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Metal–ligand interfaces for well-defined gold nanoclusters

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Science China Chemistry 2024年第3期67卷 806-823页

作者： Dan yang Yating Wu Zhaotong yuan Chunmei Zhou Yihu Dai Xiaoyue Wan yan Zhu yanhui yang Institute of Advanced Synthesis School of Chemistry and Molecular EngineeringNanjing Tech UniversityNanjing 211816China School of Chemistry and Chemical Engineering Nanjing UniversityNanjing 210093China College of Material and Chemical Engineering Minjiang UniversityFuzhou 350108China

Ligand engineering for well-defined gold nanoclusters(Au NCs) is getting more extensive attention. Organizing the Au-ligand interfaces on gold NCs can achieve the structural and functional control. This review focuses on the Au-ligand interfaces including gold-phosphorus(Au-P), gold-sulfur(Au-S), gold-selenium(Au-Se), gold-carbon(Au-C), and gold-nitrogen(Au-N), derived from the bonding between Au atoms and the different ligands(e.g., organic phosphine, thiolate, selenolate, alkynyl,n-heterocyclic carbene and nitrogenous ligands). The formation mechanism of Au-ligand interfaces is well discussed. In addition, the effects of Au-ligand interfaces on the stability, optical property, and catalysis are also presented. We hope the advances in this research area can boost the development of Au NC sciences.

关键词： Au nanoclusters well-defined structures metal–ligand interfaces formation mechanism structure–property correlation

Re-evaluating the nano-sized inorganic protective layer on Cu current collector for anode free lithium metal batteries

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Chinese Chemical Letters 2024年第7期35卷 452-455页

作者： Shuo Zhang Haitao Liao Zhi-Qun Liu Chong yan Jia-Qi huang School of Materials Science&Engineering Beijing Institute of TechnologyBeijing 100081China Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China Wuxi Yiwen Microelectronics Technology Co. Ltd.Wuxi 214000China Shanxi Research Institute for Clean Energy Tsinghua UniversityTaiyuan 030032China

Anode free lithium metal batteries(AF-LMBs)have conspicuous advantages both in energy density and the compatibility of battery manufacturing ***,the limited cycle life of AF-LMBs is a crucial factor hindering its practical *** or nitride artificial inorganic solid electrolyte interphase(SEI)has been found as an effective method to prolong the lifespan of ***,by investigating the impact of nano-sized inorganic gradient layers(LiF or Li3N)on initial Li deposition behavior,we notice that the Li^(+) diffusion barrier and the deposition morphology are highly depended on the thickness of inorganic *** protective layers cause larger overpotential as well as more aggregated Li^(+) *** study reveals that the ideal SEI should be synthesized thin and uniformly enough and uncontrollable artificial SEI can cause damage to the lifespan of AF-LMBs.

关键词： Anode free lithium metal battery Solid electrolyte interphase Nano-sized protective layer Lithium fluoride Li deposition behavior

Incremental Data Stream Classification with Adaptive Multi-Task Multi-View Learning

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Big Data Mining and Analytics 2024年第1期7卷 87-106页

作者： Jun Wang Maiwang Shi Xiao Zhang yan Li Yunsheng yuan Chengei yang Dongxiao Yu School of Computer Science and Technology Shandong UniversityQingdao 266237China School of Software Shandong UniversityJinan 250101China

With the enhancement of data collection capabilities,massive streaming data have been accumulated in numerous application ***,the issue of classifying data streams based on mobile sensors can be formalized as a multi-task multi-view learning problem with a specific task comprising multiple views with shared features collected from multiple *** incremental learning methods are often single-task single-view,which cannot learn shared representations between relevant tasks and *** adaptive multi-task multi-view incremental learning framework for data stream classification called MTMVIS is proposed to address the above challenges,utilizing the idea of multi-task multi-view ***,the attention mechanism is first used to align different sensor data of different *** addition,MTMVIS uses adaptive Fisher regularization from the perspective of multi-task multi-view learning to overcome catastrophic forgetting in incremental *** reveal that the proposed framework outperforms state-of-the-art methods based on the experiments on two different datasets with other baselines.

关键词： data stream classification mobile sensors multi-task multi-view learning incremental learning

Machine learning enabling prediction in mechanical performance of Ti6Al4V fabricated by large-scale laser powder bed fusion via a stacking model

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Frontiers of Mechanical Engineering 2024年第4期19卷 29-43页

作者： Changjun HAN Fubao yan Daolin yuan Kai LI Yongqiang yanG Jiong ZHANG Di WANG School of Mechanical and Automotive Engineering South China University of TechnologyGuangzhou 510641China Department of Mechanical Engineering College of EngineeringCity University of Hong KongHong Kong 999077China

Determining appropriate process parameters in large-scale laser powder bed fusion(LPBF)additive manufacturing pose formidable challenges that necessitate advanced approaches to minimize trial-and-error during *** work proposed a data-driven approach based on stacking ensemble learning to predict the mechanical properties of Ti6Al4V alloy fabricated by large-scale LPBF for the first *** method can adapt to the complexity of large-scale LPBF data distribution and exhibits a more generalized predictive capability compared to base ***,the stacking model utilized artificial neural network(ANN),gradient boosting regressor,kernel ridge regression,and elastic net as base models,with the Lasso model serving as the *** optimization and cross-validation were utilized for model optimization and training based on a limited data set,resulting in higher predictive accuracy compared to traditional artificial neural network *** statistical analysis of the ANN and stacking models indicates that the stacking model exhibits superior performance on the test set,with a coefficient of determination value of 0.944,mean absolute percentage error of 2.51%,and root mean squared error of 27.64,surpassing that of the ANN *** statistical metrics demonstrate superiority over those obtained from the ANN *** results confirm that by integrating the base models,the stacking model exhibits superior predictive stability compared to individual base models alone,thereby providing a reliable assessment approach for predicting the mechanical properties of metal parts fabricated by the LPBF process.

关键词： machine learning laser powder bed fusion ensemble learning stacking algorithm additive manufacturing

Effect of MgO-Cr_(2)O_(3) and Mg0-MgAl_(2)0_(4)-based refractories on refractory-steel interface reaction and cleanliness of pipeline steel

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Journal of Iron and Steel Research International 2024年第4期31卷 849-860页

作者： Guang-mei yang Cheng yuan Chang Liu Qiang Wang Guang-qiang Li Yong-shun Zou Ao huang The State Key Laboratory of Refractories and Metallurgy Wuhan University of Science and TechnologyWuhan 430081HubeiChina Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education Wuhan University of Science and TechnologyWuhan 430081HubeiChina

The interaction of MgO-MgAl_(2)O_(4)-based and MgO-Cr_(2)O_(3)-based refractories with X70 molten steel was studied by immersion experiments at 1560℃.The effects of immersion time(30 and 60 min)on the contents of total oxygen(TO),Al,Nb,Si,Mn,and Cr as well as the composition,number density,and size distribution of inclusions in the molten steel were *** influence of the penetration and erosion degree of the molten steel to the refractory on the steel-refractory interface layer was *** results show that,at 1560℃,the MgO-MgAl_(2)O_(4)-based refractory can better control the contents of TO and the composition of molten steel compared with the MgO-Cr_(2)O_(3)-based *** TO content is only 16×10^(-4) wt.%in the molten steel after reacted with the Mg0-MgAl_(2)O_(4)-based refractory at the end point of refining,4 accounting for 11.5%of that reacted with the MgO-Cr_(2)O_(3)-based refractory(139×10^(-4) wt.%).The number density of inclusions is only 14 mm^(-2),and the average size ofinclusions is only 1.31μm,with thelargest proportion of inclusions in 1-2μm(70%).The Al_(2)O_(3)-MnS-CaO complex inclusions in the original steel changed to complex inclusions dominated by Cr-Nb-Mn-S-O and ***_(2)O_(3),corresponding to the MgO-Cr_(2)O_(3)-based and MgO-MgAl_(2)O_(4)-based refractories,*** ***_(2)O_(3) layer was formed at the reaction interface between MgO-MgAl_(2)O_(4)-based refractory and molten steel,which is helpful to restrict the erosion of refractories and the pollution of molten *** damage mechanism of the MgO-Cr_(2)O_(3)-based refractory is mainly permeation and chemical reaction,while the damage of the MgO-MgAl_(2)O_(4)-based refractory is mainlyscouring erosion.

关键词： MgO-Cr_(2)O_(3)-based refractory MgO-MgAl O_(4)-based refractory Nonmetallic inclusion Erosion interface layer Steel penetration

Wearable pressure sensors based on antibacterial and porous chitosan hydrogels for full-range human motion detection

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Science China(Technological Sciences) 2024年第8期67卷 2475-2484页

作者： ZHANG YingXin LIU HanGuang JIN ShunYu LI YaJuan ZHANG Wan ZHOU Hang NIE ZanXiang huang yuan School of Microelectronics Science and Technology Sun Yat-sen UniversityGuangzhou 510275China Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of ChinaHefei 230022China Department of Clinical Laboratory the First Affiliated Hospital of Anhui Medical UniversityHefei 230022China School of Electronic and Computer Engineering Peking University Shenzhen Graduate SchoolShenzhen 518055China Zinergy Shenzhen Ltd. Shenzhen 518109China

Wearable pressure sensors made from conductive hydrogels hold significant potential in health ***,limited pressure range(Pa to hundreds of kPa)and inadequate antibacterial properties restrict their practical applications in diagnostic and health ***,a wearable high-performance pressure sensor was assembled using a facilely prepared porous chitosan-based hydrogel,which was constructed from commercial phenolphthalein particles as a sacrificial *** relationship between the porosity of hydrogels and sensing performance of sensors was systematically ***,the wearable pressure sensor,featuring an optimized porosity of hydrogels,exhibits an ultrawide sensing capacity from 4.83 Pa to 250 k Pa(range-to-limit ratio of 51,760)and high sensitivity throughout high pressure ranges(0.7 kPa~(-1),120–250 kPa).The presence of chitosan endows these hydrogels with outstanding antibacterial performance against *** and ***,making them ideal candidates for use in wearable *** features allow for a practical approach to monitor full-range human motion using a single device with a simple structure.

关键词： porous hydrogels antibacterial performances wearable pressure sensors full-range human motion chitosan

Toward understanding the cross-linking from molecular chains to aggregates by engineering terminals of supramolecular hyperbranched polysiloxane

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Aggregate

Aggregate 2024年第1期5卷 228-235页

作者： yuanbo Zhang Junshan yuan Jingzhi Hu Zhixuan Tian Weixu Feng Hongxia yan Shaanxi Key Laboratory of Macromolecular Science and Technology Xi’an Key Laboratory of Hybrid Lumines-cent Materials and Photonic DeviceSchool of Chemistry and Chemical engineeringNorthwestern Polytechnical UniversityXi’anChina

Crosslinking thermosets with hyperbranched polymers confers them superior comprehensive ***,it still remains a further understanding of polymer crosslinking from the molecular chains to the role of *** this study,three hyperbranched polysiloxane structures(HBPSi-R)are synthesized as model macromolecules,each featuring distinct terminal groups(R denotes amino,epoxy,and vinyl groups)while similar molecular backbone(Si-O-C).These structures were subsequently copolymerized with epoxy monomers to construct interpenetrating HBPSi-R/epoxy/anhydride co-polymer *** spatial molecular configuration and flexible Si-O-C branches of HBPSi-R endow them with remarkable reinforcement and toughening ***,an optimum impact strength of 28.9 kJ mol^(−1) is achieved with a mere 3%loading of HBPSi-V,nearly three times that of the native epoxy(12.9 kJ mol^(−1)).By contrasting the terminal effects,the aggregation states and crosslinking modes were proposed,thus clarifying the supramolecular-dominant aggregation mechanism and covalent-dominant dispersion mechanism,which influences the resulting material *** work underscores the significance of aggregate science in comprehending polymer crosslinking and provides theoretical insights for tailoring material properties at a refined molecular level in the field of polymer science.

关键词： aggregates crosslinking hyperbranched polymers

Microstructures and mechanical properties of a commercial Mg-Al-Zn-Mn alloy with various hot-extrusion processes

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Rare Metals 2024年第3期43卷 1329-1336页

作者： He Ma Fan-Zhi Meng Qiang yang Ze-Feng Xie yuan-Ding huang Xin Qiu State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun130022China School of Materials Science and Engineering Changchun University of Science and TechnologyChangchun130022China MagIC-Magnesium Innovation Center Helmholtz-Zentrum Geesthacht21502GeesthachtGermany Engineering Research Center of Optoelectronic Functional Materials Ministry of EducationChangchun University of Science and TechnologyChangchun130022China

Mg-Al-Zn-Mn(AZ)system alloys have become widely used due to their good castability,excellent formability and outstanding corrosion resistance[1-6].However,their strength is still much lower than that of traditional Mg... 详细信息

关键词： alloys alloy corrosion

Novel wreck salvaging method using curved rectangular pipe basing method:A case study of"yangtze River EstuaryⅡ"ancient shipwreck salvage project

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Underground Space 2024年第5期18卷 97-113页

作者： Qianwei Zhuang Guofang Gong Dongrong Zhou Chi Zhang Xin huang Xiaodong Zhu Weihao yuan Deng Li School of Mechanical Engineering Zhejiang UniversityHangzhou 310030China Shanghai Tunnel Engineering Co.Ltd. Shanghai 200137China Department of Geotechnical Engineering College of Civil EngineeringTongji UniversityShanghai 200092China College of Civil Engineering and Architecture Xinjiang UniversityUrumqi 830047China Shanghai Salvage Company Shanghai 200090China

Shipwreck salvage is a risky,time-consuming,and expensive *** there are many sunken ships along coastlines and in the open seas,the salvage process of a sunken ship has rarely been *** integrated salvage of the"yangtze River EstuaryⅡ"shipwreck used a novel method with 22 closely locked curved rectangular pipes to form a watertight base that wrapped the shipwreck *** basing was lifted out of the water using a powerful crane situated on an engineering *** the first time,the tunneling method was used in a shipwreck salvage project,significantly reducing the disturbance to the shipwreck and its stowage,thereby preserving the original state and integrity of the shipwreck to the greatest *** this study,the basic concepts of the salvage method and process are *** to critical issues in the new salvage method are provided,including jacking force prediction and major considerations for the structural design of the salvage *** design of the salvage system and salvage process of the"yangtze River EstuaryⅡ"shipwreck are *** monitored jacking force,pipe deformation,and observed water-tightness verified that the proposed method was effective and *** possible application scenarios for the proposed method are presented at the end.

关键词： Pipe jacking Shipwreck salvage yangtze River EstuaryⅡ Structural design