± 4.8 mg P/（g ***）） were similar. Specific phosphorus uptake rates under anoxic and aerobic conditions were 26.3 ± 4.8 mg P/（g ***）（An-Ax SBR） and 25.6 ± 2.8 mg P/（g ***）（An-Ox SBR）, respectively, which were also similar. In addition, an analysis of relationship of poly-β-hydroxyalkanoates （PHA） synthesized under anaerobic conditions with phosphorous release （Preleased/PHAsynthesized） and of PHA utilized under anoxic and aerobic conditions with phosphorous uptake （Puptaked/PHAutilized） verified that biological activities of EBPR per unit biomass between DPAO and PAO were similar. An analysis of the specific denitrification rate of DPAO showed that NO3-N can be denitrified at a rate that does not substantially differ from that of an ordinary denitrifier without additional consumption of organic carbon when the PHA stored inside the cell under anaerobic conditions is sufficiently secured.

关键词： denitrifying EBPR poly-β-hydroxyalkanoates specific phosphorus release rate specific phosphorus uptake rate

GPU-Driven Scalable Parser for OBJ Models

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journal of Computer Science & Technology 2018年第2期33卷 417-428页

作者： Sunghun jo yuna Jeong Sungkil lee Department of Software Sungkyunkwan University Suwon 16419 Korea

This paper presents a scalable parser framework using graphics processing units （GPUs） for massive text-based files. Specifically, our solution is designed to efficiently parse Wavefront OBJ models texts of which specify 3D geometries and their topology. Our work bases its scalability and efficiency on chunk-based processing. The entire parsing problem is subdivided into subproblems the chunk of which can be processed independently and merged seamlessly. The within-chunk processing is made highly parallel, leveraged by GPUs. Our approach thereby overcomes the bottlenecks of the existing OBJ parsers. Experiments performed to assess the performance of our system showed that our solutions significantly outperform the existing CPU-based solutions and GPU-based solutions as well.

关键词： 3D model Wavefront OBJ parser GPU

Loss of fragile histidine triad and amplification of 1p36.22 and 11p15.5 in primary gastric adenocarcinomas

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World journal of Gastroenterology 2012年第33期18卷 4522-4532页

作者： Ji-yun lee Department of Pathology College of Medicine Korea University Seoul 136-705 South Korea

AIM: To investigate the genomic copy number alterations that may harbor key driver genes in gastric tumorigenesis. METHODS: Using high-resolution array comparative genomic hybridization (CGH), we investigated the genomic alterations of 20 advanced primary gastric adenocarcinomas (seventeen tubular and three mucinous) of Chinese patients from the Jilin province. Ten matching adjacent normal regions from the same patients were also studied. RESULTS: The most frequent imbalances detected in these cancer samples were gains of 3q26.31-q27.2, 5p, 8q, 11p, 18p, 19q and 20q and losses of 3p, 4p,18q and 21q. The use of high-resolution array CGH increased the resolution and sensitivity of the observed genomic changes and identified focal genetic imbalances, which included 54 gains and 16 losses that were smaller than 1 Mb in size. The most interesting focal imbalances were the intergenic loss/homozygous deletion of the fragile histidine triad gene and the amplicons 11q13, 18q11.2 and 19q12, as well as the novel amplicons 1p36.22 and 11p15.5. CONCLUSION: These regions, especially the focal amplicons, may harbor key driver genes that will serve as biomarkers for either the diagnosis or the prognosis of gastric cancer, and therefore, a large-scale investigation is recommended.

关键词： Array comparative genomic hybridization Amplicon Gastric adenocarcinoma Oncogene Fragile histidine triad

Indolo[3,2,1-jk]carbazole-derived planar electron transport materials realizing high efficiency in green phosphorescent organic light-emitting diodes

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Science China Materials 2023年第11期66卷 4437-4444页

作者： Sejeong Um Unhyeok jo Jun Yeob lee School of Chemical Engineering Sungkyunkwan University 2066Seobu-roJangan-guSuwonGyeonggi16419Republic of Korea SKKU Advanced Institute of Nano Technology Sungkyunkwan University 2066Seobu-roJangan-guSuwonGyeonggi16419Republic of Korea SKKU Institute of Energy Science and Technology Sungkyunkwan University 2066Seobu-roJangan-guSuwonGyeonggi16419Republic of Korea

Two novel electron transporting materials(ETMs),2-(4,6-diphenyl-1,3,5-triazin-2-yl)indolo[3,2,1-jk]-carbazole(DPTrz-ICz)and 5,11-bis(4,6-diphenyl-1,3,5-triazin-2-yl)-2-phenylindolo[3,2,1-jk]carbazole(2DPTrz-ICz),were developed based on the indolo[3,2,1-jk]carbazole(ICz)core,combined with 2,4-diphenyl-1,3,5-triazine(DPTrz).The introduced ICz core in ETM exhibited enhanced intermolecular charge transport properties owing to its planar and rigid geometry and high triplet energy,demonstrating the potential of designing ***,2DPTrz-ICz,featuring high triplet energy of 2.84 eV,effectively prevented triplet exciton quenching and showed increased electron mobility owing to the activation of intermolecular hopping charge transfer facilitated by stacking *** two materials were utilized as ETMs in green phosphorescent organic light-emitting diodes.2DPTrz-ICz exhibited a superior external quantum efficiency of 21.5%,higher than that of the spirobifluorene-derived ETM.

关键词： electron transport layer indolocarbazole efficiency OLED

CXC chemokines and chemokine receptors in gastric cancer: From basic findings towards therapeutic targeting

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World journal of Gastroenterology 2014年第7期20卷 1681-1693页

作者： Hyo Jin lee Ik-Chan Song Hwan-Jung yun Deog-Yeon jo Samyong Kim Division of Hematology/Oncology Department of Internal MedicineSchool of Medicine Chungnam National University and Chungnam National University HospitalDaejeon 301-721South Korea Cancer Research Institute Chungnam National UniversityDaejeon 301-721South Korea Division of Hematology/Oncology Department of Internal MedicineChungnam National University HospitalDaejeon 301-721South Korea

Gastric cancer is the fourth most common cancer,and the second-highest cause of cancer-related deaths *** extensive research to identify novel diagnostic and therapeutic agents,patients with advanced gastric cancer suffer from a poor quality of life and poor prognosis,and treatment is dependent mainly on conventional cytotoxic *** improve the quality of life and survival of gastric cancer patients,a better understanding of the underlying molecular pathologies,and their application towards the development of novel targeted therapies,is urgently *** are a group of small proteins associated with cytoskeletal rearrangements,the directional migration of several cell types during development and physiology,and the host immune response via interactions with G-protein coupled *** is also growing evidence to suggest that chemokines not only play a role in the immune system,but are also involved in the development and progression of *** gastric cancer,CXC chemokines and chemokine receptors regulate the trafficking of cells in and out of the tumor *** chemokines and their receptors can also directly influence tumorigenesis by modulating tumor transformation,survival,growth,invasion and metastasis,as well as indirectly by regulating angiogenesis,and tumor-leukocyte *** this review,we will focus on the roles of CXC chemokines and their receptors in the development,progression,and metastasis of gastric tumors,and discuss their therapeutic potential for gastric cancer.

关键词： Chemokine Chemokine receptor Gastric neoplasm Therapeutic target

Flexural-wave-generation using a phononic crystal with a piezoelectric defect

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Applied Mathematics and Mechanics(English Edition) 2023年第8期44卷 1241-1262页

作者： S.H.jo D.lee Department of Mechanical Roboticsand Energy EngineeringDongguk UniversitySeoul 04620Republic of Korea Department of Mechanical Engineering Seoul National UniversitySeoul 08826Republic of Korea

This paper proposes a method to amplify the performance of a flexural-wave-generation system by utilizing the energy-localization characteristics of a phononic crystal(PnC)with a piezoelectric defect and an analytical approach that accelerates the predictions of such wave-generation *** proposed analytical model is based on the Euler-Bernoulli beam *** proposed analytical approach,inspired by the transfer matrix and S-parameter methods,is used to perform band-structure and time-harmonic analyses.A comparison of the results of the proposed approach with those of the finite element method validates the high predictive capability and time efficiency of the proposed model.A case study is explored;the results demonstrate an almost ten-fold amplification of the velocity amplitudes of flexural waves leaving at a defect-band frequency,compared with a system without the ***,design guidelines for piezoelectric-defect-introduced PnCs are provided by analyzing the changes in wave-generation performance that arise depending on the defect location.

关键词： phononic crystal(PnC) defect wave-generation fexural wave analytical model