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Activating Inert Sites in Cobalt Silicate Hydroxides for Oxygen Evolution through Atomically Doping

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Energy & Environmental Materials 2022年第2期5卷 655-661页

作者： Jiexin Zhu Lixue Xia Wenxuan Yang Ruohan Yu Wei Zhang Wen Luo yuhang dai Wei Wei Liang Zhou Yan Zhao Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China International School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200China

Metal silicate hydroxides have been recognized as efficient oxygen evolution reaction(OER)electrocatalysts,yet tailoring of their intrinsic activity remains ***,Fe had been incorporated into cobalt silicate hydroxide nanosheets and the resulted material achieves a competitive OER catalytic *** is found that the doping state obviously affects the electrical transport ***,highly dispersed Fe atoms(low-concentration Fe doping)trigger slight electron transfer to Co atoms while serried Fe(highconcentration Fe doping)attract vast *** introducing 6 at.%Fe doping,partial relatively inert Co sites are activated by atomically dispersed Fe,bearing an optimal metal 3d electronic occupation and adsorption capacity to oxygen *** introduced Co-O-Fe unit trigger the p-donation effect and decrease the number of electrons in p*-antibonding orbitals,which enhance the Fe-O covalency and the structural *** a result,the sample delivers a low overpotential of 293 mV to achieve a current density of 10 mA cm^(-2).This work clarifies the superiority of atomically dispersed doping state,which is of fundamental interest to the design of doped catalyst.

关键词： atomically doping electrochemistry electron transfer metal silicate hydroxides oxygen evolution

Litterfall seasonality and adaptive strategies of tropical and subtropical evergreen forests in China

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Journal of Plant Ecology 2022年第2期15卷 320-334页

作者： yuhang dai Fanxi Gong Xueqin Yang Xiuzhi Chen Yongxian Su Liyang Liu Jianping Wu Xiaodong Liu Qingling Sun College of Forestry and Landscape Architecture South China Agricultural UniversityGuangzhou 510630China Guangdong Province Key Laboratory for Climate Change and Natural Disaster Studies School of Atmospheric SciencesSun Yat-sen University&Southern Marine Science and Engineering Guangdong LaboratoryZhuhai 519082China College of Earth Sciences Chengdu University of TechnologyChengdu 610000China Key Lab of Guangdong for Utilization of Remote Sensing and Geographical Information System Guangdong Open Laboratory of Geospatial Information Technology and ApplicationGuangzhou Institute of GeographyGuangdong Academy of SciencesGuangzhou 510070China

Tropical and subtropical evergreen broad-leaved forests(EBFs)and needle-leaved forests(ENFs)in China exhibit complex leaf shedding strategies in responses to soil water availability,vapor pressure deficits(VPDs)and sunlight ***,the seasonal variations and triggers of litterfall differ significantly in tropical/subtropical forests,and there are still many ***,we aim to explore the distinct climatic factors of seasonal litterfall in a climate–phenology correlation *** collected seasonal litterfall data from 85 sites across tropical/subtropical China and used linear correlation coefficients between sunlight and rainfall to partition synchronous/asynchronous *** phase analysis and structural equation model analysis were conducted to model the climatic triggers of tropical *** indicated two types of tropical litterfall phenology under two types of *** synchronous climates,where seasonal sunlight and rainfall are positively correlated,the litterfall peak of the unimodal phenology and the first litterfall peak of the bimodal phenology both happen at the end of dry *** second litterfall peak of the bimodal phenology occurs at the end of rainy season due to water *** asynchronous climates,where seasonal sunlight and rainfall are negatively correlated,VPD shows consistent seasonal variations with incoming *** leaf senescence is accelerated at the end of dry season by higher VPD;while soil water deficit is in anti-phase with sunlight and mainly controls the second litterfall peak of the bimodal phenology in *** findings provide an important reference for modeling tropical phenology in Earth system models.

关键词： tropical/subtropical forests phenology leaf shedding strategy litterfall water stress rejuvenation

Nanodiamond-Assisted High Performance Lithium and Sodium Ions Co-Storage

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Energy & Environmental Materials 2024年第6期7卷 94-105页

作者： Xiaochen Sun Xuan Gao Chang Su Wei Cheng Nan Gao Xin Zhang Mengmeng Gong Haobo Dong yuhang dai Guanjie He Hongdong Li State Key Lab of Superhard Materials College of PhysicsJilin UniversityChangchun130012 China Christopher Ingold Laboratory Department of ChemistryUniversity College London20 Gordon StreetLondonWC1H 0AJ UK Nuffield College University of OxfordNew RoadOxford OX11NFUK

While lithium resources are scarce for high energy-dense lithium-ion batteries(LIBs),sodium-ion batteries(SIBs),serving as an alternative,inherently suffer from low capacity and the high-cost use of non-graphite *** Li-and Na-ions within a single battery system is expected to mitigate the shortcomings of both systems while leveraging their respective *** this study,we developed and assembled a nanodiamonds(NDs)-assisted co-Li/Na-ion battery(ND–LSIB).This innovative battery system comprised a commercial graphite anode,an ND-modified polypropylene(DPP)separator,a hybrid lithium/sodium-based electrolyte,and a *** is theoretically and experimentally demonstrated that the ND/Li co-insertion can serve as an ion-drill opening graphite layers and reconstructing graphite anodes into few-layered graphene with expanding interlayer space,achieving highly efficient Li/Na storage and the theoretical maximum of LiC_(6)for Li storage in *** addition,ND is helpful for creating a LiF-/NaF-rich hybrid solid electrolyte interface with improved ionic mobility,mechanical strength,and ***,ND–LSIBs have higher specific capacities~1.4 times the theoretical value of LIBs and show long-term cycling *** study proposes and realizes the concept of Li/Na co-storage in one ion battery with compatible high-performance,cost-effectiveness,and industrial prospects.

关键词： battery lithium electrolyte

Interface-induced polymerization strategy for constructing titanium dioxide embedded carbon porous framework with enhanced chemical immobilization towards lithium polysulfides

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Nano Research 2024年第3期17卷 1473-1481页

作者： Yue Ouyang Xiaoxiao Li Jiexin Zhu Wei Zong yuhang dai Xuan Gao Wei Zhang Shengyuan Yang Roohollah Bagherzadeh Feili Lai Yue-E Miao Tianxi Liu State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringDonghua University2999 North Renmin RoadShanghai 201620China The Key Laboratory of Synthetic and Biological Colloids Ministry of EducationSchool of Chemical and Material EngineeringJiangnan UniversityWuxi 214122China Advanced Fibrous Materials LAB Institute for Advanced Textile Materials and Technologies(ATMT)School of Advanced Materials and ProcessesAmirkabir University of TechnologyTehran 15914Iran Christopher Ingold Laboratory Department of ChemistryUniversity College London20 Gordon StreetLondon WC1H 0AJUK Department of Chemistry KU LeuvenCelestijnenlaan 200FLeuven 3001Belgium

The shuttle effect induced by soluble lithium polysulfides(LiPSs)is known as one of the crucial issues that limit the practical applications of lithium-sulfur(Li-S)***,a titanium dioxide nanoparticle embedded in nitrogen-doped porous carbon nanofiber(TiO_(2)@NCNF)composite is constructed via an interface-induced polymerization strategy to serve as an ideal sulfur *** the protection of the nanofiber walls,the uniformly dispersed TiO_(2) nanocrystalline can act as capturing centers to constantly immobilize LiPSs towards durable sulfur ***,the mesoporous microstructure in the fibrous framework endows the TiO_(2)@NCNF host with strong physical reservation for sulfur and LiPSs,sufficient pathways for electron/ion transfer,and excellent endurance for volume *** expected,the sulfur-loaded TiO_(2)@NCNF composite electrode presents a fabulous rate performance and long cycle lifespan(capacity fading rate of 0.062%per cycle over 500 cycles)at 2.0 ***,the assembled Li-S batteries harvest superb areal capacity and cycling stability even under high sulfur loading and lean electrolyte conditions.

关键词： interface-induced polymerization electrospun porous nanofibers lithium-sulfur(Li-S)batteries high sulfur loading lithium polysulfides(LiPSs)immobilization

From bibliometric analysis: 3D printing design strategies and battery applications with a focus on zinc‐ion batteries

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SmartMat 2024年第1期5卷 59-82页

作者： Xuan Gao Kejiang Liu Chang Su Wei Zhang yuhang dai Ivan P.Parkin Claire J.Carmalt Guanjie He Christopher Ingold Laboratory Department of ChemistryUniversity College LondonLondonUK Electrochemical Innovation Lab(EIL) Department of Chemical EngineeringUniversity College LondonLondonUK Department of Physics Hong Kong Baptist UniversityHong KongChina Nanyang Technopreneurship Center Nanyang Technological UniversitySingaporeSingapore

Three‐dimensional(3D)printing has the potential to revolutionize the way energy storage devices are designed and *** this paper,we explore the use of 3D printing in the design and production of energy storage devices,especially zinc‐ion batteries(ZIBs)and examine its potential advantages over traditional manufacturing methods.3D printing could significantly improve the customization of ZIBs,making it a promising strategy for the future of energy *** particular,3D printing allows for the creation of complex,customized geometries,and designs that can optimize the energy density,power density,and overall performance of ***,we discuss and compare the impact of 3D printing design strategies based on different configurations of film,interdigitation,and framework on energy storage devices with a focus on ***,3D printing enables the rapid prototyping and production of batteries,reducing leading times and costs compared with traditional manufacturing ***,there are also challenges and limitations to consider,such as the need for further development of suitable 3D printing materials and processes for energy storage applications.

关键词： 3D printing battery commercialization bibliometric analysis electrode configurations zinc‐ion battery

Trace Amounts of Triple-Functional Additives Enable Reversible Aqueous Zinc-Ion Batteries from a Comprehensive Perspective

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Nano-Micro Letters 2023年第6期15卷 143-154页

作者： Ruwei Chen Wei Zhang Quanbo Huang Chaohong Guan Wei Zong yuhang dai Zijuan Du Zhenyu Zhang Jianwei Li Fei Guo Xuan Gao Haobo Dong Jiexin Zhu Xiaohui Wang Guanjie He Electrochemical Innovation Lab Department of Chemical EngineeringUniversity College LondonLondon WC1E 7JEUK State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhou 510640People’s Republic of China University of Michigan‑Shanghai Jiao Tong University Joint Institute Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China

Although their cost-effectiveness and intrinsic safety,aqueous zinc-ion batteries suffer from notorious side reactions including hydrogen evolution reaction,Zn corrosion and passivation,and Zn dendrite formation on the *** numerous strategies to alleviate these side reactions have been demonstrated,they can only provide limited performance improvement from a single ***,a triple-functional additive with trace amounts,ammonium hydroxide,was demonstrated to comprehensively protect zinc *** results show that the shift of electrolyte pH from 4.1 to 5.2 lowers the HER potential and encourages the in situ formation of a uniform ZHS-based solid electrolyte interphase on Zn ***,cationic NH^(4+)can preferentially adsorb on the Zn anode surface to shield the“tip effect”and homogenize the electric *** from this comprehensive protection,dendrite-free Zn deposition and highly reversible Zn plating/stripping behaviors were ***,improved electrochemical performances can also be achieved in Zn//MnO_(2)full cells by taking the advantages of this triple-functional *** work provides a new strategy for stabilizing Zn anodes from a comprehensive perspective.

关键词： Aqueous zinc-ion battery Cationic shielding effect Solid electrolyte interphase pH value Triple-functional additive

From lab to market:a review of commercialization and advances for binders in lithium-,zinc-,sodium-ion batteries

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Nano Research Energy 2024年第1期3卷 152-171页

作者： Chang Su Xuan Gao Kejiang Liu yuhang dai Haobo Dong Yiyang Liu Jiayan Zhu Qiuxia Zhang Hongzhen He Guanjie He Department of Management Technologyand EconomicsETH ZürichZürich 8092Switzerland Christopher Ingold Laboratory Department of ChemistryUniversity College LondonLondon WC1H0AJUK Electrochemical Innovation Lab Department of Chemical EngineeringUniversity College LondonLondon WC1E7JEUK Department of Physics Hong Kong Baptist UniversityHong Kong 999077China State Key Lab of Superhard Materials College of PhysicsJilin UniversityChangchun 130012China

The paper discusses the progress and commercialization of binders for energy storage applications,such as *** explains the role of binders in holding together active materials and current collectors,and highlights the challenges associated with conventional organic solvents in *** potential of aqueous binders is introduced as a cost-effective and environmentally friendly *** advantages and limitations of different types of binders are discussed,and the importance of binder selection for optimal battery performance is *** current state of commercialization of binders is reviewed,and the need for collaboration between researchers,manufacturers,and policymakers to develop and promote environmentally friendly and cost-effective binders is *** paper concludes by outlining future directions for research and development to further improve the performance and commercialization of binders,while addressing limitations such as lack of standardization,high cost,and long-term stability and reliability.

关键词： battery commercialization binder energy storage

Metal–organic frameworks and their derivatives for optimizing lithium metal anodes

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eScience 2024年第4期4卷 7-26页

作者： Zhaoyang Wang Zijuan Du Yiyang Liu Caroline EKnapp yuhang dai Jianwei Li Wei Zhang Ruwei Chen Fei Guo Wei Zong Xuan Gao Jiexin Zhu Chuanliang Wei Guanjie He Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology College of Chemistry EngineeringLiaocheng UniversityLiaocheng 252059China State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430070China Christopher Ingold Laboratory Department of ChemistryUniversity College LondonLondon WC1H 0AJUK School of Chemistry and Chemical Engineering Shandong UniversityJinan 250061China Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources Qinghai Institute of Salt LakesChinese Academy of Sciences(CAS)Xining 810008China

Lithium metal anodes(LMAs)have been considered the ultimate anode materials for next-generation ***,the uncontrollable lithium dendrite growth and huge volume expansion that can occur during charge and discharge seriously hinder the practical application of ***–organic framework(MOF)materials,which possess the merits of huge specific surface area,excellent porosity,and flexible composition/structure tunability,have demonstrated great potential for resolving both of these *** article first explores the mechanism of lithium dendrite formation as described by four influential ***,based on an in-depth understanding of these models,we propose potential strategies for utilizing MOFs and their derivatives to suppress lithium dendrite *** then provide a comprehensive review of research progress with respect to various applications of MOFs and their derivatives to suppress lithium dendrites and inhibit volume *** paper closes with a discussion of perspectives on future modifications of MOFs and their derivatives to achieve stable and dendrite-free lithium metal batteries.

关键词： Metal–organic frameworks Lithium metal batteries Lithium metal anodes Lithium dendrite formation mechanism Lithium dendrite inhibition strategy

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铥镱双掺氧化钆钇透明陶瓷的制备与发光性能

硅酸盐学报 2017年第10期45卷 1474-1480页

作者：李剑代雨航朱忠丽长春理工大学化学与环境工程学院长春130022

采用柠檬酸燃烧法制备了(GdY)_2O_3:Tm,Yb粉体,并确定其制备工艺条件为:煅烧温度1 000℃,Gd^(3+)、Tm^(3+)、Yb^(3+)掺杂的摩尔分数分别为20%、4%、5%。以此条件得到的粉体的平均粒径约65 nm。粉体的发射光谱表明:在980 nm激发源激发下,... 详细信息

采用柠檬酸燃烧法制备了(GdY)_2O_3:Tm,Yb粉体,并确定其制备工艺条件为:煅烧温度1 000℃,Gd^(3+)、Tm^(3+)、Yb^(3+)掺杂的摩尔分数分别为20%、4%、5%。以此条件得到的粉体的平均粒径约65 nm。粉体的发射光谱表明:在980 nm激发源激发下,在484 nm处得到的蓝光,对应于Tm^(3+)的1G4→3H6能级跃迁;在658 nm处得到的红光,对应于Tm^(3+)的3F2→3H6能级跃迁。用制备的粉体作为原料,采用真空烧结法制备(GdY)_2O_3:Tm,Yb陶瓷,其烧结工艺条件为:烧结温度为1 750℃,保温20 h。制备的陶瓷在400~3 300 nm波长范围内的平均透过率为71%。

关键词：铥-镱双掺杂氧化钆钇柠檬酸燃烧法冷等静压-真空烧结法光谱性能