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Facile synthesis of C_(3)N_(4)-supported metal catalysts for efficient CO_(2) photoreduction

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nano Research 2022年第1期15卷 551-556页

作者： yun-nan gong Bi-Zhu Shao Jian-Hua Mei Wei Yang Di-Chang Zhong Tong-Bu Lu Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and EngineeringSchool of Chemistry and Chemical EngineeringTianjin University of TechnologyTianjin 300384China Key Laboratory of Jiangxi University for Functional Material Chemistry College of Chemistry&Chemical EngineeringGannan Normal UniversityGanzhou 341000China

Facile synthesis of photocatalysts with highly dispersed metal centers is a high-priority target yet still a significant challenge.In this work,a series of Co-C_(3)N_(4) photocatalysts with different Co contents atomically dispersed on g-CaN4 have been prepared via one-step thermal treatment of cobalt-based metal-organic frameworks(MOFs)and urea in the air.Thanks to the highly dispersed and rich exposed Co sites,as well as good charge separation efficiency and abundant mesopores,the optimal 25-Co-C_(3)N_(4),in the absence of noble metal catalysts/sensitizers,exhibits excellent performance for photocatalytic C0_(2) reduction to CO under visible.light irradiation,with a high CO evolution rate of 394.4μmol·g^(-1)·h^(-1),over 80 times higher than that of pure g-C_(3)N_(4)(4.9μmol·g^(-1)·h^(-1)).In:addition,by this facile synthesis strategy,the atomically dispersed Fe and Mn anchoring on g-C_(3)N_(4)(Fe-C_(3)N_(4) and Mn-C_(3)N_(4))have been also obtained,indicating the reliability and universality of this strategy in synthesizing photocatalysts with highly dispersed metal centers.This work paves a new way to develop cost-effective photocatalysts for photocatalytic C0_(2) reduction.

关键词： metal-organic frameworks highly dispersed metal g-C_(3)N_(4) photocatalysts C02 reduction

An Exceptionally Stable Lanthanum-Carboxylate Metal-Organic Framework with Highly Selective Adsorption of Gas and Vapor

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An Exceptionally Stable Lanthanum-Carboxylate Metal-Organic ...

A Two-Fold Interpenetrating Porous Metal–Organic Framework with Large Solvent-Accessible Volume: Gas Sorption and Luminescent Properties

中国化学会第七届全国结构化学学术会议

作者： yun-nan gong Peng Xiong Key Laboratory of Jiangxi University for Functional Material Chemistry College of Chemistry & Chemical Engineering Gannan Normal University

The development of porous metal–organic frameworks(MOFs)that can retain structural integrity under harsh physical and chemical conditions is essential if they are considered as candidates for use in gas storage and separation,catalysis and energy conversion applications.Herein,a previously known lanthanum-carboxylate metal-organic framework of formula

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A Two-Fold Interpenetrating Porous Metal–Organic Framework ...

Complete response of a locally advanced pulmonary hepatoid adenocarcinoma patient to perioperative XELOX-containing chemoimmunotherapy

中国化学会第九届全国无机化学学术会议

作者： yun-nan gong Di-Chang Zhong Key Laboratory of Jiangxi University for Functional Material Chemistry College of Chemistry ＆ Chemical Engineering Gannan Normal University

Porous metal-organic frameworks（MOFs） have been given great attention not only due to their intriguing structures and diverse topologies, but also due to their potential applications in gas storage and separation,ion-exchange, catalysis, and molecular sensing.[1-3] Herein, we have successfully synthesized a new two-fold interpenetrating luminescent porous metal-organic framework with large solvent-accessible volume of 51% per unit cell volume. The compound exhibits gas sorption behaviors for N2, H2 and CO2 gases. Furthermore, it also shows guest-responsive luminescent changes toward different solvent molecules.

关键词： Metal-organic frameworks two-fold interpenetrating gas sorption molecular sensing

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Genes & Diseases 2024年第1期11卷 1-3页

作者： Kaiyan Chen Ying Yu Zhiyu Huang Lei gong yun Fan The Cancer Hospital of the University of Chinese Academy of Sciences(Zhejiang Cancer Hospital) HangzhouZhejiang 310022China Institute of Basic Medicine and Cancer(IBMC) Chinese Academy of SciencesHangzhouZhejiang 310022China Department of Thoracic Medical Oncology Zhejiang Cancer HospitalHangzhouZhejiang 310022China Department of Oncology The Second Clinical Medical College of Zhejiang Chinese Medical UniversityHangzhouZhejiang 310053China

With morphological features resembling hepatocellular carcinoma,hepatoid adenocarcinoma of the lung(HAL)is a rare and aggressive subtype of lung cancer with a 5-year survival of only 8%.1 Most HAL patients present increased serum alpha-fetoprotein(AFP)levels that are commonly related to poor prognosis.Most insights into HAL have come from case series or reports,and TP53 is frequently mutated in HAL.The heterogeneity of HAL complicates the diagnosis.With no established standard,the management of HAL is modeled on that of classical lung adenocarcinoma,although with dismal outcomes.2 Herein,we reported the effective management of a stage IIIb HAL patient with perioperative chemoimmunotherapy and curative-intent surgery.The patient remained disease-free and minimal residual disease(MRD)-negative for more than one year after surgery.

关键词： adenocarcinoma patient lung

Study on creep deformation and energy development of underground surrounding rock under four‐dimensional support

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Deep Underground Science and Engineering 2024年第1期3卷 25-38页

作者： Zhanguo Ma Junyu Sun Peng gong Pengfei Yan nan Cui Ruichong Zhang School of Mechanics and Civil Engineering China University of Mining and TechnologyXuzhouChina State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering China University of Mining and TechnologyXuzhouChina Department of Mining Engineering Colorado School of MinesGoldenUSA

There is an urgent need to develop optimal solutions for deformation control of deep high‐stress roadways,one of the critical problems in underground engineering.The previously proposed four‐dimensional support(hereinafter 4D support),as a new support technology,can set the roadway surrounding rock under three‐dimensional pressure in the new balanced structure,and prevent instability of surrounding rock in underground engineering.However,the influence of roadway depth and creep deformation on the surrounding rock supported by 4D support is still unknown.This study investigated the influence of roadway depth and creep deformation time on the instability of surrounding rock by analyzing the energy development.The elastic strain energy was analyzed using the program redeveloped in FLAC3D.The numerical simulation results indicate that the combined support mode of 4D roof supports and conventional side supports is highly applicable to the stability control of surrounding rock with a roadway depth exceeding 520 m.With the increase of roadway depth,4D support can effectively restrain the area and depth of plastic deformation in the surrounding rock.Further,4D support limits the accumulation range and rate of elastic strain energy as the creep deformation time increases.4D support can effectively reduce the plastic deformation of roadway surrounding rock and maintain the stability for a long deformation period of 6 months.As confirmed by in situ monitoring results,4D support is more effective for the long‐term stability control of surrounding rock than conventional support.

关键词： coal mines elastic strain energy four‐dimensional support large roadway depth long‐term stability control plastic deformation surrounding rock

Surface structural transformation of Ni2P@C electrocatalysts for overall alkaline water splitting

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Progress in Natural Science:Materials International 2024年第1期34卷 102-107页

作者： Kun Yang Xinjuan Liu Jun Xu yun gong Shuling Shen Jinchen Fan Xiaojie Zhang Yuhua Xue School of Materials and Chemistry University of Shanghai for Science and Technology National&Local Joint Engineering Research Center for Mineral Salt Deep Utilization Huaiyin Institute of Technology

Understanding the surface restructuring, including atomic rearrangement and chemical composition adjustments,is urgent to accelerate electrocatalytic reactions. Herein, we focus on the surface restructuring and active species for phosphide especially Ni2P during the water splitting process by combination of in-situ Raman and ex-situ X-ray photoelectron spectroscopy. Results confirm that NiOOH and NiOO* are formed during OER, while Niδ+-Hadactive sites are formed during HER. In situ-formed NiOOH/Ni2P@C and Niδ+/Ni2P@C show enhanced water splitting（1.514 V at 10 mA/cm2） and NO3RR(86% and 668 μmol h-1cm-2for NH3Faraday efficiency and yield)activities. In-depth investigation of the surface dynamic changes can provide guidance for establishing the relation of structure-electrocatalytic activity.

关键词： Dynamic surface restructuring Phase structural transition In-situ Raman spectra Ni_2P@C Overall water splitting

Universal paradigm of ternary metacomposites with tunable epsilon-negative and epsilon-near-zero response for perfect electromagnetic shielding

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Rare Metals 2024年第2期43卷 796-809页

作者： yun-Peng Qu yun-Lei Zhou Yang Luo Yao Liu Jun-Fei Ding Yan-Li Chen Xiu gong Jing-Liang Yang Qiong Peng Xiao-Si Qi College of Physics Guizhou UniversityGuiyang550025China Hangzhou Institute of Technology Xidian UniversityHangzhou311231China Department of Materials ETH Zurich8093ZurichSwitzerland Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials(Ministry of Education) Shandong UniversityJinan250061China

CaCu_(3)Ti_(4)O_(12)(CCTO)ceramic nanocomposites incorporating graphene–carbon black(GRCB)fillers were fabricated by spark plasma sintering process.The percolative effects of conductive GRCB fillers on dielectric response of GRCB/CCTO ternary metacomposites were systematically investigated.The weakly real permittivity(ε′)-negative response(ε′~−1×10^(2))was achieved which originated from weakly low-frequency plasmonic state of free carriers within constructed GRCB networks.With enhancing three-dimensional GRCB network,the plasma frequency of metacomposites increased while the damping factor decreased.Herein,theε′-negative values of metacomposites were tuned from−10^(2) to−10^(4) orders of magnitude andε′-near-zero(ENZ)frequencies from~142 to~340 MHz which substantially benefited from the moderate carrier concentration of GRCB dual fillers.The Drude model and equivalent circuit models were adopted to demonstrate dielectric and electrical characteristics.The obtained metacomposites show strong EM shielding effect along with enhanced plasmonic oscillation and even better achieving perfect EM shielding effect in ENZ media.This work achieves the tunableε′-negative andε′-near-zero response and more importantly clarifies its regulation mechanism in ceramic-based ternary metacomposites,which opens up the possibility of designing high-performance EM shielding materials based on metacomposites.

关键词： Metacomposites Ceramic matrix composites Negative permittivity Epsilon-near-zero Electromagnetic shielding

Bilayer Compounded Polytetrafluoroethylene Membrane for Enhanced Oil-Water Emulsion Separation

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Chinese Journal of Polymer Science 2024年第6期42卷 838-850页

作者： Yu-Liang Yang Tai-Ran Zhang Yan-Ting Han Shao-yun Guo Qin-gong Rong Jia-Bin Shen State Key Laboratory of Polymer Materials Engineering Polymer Research Institute of Sichuan UniversitySichuan Provincial Engineering Laboratory of Plastic/Rubber Complex Processing TechnologyChengdu610065China West China Hospital/West China School of Nursing Sichuan UniversityChengdu610041China Shandong Senrong New Materials Co. Ltd.Zibo256401China

In order to achieve efficient and durable oil-water emulsion separation,the membranes possessing high separation efficiency and mechanical strength attract extensive attention and are in great demand.In present study,a kind of polytetrafluoroethylene(PTFE)-based bilayer membrane was fabricated by electrospinning fibrous PTFE(fPTFE)on an expanded PTFE(ePTFE)substrate.The morphological observation revealed that the fibrous structure of the fPTFE layer could be tailored by controlling the formulation of spinning solution.The addition of appropriate polyoxyethylene(PEO)would make the fibers in the fPTFE layer finer and more uniform.As a result,the compounded membrane exhibited a small pore size of approximately 1.25µm and a substantial porosity nearing 80%.This led to super-hydrophobicity,characterized by a high water contact angle(WCA)of 149.8°,and facilitated rapid oil permeation.The water-in-oil emulsion separation experiment further confirmed that the compounded membrane not only had a high separation efficiency closing 100%,but such an outstanding separation capacity could be largely retained,either through multiple cycles of use or through strong acid(pH=1),strong alkali(pH=12),or high-temperature(100°C)treatment.Additionally,the mechanical behavior of the bilayer membrane was basically contributed by that of each layer in terms of their volume ratio.More significantly,the poor creep resistance of fPTFE layer was suppressed by compounding with ePTFE substrate.Hence,this study has laid the groundwork for a novel approach to create PTFE-based compounded membranes with exceptional overall characteristics,showing promise for applications in the realm of emulsion separation.

关键词： ePTFE Electrospinning membrane Bilayer compounding Emulsion separation

Improving iconic memory through contrast detection training with HOA-corrected vision

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Fundamental Research 2024年第1期4卷 95-102页

作者： Ling gong Junlei Zhao yun Dai Zili Wang Fang Hou Yudong Zhang Zhong-Lin Lu Jiawei Zhou State Key Laboratory of Ophthalmology Optometry and Vision ScienceEye HospitalSchool of Ophthalmology and OptometryWenzhou Medical UniversityWenzhou 325027China Institute of Optics and Electronics Chinese Academy of SciencesChengdu 610209China The Key Laboratory of Adaptive Optics Chinese Academy of SciencesChengdu 610209China Chengdu University of Traditional Chinese Medicine Chengdu 610075China Division of Arts and Sciences New York University ShanghaiShanghai 200126China Center for Neural Science Department of PsychologyNew York UniversityNew York 10003United States NYU-ECNU Institute of Brain and Cognitive Science at NYU Shanghai Shanghai 200062China

Iconic memory and short-term memory are not only crucial for perception and cognition,but also of great importance to mental health.Here,we first showed that both types of memory could be improved by improving limiting processes in visual processing through perceptual learning.Normal adults were trained in a contrast detection task for ten days,with their higher-order aberrations(HOA)corrected in real-time.We found that the training improved not only their contrast sensitivity function(CSF),but also their iconic memory and baseline information maintenance for short-term memory,and the relationship between memory and CSF improvements could be well-predicted by an observer model.These results suggest that training the limiting component of a cognitive task with visual perceptual learning could improve visual cognition.They may also provide an empirical foundation for new therapies to treat people with poor sensory memory.

关键词： Perceptual learning Iconic memory Higher-order aberrations Contrast sensitivity Short-term memory