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Synthesis and Characterization of Biodegradable Alternating Polyesteramides from Mixed Diamidediols and Sebacic Acid

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Chemical Research in Chinese Universities 2014年第1期30卷 168-175页

作者： SUN Huiyun YIN Tiao LI yue zhao Jingbo zhang Zhiyuan zhang Junying Key Laboratory of Carbon Fiber and Functional Polymers Ministry of EducationCollege of Materials Science and Engineering Beo'ing University of Chemical Technology Beijing 100029 P R. China

A series of polyesteramide prepolymers[PrePEA（0/4,8）s] having mixed alternating bisesterdiamide units was synthesized via melt polycondensation from N,N＇-bis（2-hydroxyethyl）oxamide（0） and N,N＇-bis（2-hydroxyethyl）-adipamide（4） with sebacic acid（8） at different molar *** extension of them was conducted with 2,2＇-（1,4-phenylene）-bis（2-oxazoline） and adipoyl biscaprolactamate as combined chain *** chain extended polyesteramides[ExtPEA（0/4,8）s] were characterized by proton nuclear magnetic resonance（1H NMR）,gel permeation chromatography（GPC）,differential scanning calorimetry（DSC）,thermogravimetry analysis（TGA）,wide angle X-ray scattering,tensile test and enzymatic *** results show that ExtPEA（0/4,8）s were crystalline *** had Tm up to 136.5 ℃ and initial decomposition temperature above 297.5 ℃.They crystallized in similar crystallites into Nylon-66 and degraded under the catalysis of protease or *** are thermoplastic materials with tensile strength up to 21.5 MPa and elongation at break above 64.0％.

关键词： Alternating polyesteramide Polycondensation Chain extension Diamidediol

Common causes of geriatric medical emergencies in China

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Journal of Geriatric Cardiology 2015年第1期12卷 91-92页

作者： Hong-Wei Liu Li-Na Han yue-Xiang zhao Wei zhang Department of Cardiovascular Disease South Building of PLA General Hospital Beijing 100853 China.

To the Editor One of the most significant demographic changes in our cotmtry is the increase in the elderly population. In China Mainland, the population aged 60 and older was 194 million in 2012, accounting for 14.3% of the total population. However, by 2053, it is estimated that the number of elderly will reach 487 million, representing 34.8% of the total population. Elderly patients represent an everncreasing populace in emergency medicine who often present with atypical signs and symptoms as well as eomorbidities that can complicate diagnoses and *** The geographic factors and the developmental status of the country can influence the spectrum of common geriatric emergencies. Thus, this study presents a retrospective analysis of common causes of geriatric emergencies involving 9,628 elderly patients from Jan. 2008 to Dec. 2013 in an emergency department in Beijing, China.

关键词： China Comorbidity Emergency medicine The elderly

CsI-bowl:an ancillary detector for exit channel selection inγ-ray spectroscopy experiments

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Nuclear Science and Techniques 2023年第9期34卷 32-39页

作者： Xing-Chi Han Shuo Wang Hong-Yi Wu Zhi-Huan Li Guo-Zhu Shi Ruo-Fu Chen yue-zhao zhang Shou-Yu Wang Shandong Provincial Key Laboratory of Optical Astronomy and Solar-Terrestrial Environment School of Space Science and PhysicsInstitute of Space SciencesShandong UniversityWeihai 264209China WeiHai Research Institute of Industrial Technology of Shandong University Weihai 264209China School of Physics and State Key Laboratory of Nuclear Physics and Technology Peking UniversityBeijing 100871China Institute of Modern Physics Chinese Academy of SciencesLanzhou 73000China

A particle detector array designed for light-charged particles, known as the CsI-bowl, was built for exit channel selection for in-beam γ-ray spectroscopy experiments. This device is composed of 64 CsI(Tl) detectors, organized in a structure reminiscent of a tea-bowl. High quantum efficiency photodiodes, characterized by their minimal mass, were employed to collect scintillation light. Its design, construction, particle identification resolution, and its effectiveness in relation to exit channel selection are described in this paper. In source tests, the optimal figure of merit for the identification of α-particles and γ-rays using the charge comparison method was found to be 3.3 and 12.1 for CsI detectors coupled to photodiodes and avalanche photodiodes, respectively. The CsI-bowl demonstrated effectiveness in identifying particles, specifically the emission of protons and α-particles in the58Ni(19F, xpyn) fusion–evaporation reaction, thereby enabling the selection of the desired exit channels.

关键词： Light charged particle detector array Particle identification Charge comparison method

Physics based circuit compatible model for hybrid antiferroelectric random access memory

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Science China(Information Sciences) 2025年第1期68卷 396-397页

作者： Qiuxia WU yue PENG Wenwu XIAO Wenxuan MA Shuo zhang Litao SUN Chunfu zhang Xiaohua MA yue HAO School of Microelectronics Xidian University Xi'an Uni IC Semiconductors

Since the discovery of HfO2-based ferroelectric （FE） materials in 2011,considerable advancements have been made in material preparation,mechanism research,and device realization [1].Consequently,these materials are now regarded as leading candidates for embedded non-volatile memory（eNVM）.Beyond eNVM applications,recent studies have demonstrated that memory devices with antiferroelectric（AFE） films can achieve high response speeds,low latency,and reduced power consumption while maintaining excellent endurance characteristics [2,3].Additionally,the typical double hysteresis loops and multiple non-overlapping polarization current peaks of AFE films offer a novel approach to designing multistate ***,in order to further promote the application of high storage density AFE,an AFRAM electronic design automation （EDA） model must be developed,and it has yet to be proposed.

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Channel pruning on frequency response

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Science China(Information Sciences) 2025年第1期68卷 159-170页

作者： Hang LIN Yifan PENG Lin BIE Chenggang YAN Xibin zhao yue GAO School of Software Tsinghua University School of Automation Hangzhou Dianzi University

Network pruning has a significant role in reducing network parameters and accelerating the inference time of the network. Some existing methods prune the network based on the frequency of the data, and finally obtain a sub-network with high accuracy. However, according to our experimental analysis, different frequencies of information in the data contribute differently to the accuracy of the model, and using this information directly for pruning without making a selection will lead to incorrect results. We believe that pruning should retain the convolutional kernels in the network that process important information, while those kernels that process unimportant information should be removed. In this paper, we first investigate the meaning of each frequency band information in the spectrum and their contribution to the prediction accuracy of the network,and according to these results, we propose a new pruning method based on frequency response(PFR). Our PFR finds and removes the convolutional kernels in the network that specialize in processing unimportant information, resulting in a compact neural network model. PFR obtains significant experimental results on different datasets, for example, a 56.0% raduction of float points operations(FLOPs) on Res Net-50 and only 0.37% of Top-1 accuracy degradation on the Image Net dataset.

关键词： deep learning model compression filter pruning channel pruning frequency response

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Design and tests of the prototype a beam monitor of the CSR external target experiment

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Nuclear Science and Techniques 2022年第3期33卷 137-151页

作者： Hu-Lin Wang Zhen Wang Chao-Song Gao Jian-Wei Liao Xiang-Ming Sun Hai-Bo Yang Cheng-Xin zhao Jun Liu Peng Ma Zi-Li Li Bi-Hui You Ping Yang Di Guo Le Xiao Dong-Liang zhang yue-zhao zhang Sheng Dong Wan-Han Feng Yu-Xin Qiao Zheng-Yu Hu Qing-Wen Ye Zeng-Tao Guo Guang-Ming Huang Feng Liu PLAC Key Laboratory of Quark and Lepton Physics(MOE)Central China Normal UniversityWuhan 430079China Hubei Provincial Engineering Research Center of Silicon Pixel Chip&Detection Technology Wuhan 430079China School of Physics and Electronic Science Guizhou Normal UniversityGuiyang 550001China Institute of Modern Physics Chinese Academy of SciencesLanzhou 730000China

A prototype beam monitor was designed to provide tracking information for heavy-ion projectiles for the cool storage ring(CSR)external target experiment(CEE)at the Heavy Ion Research Facility in Lanzhou(HIRFL).High granularity and direct charge sensing are the main features of this *** measures the beam position in a two-dimensional(2D)plane transverse to the beam direction on an event-by-event *** current design consists of two field cages inside a single vessel that operates independently and has electrical drift fields in orthogonal *** tests of the prototype were performed using a^(241)Am a *** results show that a spatial resolution of less than 40μm and a time resolution of less than 600 ns can be achieved.

关键词： CEE Beam monitor Heavy ion Topmetal sensor Tracking Field cage

HNRNPC as a pan-cancer biomarker and therapeutic target involved in tumor progression and immune regulation

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Oncology Research 2025年第1期33卷 83-102页

作者： yueZHOU zhang zhao zhang JINXIN DONG CHANGAN LIU Department of Hepatobiliary Surgery The Second Affiliated Hospital of Chongqing Medical UniversityChongqing400016China Department of Hepatobiliary Surgery The First Affiliated Hospital of Chongqing Medical UniversityChongqing400016China

Background:Aberrant expression of RNA-binding proteins(RBPs)has been linked to a variety of diseases,including hematological disorders,cardiovascular diseases,and multiple types of *** nuclear ribonucleoprotein C(HNRNPC),a member belonging to the heterogeneous nuclear ribonucleoprotein(hnRNP)family,plays a pivotal role in nucleic acid *** studies have underscored the significance of HNRNPC in tumorigenesis;however,its specific role in malignant tumor progression remains inadequately ***:We leveraged publicly available databases,including The Cancer Genome Atlas(TCGA),to explore the potential involvement of HNRNPC across various ***,we performed experimental validation studies focused on liver ***:Our analysis revealed that HNRNPC is overexpressed in a wide range of common malignancies,including liver and lung cancers,and is strongly linked to unfavorable ***,HNRNPC was observed to be closely linked to tumor *** immune checkpoint analysis and immune cell infiltration assessment,HNRNPC emerged as a potential target for modulating tumor ***,silencing of HNRNPC markedly inhibited the proliferation,metastasis,and infiltration of liver cancer ***:In summary,our findings highlight HNRNPC as a prognostic marker in various cancers,including liver cancer,and suggest its involvement in shaping the tumor immune *** insights offer potential avenues for improving clinical outcomes in tumors with elevated HNRNPC expression,particularly through immunotherapeutic strategies.

关键词： Heterogeneous nuclear ribonucleoprotein C(HNRNPC) Pan-cancer analysis Tumor immunity Prognostic biomarker Immunotherapeutic target Hepatocellular carcinoma

Decision making module based on stochastic magnetic tunnel junctions

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Science China(Physics,Mechanics & Astronomy) 2025年第1期Mechanics & Astronomy) .卷 202-209页

作者： Yifan Miao Li zhao Yajun zhang Zhe Yuan Center for Advanced Quantum Studies and Department of Physics Beijing Normal University Institute for Nanoelectric Devices and Quantum Computing Fudan University Interdisciplinary Center for Theoretical Physics and Information Sciences Fudan University

In biological neural systems, noise is ubiquitous but does not affect the correct decisions made in the complex cognitive ***-making in biological neural system is typically achieved by accumulating input information over a period of *** by recent developments in neurosciences, we design a decision-making module based on spintronic devices, utilizing superparamagnetic tunnel junctions as artificial neurons. The feasibility of this decision-making module is verified through circuit simulations. Taking a multi-layer perceptron as an example, the module significantly improves the accuracy of the perceptron in the handwritten digit recognition task. Furthermore, the spintronic decision-making module offers advantages over the conventional pooling methods, such as adaptive decision time, high performance and the absence of analog-to-digital conversion. The decision-making module is flexible to be integrated into artificial neural networks and provides a general yet effective solution to enhance performance against device noise.

关键词： neuromorphic computing spintronics magnetic tunnel junction neural networks

Efficient photocatalytic reduction of CO2 to formate by a molecular noble metal-free system

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Science China Chemistry 2025年第1期68卷 152-156页

作者： Lihua zhang Lingjing Chen Huatian Shi yue Wei Gui Chen Tai-Chu Lau School of Environment and Civil Engineering Research Center for Eco-environmental Engineering Dongguan University of Technology Department of Chemistry and Institute of Molecular Functional Materials City University of Hong Kong

Reducing CO2to carbon-neutral solar fuels can not only alleviate the energy demand but also mitigate the greenhouse *** present,developing an efficient non-noble metal photo/electrocatalytic system for converting CO2to a specific product beyond CO is still a big ***,we report a new cobalt complex bearing 2,2′-bi-1,10-phenanthroline ligand that can photocatalytically reduce CO2to formate （HCOO-）.Turnover number （TON） for HCOO-up to 677 with 99%selectivity can be achieved using organic dyes purpurin as photosensitizer and 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole （BIH） as sacrificial reductant in a CO2-saturated NMP/TEA （v/v,3:1） solution under visible light *** potential electrolysis at-1.41 V （***/Ag Cl） in the presence of 12 m M Et3NHBF4also produced HCOO-with Faradaic efficiency of 39%.Spectroscopic and electrochemical studies suggest that a[CoI-H]species is the key intermediate for CO2reduction.

关键词： photocatalysis noble metal-free CO2 reduction formate cobalt hydride