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Conversion of Lignin into Porous Carbons for High-Performance Supercapacitors via Spray Drying and KOH Activation: Structure-Properties Relationship and Reaction Mechanism

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Journal of Renewable Materials 2024年第7期12卷 1207-1218页

作者： Shihao Feng qin Ouyang Jing huang Xilin Zhang Zhongjun Ma Kun Liang qing huang Zhejiang Key Laboratory of Data-Driven High-Safety Energy Materials and Applications Ningbo Key Laboratory of Special Energy Materials and ChemistryNingbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo315201China Engineering Laboratory of Advanced Energy Materials Qianwan Institute of CNITECHNingbo315336China School of Physics Henan Normal UniversityXinxiang453007China School of Environment Henan Normal UniversityXinxiang453007China

Lignin-derived porous carbons have emerged as promising electrode materials for ***,the challenge remains in designing and controlling their structure to achieve ideal electrochemical performance due to the complex molecular structure of lignin and its intricate chemical reactions during the activation *** this study,three porous carbons were synthesized from lignin by spray drying and chemical activation with vary-ing KOH *** speciﬁc surface area and structural order of the prepared porous carbon continued to increase with the increase of the KOH ***-mass spectrometry(TG-MS)was employed to track the molecular fragments generated during the pyrolysis of KOH-activated lignin,and the mechanism of the thermochemical conversion was *** the thermochemical conversion of lignin,KOH facili-tated the removal of H2 and CO,leading to the formation of not only more micropores and mesopores,but also more ordered carbon *** pore structure exhibited a greater impact than the carbon structure on the electrochemical performance of porous *** optimized porous carbon exhibited a capacitance of 256 F g-1 at a current density of 0.2 A g-1,making it an ideal electrode material for high-performance supercapacitors.

关键词： Lignin porous carbon KOH activation mechanism supercapacitor

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Tuning the solubility of polysulfides for constructing practical lithium-sulfur battery

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Journal of Energy Chemistry 2024年第8期95卷 611-617,I0013页

作者： Jiapeng Li Jianlong Cong Haijin Ji Ting Shi Lixia yuan Yunhui huang State Key Laboratory of Material Processing and Die&Mold Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074HubeiChina

Li-S batteries are regarded as one of the most promising candidates for next-generation battery systems with high energy density and low ***,the dissolution-precipitation reaction mechanism of the sulfur(S)cathode enhances the kinetics of the redox processes of the insulating sulfu r,which also arouses the notorious shuttle effect,leading to serious loss of S species and corrosion of Li *** get a balance between the shuttle restraining and the kinetic property,a combined strategy of electrolyte regulation and cathode modification is proposed via introducing 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoroprpyl ether(HFE)instead of 1,2-dimethoxyethane(DME),and SeS_(7)instead of S_*** introduction of HFE tunes the solvation structure of the LiTFSI and the dissolution of intermediate polysulfides with Se doping(LiPSSes),and optimize the interface stability of the Li anode *** minor Se substitution compensates the decrease in kinetic due to the decreased solubility of *** this way,the Li-SeS_(7)batteries deliver a reversible capacity of 1062 and 1037 mAh g^(-1)with 2.0 and 5.5 mg SeS_(7)cm^(-2)loading condition,***,an electrolyte-electrode loading model is established to explain the relationship between the optimal electrolyte and cathode *** makes more sense to guide the electrolyte design for practical Li-S batteries.

关键词： Li-S batteries Lithium polysulfides Solubility Shuttle effect Interface Se doping

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An Innovative K-Anonymity Privacy-Preserving Algorithm to Improve Data Availability in the Context of Big Data

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Computers, Materials & Continua 2024年第4期79卷 1561-1579页

作者： Linlin yuan Tiantian Zhang Yuling Chen Yuxiang Yang huang Li State Key Laboratory of Public Big Data College of Computer Science and TechnologyGuizhou UniversityGuiyang550025China College of Information Engineering Guizhou Open UniversityGuiyang550025China Guizhou Academy of Tobacco Science Guiyang550025China

The development of technologies such as big data and blockchain has brought convenience to life,but at the same time,privacy and security issues are becoming more and more *** K-anonymity algorithm is an effective and low computational complexity privacy-preserving algorithm that can safeguard users’privacy by anonymizing big ***,the algorithm currently suffers from the problem of focusing only on improving user privacy while ignoring data *** addition,ignoring the impact of quasi-identified attributes on sensitive attributes causes the usability of the processed data on statistical analysis to be *** on this,we propose a new K-anonymity algorithm to solve the privacy security problem in the context of big data,while guaranteeing improved data ***,we construct a new information loss function based on the information quantity *** that different quasi-identification attributes have different impacts on sensitive attributes,we set weights for each quasi-identification attribute when designing the information loss *** addition,to reduce information loss,we improve K-anonymity in two ***,we make the loss of information smaller than in the original table while guaranteeing privacy based on common artificial intelligence algorithms,i.e.,greedy algorithm and 2-means clustering *** addition,we improve the 2-means clustering algorithm by designing a mean-center method to select the initial center of ***,we design the K-anonymity algorithm of this scheme based on the constructed information loss function,the improved 2-means clustering algorithm,and the greedy algorithm,which reduces the information ***,we experimentally demonstrate the effectiveness of the algorithm in improving the effect of 2-means clustering and reducing information loss.

关键词： Blockchain big data K-anonymity 2-means clustering greedy algorithm mean-center method

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Controllable Construction of Vinyl Sulfones and β-Keto Selenosulfones via Selective Oxidative Sulfonylation of Alkenes

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Chinese Journal of Chemistry 2024年第12期42卷 1367-1372页

作者： Xiang Liu yuan Zhang Yi Zheng Changfeng huang Hua Cao School of Chemistry and Chemical Engineering Guangdong Pharmaceutical UniversityZhongshanGuangdong 528458China

Comprehensive Summary The selective oxidative sulfonylation of alkenes with selenium sulfonate depended on the reaction *** electrochemical C—H sulfonylation proceeded smoothly to afford(E)-vinyl sulfones with good selectivity in an undivided cell without external *** aerobic trifunctionalization of alkenes occurred in the presence of KI in the air,which providesβ-keto selenosulfones via the formation of C—O,C—S,and C—Se bonds in *** control experiments,a plausible mechanism is proposed to rationalize the experimental results.

关键词： Synthetic methods Alkenes Difunctionalization Selenylation Sulfonylation

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Price Mechanism,Government Constraints and Carbon Trading Pilot Policy for Emission Reduction

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Data Intelligence 2024年第3期6卷 621-648页

作者： Wei huang Haili Xue qin Zhang Haoguang Liang University of Chinese Academy of Sciences 100190China National Science Library Chinese Academy of Sciences100190China China Center for Modernization Research 100190China Beijing Key Laboratory of National Belt and Road Data Analysis and Decision Support 100024China

Based on the data of 247 cities at the prefecture level in China from 2007 to 2019,this paper analyzes the impact of the carbon emissions trading(CET)pilot policy on carbon emission reduction from the perspective of the price mechanism and government *** results show that the carbon emissions and carbon intensity in the pilot areas are significantly reduced by adjusting the industrial structure and promoting green technology *** terms of regions,the emission reduction effect of the pilot policy in regions with a high proportion of industry is obviously weaker than that in other *** aim of the carbon emission trading policy in China that achieve carbon emission reduction is by coordinating the carbon emission trading price that fail to fulfill this aim independently and the degree of government punishment for enterprises.

关键词： Carbon emission reduction Double difference Price incentive mechanism Government restraint mechanism

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Effect of Acupuncture on Endometrial Blood Flow in Women Undergoing in vitro Fertilization Embryo Transfer: A Single Blind, Randomized Controlled Trial

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Chinese Journal of Integrative Medicine 2024年第1期30卷 10-17页

作者： DONG Hao-xu Wu Xiao ZHOU qin huang Dong-mei ZHANG Ming-min huang Guang-ying YANG Wei Department of Integrated Traditional Chinese and Western Medicine Tongji HospitalHuazhong University of Science and TechnologyWuhan(430030)China Department of Obstetrics and Gynecoiogy Tongji HospitalHuazhong University of Science and TechnologyWuhan(430030)China Institute of Integrated Traditional Chinese and Western Medicine Tongji HospitalHuazhong University of Science and TechnologyWuhan(430030)China Department of Reproductive Medicine Tongji HospitalHuazhong University of Science and TechnologyWuhan(430030)China

Objective: To evaluate the effect of manual acupuncture on endometrial blood flow parameters by three-dimensional(3D) power Doppler ultrasound in women undergoing in vitro fertilization embryo transfer(IVF-ET). Methods: Seventy patients undergoing IVF-ET were equally randomized into traditional or sham acupuncture treatment group for totally 4 days(from the day of oocyte aspiration to the day of embryo transfer) of treatment by random envelope method at the Reproductive Medicine Center and Outpatient Department of Integrated Traditional Chinese and Western Medicine, Tongji Hospital, Tongji Medicine College, Huazhong University of Science and Technology from January 2013 to December 2015. Patients in the traditional acupuncture group accepted traditional acupuncture methods with manual acupuncture, and Zhongji(CV3), Qihai(CV 6), Sanyinjiao(SP6), Taichong(LR 3), Tianshu(ST 25), Guilai(ST 29) and Zusanli(ST 36) were chosen. Patients at the sham acupuncture group accepted shallow acupuncture methods at 4 non-meridian points at each shoulder and upper arm. Outcome measures included endometrial ultrasonic indices such as vascularization index(VI), flow index(FI) and vascularization flow index(VFI), endometrial thickness and volume, subendometrial VI(sVI), subendometrial FI(sFI), subendometrial VFI(sVFI), implantation rate, clinical pregnancy rate, abortion rate, live birth rate and number of live births. Results: Finally, 34 patients in the traditional acupuncture group and 35 in the sham acupuncture group completed this trial. VI, FI and VFI of the traditional acupuncture group were significantly higher than those in the sham acupuncture group(P0.05). Conclusions: Manual acupuncture performed after oocyte aspiration and before transplantation improved the endometr

关键词： acupuncture endometrial blood flow endometrial receptivity in vitro fertilization randomized controlled trial

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SeeMore: a spatiotemporal predictive model with bidirectional distillation and level-specific meta-adaptation

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Science China(Information Sciences) 2024年第8期67卷 147-171页

作者： Yuqing MA Wei LIU Yajun GAO Yang yuan Shihao BAI Haotong qin Xianglong LIU State Key Lab of Software Development Environment Beihang University

Predicting future frames using historical spatiotemporal data sequences is challenging and critical, and it is receiving a lot of attention these days from academic and industrial scholars. Most spatiotemporal predictive algorithms ignore the valuable backward reasoning ability and the disparate learning complexities among different layers and hence, cannot build good long-term dependencies and spatial correlations,resulting in suboptimal solutions. To address the aforementioned issues, we propose a two-stage coarse-to-fine spatiotemporal predictive model with bidirectional distillation and level-specific meta-adaptation(See More)in this paper, which includes a bidirectional distillation network(BDN) and a level-specific meta-adapter(LMA), to gain bidirectional multilevel reasoning. In the first stage, BDN concentrates on bidirectional dynamics modeling and coarsely constructs spatial correlations of different layers, while LMA is introduced in the second fine-tuning stage to refine the multilevel spatial correlations from a meta-learning *** particular, BDN mimics the forward and backward reasoning abilities of humans in a distillation manner,which aids in the development of long-term dependencies. The LMA views learning of different layers as disparate but related tasks and guides the transfer of learning experiences among these tasks through learning complexities. Thus, each layer could be closer to its solutions and could extract more informative spatial correlations. By capturing the enhanced short-term spatial correlations and long-term temporal dependencies,the proposed model could extract adequate knowledge from sequential historical observations and accurately predict future frames whose backtracking preconditions are consistent with the historical sequence. Our work is general and robust enough to be integrated into most spatiotemporal predictive models without requiring additional computation or memory cost during inference. Extensive experimen

关键词： spatiotemporal predictive learning knowledge transfer bidirectional distillation network level-specific meta-adapter coarse-to-fine training

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Measurement of the high energyγ-rays from heavy ion reactions usingČerenkov detector

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Nuclear Science and Techniques 2024年第2期35卷 123-130页

作者： Da-Wei Si Yan Zhou Sheng Xiao Zhi qin Dong Guo Yu-Hao qin Yi-Jie Wang Bo-yuan Zhang Bai-Ting Tian Zhi-Gang Xiao Department of Physics Tsinghua UniversityBeijing 100084China

The energetic bremsstrahlung photons up to 100 MeV produced in heavy ion collisions can be used as a sensitive probe for short-range correlation in atomic nuclei. The energy of the γ-rays can be measured by collecting the Čerenkov light in the medium induced by the fast electrons generated in the Compton scattering or electromagnetic shower of the incident γray. Two types of detectors based on pure water and lead glass as sensitive materials were designed for this purpose. The γresponse and optical photon propagation in the detectors were simulated based on electromagnetic and optical processes in Geant4. The inherent energy resolutions of 0.022(4) + 0.51(2)∕E^(1/2)_(γ) for water and 0.0026(3) + 0.446(3)∕E^(1/2)_(γ) for lead glass were obtained. The geometry sizes of the lead glass and water were optimized to 30 cm × 30 cm × 30 cm and 60 cm × 60 cm ×120 cm, respectively, to detect high-energy γ-rays at 160 MeV. The Hough transform method was applied to reconstruct the direction of the incident γ-rays, providing the ability to experimentally distinguish the high-energy γ-rays produced in the reactions on the target from random background cosmic-ray muons.

关键词： Bremsstrahlungγ-rays Čerenkov Geant4 Energy resolution Direction reconstruction Hough transform

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High critical current density in Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12) electrolyte via interfacial engineering with complex hydride

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Rare Metals 2024年第2期43卷 692-701页

作者： Ying-Tong Lv Teng-Fei Zhang Zhao-Tong Hu Guang-Lin Xia Ze-Ya huang Zhen-Hua Liu Li-Hua Que Cai-Ting yuan Fang-qin Guo Takayuki Ichikawa Xue-Bin Yu College of Materials Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing210016China Centre for Hydrogenergy College of Materials Science and TechnologyNanjing University of Aeronautics and AstronauticsNanjing210016China Department of Materials Science Fudan UniversityShanghai200433China Graduate School of Advanced Science and Engineering Hiroshima University1-4-1 KagamiyamaHigashi-Hiroshima739-8527Japan

Garnet-type solid-state batteries(SSBs)are considered to be one of the most promising candidates to realize next-generation lithium metal batteries with high energy density and ***,the dendrite-induced short-circuit and the poor interfacial contact impeded the practical ***,interface engineering to achieve low interfacial resistance without high temperature calcination was developed,which Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO)was simply coated with complex hydride(Li_(4)(BH_(4))_(3)I(3L1L))in various mass ratios n(Li_(4)(BH_(4))_(3)I)-(100−n)LLZTO(10≤n≤40).The interfacial conductivity increases by more than three orders of magnitude from 8.29×10^(−6)S·cm^(−1)to 1.10×10^(−2)S·cm^(−1).Symmetric Li cells exhibit a high critical current density(CCD)of 4.0 mA·cm^(−2) and an excellent cycling stability for 200 h at 4.0 mA·cm^(−2).SSBs with polymeric sulfur-polyacrylonitrile(SPAN)cathode achieve a high discharge capacity of 1149 mAh·g^(−1) with a capacity retention of 91%after 100 cycles(0.2 C).This attempt guides a simple yet efficient strategy for obtaining a stable Li/LLZTO interface,which would promote the development of solid-state batteries.

关键词： Hydrides Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO) Critical current density Solid-state electrolytes(SSEs) Lithium-sulfur batteries

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Full-parameter omnidirectional transformation optical devices

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National Science Review 2024年第3期11卷 92-99页

作者： yuan Gao Yu Luo Jingjing Zhang Zhengjie huang Bin Zheng Hongsheng Chen Dexin Ye Interdisciplinary Center for Quantum Information State Key Laboratory of Extreme Photonics and InstrumentationZJU-Hangzhou Global Scientific and Technological Innovation CenterZhejiang University School of Electrical and Electronic Engineering Nanyang Technological University CNRS-InternationalNTU-Thales Research Alliance Nanyang Technological University Institute of Electromagnetic Space Southeast University State Key Laboratory of Millimeter Waves Southeast University International Joint Innovation Center The Electromagnetics Academy at Zhejiang University Zhejiang University Key Laboratory of Advanced Micro/Nano Electronic Devices&Smart Systems of Zhejiang Jinhua Institute of Zhejiang UniversityZhejiang University Shaoxing Institute of Zhejiang University Zhejiang University

Transformation optics(TO) provides an unprecedented technique to control electromagnetic(EM) waves by engineering the constitutive parameters of the surrounding medium through a proper spatial transformation. In general, ideal transformation optical devices require simultaneous electric and magnetic responses along all three dimensions. To ease the practical implementation, previous studies usually made use of reduced parameters or other simplified approaches, which inevitably introduce extra reflection or unwanted phase shift. Up to today, experimental realizations of full-parameter transformation optical devices in free space are still quite limited. Here, a general design strategy is proposed to solve this *** a specific example, a full-parameter spatial-compression TO medium with constitutive parameters taking the diagonal form diag(a, a, 1/a) for the TM wave incidence was designed and realized experimentally. Such spatial-compression TO media were then applied to the implementation of an ideal omnidirectional invisibility cloak capable of concealing a large-scale object over a wide range of illumination angles. Both the simulation and experiment confirm that the cloak allows for nearly unity transmission of EM waves in the forward direction without introducing extra scattering or phase shift. This work constitutes an important stepping stone for future practical implementation of arbitrary full-parameter omnidirectional transformation optical devices.

关键词： transformation optical devices omnidirectional impedance matching full-parameter invisibility cloak

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