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High-safety and high-voltage lithium metal batteries enabled by nonflammable diluted highly concentrated electrolyte

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Nano Research 2024年第4期17卷 2638-2645页

作者： Han Zhang Ziqi Zeng Shuping Wang yuanke wu Changhao Li Mengchuang Liu Xinlan Wang Shijie Cheng Jia Xie State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074China State Grid Anhui Electric Power Research Institute Anhui Province Key Laboratory of Electric Fire and Safety Protection(State Grid Laboratory of Fire Protection for Transmission and Distribution Facilities)Hefei 230601China School of Chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan 430074China

Lithium metal batteries(LMBs)show great promise for achieving energy densities over 400 Wh·kg^(-1).However,highly flammable organic electrolytes are a long-lasting problem that triggers safety hazards and hinders the commercial application of ***,a nonflammable diluted highly concentrated electrolyte(DHCE)with ethoxy(pentafluoro)cyclotriphosphazene(PFPN)as a diluent is developed to simultaneously achieve high safety and cycling stability of high-voltage *** optimal DHCE not only ensures reversible Li deposition/dissolution behavior with a superior average Coulombic efficiency(CE)over 99.1%on lithium metal anode(LMA),but also suppresses side reactions and stress crack on the LiCoO_(2)(LCO)under high cut-off *** newly developed DHCE exhibits high thermal stability,showing complete nonflammability and reduced heat generation between the electrolyte and delithiated LCO/cycled *** work offers an opportunity for rational designing nonflammable electrolytes toward high-voltage and safe LMBs.

关键词： lithium metal batteries thermal stability nonflammable electrolyte high-voltage phosphazene

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“In-N-out” design enabling high-content triethyl phosphate-based non-flammable and high-conductivity electrolytes for lithium-ion batteries

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Science China Chemistry 2024年第2期67卷 724-731页

作者： Mengchuang Liu Fenfen Ma Zicheng Ge Ziqi Zeng Qiang wu Hui Yan yuanke wu Sheng Lei Yanli Zhu Shijie Cheng Jia Xie State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan430074China School of Chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan430074China GuSu Laboratory of Materials Suzhou215123China Institute of Metal Research Chinese Academy of SciencesShenyang110000China State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing100081China

Safety issues related to flammable electrolytes in lithium-ion batteries(LIBs) remain a major challenge for their extended *** use of non-flammable phosphate-based electrolytes has proved the validity in inhibiting the combustion of ***,the strong interaction between Li^(+) and phosphate leads to a dominant solid electrolyte interphase(SEI) with limited electronic shielding,resulting in the poor Li^(+) intercalation at the graphite(Gr) anode when using high-phosphate-content *** mitigate this issue and improve Li^(+) insertion,we propose an “In-N-Out” strategy to render phosphates “noncoordinative”.By employing a combination of strongly polar solvents for a “block effect” and weakly polar solvents for a “drag effect”,we reduce the Li^(+)–phosphate *** a result,phosphates remain in the electrolyte phase(“In”),minimizing their impact on the incompatibility with the Gr electrode(“Out”).We have developed a non-flammable electrolyte with high triethyl phosphate(TEP) content(>60 wt.%),demonstrating the excellent ion conductivity(5.94 mS cm^(-1) at 30 ℃) and reversible Li^(+) intercalation at a standard concentration(~1 mol L^(-1)).This approach enables the manipulation of multiple electrolyte functions and holds the promise for the development of safe electrochemical energy storage systems using non-flammable electrolytes.

关键词： lithium-ion batteries graphite anode high-phosphate-content electrolytes non-flammable electrolyte excellent ion conductivity standard concentration

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基于接触压力分布和非均匀热流密度的列车制动盘热机耦合分析

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机械工程学报 2023年第3期59卷 165-175页

作者：张庆贺卢纯吴元科赵婧莫继良西南交通大学机械工程学院成都610031 西南交通大学轨道交通运维技术与装备四川省重点实验室成都610031

针对铁路列车制动闸片摩擦块排布方式对制动盘热机耦合响应状态影响显著的问题,提出了一种考虑接触压力分布和非均匀热流密度的热机耦合仿真分析方法。通过在轨道车辆制动性能试验台上进行的制动台架试验,从温度的角度验证了所提方法的... 详细信息

针对铁路列车制动闸片摩擦块排布方式对制动盘热机耦合响应状态影响显著的问题,提出了一种考虑接触压力分布和非均匀热流密度的热机耦合仿真分析方法。通过在轨道车辆制动性能试验台上进行的制动台架试验,从温度的角度验证了所提方法的正确性。在此基础上,建立了列车全尺寸盘型制动系统有限元仿真分析模型,对现有铁路列车制动闸片摩擦块的排布方式进行了优化分析。结果表明,合理的制动闸片摩擦块排布方式可以显著降低制动盘面的温度和应力峰值,在改善制动盘面温度和应力分布的同时,提供较为优异的制动性能。研究成果可为铁路列车盘型制动系统热机耦合分析提供一种快速有效的仿真分析方法,同时可为铁路列车制动闸片摩擦块的排布优化提供指导方向。

关键词：制动盘摩擦块排布接触压力分布热机耦合响应非均匀热流密度

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时变接触特性表面对界面摩擦学行为的影响

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摩擦学学报 2022年第1期42卷 104-112页

作者：王安宇吴元科项载毓孙瑞雪莫继良西南交通大学机械工程学院摩擦学研究所四川成都610031 轨道交通运维技术与装备四川省重点实验室四川成都610031

通过在锻钢基材表面沟槽中分别填充灰铸铁HT300、Mn-Cu合金和Mn-Cu阻尼合金材料获得具有时变接触特性的表面,并对锻钢光滑表面试样和时变接触特性表面进行摩擦学试验,研究不同时变接触特性表面对界面摩擦学行为(摩擦噪声、摩擦振动以及... 详细信息

通过在锻钢基材表面沟槽中分别填充灰铸铁HT300、Mn-Cu合金和Mn-Cu阻尼合金材料获得具有时变接触特性的表面,并对锻钢光滑表面试样和时变接触特性表面进行摩擦学试验,研究不同时变接触特性表面对界面摩擦学行为(摩擦噪声、摩擦振动以及磨损行为)的影响.结果表明:填充HT300的时变接触特性表面缓解了界面磨损,有效延续摩擦系统的稳定状态,抑制摩擦振动和噪声的产生;相反,填充Mn-Cu合金和填充Mn-Cu阻尼合金的时变接触特性表面加剧了界面磨损,加速了摩擦系统不稳定状态的出现,进而激发出高强度的摩擦振动和噪声.在本研究中,摩擦系统失稳引起摩擦振动和噪声主要归因于摩擦磨损过程中黏着撕裂和犁削等界面作用,填充材料的阻尼特性未能起到减振降噪的效果.

关键词：时变接触特性填充材料磨损特征摩擦振动噪声

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基于界面调控的摩擦系统减振降噪方法

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振动与冲击 2022年第15期41卷 146-152页

作者：王权王安宇吴元科尹家宝项载毓莫继良西南交通大学牵引动力国家重点实验室成都610031 西南交通大学轨道交通运维技术与装备四川省重点实验室成都610031 四川航天职业技术学院飞行器制造系成都610100

为寻求抑制摩擦振动及噪声的新方法,分别探讨了在摩擦副背面安装阻尼元件以及在摩擦副表面加工沟槽型织构两种手段对摩擦界面的调控效果,并在此基础上将两种调控摩擦界面的手段组合,对得到的3种不同界面调控方法调控的摩擦系统进行摩擦... 详细信息

为寻求抑制摩擦振动及噪声的新方法,分别探讨了在摩擦副背面安装阻尼元件以及在摩擦副表面加工沟槽型织构两种手段对摩擦界面的调控效果,并在此基础上将两种调控摩擦界面的手段组合,对得到的3种不同界面调控方法调控的摩擦系统进行摩擦噪声试验,并利用有限元分析方法和压力测试结果揭示其作用机理。结果表明,摩擦副背面安装阻尼元件或摩擦副表面加工沟槽型织构均可以改善摩擦界面贴合程度,从而提高摩擦系统的稳定性,抑制摩擦振动及噪声产生。以上两种界面调控方法组合后摩擦界面贴合程度进一步增大,因此在抑制摩擦振动及噪声方面表现出更大的潜力。此外,摩擦副背面安装的阻尼元件在增大界面贴合程度的同时,还可以使界面贴合更加稳定。

关键词：界面调控摩擦振动噪声阻尼元件沟槽型织构界面贴合

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Ballistic performances of the hourglass lattice sandwich structures under high-velocity fragments

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Defence Technology（防务技术） 2024年第1期31卷 312-325页

作者： He-xiang wu Jia Qu Lin-zhi wu Key Laboratory of Advanced Ship Materials and Mechanics College of Aerospace and Civil EngineeringHarbin Engineering UniversityHarbin150001China School of Civil Engineering Northeast Forestry UniversityHarbin150040China

In this paper,the numerical simulation method is used to study the ballistic performances of hourglass lattice sandwich structures with the same mass under the vertical incidence of *** is paid to elucidating the influences of rod cross-section dimensions,structure height,structure layer,and rod inclination angle on the deformation mode,ballistic performances,and ability to change the ballistic direction of *** results show that the ballistic performances of hourglass lattice sandwich structures are mainly affected by their structural *** this respect,structural parameters optimization of the hourglass lattice sandwich structures enable one to effectively improve their ballistic limit velocity and,consequently,ballistic performances.

关键词： Hourglass lattice sandwich structures Ballistic performances high-velocity Finite element analysis

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Resilience-incorporated seismic risk assessment of precast concrete frames with“dry”connections

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Earthquake Engineering and Engineering Vibration 2024年第2期23卷 403-425页

作者： wu Chenhao Tang Yuchuan Cao Xuyang wu Gang Key Laboratory of Concrete and Prestressed Concrete Structures of the Ministry of Education Nanjing 211102China Department of Civil and Environmental Engineering University of CaliforniaLos AngelesCA 90095USA School of Civil Engineering Southeast UniversityNanjing 211102China College of Civil and Transportation Engineering Hohai UniversityNanjing 210024China

A resilience-incorporated risk assessment framework is proposed and demonstrated in this study to manifest the advantageous seismic resilience of precast concrete frame(PCF)structures with“dry”connections in terms of their low damage and rapid *** framework integrates various uncertainties in the seismic hazard,fragility,capacity,demand,loss functions,and post-earthquake *** this study,the PCF structures are distinguished from ordinary reinforced concrete frame(RCF)structures by characterizing multiple limit states for the PCF based on its unique damage ***,probabilistic story-wise pushover analyses are performed to yield story-wise capacities for the predefined limit *** the seismic resilience analysis,a step-wise recovery model is proposed to idealize the functionality recovery process,with separate considerations of the repair and non-repair *** recovery model leverages the economic loss and downtime to delineate the stochastic post-earthquake recovery curves for the resilience loss *** such,contingencies in the probabilistic post-earthquake repairs are incorporated and the empirical judgments on the recovery parameters are largely *** proposed framework is demonstrated through a comparative study between two“dry”connected PCFs and one RCF designed as alternative structural systems for a prototype *** results from the risk quantification indicate that the PCFs show reduced loss hazards and lower expected losses relative to the ***,the PCF equipped with energy dissipation devices at the“dry”connections largely reduces the expected economic loss,downtime,and resilience loss by 29%,56%,and 60%,respectively,compared to the RCF.

关键词： precast concrete frame non-emulative precast system seismic resilience seismic risk functional recovery

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New findings on the influence of El Ni?o events on tropical cyclone formation

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Science China Earth Sciences 2024年第3期67卷 892-893页

作者： Liguang wu Fudan University Department of Atmospheric and Oceanic Sciences Institute of Atmospheric Sciences

Tropical cyclones typically form over warm tropical and subtropical ocean surfaces, as their formation and intensification rely primarily on the energy provided by the ocean. Pioneering research by Gray (1968) revealed that the formation of tropical cyclones requires the sea surface temperature (SST) to be no less than 26.5°C. Consequently, SST is commonly recognized as a crucial parameter among the environmental factors influencing tropical cyclone formation(Gray, 1979; Emanuel and Nolan, 2004).

关键词： INDEX

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Two-dimensional semiconductor heterostructures for photocatalytic CO_(2)conversion

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Science China Chemistry 2024年第8期67卷 2434-2447页

作者： Yang wu Mingyu wu Yongfu Sun Yi Xie Hefei National Research Center for Physical Sciences at Microscale University of Science and Technology of ChinaHefei 230026China

The CO_(2)reduction into carbon-contained fuel via solar energy offers the powerful tools to realize the zero-emission carbon *** to the intriguing features of the two-dimensional(2D)heterostructures,it is susceptible to modulate the electronic structure as well as the surface geometry for optimizing the photocatalytic CO_(2)*** this perspective,we surveyed the fundamental insights of 2D semiconductor heterostructures,involving the fabrication strategies and classification of the 2D semiconductor ***,we have detailly discussed the overview of 2D semiconductor heterostructure for optimizing CO_(2)photocatalytic influenced factors,including the solar energy utilization,photogenerated carriers separation,and redox reaction ***,we showed the significant advantages of 2D heterostructures in elevating CO_(2)photoreduction performance,focusing on activity,selectivity and *** analyzing the limitations and developments,we ended by putting forward insights into the further researches about the CO_(2)photocatalysts and reactor design,even industrial applications.

关键词： two-dimensional semiconductor heterostructures photocatalysis CO_(2)conversion

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The Functional Redundancy of Neddylation E2s and E3s in Modulating the Fitness of Regulatory T Cells

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Research 2024年第2期2023卷 373-387页

作者： Di wu Yi Sun Cancer Institute(Key Laboratory of Cancer Prevention and Intervention China National Ministry of Education)of the Second Affiliated Hospital and Institute of Translational MedicineZhejiang University School of MedicineHangzhou 310029China Cancer Center of Zhejiang University Hangzhou 310029China Zhejang Provincial Clinical Research Center for Cancer Zhejang ProvinceChina Key Laboratory of Molecular Biology in Medical Sciences Zhejang ProvinceChina Research Center for Life Science and Human Health Binjiang Institute of Zhejiang UniversityHangzhou 310053China

Neddylation is necessary for activation of Cullin-RING ligases(CRLs),which degrade various immune regulatory *** recent study showed that while depletion of neddylation E2-E3 pair Ube2f-Sag in regulatory T(T_(reg))cells had no obvious phenotype,the same depletion of either Ube2m or Rbx1 caused inflammation disorders with different *** these E2s or E3s compensate each other in functional regulations of T_(reg)cells is,however,previously *** this report,we generated Foxp3^(Cre);Ube2m^(fl/fl);Ube2f^(fl/fl)or Foxp3^(Cre);Rbx1^(fl/fl);Sag^(fl/fl)double-null mice by simultaneous deletion of both neddylation E2s or E3s in T_(reg)cells,***,Ube2m&Ube2f double-null mice developed much severe autoimmune phenotypes than did Ube2m-null mice,indicating that Ube2m markedly compensates Ube2f in T_(reg)*** minor worsened autoimmune phenotypes seen at the very early stage in Rbx1&Sag double-null than Rbx1-null mice is likely due to already severe phenotypes of the later,indicating a minor compensation of Rbx1 for *** RNA profiling-based analyses revealed that up-and down-regulations of few signaling pathways in T_(reg)cells are associated with the severity of autoimmune ***,severer inflammation phenotypes seen in mice with double E3-null than with double E2-null T_(reg)cells indicate a neddylation-independent mechanism of 2 E3s,also known to serve as the RING component of CRLs in regulation of T_(reg)cell fitness.

关键词： Foxp3 inflammation markedly

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