检索结果-南通市图书馆

Extracellular vesicles-coupled miRNAs from oviduct and uterus modulate signaling pathways related to lipid metabolism and bovine early embryo development

在线全文

学校读者我要写书评

暂无评论

Journal of Animal Science and Biotechnology 2024年第4期15卷 1528-1549页

作者： Rosane Mazzarella Karina Canon‑Beltran yulia N.Cajas Meriem Hamdi Encina M.Gonzalez Juliano C.da Silveira Claudia L.v.Leal D.Rizos Department of Animal Reproduction INIA-CSICMadridSpain Department of Biochemistry and Molecular Biology Veterinary FacultyComplutense University of Madrid(UCM)MadridSpain Department Agrarian Production Technical University of MadridUPMMadridSpain Departamento de Ciencias Biologicas Universidad Tecnica Particular de LojaUTPLLojaEcuador Department of Anatomy and Embryology FV-UCMMadridSpain Department of veterinary Medicine FZEA-USPPirassunungaBrazil

Background Extracellular vesicles(Evs) present in oviductal(OF) and uterine fluid(UF) have been shown to enhance bovine embryo quality during in vitro culture by reducing lipid contents and modulating lipid metabolism-related genes(LMGs), while also influencing cell proliferation, suggesting their involvement on the regulation of different biological pathways. The regulation of signaling pathways related to cell differentiation, proliferation, and metabo-lism is crucial for early embryo development and can determine the success or failure of the pregnancy. Bioactive molecules within Evs in maternal reproductive fluids, such as micro RNAs(miRNAs), may contribute to this regulatory process as they modulate gene expression through post-transcriptional *** This study evaluated miRNA cargo in OF-Evs from the early luteal phase and UF-Evs from the mid-luteal phase, coinciding with embryo transit within oviduct and uterus in vivo, and its possible influence on LMGs and sign-aling pathways crucial for early embryo development. A total of 333 miRNAs were detected, with 11 exclusive to OF, 59 to UF, and 263 were common between both groups. From the 20 differentially expressed miRNAs, 19 up-regulated in UF-Evs(bta-miR-134, bta-miR-151-3p, bta-miR-155, bta-miR-188, bta-miR-181b, bta-miR-181d, bta-miR-224, bta-miR-23b-3p, bta-miR-24-3p, bta-miR-27a-3p, bta-miR-29a, bta-miR-324, bta-miR-326, bta-miR-345-3p, bta-miR-410, bta-miR-652, bta-miR-677, bta-miR-873 and bta-miR-708) and one(bta-miR-148b) in OF-Evs. These miRNAs were predicted to modulate several pathways such as Wnt, Hippo, MAPK, and lipid metabolism and degradation. Differ-ences in miRNAs found in OF-Evs from the early luteal phase and UF-Evs from mid-luteal phase may reflect differ-ent environments to meet the changing needs of the embryo. Additionally, miRNAs may be involved, particularly in the uterus, in the regulation of embryo lipid metabolism, immune system, and *** Our study su

关键词： Embryo-maternal interaction Epigenetic Exosomes Mammalian Preimplantation Reproductive fluids

Olefin Polymerization Behavior of Titanium(Iv) Complexes with Fluorinated and Non-fluorinated Aliphatic Phenoxyimine Ligands

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Polymer Science 2024年第1期42卷 52-62,I0007页

作者： vladislav A.Tuskaev Kasim F.Magomedov Svetlana Ch.Gagieva Dmitry A.Kurmaev yulia v.Nelyubina Evgenii K.Golubev Maria D.Evseeva viktor G.vasil'ev Galina G.Nikiforova Mikhail I.Buzin vyacheslav S.Bogdanov Boris M.Bulychev Department of Chemistry M.V.Lomonosov Moscow State UniversityMoscow 119992Russian Federation A.N.Nesmeyanov Institute of Organoelement Compounds Russian Academy of SciencesMoscow119991Russian Federation Enikolopov Institute of Synthetic Polymer Materials Russian Academy of SciencesMoscow 117393Russian Federation

A series of Ti(Ⅳ) dichloride and dialkoxide com plexes with phenoxyimine ligands containing fluorinated and nonfluorinated aliphatic imine fragments have been *** molecular structures of complexes 1 and 4 were established by single-crystal X-ray diffraction *** complexes adopt a distorted octahedral coordination structure around the titanium atom and two oxygen atoms are situated in trans position while two nitrogen atoms and two outgoing ligands(Cl or iPrO) are situated in cis *** of activators(MMAO-12 and combinations Et_nAICl_(3-n)+Bu_(2)Mg) and outgoing ligand(Cl or iPrO) nature on the catalytic activity and properties of the resulting polymers was *** Ti complexes,despite the nature of the outgoing ligands(Cl or iPrO) in the presence of Al/Mg activators,was found to display a high ethylene polymerization activity in the range 1600-3830 kg_(polymer)·mol_(Ti)^(-1)·h^(-1)·atm^(-1) with a viscosity average molecular weight(M_v) value in the range 1.1×10~6-7.1×10~6 Dalton(Da).The resulting UHMWPE can be processed by a solventless method into high-strength and high-modulus oriented *** rheological characteristics of a polymer melt have been *** absence of a cross-over point did not allow to compare the values of the molecular weight distribution of polymers obtained on fluorinated and non-fluorinated pre-catalysts,however,the estimation of the entanglement density is in good agreement with the mechanical characteristics of oriented film *** activation with methylalumoxane,the activity of the com plexes decreased very significantly;however,a polymer with a molecular weight of about 12 million Da was *** the process of ethylene/octene-1 copolymerization,fluorine-containing precatalysts showed a clear advantage over non-fluorinated analogues both in activity and in comonomer content.

关键词： FI catalysts Titanium(Iv) (Co)polymerization Al/Mg co-catalyst Ultra-high molecular weight polyethylene

Waxes in asphaltenes of crude oils and wax deposits

在线全文

学校读者我要写书评

暂无评论

Petroleum Science 2016年第4期13卷 737-745页

作者： yulia M.Ganeeva Tatiana N.Yusupova Gennady v.Romanov A.E. Arbuzov Institute of Organic and Physical Chemistry Kazan Scientific Center Russian Academy of Sciences Institute of Geology and Petroleum Technologies Kazan (Volga region) Federal University

Composition and molecular mass distribution of n-alkanes in asphaltenes of crude oils of different ages and in wax deposits formed in the borehole equipment were studied. In asphaltenes, n-alkanes from C12 to C60 were detected. The high molecular weight paraffins in asphaltenes would form a crystalline phase with a melting point of 80–90 ℃. The peculiarities of the redistribution of high molecular paraffin hydrocarbons between oil and the corresponding wax deposit were detected. In the oils, the high molecular weight paraffinic hydrocarbons C50–C60were found, which were not practically detected in the corresponding wax deposits.

关键词： Waxes Asphaltenes Hydrocarbon composition Crude oil Wax deposit

Growth of Micropropagated Solanum tuberosum *** under Artificial Solar Spectrum and Different Mono-and Polychromatic LED Lights

在线全文

学校读者我要写书评

暂无评论

Horticultural Plant Journal 2022年第2期8卷 205-214页

作者： Olga v.Grishchenko Eugeny P.Subbotin Irina v.Gafitskaya yulia v.vereshchagina Elena v.Burkovskaya yulia A.Khrolenko valeria P.Grigorchuk Olga v.Nakonechnaya victor P.Bulgakov Yuri N.Kulchin Federal Scientific Center of the East Asia Terrestrial Biodiversity Far Eastern Branch of the Russian Academy of SciencesVladivostok 690022Russia Institute of Automation and Control Processes Far Eastern Branch of the Russian Academy of SciencesVladivostok 690041Russia

In agriculture,LED light sources have increasingly replaced the standard luminescent lamps and have acquired an important role in plant *** studied the effect of different light sources such as narrow-band LEDs(bright blue,blue,green,yellow,deep red,and red)and wide-band LEDs(cold white,white,warm white,full spectrum,and an artificial solar spectrum sun box constructed by us)on development of potato plantlets in *** luminescent lamps were used as a *** light intensity of 49μmol·m^(-2)·s^(-1)was provided in all light *** showed that the long-wave narrow-band light treatments were inapplicable for potato micropropagation,because plantlets were weak with small leaves,inhibited roots,and significantly elongated *** lights provided growth of shortened plantlets with large leaves,well-growing roots,and abundant green *** chlorophyll content was lower under blue and bright blue light and was at the same level in the remained *** differences in the stomatal apparatus development were observed depending on the light *** differences were not always reflected in the plantlet phenotype:e.g.,plantlets under blue and bright blue lights showed no differences in any characteristics except stomatal density and size of stomatal guard *** found no significant effect of blue light portion in the white lights and full spectrum on plantlet *** artificial solar spectrum sun box was the most suitable for potato micropropagation,because it supported the development of plantlets with good fitness,uniform internodes length,abundant roots and green mass accumulation.

关键词： Solanum tuberosum LED Artificial solar light Growth Micropropagation

Expansion of Juniperus sibirica *** a response to climate change and associated effect on mountain tundra vegetation in the Northern Urals

在线全文

学校读者我要写书评

暂无评论

Journal of Mountain Science 2020年第10期17卷 2339-2353页

作者： Andrey A.GRIGORIEv yulia v.SHALAUMOva Olga v.EROKHINA Svetlana Yu.SOKOvNINA Elizaveta I.vaTOLINA Martin WILMKING Institute of Plant and Animal Ecology UB RAS Laboratory of Geoinformation TechnologyEkaterinburgRussia Institute of Industrial Ecology UB RAS Laboratory of Mathematical Modeling in Ecology and MedicineEkaterinburgRussia Institute of Plant and Animal Ecology UB RAS Laboratory of Vegetation and Mycobiota BiodiversityEkaterinburgRussia Institute of Plant and Animal Ecology UB RAS Laboratory of Dynamics of Arctic EcosystemsLabytnangiRussia Department of Forest Taxation and Forest Management Institute of Forest and Nature ManagementUral state Forest Engineering UniversityEkaterinburgRussia Institute for Botany and Landscape Ecology Greifswald UniversityGreifswaldGermany

Shrub expansion into arctic and alpine tundra is one of the prominent vegetation changes currently *** studied the expansion of shrub vegetation into high elevation tundra in the Kvarkush Range of the Northern Ural mountains,*** structure analysis of the dominant shrub Juniperus sibirica *** to support ongoing upslope advance of shrubs,a process particularly active in the second half of the 20 th *** found a close connection between the expansion of shrub vegetation and the general change in climatic conditions of the cold season(months with mean airtemperature below 0°Сfrom November to March).In general,the greatest influence on the distribution of *** is exerted by the climate conditions of the beginning(November-January)and the end(March)of the cold *** increasing elevation,the correlation coefficients between the establishment of *** shrubs and the precipitation of the beginning of the cold season increased,and reached maximum values at the top elevation level of the study ***,the upwards shift of *** into typical mountain tundra does not lead to changes in the ecological structure of vegetation at this stage,but simply a decrease in the area of mountain tundra.

关键词： Juniperus sibirica Expansion Tundra vegetation Plant communities Climate changes Northern Ural mountains

Experimental and ab initio study of Ba_(2)Na_(3)(B_(3)O_(6))_(2)F stability in the pressure range of 0–10 GPa

在线全文

学校读者我要写书评

暂无评论

International Journal of Minerals,Metallurgy and Materials 2023年第9期30卷 1846-1854页

作者： Nursultan E.Sagatov Tatyana B.Bekker yulia G.vinogradova Alexey v.Davydov Ivan v.Podborodnikov Konstantin D.Litasov Sobolev Institute of Geology and Mineralogy Siberian Branch of Russian Academy of SciencesNovosibirsk 630090Russia Department of Geology and Geophysics Novosibirsk State UniversityNovosibirsk 630090Russia Research and Development Department Novosibirsk State University of ArchitectureDesign and Arts(NSUADA)Novosibirsk 630099Russia vereshchagin Institute for High Pressure Physics Russian Academy of SciencesTroitsk 108840Russia Fersman Mineralogical Museum Russian Academy of SciencesMoscow 119071Russia

Both numerical and experimental studies of the stability and electronic properties of barium–sodium metaborate Ba_(2)Na_(3)(B_(3)O_(6))_(2)F(P63/m) at pressures up to 10 GPa have been carried out. Electronic-structure calculations with HSE06 hybrid functional showed that Ba_(2)Na_(3)(B_(3)O_(6))_(2)F has an indirect band gap of 6.289 ev. A numerical study revealed the decomposition of Ba_(2)Na_(3)(B_(3)O_(6))_(2)F into the BaB_(2)O_(4),Na BO_(2), and NaF phases above 3.4 GPa at 300 K. Subsequent high-pressure high-temperature experiments performed using ‘Discoverer-1500’DIA-type apparatus at pressures of 3 and 6 GPa and temperature of 1173 K confirmed the stability of Ba_(2)Na_(3)(B_(3)O_(6))_(2)F at 3 GPa and its decomposition into BaB_(2)O_(4), NaBO_(2), and NaF at 6 GPa, which was verified by energy-dispersive X-ray analysis and Raman spectroscopy. The observed Raman bands of the Ba_(2)Na_(3)(B_(3)O_(6))_(2)F phase were assigned by comparing the experimental and calculated spectra. The experimental Raman spectra of decomposition reaction products obtained at 6 GPa suggest the origin of a new high-pressure modification of barium metaborate BaB_(2)O_(4).

关键词： density functional theory phase stability borate high pressure Raman spectroscopy

, Optimization Studies on Synthesis of TKX-50

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Chemistry 2017年第1期35卷 98-102页

作者： yulia D. Golenko Maxim A. Topchiy Andrey F. Asachenko Mikhail S. Nechaev Dmitriy v. Pleshakov A. v. Topchiev Institute of Petrochemical Synthesis Russian Academy of Sciences Moscow 119991 Russian Federation Mendeleyev University Miusskaya sq. 9 Moscow 125047 Russian Federation

A systematic study of TKX-50 and ABTOX synthesis using both Klap6tke and Tselinskii modified procedures is described. The influence of temperature, moisture, acid amount and nature on the most critical synthesis step - diazidoglyoxime cyclization is shown. Experimental results show that presence of moisture in reaction mixture leads to product yield decreasing. The reaction temperature is another key parameter affecting product yield. High reaction temperature shows negative influence on the product yield in Klap6tke method. In Tselinskii procedure the yield of product grows with the reaction temperature increasing. For Klap6tke one-pot method, combination of N-methyl-2-pyrrolidone with 1,4-dioxane is the best solvent, whereas Tselinskii one-pot procedure gives high yield of product when combination of toluene with 0.5 equiv, of 1,8-diazabicyclo[5.4.0]undec-7-ene （DBU） is used. Us- ing optimized conditions one-pot five-step synthesis of TKX-50 starting from glyoxime is successfully performed and scaled up to 50 g.

关键词： TKX-50 ABTOX energetic salts tetrazoles solvent effects

Determination of Iron in Water Solution by Time-Resolved Femtosecond Laser-Induced Breakdown Spectroscopy

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Plasma Science and Technology 2015年第11期17卷 975-978页

作者： Sergey S.GOLIK Alexey A.ILYIN Michael Yu.BABIY yulia S.BIRYUKOva vladimir v.LISITSA Oleg A.BUKIN Far Eastern Federal University Institute of Automation and Control Processes Far Eastern BranchRussian Academy of Sciences

The influence of the energy of femtosecond laser pulses on the intensity of Fe I （371.99 nm） emission line and the continuous spectrum of the plasma generated on the surface of Fe^3＋ water solution by a Ti： sapphire laser radiation with pulse duration 〈45 fs and energies up to 7 mJ is determined. A calibration curve was obtained for Fe3＋ concentration range from 0.5 g/L to the limit of detection in water solution, and its saturation was detected for concentrations above 0.25 g/L, which is ascribed to self-absorption. The 3σ- limit of detection obtained for Fe in water solution is 2.6 mg/L in the case of 7 mJ laser pulse energy. It is found that an increase of laser pulse energy insignificantly affects on LOD in the time-resolved LIBS and leads to a slight improvement of the limit of detection.

关键词： femtosecond laser-induced breakdown spectroscopy LIBS femtosecond plasma iron analysis of water atomic emission spectroscopy limit of detection

Synthesis of ferromagnetic La1-xSrxMnO3 nanoparticles by precipitation from diethylene glycol solution and their properties

在线全文

学校读者我要写书评

暂无评论

Journal of Advanced Ceramics 2016年第3期5卷 197-203页

作者： yulia SHLAPA Sergii SOLOPAN Oleksandr YELENICH volodymyr TRACHEvSKII Anatolii BELOUS v.I.vernadsky Institute of General and Inorganic Chemistry NAS of Ukraine32/34 Palladina Avenue 03680 Kyiv 142 Ukraine Technical Center NAS of Ukraine

La1−x Sr x MnO3 nanoparticles were synthesized by precipitation from diethylene glycol solution. Features of synthesis were studied using 1Н, 13С, 139La... 详细信息

La1−x Sr x MnO3 nanoparticles were synthesized by precipitation from diethylene glycol solution. Features of synthesis were studied using 1Н, 13С, 139La nuclear magnetic resonance (NMR) investigations. The obtained results showed that the complexation reaction between diethylene glycol and metal cations takes place during the synthesis. These complexes decomposed at 200 °C and an amorphous precursor (La,Sr)MnO3 was formed. According to X-ray results, the crystallization of the perovskite structure began at 600 °C and finished at 800 °C. Microstructural studies showed that obtained nanoparticles are weakly agglomerated and have small sizes. Based on these nanoparticles, magnetic fluid was prepared which was effectively heated under an alternating magnetic field.

关键词： manganite perovskite precipitation complexation reaction diethylene glycol nuclear magnetic resonance (NMR)