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Progress and prospects of chiral nanomaterials for biosensing platforms

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Rare Metals 2024年第6期43卷 2469-2497页

作者： Yu-Cheng Ouyang Bong-Jun Yeom yuan Zhao wei Ma School of Food Science and Technology State Key Laboratory of Food Science and ResourcesJiangnan UniversityWuxi 214122China Key Laboratory of Synthetic and Biological Colloids Ministry of EducationSchool of Chemical and Material EngineeringJiangnanUniversityWuxi214122China Department of Chemical Engineering Hanyang UniversitySeoul04763RepublicofKorea

Chiral nanomaterials have distinct chiroptical properties of preferential interactions to circularly polarized ***-based biosensors have emerged for detection of biomolecules,ions and cells in recent *** review provides an extensive overview of biosensors based on chiral nanomaterials,starting with approaches to chiral nanomaterials construction in terms of fabrication *** of chiral nanomaterials and their biosensor applications is presented for different material types,with special emphasis on the role and importance of material properties and signal generation in *** assessed the technological prospects of the emerging fields of chiral construction,circularly polarized luminescence,Raman optical activity and so on along with their current *** venues for future research on chiral nanomaterials in fabrication,biosensing,disease diagnosis and treatment are also presented in the review.

关键词： Chiral nanomaterials Circular dichroism Biosensors

Density-Functional Theories for Polyelectrolyte Systems

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Chinese Journal of Polymer Science 2024年第9期42卷 1302-1312,I0006页

作者： jia-wei Zhang Yu-Hang Zhang Bao-Hui Li Qiang Wang School of Physics Nankai UniversityTianjin90001China Department of Chemical and Biological Engineering Colorado State University1370 Campus DeliveryFort CollinsCO80523-1370USA

Polymer density-functional theories(PDFTs)have distinct advantages in the study of polyelectrolyte(PE)systems over experiments and molecular *** we give an introductory review of some PDFTs recently developed for PE *** start with a general formalism of PDFTs and its relation to the widely used polymer self-consistent field theory(SCFT),then explain the various correlations that are neglected in SCFT but can be accounted for in PDFTs,including those due to the excluded-volume interaction and chain connectivity of uncharged polymers,the electrostatic correlations of small ions,and the chain correlations in *** also list some applications of PDFTs for PE systems,and finally give some perspectives on future *** hope that our review can attract more researchers to apply and further develop PDFTs as a promising class of theoretical and computational tools.

关键词： Polymer density-functional theories Polyelectrolytes Correlations

Impact of Carbon Chain Structures in the Backbone on the Flexibility of Modified Polyarylene Sulfide Resins: Molecular Dynamics Simulations and Mesoscopic Analysis

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Chinese Journal of Polymer Science 2024年第4期42卷 544-557页

作者： Chi Zhang Rong Liu Jing-yuan Liu Wen-wei jiang Key Laboratory of Fine Chemical Engineering and Functional Materials School of Chemical EngineeringSichuan UniversityChengdu610065China

In the domain of high-performance engineering polymers, the enhancement of mechanical flexibility in poly(phenylene sulfide) (PPS) resins has long posed a significant challenge. A novel molecular structure, designated as PP-He-IS, wherein imide rings and an aliphatic hexylene chain are covalently incorporated into the PPS backbone to enhance its flexibility, is introduced in this study. Molecular dynamics (MD) simulations are employed to systematically explore the effects of diversifying the backbone chain structures by substituting phenyl units with alkyl chains of varying lengths, referred to as PP-A-IS where “A” signifies the distinct intermediary alkyl chain configurations. Computational analyses reveal a discernable decrement in the glass transition temperature (Tg) and elastic modulus, counterbalanced by an increment in yield strength as the alkyl chain length is extended. Notably, the PP-He-IS variant is shown to exhibit superior yield strength while simultaneously maintaining reduced elastic modulus and Tg values, positioning it as an advantageous candidate for flexible PPS applications. Mesoscopic analyses further indicate that structures such as PP-He-IS, PP-Pe-IS, and PP-Bu-IS manifest remarkable flexibility, attributable to the presence of freely rotatable carbon-carbon single bonds. Experimental validation confirms that a melting temperature of 504 K which is lower than that of conventional PPS, and lower crystallinity are exhibited by PP-He-IS, thereby affording enhanced processability without compromising inherent thermal stability. Novel insights into the strategic modification of PPS for mechanical flexibility are thus furnished by this study, which also accentuates the pivotal role played by molecular dynamics simulations in spearheading high-throughput investigations in polymer material modifications.

关键词： Molecular dynamics simulations Polyarylene Sulfide Main-chain modifications Flexibility Aliphatic hexylene chain

A brief review of tribological properties for black phosphorus

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Friction 2024年第5期12卷 823-844页

作者： Fanfan LV wei WANG Jinjin LI yuan GAO Kuaishe WANG College of Metallurgical Engineering Xi’an University of Architecture and TechnologyXi’an710055China State Key Laboratory of Tribology in Advanced Equipment Tsinghua UniversityBeijing10084China

Black phosphorus (BP) is a new class of two-dimensional (2D) layered material, which shows the unanticipated characteristics in many aspects including electronics, transistors, sensors, energy storage, batteries, photocatalysis, and other applications due to its high charge carrier mobility, tunable direct bandgap, and unique in-plane anisotropic structure. In addition, BP has drawn tremendous attention in the field of tribology due to the low shear strength, the layered structure, and the weak connected force between the layers by van der Waals interaction. In recent years, many significant progresses have been made in experimental studies on BP materials as solid lubricants or lubrication additives. This work offers a review of researching regarding the tribological properties of BP. Moreover, the lubrication mechanisms of BP as the lubrication additive including the formation of the tribo-film, micro-bearing effect, and self-repair performance are also summarized. Finally, the current challenges and prospects of BP material as lubricant are proposed.

关键词： black phosphorus(BP) two-dimensional(2D)layered material lubrication additives tribological mechanisms

Numerical simulation of transient characteristics in a bulb turbine during the load rejection process

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Journal of Hydrodynamics 2024年第1期36卷 170-183页

作者： Yue Lu Yu-quan Zhang Zhong-wei He yuan Zheng College of Water Conservancy and Hydropower Engineering Hohai UniversityNanjing210098China College of Energy and Electrical Engineering Hohai UniversityNanjing210098China Huadong Engineering Corporation Ltd. Hangzhou311122China

To evaluate the safety of the bulb tubular turbine,the dynamic hydraulic characteristics of a hydropower station system during the load rejection process are studied through numerical simulations and a prototype *** the developed model,a dynamic grid technology(DGT)controls the closure of the guide vane and the blade,whilst the moment balance equation and the user-defined function(UDF)provide the runner’s rotation *** 3-D transient simulation method can well predict the rotation speed and mass flow curves in the state of load *** simulation outcomes of the system performance are basically consistent with the measurement data of the *** observed,the runner is subjected to the reversely increased torque and axial force,the system is in a braking phase,and the maximum speed peaks at 144.6%of the rated ***,the internal flow of the runner is greatly affected by the closure of the guide vane,and the draft tube forms an eccentric spiral vortex *** breaks downstream,aggravating the instability of the draft ***,the transient characteristics span for the first five seconds,demonstrating the importance of establishing an efficient governing *** obtained results are useful for designing the turbine’s flow channel with a double regulating function and comprehending the turbine’s transient characteristics.

关键词： Bulb tubular turbine load rejection numerical simulation dynamic grid prototype test

Engineering vascularized organotypic tissues via module assembly

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International Journal of Extreme Manufacturing 2024年第1期6卷 155-175页

作者： Zhenzhen Zhou Changru Liu Yuting Guo yuan Pang wei Sun Biomanufacturing Center Department of Mechanical EngineeringTsinghua UniversityHaidian DistrictBeijing 100084People’s Republic of China Biomanufacturing and Rapid Forming Technology Key Laboratory of Beijing Beijing 100084People’s Republic of China Key Laboratory for Advanced Materials Processing Technology Ministry of EducationBeijing 100084People’s Republic of China Department of Mechanical Engineering Drexel UniversityPhiladelphiaPA 19104United States of America

Adequate vascularization is a critical determinant for the successful construction and clinical implementation of complex organotypic tissue models. Currently, low cell and vessel density and insufficient vascular maturation make vascularized organotypic tissue construction difficult,greatly limiting its use in tissue engineering and regenerative medicine. To address these limitations, recent studies have adopted pre-vascularized microtissue assembly for the rapid generation of functional tissue analogs with dense vascular networks and high cell density. In this article, we summarize the development of module assembly-based vascularized organotypic tissue construction and its application in tissue repair and regeneration, organ-scale tissue biomanufacturing, as well as advanced tissue modeling.

关键词： vascularized organotypic tissue module assembly regenerative medicine tissue engineering

Self-assembly Induced by Complexation of Diblock Copolyelectrolytes and Oppositely Charged Homopolymers

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Chinese Journal of Polymer Science 2024年第9期42卷 1321-1332,I0006页

作者： Ling Zhao Zhi-yuan Yin jia-Di jiang Er-Qiang Chen Shuang Yang Beijing National Laboratory for Molecular Sciences Key Laboratory of Polymer Chemistry and Physics of Ministry of EducationCenter for Soft Mater Science and EngineeringCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing100871China Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular EngineeringPeking UniversityBeijing100871China

We investigate the solution self-assembly of a mixture of positively charged homopolymers and AB diblock copolymers,in which the A blocks are negatively charged,and the B blocks are *** electrostatic complexation between oppositely charged polymers drives the formation of many ordered *** microstructures and phase diagrams are calculated using self-consistent field theory(SCFT)based on an ion-pair model with an equilibrium constant K to characterize the strength of binding between positively and negatively charged *** effects of the charge ratio,representing the ratio of charges from the homopolymer over all charges from polymers in the system,on the ordered structure are systematically studied,both for hydrophobic and hydrophilic A *** charge ratio plays an important role in determining the phase boundaries in the phase diagram of salt concentration versus polymer *** also provide information about the varying tendency of the domain spacing and core size of the spherical phase when the charge ratio is changed,and the results are in good agreement with *** studies provide a deep understanding of the self-assembled microstructures of oppositely charged diblock copolymer-homopolymer systems.

关键词： Self-assembly Polyelectrolyte complexation Self-consistent field theory Ion-pair

Experimental crushing behavior and energy absorption of angular gradient honeycomb structures under quasi-static and dynamic compression

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Defence Technology（防务技术） 2024年第6期36卷 47-63页

作者： jiachen Li Yuchen wei Hao Wu Xingyu Shen Mengqi yuan State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing 100081China Institute of Occupational Health China Academy of Safety Science and TechnologyBeijing 100012China Beijing Institute of Technology Chongqing Innovation Center Chongqing 401120China

The high variability of shock in terrorist attacks poses a threat to people's lives and properties,necessitating the development of more effective protective *** study focuses on the angle gradient and proposes four different configurations of concave hexagonal honeycomb *** structures'macroscopic deformation behavior,stress-strain relationship,and energy dissipation characteristics are evaluated through quasi-static compression and Hopkinson pressure bar impact *** study reveals that,under varying strain rates,the structures deform starting from the weak layer and exhibit significant interlayer ***,interlayer shear slip becomes more pronounced with increasing strain *** terms of quasi-static compression,symmetric gradient structures demonstrate superior energy absorption,particularly the symmetric negative gradient structure(SNG-SMS)with a specific energy absorption of 13.77 J/cm~*** dynamic impact,unidirectional gradient structures exhibit exceptional energy absorption,particularly the unidirectional positive gradient honeycomb structure(UPG-SML)with outstanding mechanical *** angle gradient design plays a crucial role in determining the structure's stability and deformation mode during *** interlayer separations result in a more pronounced negative Poisson's ratio effect and enhance the structure's energy absorption *** findings provide a foundation for the rational design and selection of seismic protection structures in different strain rate impact environments.

关键词： Negative Poisson's ratio Gradient honeycomb structure Quasi-static compression Dynamic impact Titanium alloy

Tuning the surface electronic structure of noble metal aerogels to promote the electrocatalytic oxygen reduction

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Journal of Energy Chemistry 2024年第2期89卷 557-564,I0013页

作者： Hongxing yuan wei Gao Xinhao Wan jianqi Ye Dan Wen State Key Laboratory of Solidification Processing School of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072ShaanxiChina

The sluggish kinetics of the oxygen reduction reaction(ORR)is the bottleneck for various electrochemical energy conversion *** the electronic structure of electrocatalysts by ligands has received particular attention in deriving valid ORR ***,the surface electronic structure of Ptbased noble metal aerogels(NMAs)was modulated by various organic ligands,among which the electron-withdrawing ligand of 4-methylphenylene effectively boosted the ORR *** calculations suggested the smaller energy barrier for the transformation of O^(*) to OH^(*) and downshift the d-band center of Pt due to the interaction between 4-methylphenylene and the surface metals,thus enhancing the ORR intrinsic *** Pt3Ni and Pt Pd aerogels with 4-methylphenylene decoration performed significant enhancement in ORR activity and durability in different ***,the 4-methylphenylene modified Pt Pd aerogel exhibited the higher halfwave potential of 0.952 V and the mass activity of 10.2 times of commercial Pt/*** work explained the effect of electronic structure on ORR electrocatalytic properties and would promote functionalized NMAs as efficient ORR electrocatalysts.

关键词： Noble metal aerogels Surface electronic structure ORR Electrocatalyst Organic ligands